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By Allan Martin, R. A. Swalin

Diffusion rates of manganese, aluminum, titanium, and tungsten in nickel were measured at temperatures between 1100° and 1300°C. Activation energies, Q, and values of the frequency factor, Do, were calculated for each system. Values of Q were found to be within 15 pet of that for self-diffusion of nickel in agreement with present theories of diffusion. ONE of the most interesting problems in diffusion concerns factors governing the order of diffusion coefficients of various solutes in a common solvent metal at low solute concentrations. An early suggestion by Rhines and Mehl' was that diffusion coefficients might each approach that of the self-diffusion coefficient of the solvent itself. Later Thomas and Birchenall' pointed out correlations between the order of the diffusion coefficients and the freezing point depressions of the solvent by the various solutes. Other correlations have been sought. To settle this question it seems likely that much more data will be needed and, in particular, data collected at low solute concentrations. This type can be obtained by special analytical techniques as well as by use of radioactive tracers. The following study was made of diffusion of manganese, aluminum, titanium, and tungsten in a common solvent, nickel, at relatively low solute concentrations: 1—Production of alloys of nickel with manganese, aluminum, titanium. and tungsten at concentrations of the order of 1 atomic pet. 2—Use of pressure-welded diffusion couples in cylindrical form. 3—Diffusion anneals in the temperature range of 1100" to 1300°C. 4—Lathe sectioning of the diffused couples. 5—Spectrophotometric analyses of lathe turnings for the solute being studied. 6—Calculation of the diffusion coefficient for each of the solutes as a function of temperature. 7—Interpretation of results with current theories of diffusion. Experimental Work Materials—Two types of nickel were used in this research. The grade designated as Vacuum melted Mond nickel was used for all diffusion systems except the Mn-Ni system for which the Vacuum melted electrolytic nickel was used. Analyses of the two grades are given in Table I. The manganese used in making alloys was 99.9 + pet pure, aluminum 99.99 pet pure, titanium 99.9 pet pure, and tungsten of C.P. grade powder. Alloys used in this investigation were prepared by melting in vacuo or under a low pressure of argon. After melting, all heats except those of nickel-manganese were poured into a cylindrical copper mold 3 in. long and 1 in. ID. In the case of nickel-manganese, the alloys were solidified in the melting crucible. For nickel-aluminum heats alumina crucibles were used and for all other heats, zirconia crucibles.

Jan 1, 1957

By Daniel Edelstein

Demand for arsenic trioxide dropped markedly during 1983, primarily as a result of a 27% reduction in cotton planting. As an oversupply of arsenic trioxide developed, prices declined for both domestic and imported material. Domestic Data Coverage.-Commercial-grade arsenic trioxide and arsenic metal were produced by only one U.S. company, which voluntarily reported its production to the Bureau of Mines. To prevent disclosure of proprietary data, the production data have been withheld.

Jan 1, 1984

The morning session opened at 9:00 a.m. and was presided over by Carlyle F. Gronning, Chairman, Industrial Commission, State of Utah, Salt Lake City, Utah. The first speaker was John A. Fagnant, Vice President-Sales, Kemmerer Coal Company, Frontier, Wyoming. Subject - "Open Pit Coal Mining, Western States." Mr. Fagnant is a graduate of Colorado School of Mines, 1937 Degree, Metalurgical Engineer His career in the mineral industry began at the Arthur Mill of Kennecott Copper Company. For nine years he was with Allis Chalmer Company in Milwaukee, Wisconsin as a Sales Engineer in the Mining Machinery Division. Following five years in private business, he joined The Kemmerer Coal Company as a special projects engineer specializing in coal carbonization. He was assigned the job of Sales Manager in 1968 and promoted to Vice President of Sales in 1970. Member of A.I.M.M.E.

Jan 1, 1975

By F. W. Brown, F. C. Gibson

"INTRODUCTION There is urgent need for a satisfactory permissible multiple-shot blasting unit capable of firing 10 detonators in series and safe for use in underground mining where a. gas-ignition hazard may exist.. As there is at present no entirely satisfactory permissible unit of either the battery or generator type, tile described capacitor-battery type has been developed. Consideration of the Bureau of Nines approval schedule pertaining to the generator and magne to-type units and of the electrical characteristics of the unit described in this report indicate that this unit should meet Bureau of Mines permissible requirements.This report gives a detailed description of the design and operation and results of tests to determine safety of operation in gassy atmospheres.DESIGN AND OPERATION OF UNITOperation of the vibrator-type multiple-shot blasting unit is based upon utilization of the discharge energy from a capacitor charged to a given. voltage and having capacitance adequate to store enough energy to initiate 10 detonators in series. The primary source of energy is a 4-volt cap lamp battery such as is carried for illumination on the person of underground workers in nearly all mines. As this battery is already available and is recharged daily it is considered to be a reliable and convenient source of energy for a blasting unit. Figure 1 is a schematic diagram of the circuit for an improved unit, and figures 2 and 3 are views of the experimental unit. The battery potential is applied through a radio-type synchronous vibrator (8) to an 8-volt center-tapped primary of a small transformer (9) having a high-voltage center-tapped secondary. The vibrator introduces an alternating low-voltage potential into the primary and mechanically produces full-wave, rectified, pulsating, direct current from the secondary. A buffing condenser (11) across the secondary gives the proper wave form for long vibrator life: a resistor (12) its in series with this condenser across the total secondary to protect the transformer in case of• failure .of this capacitor. A voltage divider (10) with an adjustable slider permits accurate adjustment of the potential applied to the high-capacity firing condenser (5)."

Oct 1, 1947

THIS article describes the origin and details of a hydraulically operated switch to control the operation of an automatic underground pumping system. This system was installed in December, 1939, on the 2,350-foot level at No. 5 shaft of the Buffalo Ankerite mine. The pumping unit consists of an 8-stage centrifugal pump direct-connected to a 150 h .p., 2,200 volt motor. Pumping capacity is 200 gallons per minute under a 1,315-foot head and with a flooded suction. The control consists of a 200 amp., 2,200 volt oil-immersed starter with thermal overload protection, thermal protection on the pump, and a flow switch that is bypassed for 30 seconds after the pump starts. The 30-second time lag is operated by a relay mounted on the panel. There is a swing check valve in the discharge line of the pump which originally operated the flow switch by means of a connected outside lever which closed the switch as the check valve opened.

Jan 1, 1945

As part of the response to the increased demand for products such as iron ore, coal and gold many resource companies have identified the need to develop strategies focused on attracting high demand professionals and retaining current employees in the business. Recent graduates are entering a time where they can expect high starting salaries, attractive benefits and lifestyle options. At the same time high work expectations and large demands on both personal and professional development will also be the norm. Some of the challenges faced may include high demands on performance, working with limited resources, long hours, and tackling unfamiliar areas of work with little guidance. However, managing your career and these challenges effectively can give you valuable experience in a short amount of time. By offering situations from my relatively short, yet active, career in the mining industry during these boom times I will raise some key points on how to best leverage your commodity and make the most of a bullish market.

Jan 1, 2006

By H. Landsberg

In a previous report1 it was pointed out that a successful attack on roof troubles has to be preceded by extensive scouting. As Lord Kelvin once said, scientific progress can be made only if accurate data are available: "unless you measure, you do not know." The Convergence Recorder For the observation of roof movements in mines the convergence recorder has shown that it will enable us to get some of the necessary information. Results with convergence recorders were first published by Winstanley and other English investigators for rapidly moving longwall faces. In their investigations the speed of work and the heavy overburden produced a considerable amount of absolute values of convergence in a short time. Under the conditions frequently encountered in our investigations in Central Pennsylvania, under shallow, overburden and in mines with slowly proceeding extraction, the movements observed were much less in absolute value, for an equal interval of time. This mas partly because the mines in which our studies were carried on frequently had idle days, sometimes four or five in succession. Therefore continuous records were not employed and a simple convergence gauge was built. In its first models, it consisted only of two telescoping tubes pressed against roof and floor by a coil spring. At the side of the lower tube a rule divided into 1/2-mm. divisions mas fixed and a knife-edge, which was attached to the upper tube, mas slid over the scale in case of convergence between roof and floor. While the larger motions could be read on this device, it seemed to be desirable to increase the accuracy by inserting between the two tubes a dial meter reading in 1/1000 in. Such a gauge was first built in April 1937 and installed for experimental purposes in a bituminous coal mine in Pennsylvania (Fig. I). It was read at least once daily, 24 hr. apart, and if feasible at shorter intervals. After several months of experience it can be said that this type of gauge answers the scientific as well as the practical needs. It is easier to handle than the recorder; no clock is used, there are no pen troubles. The price of

Jan 1, 1938

By A Gene Riggs

The Cerrejon Coal Project in Colombia, South America is one of the largest coal mines in the world. The mine is located in northeastern Colombia on the La Guajira penninsula. The area is in a remote valley 132 miles east of the city of Barranquilla.

Jan 1, 1984

By Michel Massé

Eleonore Project- Agenda ? Purpose and Technical Overview ? SmartEXEC Control Capabilities ? SmartEXEC System Archetecture ? SmartEXEC System Advantage Eleonore Project- Purpose and Technical Overview ? Control air quality while maintaining target production levels at minimum energy operating cost ? Improve safety, work place conditions and operation flexibility ? Reduce energy consumption and green house gases footprint

Aug 1, 2013

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Jan 1, 2008

By Frank G. Miller, Ralph A. Seban

Problems relating to thermal methods of oil recovery have been given increasing attention during the past year. The nature of the physical and chemical processes underlying thermal recovery are not yet well understood. The need for pertinent basic information is recognized generally. One of the processes involved is the transfer of heat by conduction in oil reservoir rocks containing moving reservoir fluids. This technical note deals with heat conduction in a laboratory sand column filled with a moving hydrocarbon and therefore should be contributory to the presently inadequate fund of knowledge on thc over-all subject. In an analysis of the flow of vaporiziny propane through a horizontal column of sand, one of the present author9 demonstrated correspondence between thc measured values of pressure along the length of the column and those predicted by a theory which postulated that the enthalpy of the propane was invariable along the length of the column. This postulate way implied as a deduction from the principle of conservation of energy but the details of the deduction were not given. The specific purpose of this technical note is the presentation of these details both as an adjunct to the earlier analysis and to supply some additional details on the processes involved in this type of flow. Results disclose that rates of heat transfer by conduction, in the direction of fluid motion, generally would be small for systems of the type studied. FUNDARIENrAI. ENERGY EiQUAI-[ON The principle of conservation of energy may be applied to a section of the porous material on the basis that heat transfer, like fluid flow, is possible in the x direction only. Transfer of heat in the y and z di'rections is prevented by suitable insulation or by taking the medium as infinite in directions perpendicular to the x axis. For steady state heat conduction and conditions of steady fluid flow the principle of conservation of energy specifies that any reduction in the enthalpy rate increases the flow of heat in the same proportion. Stated mathematically, dH KA 87 —- = - — - — U) * dx W dx........ Lvhere is the flow of heat in the positive x W dx direction. TEMPERATURE DISTRIBUTION IN DIRECTION OF FLOW The column of sand used in the previoi~sly described research is divisible into three different flow regimes. each of which may be analyzed independently. In the entrance region the liquid approaches the saturation state. A transition region is postulated following the transverse section at which the saturation state of the liquid is attained. In this transition region gas and liquid phases are both envisioned as present, with no vaporization occurring and with fluid movement restricted to the liquid. The upstream end of the exit region is at the transverse section of the column where the fraction of the pore space occupied by gas first becomes great enough for gas flow and where vaporization of the liquid begins. Fig. 1 indicates schematicaHy the thermodynamic processes undergone hv the fluid in the three flow regimes.

Jan 1, 1956

By George S. Rice

"Soon after the armistice, an investigation was conducted by the writer on the use of liquid oxygen for explosive purposes in Germany, so far as the conditions of such investigation wore permitted at the time. The results of this inquiry were published in Technical Paper 243, entitled ""Development of Liquid Oxygen Explosives during the War.""Recently, through the courtesy of Dr. C. L. Parsons, former chief chemist of the Bureau, who was visiting Germany, and Mr. Chester L. Benson, of the American Expeditionary Forces in Germany, data was obtained from the Deutsche Oxhydric A. G., Surth near Cologne, (one of the principal manufacturers of liquid oxygen installation) concerning the number of plants which bad been installed in Germany during the period following the armistice. An analysis of the figures obtained shows the following installations in different kinds of mining operations:"

Sep 1, 1920

Jan 1, 1920

By John Vynne

Too often, a mine’s operations, including drilling, blasting, loading, hauling, crushing, processing, etc., are considered independent steps, rather then a continuous process. In fact, these are interdependent operations with each step in the process having an impact on subsequent operations. If the effectiveness of the drilling and blasting operations can be improved, they will impact the entire mining process. Some of the resulting improvements include: level benches on grade; fragmentation and diggability with the result being reduced loading times; haul cycles improvements; and the crushing and milling operations will be more efficient and less energy consumed. Thunderbird refers to this as “Drill to Mill” information cycle or process. This paper focuses on two of the technological enhancements Thunderbird has added to its drill monitors that allow the mines to impact the “Drill to Mill” concept. These enhancements are: incorporating global positioning satellites into drill monitors; and radio off-loading of data.

Jan 1, 2001

By Braden T. Lusk, Shannon P. Lusk, Kyle A. Perry

A high explosives shock tube has been constructed and developed to test blast resistant windows with pressure versus time waveforms similar to waveforms generated by arena testing. Calibration of the high explosives shock tube, or Large Arena Test Simulator (LATS), included numerous tests performed by detonating varying charge weights at different distances from three piezoelectric pressure sensors located at one end of the shock tube (where the test subject would be installed). The maximum reflected pressure and positive phase impulse were calculated for each waveform generated in the tests. Pressure versus distance and impulse versus distance graphs were generated. Results have been graphed in order to predict charge weights and distances that correlate to the desired pressure and impulse at the end of the tube for future tests. This is a valuable tool when testing expensive, job specific components so the loading requirements are met on the first attempt.

Jan 1, 2010

By J L. Merritt

Effective minesite water management requires that this issue be treated as a risk management exercise. The management process is generally far from simple and by necessity must involve a range of personnel covering a siteÆs commercial, operational and environmental interests and responsibilities. The challenge to be collectively faced by these stakeholders is to strike the correct balance between risk and cost. On the other hand, the challenge to be faced by technical services support personnel is to provide stakeholders with information in a format that they can use with confidence. This paper presents the application of continuous operational simulation (OPSIM) modelling techniques to establish appropriate risk profiles for minesite operations. It is necessary that the format of these risk profiles be generic and equally applicable for defining the risk of occurrence for a relatively comprehensive range of activities û eg from of a non-compliant discharge, to the risk of failure to meet production targets. What is more, the profiles need to be quantitatively based and capable of reflecting change in system response to varied operational or management strategies. The techniques presented in this paper are based around a key assumption that long-term records of the climate contain within them sets of sequences that are representative of what can be expected in the future û that is, the droughts, floods, cyclones, good years and bad, long or short, and everything in between. Therefore, if these historical records are run through an OPSIM model for a particular site, then the simulated operational characteristics can be taken as being representative of what can be expected in the future, in the long-term. This lends itself to statistical analysis and translation into the required risk based format. Water Solutions Pty Ltd have been working with Capricorn Coal Management to develop a relatively comprehensive OPSIM model of their operations at German Creek Mine, Central Queensland. Outcomes from the modelling have been used in recent times to provide mine management with risk-based guidelines for both securing and containing mine water inventories. One of the more interesting tasks has been to establish risk based inventory levels that, if reached, would trigger the immediate implementation of a contract for the desalination and re-use of mine water, at predefined rates. Also, lead-time warning of the occurrence of a possible trigger is of importance to operational and commercial planning. To service this requirement the OPSIM model is regularly used to produce lead-time estimates to defined levels of confidence. Case studies of these, and other, applications of the OPSIM model at German Creek Mine are presented in this paper and serve to demonstrate an effective methodology for practical risked based water management.

Jan 1, 2003

By Richard S. Dennis

Acid recovery employs ion exchange (I-X) resin as separation media for inorganic acids from dissolved metallic salts by physical adsorption and without the use of chemicals. This technology has been used for years on spent etching and plating liquors to recover acid for reuse in the bath and to reduce waste acid neutralization costs. It is also used for electrolyte treatment to facilitate valuable metal recovery via acidity reduction. TETRA's ccrxr'" I-X contactor has been used successfully for acid separation from its metallic salt counterpart in a simple, continuous operating mode using strong base anion resins. Efficient separation is enhanced by acid reconcentration to nearly its original strength or as high as 14-20%. Continuous treatment also recovers heat to the tankhouse or bath and improves metal quality due to consistent acid quality. Conventional fixed bed ion exchange (I-X) systems are impractical for acid recovery because of complex control design and large resin inventories needed to process very low liquid-to-resin treatment ratios associated with strong acid concentrations.

Jan 1, 1996

By K. H. Hiller

A rotational viscometer has been designed which perrnits the measurement of the rheological properties of drilling muds and other non-Newtonian fluids under conditions equivalent to those in a deep borehole (350F, 10,000 psi). The important mechanical features of this instrument are described, and its design criteria are discussed. The flow equations for the novel configuration of the viscometer are derived and the calibration procedures are described. The data and their interpretation, resulting from measurement of the flow properties and static gel strengths of homoionic montmorillonite suspensiom at high temperatures and pressures, are presented. Data are also presented for the flow behavier of typical drilling fluids at high temperatures and pressures. The pressure losses in the drill pipe and the annulus depend critically upon the flow parameters of the drilling fluid. This work demonstrates the need to measure these parameters under bottom-hole conditions in order to obtain a reliable estimate of the pressure losses in the mud system. INTRODUCTION The rheological properties of drilling fluids are affected by temperature and pressure, but the extent of these effects on the dynamic flow properties is not well known. Measurements of changes of the flow properties of clay-water drilling muds with temperature have been reported by Srini-Vasan and Gatlin.1 The temperatures reported did not exceed 200F, a limitation imposed by the apparatus used by these authors. The rheological properties of clay suspensions were measured at temperatures up to 100C by Gurdzhinian.' Neither the nature of the exchange ions in the clay suspensions nor the degree of purity were defined in his work, nor were the measurements extended to currently used drilling fluids. The lack of systematic measurements of dynamic flow properties at high temperatures and pressures seems the more surprising since during the last decade the importance of the control of the hydraulic properties of drilling fluids has come to be widely recognized. Very good mathematical treatments of the friction losses in drill pipe and annulus have been developed.3 4 These treatments are based on the assumption that drilling fluids behave as Bingham plastic fluids. Quite often this assumption is justified, while in other cases a power law equation pro- duces better fit than the Bingham model does. For convenience in applying viscometer data to pressure-drop calculations, the Bingham plastic flow equation is preferable and, therefore, has been applied to the data reported in this paper, although other equations may fit these data more accurately. In a Bingham plastic fluid the relationship between the shearing stress 7 and the rate of shear D is given by the following equation: where is the plastic viscosity and 4 the yield point. If 4 = 0, the equation for simple Newtonian flow, 7 = pD, is obtained. Two empirical constants are required for the description of laminar flow of a Bingham plastic fluid, and calculations of the flow behavior at high temperatures and pressures cannot be better than is permitted by the accuracy with which these constants are known. For this reason a high-pressure, high-temperature rhe-ometer has been designed to measure the plastic viscosity the yield point +, and the static gel strength S, at pressures up to 10,000 psi and temperatures up to 350F. The important features of its design will be described. The results of measurements on homoionic clay slurries will be discussed insofar as they are relevant to an understanding of the general flow behavior of clay-water drilling fluids. The results of measurements on some typical drilling fluids will be presented also, and their practical implications will be briefly discussed. DESCRIPTION OF EQUIPMENT MECHANICAL FEATURES A viscometer designed to measure the plastic viscosity, yield point and gel strength of non-Newtonian fluids must permit the measurement of the shearing stress t at any given rate of shear D. This is possible only if t and D are approximately uniform throughout the entire sheared sample. A Couette apparatus is the most convenient method of realizing this condition, as has been pointed out by Grodde." The "high-pressure, high-temperature rheometer" described in this paper is basically a rotational Couette viscometer that is immersed in a cell in which pressure and temperature can be controlled over the range of interest. Fig. 1 shows schematically the important features of the pressure cell and associated equipment. The heart of the instrument is the rotating cup. It is shown more clearly in Fie. 2. which revresents the lower one-third of the pressure cell (below the input drive shaft shown in Fig. 1), and it is shown in detail in Fig. 3. For measurements of dynamic flow properties, the rotating cup is driven by a 1/2-hp electric motor, which operates through a Vickers

By M P. Simpson

Forty one whole rock samples from the Gold Cross low-sulfidation epithermal Au-Ag deposit have d18O values that range from 4.4 to 9.3 per mil, with an average value of 7.0 per mil. Unaltered and weakly altered rocks have d18O values greater than eight per mil, and the orebody is surrounded by samples that are depleted in 18O. A strongly silicified sample adjacent to the Empire Vein System has a d18O value of 9.0 per mil, similar to previously reported analyses of vein quartz (7.0 to 11.7ë, average 9.4ë). This suggests that, in detail, Golden Cross may have a zone of 18O-enriched wall rocks in the core of the deposit, adjacent to the main underground veins. Although some workers have suggested that stable isotope geochemistry may provide useful information for epithermal mineral deposit exploration, at Golden Cross this is not the case. Alteration minerals, major elements and trace elements all define larger, less ambiguous halos than the zone of 18O-depleted wall rocks.

Jan 1, 2001

By Chris Mark

Perhaps the most significant development in coal mine ground control during the last century was the introduction of roof bolting during the late 1940's and 1950's. From an engineering standpoint, roof bolts are inherently more effective than the wood timbers they replaced. Roof bolts promised to dramatically reduce the number of roof fall accidents, which then claimed hundreds of lives each year, and they were initially hailed as "one of the great social advances of our time." Roof bolting also emerged at a time of rapid technologic transformation of the coal industry, and greatly accelerated the transition to trackless, rubber-tired face haulage. The U.S. Bureau of Mines quickly became the new roof support's strongest advocate. Some state agencies and miners were skeptical at first, but nearly everyone was soon won over. Case histories were reported showing that roof falls could be largely eliminated while productivity increased dramatically. Little wonder that, in the words of one contemporary observer, "roof bolting has been adopted more rapidly than any other new technology in the history of coal mine mechanization." Yet by the end of the 1950's, it was clear that roof fall fatality incidence rates had actually increased. It would be another decade before the superior ground support provided by roof bolts would clearly save lives, The story of how roof bolting was implemented by the mining industry, but took so long to live up to its promise, is a fascinating example of the interaction between economics, technology, regulation, and science. It still has important lessons for today.

Jan 1, 2002