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By Djk Arentsen

A new technique to drive tubular piles by impact hammer inside the pile has confirmed a dramatic reduction of noise and the opportunity to save steel. Also a reduction in driving time and a higher bearing capacity has been observed during a test program of this technique. As part of the so-called "Down-the-hole" driving technique, a wave equation analysis has been developed to calculate driveability and pile stress. The main feature of the new "Down-the-hole" technique is the development of a patented device allowing uncoupled penetration of pile tip and pile shaft, which makes it possible to drive both closed or open end piles and reduce the stress level induced in the pile wall. During a test program, a number of instrumented piles were driven and compared with traditional driving of the same pile with the same hammer on top (also instrumented). Also the stresses and performances were compared with precalculations. This paper, explains the technique and presents the test and noise results, in comparison with traditional top-pile-driving. The "Down-the-hole" driving technique is an interesting alternative for special applications where traditional pile driving requires a large wall thickness or in areas where noise is a hot item.

Jan 1, 1996

o Resource production is essential for society. o Demand for resources will increase as population grows.o Resource industries are the main consumer of trained geologists.o The lead time from(1) training to productivity(2) research to resource production is measured in years.o An adequate supply of well trained geologists and successful geological research is an important agent in ensuring cost effective, adequate supply of mineral resources for society. Therefore the main beneficiary of geological education is society itself.o Society is paradoxically apathetic or antagonistic to the resource industry because (1) it represents change(2) lobby groups working for other causes have successfully moulded a bogey man image for the resource industry in the public eye.Professional training and research for resource industries consequently lack popular support. Funding is at an absurdly low level in comparison with the economic importance of resource supply.

Jan 1, 1990

By W. F. Netzeband

Jan 1, 1927

By X B. Sun

Mining work is a high-risk operatation under a special environment. It is affected by space, lighting, noise, vibration, dust, air pollution, etc as well as coal seam conditions, complicated geology construction, combustion of coal, gas, coal dust, etc. Factors which affects safety production are numerous, eg natural conditions, technical equipment level, producersÆ and managersÆ qualities. It is a complex system engineering to ensure mining safety and high efficiency. Among the ideology, methods and measures of safety management are the most important factors besides safety technology. Mine productive environment is a main problem that affects minerÆs work as far as safety and health are concerned. Combining ChinaÆs mine productive environment situation and using human ergonomics theory, this paper explores a series of measures and suggestions as to how to reinforce safety management, how to build up the safety management ideology, how to improve the mine production environment, how to decrease coal mine accidents, and how to ensure mining safety and high efficiency.

Jan 1, 2003

By Carl G. Bock

INTRODUCTION Rapid transit systems involving near surface tunneling in hard rock are becoming more numerous, especially along the northeast corridor of the East Coast. Tunneled systems are under construction in Washington, D.C. and are being planned for Atlanta, Buffalo and Baltimore. Near surface tunneling is defined for this paper as being that in which the crown is 100 feet or less below ground surface. For Rosslyn Station, the total cover ranged from 52 to 70 feet. The rock cover, however, ranged from 40 to 50 feet which is slightly less than the station height and about two-thirds of its width. Rosslyn Station (Fig. 1) is the only station excavated completely in hard rock in the Virginia portion of the 98.5 mile Washington Metropolitan Area Transit Authority's (WMATA) rapid transit system. The station site, oriented in a north-south direction beneath a main thoroughfare and flanked by multistory office buildings, was fixed by the need to serve a dense population center at a specific location and geologic conditions were a secondary consideration in siting. There was no previous underground rock excavation in the Washington Metropolitan Area of the size and scope of Rosslyn Station that offered a practical case history guide to the geologic conditions and excavation problems to be encountered. GEOLOGY The regional geology of the Washington Metropolitan Area is divided into two physiographic provinces by the northeast trending Fall Line (Fig. 2). Northwest of this boundary is the Piedmont Province

Jan 1, 1974

By S. Gaydardzhiev

Laboratory batch tests having preliminary and orientation character aiming at improvement of the molybdenum flotation at Ellatzite copper processing plant in Bulgaria have been conducted. The following technological parameters have been screened to study their influence on the grade and recovery of copper and molybdenum during the rougher flotation stage: flotation pulp density, pH, addition of secondary collector and replacement of MIBC by pine oil as a frother. The results have shown that slightly better grade/recovery figures could be obtained for both copper and molybdenum at lower flotation pulp densities. The addition of kerosene has improved the recovery of molybdenum however, on the expense of that of copper. The effects from pH variation and the replacement of MIBC by pine oil as a frother have been almost negligible.

Sep 1, 2012

By W. Irwin

Global warming hitherto viewed as a distant threat to the environment, is now the subject of fierce goo-political debate. The debate centres around the time frame required to achieve environmental compliance, and the cost implications of meeting that objective. Since coal is the fuel of choice for power generation, the priority objective of energy producers is the pursuit of environmental protection measures that allow coal to be burned without any attendant negative impact on the environment. From an environmental point of view, public attention is today firmly focused on the impact that all industrial activity has on the environment, and coal is singled out from other fossil fuels as being the product of an inefficient smokestack industry. Despite coal's poor public image it is unrealistic to suggest as some do, that use of this fossil fuel as a primary energy source should be drastically curtailed. Coal which already generates about 35% of the world's electricity is continuing to increase its share of this rapidly expanding market, and to argue against its use is flying in the face of reality. However, changes are required in the way coal is used in some of the new clean coal technologies, since many include advanced methods of combustion. Indeed changes in the way coal is used is a vital link to the future of coal as a primary source of energy, and increased coal utilization will be directly linked to changes in its use. Discussion of various issues that affect coal utilization are the focus of this paper.

Jan 1, 1998

By David Deglon, Martin Harris, Mehdi Safari

"This study investigates the effect of energy/power input on the flotation of a platinum ore in a pilot-scale oscillating grid flotation cell. Oscillating grids generate near ideal hydrodynamic environments, characterised by turbulence which is relatively homogeneous and isotropic. Secondary rougher feed and primary cleaner tail streams were floated in a pilot-scale oscillating grid flotation cell at power inputs from 0 to 2.5 W/kg, using 0.50 and 1.50 mm bubbles. From this study one may conclude that the effect of energy/power input on the flotation rate is strongly dependent on the particle and bubble size. Flotation rates generally increase with increasing particle size and decreasing bubble size. Increasing energy input generally leads to an increase in the flotation rate for finer particles and an optimum flotation rate for intermediate & coarse particles. Optimum conditions for intermediate/coarse platinum ore particles are using small bubbles at low energy inputs, or large bubbles at higher energy inputs. These results suggest that higher energy inputs are generally beneficial for the flotation of platinum ores as these consist predominantly of finer particles (-75 µm) and most industrial flotation applications operate with larger bubbles (1.0-2.0 mm).INTRODUCTIONThere is a considerable body of experimental and theoretical evidence to suggest that energy/power input plays an important role in flotation kinetics, particularly in the finer particle sizes where flotation efficiency is poor (Deglon, 2005). A number of excellent studies into the effect of energy on flotation kinetics have been carried out in impeller stirred cells (Ahmed and Jameson, 1985; Deglon, 2002; Pyke et al., 2003; Newell and Grano, 2006). Investigations using this type of cell have a number of limitations. The impeller influences particle suspension, bubble break-up and agitation in the cell. In addition, turbulence is highly inhomogeneous and anisotropic, with power intensities near the impeller orders of magnitude higher than those found elsewhere in the cell (Deglon, 1998; Koh and Schwarz, 2003; Schubert, 1999, 2008). These limitations have resulted in the development of novel cells for the investigation of energy input."

Jan 1, 2016

By P. J. Mackey, Elsie Kossatz

The small town of Bruce Mines lies a few miles east of Sault Ste. Marie, Ontario on the north shore of Lake Huron. This was the site of the first copper mine. This copper smelter used a reverberatory furnace, based on the Welsh process, and operated in the period of 1849 to 1850, when the plant was destroyed by fire. During the period of 1850 to about 1869, crushed and sorted ore was shipped to England and later to the United States. In 1869, a roastleach plant, based on the Henderson Process, was constructed at Bruce Mines and was operated until about 1872. This short article describes the early development of this historic operation. Although the rich copper ore found in the vicinity of Bruce Mines was known to the Indians, its discovery in or about 184 7 was credited to Mr. Keating, who named the area Bruce in honour of Lord Elgin (James Bruce), Canada's Governor General. In 1848, the property was acquired by the Montreal Mining Company for 40 000 pounds sterling and the company immediately sent a small party to investigate the deposit. The party sank a shaft on a lode within a hundred yards of the lake and also reported two adjacent lodes farther inland, which were left undeveloped until the turn of the century. Initially, the foundation of the headframe and hoist was built above the frost line and when the machinery was set in motion it collapsed. Eventually, the shaft was to reach a depth of 300 feet. By 1849, the property was well established and the small settlement consisted of 77 miners, 65 labourers, 4 boys, 11 tradesmen, including blacksmiths and carpenters, 2 mining captains, 1 engineer, 2 clerks and 1 superintendent. The community, including the workers' families, numbered about 250.

Jan 1, 1999

By Yukika Miyashita, Takahiro Inoue, Kenji Namikawa, Masashi Matsumoto, Junichi Koseki, Yoshihiro Terashima

"In order to construct an underground two-layer expressway branch junction structure with a height of 14.7 m and a width of 22.3 m, two shield tunnels in each layer were combined by using a non-cut-and-cover enlargement method in sedimentary soft rock. Before and during the construction work, preliminary analysis, in-situ investigations and laboratory tests were conducted to ensure the construction safety and to evaluate the deformation characteristics of sedimentary soft rock. The construction project was safely executed without any water leakage or collapse of tunnel working face. The predicted results from preliminary analysis were almost similar to the measured values. From the detailed investigation of measured results, it was confirmed that the deformation characteristic of the sedimentary soft rock was observed to a small extent as the ground deformation derived from construction work. INTRODUCTION In recent years, some newly constructed urban expressways in Japan are being planned as underground structures due to the consideration of roadside environment. The construction of such underground expressways is frequently conducted using a shield tunneling, a typical one of non-cut-and-cover methods, to prevent any adverse effect to traffic in arterial roads, operation of nearby commercial establishments, and daily lives of local residents during construction work. For underground urban expressway, the connections with existing road network on ground surface or on elevated sections are indispensable, which require the construction of an underground branch junction with large cross-section. This raises a technical difficulty regardless of the open-cut or non-open-cut construction method."

Jan 1, 2016

By Ted H. Eyde

Specialty sand and bentonite are produced in the plateau province from the Bidahochi Formation near Sanders, Apache County, Arizona. It appears that deposits of both sand and bentonite formed during the Pliocene in fluvial and lacustrine environments, respectively, along the west side of the Defiance Uplift. The bentonite is an alteration product of airborne vitric ash that fell or was washed into lakes. In the Cheto district, the individual bentonite horizons, which range from less than a foot to more than 10 feet thick, are restricted to the position of the medial volcanic member. Bentonite production began at the Allentown mine in 1924 and the Chambers mine in 1926. In 1933 strip mining of the extensive deposits in the Cheto district commenced. Production increased each year to a peak of 270,000 tons in 1957. As a result of the introduction of synthetic zeolites into petroleum refining, production declined. About 40,000 tons of bentonite are currently produced from the district each year. Bentonite is shipped out of State for processing into desiccants, thickeners, and acid-activated clay products. The specialty sand was derived from Permian sandstones and deposited by streams draining the Defiance Uplift. Although stream channels are usually restricted to the upper member of the Bidahochi, stratigraphically above the bentonite horizon, a few actually cut through the bentonite. The well-sorted sand, suitable for use as a proppant in hydraulically fractured oil and gas wells, is localized in elongate lenses along the margins of the channels. These lenses range from 5 to 50 feet in thickness and often extend thousands of feet in both width and length. The sand is about 97 percent silica, has a yield of 40 percent in the minus 20 plus 40 mesh size fraction, and has a roundness of 0.6 to 0.7 on the Krumbein scale. Production of this sand began about 1961. All of the current production, which amounts to about 40,000 tons per year, is sold in the petroleum-producing area near Farmington, New Mexico.

Jan 1, 1987

By Peter R. Morris

The effecl of preferred orienlation on X-vay dzffvaction measurements of retained austenzte was investigated for four precipitation-hardening staznless steels in sheet form. A method is preserzted for estimating the ervor in measurement associated with a given samplirig direction. The method was used to select an "optimum" sampling direclion in order to minimize errors in measurement due to preferred orientation. hleasuremenls of retained austenite content employing lhe proposed sampling direction are conzpaved to measuretnents enzploying the more commonly used normal direclion for a series of sawzples. THE first application of X-ray diffraction to the measurement of retained austenite in steels is due to Sekito, 1 who employed a photographic technique in which the (111) reflection from a thin strip of gold affixed to a cylindrical sample was employed as a standard. Averbach 2 introduced the "direct comparison" method in which the ratios of observed to calculated random intensity are assumed proportional to the austenite and/or martensite contents. Averbach's work forms the basis of most subsequent X-ray diffraction methods for the determination of retained austenite. Subsequent improvements are due to: Averbach and Cohen,3 who employed a sodium chloride crystal to monochromate cobalt radiation; Averbach et a1.,4 who introduced a bent sodium chloride monochromator; Mager,' who used a bent quartz crystal to monochromate chromium radiation ; Littmam, who first used a geiger counter diffractometer for this purpose; Beu and Beu and Koistinen, 11,12 who studied effects of absorption factor, surface preparation, sample geometry, integrated intensity vs peak height, choice of radiation, monochromator, and filter. The possibility of errors in measured values due to orientation effects was noted by Miller,13 who suggested examination of a surface other than the plane of rolling. Lopata and Kula 14 have developed an experimental technique in which the preferred orientation is measured in each sample. They illustrated the method for a sample containing 42 pct retained austenite. Application of their technique to the 1 to 15 pct range typical for the precipitation-hardening stainless steels does not appear feasible. EXPERIMENTAL PROCEDURE The nominal compositions of the precipitation-hardening stainless steels investigated are listed in Table I. Ingots were solution-treated, hot-rolled to approximately 0.2 in., and reduced to 0.050 in. by a suc- cession of cold rolling and annealing operations. After this treatment the 17-4PH sample was in the marten-sitic condition, while the 17-7PH, PH 14-8Mo, and PH 15-7Mo samples were in the austenitic condition. Samples of 17-7PH and PH 15-7Mo steels in the mar-tensitic condition were obtained by heating to 1750'F for 10 min and holding at -100°F for 8 hr. A sample of PH 14-8Mo steel in the martensitic condition was obtained by heating to 1700°F for 1 hr and holding at -100°F for 8 hr, followed by aging at 950" for 1 hr. POLE FIGURE DETERMINATIONS Samples were thinned to 0.003 to 0.005 in. by etching in a solution containing 250 ml reagent-grade phosphoric acid (85 to 87 pct H3PO4), 250 ml technical-grade hydrogen peroxide (30 to 35 pct H 2 O 2), and 50 to 100 ml reagent-grade hydrochloric acid (37 to 38 pct HCl). The specimens were placed in an "integrating" sample holder which provided a 1-in. oscillation in the plane of the sample. The diffractometer was aligned to measure the intensity diffracted by planes of the particular {hkl} type being studied. The sample was Set for a given latitude angle, a, measured from the plane of the sheet, and diffracted intensity recorded as the longitude angle, 0, measured in the plane of the sheet from the rolling direction, was increased from 0 to 360 deg. After a 360-deg scan of B, a was incremented by 5 deg, and the process repeated. Random standards obtained by spraying suspensions of powdered iron (bcc structure) and nickel (fcc structure) in lacquer were used to correct observed intensities for absorption and geometrical effects. Zirconium-filtered molybdenum radiation was used to determine the transmission regions of the (111) (0to 45 deg), (200) (0 to 60 deg), and (220) (0 to 45 deg) austenite and (110) (0 to 45 deg), (200) (0 to 50 deg), and (211) (0 to 35 deg) martensite pole figures. Vanadium-filtered chromium radiation was used to

Jan 1, 1968

By Alexander Levran

The main thrust of this presentation is to illustrate the growing contribution of solar energy to the mining industry by replacing existing mechanical and pneumatic tools and equipment with more effective and efficient electrical tools due to the increased efficiency and lower cost of solar energy generation. LCOE (levelized cost of energy/electricity) for solar energy is becoming highly competitive with other conventional sources of energy. The distributed architecture of solar power plants allows the supply of energy to highly remote and abandoned geographies. We will focus on the trend for this contribution to the mining industry over the next three years. Water desalination and delivery to the mining area will be topic of discussion regarding the contribution of solar systems in Latin America (LATAM) and other geographies. INTRODUCTION Increasing price pressure on the mining industry has generated a strong interest for mining companies to investigate energy costs and consumption. Currently, energy costs in mining economics contribute15% to 25% of the total commodity cost. In the past, most mines were operated by diesel gensets. Very high logistics costs for diesel supply, high and fluctuating diesel prices and theft led to very high energy prices. To overcome this problem, the mining industry has turned to solar energy, employing two main solutions: (i) adding a small scale (single level MWp energy supply) solar to an existing diesel system to create a hybrid solution operating as a microgrid environment; and (ii) replacing the existing diesel system with a large scale grid connected photovoltaic system financed by utilities or private IPP owners that signed a long-term power purchase agreement (“PPA”). In both applications, the near-term trend is to add storage and weather controls to optimize the electrical performance of the system. Use of concentrated solar solution (CSP) in the past was employed in a few remote sites to provide electrical energy to the mines. Currently this technology is not competitive with the photovoltaic (PV) systems. In some installations we have seen usage of a small hybrid system that is designed as relocatable, containerized and delivers scalable electrical power. In addition to the evolution of electrical energy sources, we see the trend of reduction of energy consumption in the mines by optimizing energy efficiency and generating load shifting solutions. Many studies of electrical energy in the mining industry support the growth of this trend in the mining industry.

Jan 1, 2019

By Fred C. Bond

The process of comminution by grinding is properly classified as an art, rather than as a science. Like most other operations concerned in ore dressing, or in the treatment of nonmetallic minerals, the mathematical relationships of rock breaking are still obscure, and much disputed. If some basic formula exists, comparable for instance to E = RI in electricity, it has not yet been placed in common use. The absence of such a comprehensive mathematical background undoubtedly is the cause of many inefficient designs and installations, as well as of much poorly oriented experimental work. On the other hand, the mathematical immaturity of the process constitutes an opportunity for a real contribution on the part of those who enjoy mental pioneering. Some of the statements made in any such exploratory work may be little more than opinions, and it is to be expected that some will later be proved untrue; but such an evolutionary development is necessary if we are ever to arrive at the fundamental laws, the discovery of which can change the empirical art into a mathematically exact science. The most significant principle of comminution that we possess is probably Rittinger's law, which states that the work done in crushing or grinding is proportional to the area of the new surface produced. There is an alternative theory, known as Kick's law, which formerly was preferred to Rittinger's but which now is rather discredited. According to Kick, the work done in comminution is proportional to the volume, or weight, of the pieces broken, or to the cube of their diameters, while according to Rittinger it is proportional to the square of the diameters. Careful determinations of size distribution below the limit of sieve sizes1 indicate strongly that under ordinary grinding conditions the amount of new surface area produced is directly proportional to the net power input. Changes in the size ratio between the balls and the particles cause important differences in the proportion of the product that passes a given mesh size, but do not affect the total amount of new surface area; they merely change the distribution of the surface among mesh sizes. The principle of constant surface area is the logical result of Rittinger's law, and it may well have an important bearing on the comminution theories of the future. Formula for Ball Wear Grinding tests have been made in the Allis-Chalmers laboratory for more than 9 years, using a standard charge of mixed balls of different sizes; and a continuous record has been kept of the rates of wear of each size. These results have been combined and plotted in various ways in order to discover the relationship that exists

Jan 1, 1943

By W. S. Ayres

[Secretary's Note.—At the Spokane meeting of the Institute, in discussion of President Brunton's address on "Modern Progress in Mining and Metallurgy in the Western United States," and at the request of members present, Mr. Ayres gave an oral account of his new separator, which is here published as an independent paper, partly because of its inherent importance and partly because it describes an improvement which did not originate in the Western United States, and therefore does not fall, strictly speaking, under the title of President Urunton's address.—R. W. R.] A brief history of the growth of the anthracite-coal preparation will give a better view-point from which to judge the present problem of separating slate from coal. At the beginning of the commercial value of anthracite, 70 years ago, only the pure portions, or " splits," of the veins were mined and shipped to market, and without any preparation or screening other than the selection, while loading, of the glassy lumps, and the rejection of the fine material and the slate that had strayed accidentally into the coal. The next step was the crushing or breaking of the coal (hence the name "breaker" as applied to the preparation-building), and the sizing of it by means of bars or revolving screens. This stage of its development marked the advent of the " breaker-boy " as a slate-picker, with his ever-increasing capriciousness. As the richer veins or a splits " became exhausted and the market demanded a still greater output, the less-pure " splits " and the thinner veins were utilized to produce the coal. Carrying as they do a far greater percentage of impurities, particularly when removing the pillars, it became necessary to build new and better equipped preparation-plants. Finally, we are now at the highest stage of complicatioii yet known to the art of coal-preparation. We are dealing with varying specific gravities, frictional difference, hardness, structure, and form in the pieces of coal and slate coming from many different veins, and

Jan 1, 1910

By Andrew L. Puwis

Methodologies were presented for computing the thermal gradient associated with single crystal solidification in macroscopic computer modeling. The. heat transfer, and solidification of a shaped investment casting model were simulated using properties from three different alloys. Following the simulation of solidification, the resultant thermal gradients (G) and rates of solidification (R) from representative points were extracted in various ways and compared: It was discovered that alloy properties have a strong influence on the computed thermal gradient and rate of solidification for the three methods investigated. Data also showed that the computed gradient for each model was very different depending on the temperature range used to compute these values.

Jan 1, 1994

By L. M. Barker

The New Cornelia Branch of the Phelps Dodge Corporation is at Ajo, Pima County, Ariz. It is at the southern terminus of the Tucson, Cornelia and Gila Bend Railroad, which connects with the Southern Pacific Railroad at Gila Bend, Ariz., approximately 43 miles to the north. History Early history of the Ajo district has been related by A. W. Allen1 and by T. A. Rickard.2 Briefly, steps looking to the large-scale development of the ore body were instituted as early as 1912. This work culminated in the equipment of the property for open-pit mining by steam shovels. Ores initially mined carried economic amounts of copper carbonates as the principal copper-bearing mineral. Treatment methods developed for the extraction of the copper content involved leaching and a 5000-ton leaching plant was constructed and placed in operation in early 1917. Description of methods and equipment employed in this plant has been given by A. A. Tobelmann and James A. Potter.3 As exhaustion of the carbonate ore body neared, and mining operations exposed an adequate tonnage of sulphide ores, a 5000-ton concentrator was constructed for their treatment. That plant has been described by H. Kenyon Burch.4 Construction was completed and the plant was placed in operation in early 1924. Changes made in the original plant to improve practices and increase production will be the subject of subsequent paragraphs of this paper. Geology Description of the geology of the Ajo district has been published by Ira B. Joralemon5 and by James Gilluly.6 The ore occurs chiefly in the porphyritic facies of Cornelia quartz monzonite, though appreciable

Jan 1, 1939

By Uwe Hess

For the Danish landworks for the coming fixed link between Denmark and Sweden across the Øresund the focus has been on the environmental aspects of the construction and operation of the facilities. This paper describes how the environmental objectives pertaining to the project have influenced the design and construction of one of the major elements of the Danish landworks, i.e. the tunnel in Sydhavnsgade and under Sydhavn Station. The chosen construction methods for the construction pit bracing and the groundwater lowering will be described along with the observed effects on the environment as shown by simulated or measured values for noise impact, settlements, pumped groundwater and extension of the drawdown cone.

Jan 1, 1996

By Ani Chitaley

A new method has been developed for handling supplies in underground bituminous coal mines. A survey indicates industry wide implementation potential for the proposed method. Reduction of supply handling accidents' by as much as 73% and improvements in the productivity of face operations by at least 3% are anticipated benefits. The new method is based on the palletization of daily supplies and the use of a forklift for carrying out the handling tasks at the underground section. A prototype of the forklift has been delivered to the U.S. Bureau of Mines. The forklift has demonstrated several important features necessary for underground supply handling such as compactness, maneuverability, visibility, ease of control and auxiliary attachments for hoisting, carrying timber and pulling. Design improvements are recommended for future generation underground forklifts. These relate to higher speed, increased battery duty cycle, higher payload and modified traction/steering to eliminate plowing of soft mine floors.

Jan 1, 1983

By J. H. Scaff, H. C. Theurer, E. E. Schumacher

The microwave region of the radio spectrum was effectively utilized in radar designs during the recent war and it has become of increasing interest in the field of communications. Work in this field has led to an important use for silicon—that of the point contact rectifiers†1 in the frequency converter of microwave (radar or radio) receivers—and has stimulated considerable interest in the electrical properties and preparation of silicon and its alloys. Silicon is an electronic semiconductor. Its conductivity at room temperature results principally from the presence of certain impurities. While for metals an increase in impurity content increases the resistivity, for semiconductors such as silicon the opposite occurs and, in general, the addition of impurities lowers the resistivity. Silicon materials may be classified into one of two groups depending upon the manner in which the impurities contribute to electrical properties. These have been termed for convenience p-type or n-type. P-type silicon develops a very large positive thermal emf against metals, has a Hall coefficient of positive sign and a low resistance direction in point contact rectification with the silicon positive with respect to the point. N-type silicon, on the other hand, develops a negative thermal emf against metals, has a Hall coefficient of negative sign and a low resistance direction in rectification with the silicon negative with respect to the point. Impurities which produce n-type silicon are called donors inasmuch as these elements contribute to electrical conductivity by donating electrons to an unfilled energy band in the silicon. On the other hand, elements which produce p-type silicon are known as acceptors as these impurities contribute to the electrical conductivity by accepting electrons from a filled energy band permitting what is known as conductivity by "holes" in which the sign of the carriers appears to be positive. A general treatment of the mechanism of conduction in semiconductors from the viewpoint of modern band theory has been given recently by Pearson,2 by Becker, Green and Pearson,3 and by Torrey and Whitmer.4 In this investigation boron and aluminum have been found to be acceptors, and phosphorus, arsenic, and antimony to be donors in silicon. Data on the effect of boron and phosphorus on the electrical properties, when present singly and in combination, have been acquired. These data are discussed in the present paper. Raw Materials Used and Methods for Adding Seeond Constituents Silicon from two sources was used in this work and these will be referred to as A and B respectively. Silicon A is a material of high purity supplied by the Electro Metallurgical Co. It is prepared by chemical purification of "commercial" silicon obtained from the arc furnace reduction of SiO2. It contains 99.8 pct silicon, minimum, with small amounts of calcium, iron, aluminum, boron, and phosphorus as the principal impurities. This material was extensively employed in these studies as well as in the commercial preparation of rectifier materials. Silicon B is a material of high purity from the du-Pont Co. It is prepared by a pyrolytic reduction of Sicl4 and is free of analytically detectable amounts of boron and phosphorus. Its use permitted study of the effect of boron and phosphorus individually on the properties. This material contains, however, spec-troscopic traees of a number of metals, some of which affect electrical and rectification properties. Typical analyses for the two grades of silicon are given in Table 1. To make controlled additions of boron to the charge it was necessary to employ a low boron content master alloy since the quantity of boron to be added was usually only a few thousandths of one percent. The alloy containing nominally one percent boron was prepared by melting chemically pure boron with silicon A using the melting techniques for 320 g silicon

Jan 1, 1950