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By T Tran, F Lucien

Supercritical fluids (SCFs) have gained recognition as solvents for the extraction of a wide range of organic materials. Their principle advantages over conventional organic solvents are that they possess much more favourable transport properties and that such properties can be easily altered by adjusting the system temperature and/or pressure. More recently, SCF solvents have been employed in the extraction of metal ions. The direct extraction of metal ions using SCFs such as CO2 is normally not possible due to the charge neutralisation requirement for solubilisation. However, extraction can be achieved with a SCF solvent containing an organic complexing agent as a cosolvent (Laintz et al, 1992; Laintz and Tachikawa, 1994; Dehghani, 1996). The role of the SCF is therefore similar to the role of a diluent in conventional liquid-liquid or solvent extraction processes. In this regard, SC-CO2 is a particularly good diluent since it exhibits good solubility for many organic complexing agents. The extraction of metals with SCF solvents has been examined mainly in the analysis of environmental samples and the treatment of metal contaminated wastes. Nonetheless, some interesting results have been reported recently on the extraction of rare earth metals, which highlight the potential of SCF solvents in mineral processing applications (Laintz and Tachikawa, 1994; Dehghani, 1996).

Jan 1, 2000

By Juan Munar Calderon

El presente texto revisa la función de la empresa de comercialización de productos mineros (MINPECO), su importancia en la economía nacional y los principales resultados alcanzados por la comercialización estatal. MINPECO es una empresa encargada de la comercialización interna y externa de productos mineros, cuyo funcionamiento está normado por su ley orgánica, disposiciones legales relativas a las empresas públicas, sus estatutos y los reglamentos internos de la empresa. El sistema actual de comercialización comprende modalidades de compra-venta, contrato de terceros, conversiones y las relaciones financieras. Asimismo se describe el ingreso de divisas y ventajas de la comercialización estatal.

Nov 20, 1978

By Narciso Tasayco Oré

El presente trabajo aborda el proceso de operación de espesadores "Dorr" y a los filtros " Oliver en cuanto al uso en la concentración de minerales por flotación. Para el espesado de los concentrados se requiere una adecuada descarga del espesador según lo indicado por el mecanismo de alarma. Asimismo, los filtros no trabajarán de modo contínuo, sino con un descanso promedio de dos horas, conforme a la ley del mineral en la alimentación.

Jun 20, 1954

By H. Huang, R. N. Gow

"EH-pH diagrams are useful tools in understanding how mineral surfaces react in solution and particularly how aqueous conditions can be changed to enhance mineral leaching processes. Successful application of these diagrams, however, requires that several considerations be kept in mind to prevent what had been termed as “gross errors” in their calculation and use. In this paper, the aqueous Cu-S system is used as the basis for explaining the mass-balanced method of calculating EH-pH diagrams with the STABCAL thermodynamic equilibrium software. A breakdown of the Gibbs’ Phase Rule and how it is used in STABCAL to modify the diagrams is included. The methodology was applied to the aqueous Cu-As-S system, and resulting diagrams were compared against examples of those generated using the predominant-ion method. The complexity of such diagrams increases with every additional component, and competition between species becomes more apparent, as can be seen by curvature in the resulting mass-balanced diagrams. The complete diagram for enargite (Cu3AsS4) is shown. It compares well with spectroelectrochemical measurements from Raman spectroscopy and cyclic voltammetry studies.IntroductionInnovation in the field of processing arsenicbearing copper ores has been of particular interest. Copper arsenic sulfosalt minerals such as enargite (Cu3AsS4) and tennanite (Cu12As4S13) are now frequently prevalent in ore bodies as the oxide and easily leachable sulfides become harder to find. These minerals, unless pretreated somehow, concentrate in copper sulfide flotation processes, in turn concentrating the arsenic levels. Increasing environmental restrictions on arsenic content for smelters makes the hydrometallurgical processing of these concentrates more favorable. While enargite is considered one of the more refractory copper sulfides, more so than chalcopyrite (CuFeS2), there are still several methods, both industrially proven and in development, that are capable of processing these ore types. Alkaline sulfide leaching can be used as a pretreatment method to solubilize arsenic selectively (Delfini et al., 2003; Anderson and Twidwell, 2008; Tongamp, Takasaki and Shibayama, 2010a, 2010b), or the entire metal content can be leached using acid-type leaches such as acidified ferric sulfate (Dutrizac, 1981; Hackl et al., 1995; Klauber, 2008), or the chloride assisted, CESL (McDonald and Muir, 2007) or nitrogen species catalyzed (Anderson, 2003) processes can be used.As development of these leaching technologies proceed, it is also important to develop an understanding of the mineral thermodynamics. To date, there are numerous studies on the Cu-Fe-S-H2O system, particularly as it relates to chalcopyrite leaching, yet few studies have done on the Cu-As-S-H2O system. Computer-generated EH-pH diagrams have been employed to illustrate the importance of thermodynamic calculations in providing insight into such a system."

Jan 1, 2016

Three years ago, when Sun Energy Development Co. (Sunedo) dedicated its Cordero mine in Wyoming, the company noted that its decision to venture into the coal industry was prompted by the need for domestic energy self-sufficiency. Now, as the energy situation assumes crisis proportions and the cry For coal intensifies, Sunedoo has begun a $21 million expansion program that will double the mine's productive capacity by the mid-1980s. When the Cordero come was originally conceived, Sunedoo obtained permission from permitting authorities to produce up to 11 million t/y (12 million stpy) of coal. But seeing opportunities in the coal market, Sunedoo returned to the agencies in 1976 and came away with permission to produce 22 million t/y (24 million stpy). Of that total permitted capacity, Cordero is expected to produce about 3.6 million tons (4 million st) this year.

Jan 9, 1979

By N. Bahrani

Photogrammetry surveys were used to document a footwall slab failure that occurred at a surface coal mine located on the eastern slope of the Rocky Mountains. Photographs taken before and after the failure provided the pre- and post-failure geometry of the slope and the failed slab. A 2D finite element model was constructed using slope profiles. The model contained joint elements that represented the bedding surface upon which the slab slid and the model was used to analyze the footwall slope. The in situ stresses, rock properties and the bedding surface shear strength and stiffness properties are discussed. The process of mining out a valley and exposing a highwall was modelled. As expected, elastic valley rebound occurred in the model, but shear stress and shear displacement reversals along the slip surface were also observed. The modelling results provided new insight into shear strength degradation that occurs when the pit floor approaches and then passes a specific point in the highwall.

Jan 1, 2009

By R. Bakish, M. A. Badiali, N. W. Kirshenbaum

One pound of ultra pul-e molybdenum has been produced containing both metallic and nonmetallic impuvities close to or less than the limits of detection. various purification methods were investigated; althouglz the use of move than one purification step was consideved, it was found that a single, caefully-controlled sublimation of MoCl5 yielded a highly puvified product without prior treatment or recourse to repeated sublimation. Hydrogen reduction of MoC1, to metal was attempted at atmospheric pressure; however, reduced pressure was necessary to obtain substantial yields. The tubular deposits of metal were consolidated into bulk fovm by electron beam melting undev high vacuum yielding a very low gas content. Boblems involved in monitoring the puvity of these materials and analytical results obtained are also presented. THE pronounced effect of even trace amounts of impurities upon fundamental properties of materials is well known to metallurgists and solid-state physicists. Consequently, groups interested in basic studies of metals have in recent years immensely stimulated the preparation and production of numerous ultra-pure metals. Increased demand by scientists for these high purity materials has necessitated development of facilities to prepare them in significant quantities; the procedures reported here were devised to produce significant quantities of ultra-pure molybdenum. Previous work performed in the field of vapor phase purification and hydrogen reduction of several other refractory metal chlorides had demonstrated valuable techniques applicable to molybdenum.' Various purification and reduction steps were individually investigated. Those procedures which showed the most favorable results with respect both to attainment of high purity and to ease of operation were then incorporated in the process utilized to produce the metal.' STARTING MATERIALS It is well known that because of differences in volatility, chlorides may be separated by fractional distillation. It was presumed that distillation of molybdenum pentachloride offered a simple and straightforward method of purification due to its relatively low boiling point. Alternatively, sublimation of the solid chloride also appeared feasible since MoC15 has both a reasonably narrow temperature range in which it exists as a liquid (a property typical of refractory metal chlorides) and a low enthalpy of sublimation. Pertinent thermochemical data of MoC15 are given in Table I. It should be noted that this compound must be handled with care as it is extremely hygroscopic. Anhydrous MoC15 was obtained from the A Metal Climax Co. METHODS OF PURIFYING MOLYBDENUM PENTACHLORIDE Distillation. It was expected that distillation methods, while affording an efficient purification, would prove simple to control and would have a higher production rate than sublimation processes. Also considered was the possibility of effecting a high degree of purification by using both these volatilization methods in conjunction—possibly a distillation followed by sublimation of the solidified condensate. Distillation of MoC15 was investigated using a single stage distillation column packed with chemically resistant glass beads. Heating coils were wound around the column and collection tube (condenser). As-received MoCl5 was charged into a flask connected with the column using a side loading arm under an argon flow. After the column and condenser were brought to about 270" and 210°C, respectively, the apparatus was lowered until the flask was fully immersed in a constant temperature fused salt bath maintained at about 285 °C. Distillation was continued for about 10 or 15 min until 50 to 70 g of distillate had been collected. Analyses of these distillations indicated that several elements, e.g., Cu, Fe, Ni, Cr, and Mg, were lowered in quantity although not all were removed to the same extent. The occurrence of Na, B, Si, and A1 in the distillates appeared to be due to contamination, possibly from corrosion of the pyrex glass. An improved distillation system of larger capacity and longer distilling column was built. Improvements were effected in lowering the amounts of such impurities as B, Mn, Ni, Na, Mg, Cr, Cu, and Fe. These studies were pursued concomitantly with efforts to purify by sublimation; it was subsequently found that although improvements in purity were obtained by distillation, sublimation processes were simpler to control and effected a high degree of purity.

Jan 1, 1963

By J. A. Organiscak

This paper examines methods for limiting occupational silica exposures for roof-bolting personnel in underground coal mining. A canopy air curtain and an air tube were evaluated as means to provide filtered air over the breathing zone of these personnel. Laboratory testing showed that dust reductions beneath the air curtain and air tube approached 60% and 40%, respectively, with low interference air velocities. The data also showed that dust reductions were highest for positions closest to the device and that these levels decreased with distance. This paper also evaluates a metal rake, a flexible insert and a rigid insert for cleaning the roof-bolter dust collector box. Less dust was produced when using the rigid insert. Surprisingly, the flexible insert was sometimes no better than scraping or raking the dust onto the mine floor. However, little dust got on the workers coveralls when using either of the inserts.

Jan 1, 2003

By A. N. Zagorodnyaya

The results of research on recovery of ammonium perrhenate from by-products of lead production are presented in the article. For the first time in the world, rhenium marketable products were produced on lead plant of Kazakhstan. Distribution of rhenium in lead production has been studied. During oxidative agglomeration of lead charge, 67.43% rhenium is sublimated and at that, 67.27% rhenium is trapped by the dusts of a system of gas purification, out of them 6.21% is transferred into different solutions, 1.89% into slime and only 0.09% into exhaust. During agglomerate smelting, up to 72% of its rhenium is sublimated and condensed in the dusts also. At leaching stage of sulphate product under dusts processing by the method of sulphatization, 15% of its content in the dusts is transferred into solution. The sorption method on the ionite ?N-21 has been proposed for recovery of rhenium from the solutions of sulphatization. At the same time, rhenium recovery from the dusts into commodity was 13%. The method of direct hydrometallurgy - leaching the dusts by solutions of sulphuric acid under presence of manganous concentrates, has been proposed as alternative method of recovery. This method has allowed increasing recovery of rhenium and other metals from the dusts into solution up to 90%~95%. Rhenium solvent extraction by ??? has been proposed for recovery of rhenium from the leaching solutions. At that, extraction of rhenium into marketable product from the dusts is above 75%.

Jan 1, 2014

By M. Patel, A. W. Piper, R. A. Forsdick

"Lead bullion is refined in kettles to remove the contained impurities such as copper, antimony, silver and bismuth. These impurities are removed sequentially by the addition of one, or more, reagents to the bath. Impurity elements react selectively with the reagents to form a dross layer on the surface that is subsequently removed for further processing. Mixing the lead bath using specific impeller designs, which form a vortex to ensure that good contact takes place, carries out the reactions. It is important that the mixing is controlled to achieve the optimum bath conditions and hence good dross grades.This paper presents initial modelling work on the kettle refining process using both physical modelling (Water Models) and mathematical modelling (Computational Fluid Dynamics - CFD). Comparisons between measured plant data and simulation results are given.IntroductionThe refining of lead bullion takes place in hemispherical kettles of varying sizes. It is normal practice to remove the impurity elements sequentially, by the addition of reagents, which selectively react with the impurity element. The impurity element forms a dross layer on the surface, which can be removed for subsequent processing at the end of the reaction period.All the refining stages in the production of lead and lead alloys involve mixing the lead bath, although different conditions are required for each stage. At Britannia Refined Metals mixing is achieved using either 3 or 4 angled or flat blade impellers, which generate a vortex in the central region of the kettle. However, throughout the industry a wide range of mixer types are used which are all trying to achieve the same result."

Jan 1, 1999

By R. Weyhe, B. Friedrich, H. Heegn

"Nickel-metal hydride batteries (Ni-MH) are storers of electrochemical energy, which have a higher specific storage capacity than lead or nickel-cadmium batteries. The demand for Nickel-metal hydride batteries is increasing rapidly since their market launch in the early 1990's. In 1999 the output of cells exceeded 80,000 tons per year (1 billion cells per year). Today there is no suitable and sustainable recycling process to recover nickel, cobalt and rare-earth metals. The discarded batteries are used in the steel industry as alloy material because they contain nickel. Cobalt and rare-earth metals are lost; they are non-recycleable.In a German governmental funded research project, IME Aachen, ACCUREC Mühlheim and UVR-FIA Freiberg are cooperating in processing as well as in creating a feasibility study. The target of this project is the development of a new recycling process for metal recovery from Ni-MH-batteries. The proposed process consists of a combination of mechanical, pyrometallurgical and hydrometallurgical processing steps.After shredding the steel shell, the various fractions of battery materials are carefully separated by mechanical processing. A hammer mill with one rotor with a perforated discharge grid of 20 mm opening, was found to be suitable for crushing the batteries to release the active mass of electrodes for metallurgical processing. The ground material is wet screened at a mesh size of 0.5 mm; thus a fine fraction is obtained with valuable components such as Ni, Co, and RE and an oversized fraction consisting of a mix of iron chips, electrodes grids, plastic chips, paper, and flocculent material of separators. The organic components are avoidable when there is a thermal step at the beginning of processing batteries.The separated fine fraction is smelted in an electric arc furnace. Any pyrometallurgical process relies on a suitable slag system. In this specific case, the process has to allow separation of nickel and cobalt as metal from the rare-earths almost quantitatively, collecting the rare-earths as well as impurities e.g. as oxides. The products are a nickel-cobalt alloy and a slag phase enriched with rare-earth oxides for further treatment to ‘mischmetal’."

Jan 1, 2003

By T. W. Sullivan

"This paper explores the history of AC static variable frequency control drive systems on open cast mining machinery, in particular electric mining shovels and electric walking draglines, over the past ten years. It critiques the peformance of these drive systems from a productivity and operating cost standpoint and evaluates the over-all success of the original design concepts as they were envisaged in the 1970s. The paper details the state-of-the-art as it exists today as well as design improvements contemplated for the immediate future.IntroductionConsidering the fact that the very first successful application of an alternating current electrical distribution system occurred at the Gold King gold mine near Ames, Colorado, U.S.A., in the year 1891, it seems somewhat ironic that almost 100 years later, AC excavator drive systems are just now becoming commonplace in the mining industry.If one were to read the biography of Lucien L. Nunn, the first person to successfully install a commercially viable alternating current power distribution system, one would quickly visualize a parallelism between his fight to achieve acceptance of his new lower cost technology and that of those commissioned with the belief that AC static variable frequency control drive systems are not only a better performing, lower cost drive system for mining excavators today, but moreover, the drive systems of the future in our industry.This paper will deal with the evolution and incorporation of AC static drive systems on open cast mining excavators. It will trace the history of the development of these drive systems in the mining industry, the current state-of-the-art concerning these systems, and what the future holds for these excavators in our industry."

Jan 1, 1990

By A. G. Naguib

In essence, any magnetic separator operates on the basis of imparting a preferential magnetic force on particles of higher magnetic susceptibility which are to be separated from particles of lower magnetic susceptibility. A certain amount of directional deviation to the particles takes place thus allowing for collecting each category of particles separately. The forces in action on particles in a wet magnetic separator of the established designs can be analyzed in a simple manner as shown in Figure 1.

Jan 1, 1972

By J. W. Leonard

Comments The venerable straight-line equation Y = Bx + A is again being rediscovered, but this time by economists, mining engineers and geologists. Two economists, William Sharpe and Harry Markowitz, from the University of Chicago and Stanford University, respectively, won the 1990 Noble Prize in economics by showing that the price of individual stocks can be related to the Dow Jones industrial average (DJIA) using the straight-line equation. According to Bill Chidester, Investment Analyst, Scientific Investment, Sharpe and Markowitz strongly emphasized the role of the beta (B) value while considering the alpha (A) value to be "pretty unimportant." Chidester claims that alpha is the "mystery" value that causes individual stocks to behave independently of popular stock-market indices, such as the DJIA. For many years, mining engineers and geologists have routinely called alpha the "nugget" or surprise element in geostatistical analyses in which a designated distance (x-axis) is related to the variance of the grade (y-axis). Because the influence of the independent variable (distance) over the dependent variable (grade variance) is ideal when alpha is equal to zero, any increase in alpha represents a loosening of influence or control within the relationship. This can be good news or bad news - good news if you are an economist sorting out off-trend stocks and bad news if you are a mining engineer trying to predict sulfur in a coal seam. With many mining trends, such as those involving the relationship of distance to the variance of grade, a mathematical relationship can be formed. In geostatistical analysis, the point where a mathematical trend ends is known as the sill. If the difference between the variance of grade at the sill and at alpha can be determined, then an estimate of the relative control for a given distance can be obtained by comparing the sill value to alpha. The extent to which alpha approaches the value of the sill provides an indication of independence or loss of trend. The alpha concept may find application with distance, time or fluid problems. The point of change can be either a change in trend or the trend limit. However, even without a clearly defined point of change or trend limit, increasing alpha values always infer loss of trend. Alpha analysis should be regarded as a valuable tool when sorting out many sets of mining data. The application of this user-friendly concept to reserves, material transport, fluid flow and other areas has been, and will continue to be, the basis of many important past and future developments in mining and geology.

Jan 1, 1996

By Suresh Menon

The explosive industry in India has passed through various stages - from a period of total dependency to a period of self sufficiency and now, is saddled with large spare capacity. The last decade and a half saw the emergence of small scale manufacturers, which until then was thriving on International technology.

Jan 1, 1998

By Patrick J. Coughlin

Shortly after Asarco Inc. purchased the Ray Mines Division from Kennecott in 1986, the company began an expansion program to increase copper production. The Bechtel Corp. oversaw engineering procurement and construction management for a new in-pit crusher, overland conveyor system and concentrator facility. Construction started in May 1990 on these facets of the expansion project. The concentrator was commissioned in February 1992. The Ray concentrator uses a single-line, semiautogenous grinding circuit (SAG) with a design through¬put of 27 kt/d (30,000 stpd). In the early 1960s, Kennecott conducted pilot plant grind tests of Ray mine ores to determine their amenability to SAG and autogenous grinding methods. Those tests, though, were not followed up. During 1973 and 1982, Kennecott conducted additional pilot testing on some of the softer ore types. In 1989, Asarco ran a final series of SAG pilot grinding tests at Lakefield Research, which became the basis of the new Ray concentrator grinding circuit. Even though pilot test work demonstrated that some of the Ray ores gave satisfactory results during the autogenous grinding tests, the SAG option was selected for the primary comminution device. Due to the wide range of mineralogies encountered in the Ray ore body, selective mining and blending of these ores would be required to achieve the necessary production efficiencies and throughput rates using an autogenous grinding circuit.

Jan 1, 1994

By Corby G. Anderson

Laboratory testing, interpretation and application of metallurgical technologies can be tedious, time consuming and costly. This paper outlines the use of proven statistical design of experimentation software for rapid optimization of laboratory testing and operating plants with limited representative sample utilization. This results in less costly required testing, a more thorough understanding of results and the ability to simultaneously optimize several variables and outcomes at once. At the Center for Advanced Mineral and Metallurgical Processing, this testing methodology has been used successfully in many metallurgical development and plant optimization projects thereby confirming its real world utility and application. Accordingly, several applied examples in flotation and hydrometallurgy will be outlined in this paper. This will include flotation testing of a copper gold ore, flotation testing of a copper, cobalt and gold ore, optimization of an industrial hydrometallurgical jarosite circuit and optimization of industrial nitrogen species catalyzed pressure leaching of a copper enargite concentrate.

Jan 1, 2006

By A. W. Fletcher

Report of discussion at February, 1971, IMM general meeting (Chairman: M. J, Cahalan President) of a paper published in Transactions/Section C (Mineral Processing & Extractive Metallurgy), vol. 79, December, 1970, pp. C247-52, and contributed remarks. Contributions are included from: Cahalan M.J., giving figures related to leaching Cu from pyrite at Rio Tinto 1880-1910; Noakes F.D.L.; Embling P.M.K.; Bradshaw A.V.; Le Roux N.W.; Kelly D.P.; and Tuovinen O.H. Questions were raised regarding impurity removal, effects of light and ultraviolet light on the bacteria, the economics of solvent extraction and the possibilities for other organisms or other metals

Dec 1, 1971

By L. A. Melis, J. W. Rowson

"Cluff Mining has successfully operated a gold recovery plant at its Cluff Lake operation in northern Saskatchewan to recover gold f rom Phase 1 uranium leach tailings. The operating circuit consists of tailings repulping, grinding, cyanidation, carbon-inpulp, gold recov ery, and cyanide destruction by acidification, volatilization and re-neutralization. The process is described and operating data and metallurgical results from the operation are provided.INTRODUCTIONCluff Mining, a Saskatchewan partnership, is owned 20 per cent by Cameco and 80 per cent by Amok Ltd. /Ltée. (Amok), manager and operator of the partnership.The current operation includes the Phase II uranium mining and milling facilities, located at Cluff Lake, 700 km north of Saskatoon, capable of processing 300 000 tonnes o f ore to produce about 4 000 000 lb UPs (1500 tonnes of uranium) per year.The Phase I operation was initially established to process the very high grade ""0"" uranium orebody from 1980 to 1983. The leach tailings from the Phase I mill operation were found to contain elevated level s of gold . These high gold values were partially due to the gravity pre-concentration step included in the uranium recovery circuit, and to the naturally high levels of gold associated with the uranium mineralization in the""0"" orebody .During the Phase I operation some 6475 tonnes of leach tails were produced and stored in a total o f 2916 large concrete containers (vaults). This method of storage was, at the time, deemed to be the preferred method of temporary storage for the tailings.This temporary storage of high-grade gold tailings facilitated the reclamation and reprocessing of the leach tail s for gold recovery. The primary reason for reprocessing the Phase 1 leach tails was to provide for long-term permanent disposal of the material as an admixture with Phase II tailings in the Cluff Lake tailings disposal area. Although there was limited tonnage, the high gold content in the material made the in stallation of a gold recovery circuit economically justifiable."

Jan 1, 1989

By T. Güyagüler, A. Güngör

Labour protection, that is prevention of occupational disease and reduction in the frequency of accident, has always been a matter of major concern of mining industry. Management and the government should promote and maintain high safety standards through some measures to reduce accident frequency and occupational disease. This can be achieved by using the science and technology for improving the working conditions, educating workers and managers about accidents and prevention techniques. The detailed analysis of an accident requires knowledge of many factors such as location, time, type, cost of accident, victim, nature of the injury, personal and environmental factors etc. that can be obtained from the standard coded accident report form. There is a need to prepare safety data in a common format to produce a common safety reporting system and ‘Occupational Health and Safety Management Tool’ is being designed to manage this by using database and Internet technology. Precautions should be taken according to results from database queries by providing comprehensive and accurate national data. To have an accident is unfortunate, however, to have an accident and learn nothing from it is unforgivable. Keywords: Occupational health and safety, Accident report form, Accident database, Occupational diseases and accidents, Safety reporting system.

Jan 1, 2003