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By A. Vidyadhar

Using pure quartz and hematite minerals, the adsorption mechanism of mixed cationic/anionic reagent schemes was investigated through Hallimond flotation studies. The flotation response of quartz and hematite independently with cationic and anionic collectors as well as with mixed cationic/anionic collector systems is assessed. The flotation response as a function of pH and collector concentration was investigated. The single mineral flotation tests in the presence of anionic collectors, quartz does not respond to flotation, but the C12 amine flotation of quartz was observed to be pH and concentration dependent. It was observed that hematite flotation recovery is maximum at acidic pH with sodium dodecyl sulphate (SDS), neutral pH with oleate, and at basic pH about 9.5 with C12 amine. Flotation results with both quartz and hematite indicate an increased adsorption of cationic collector in the presence of anionic collector apart from its own co-adsorption. The incorporation of oleate in between C12 amine molecules decreases the electrostatic head-head repulsion and thereby increasing the adsorption of C12 amine due to attractive tail-tail hydrophobic bonds, besides forming a closely packed adsorbed layer enhancing the hydrophobicity. The increase in oleate concentration beyond C12 amine concentration leads to the formation of soluble C12 amine-oleate complex / precipitate and the adsorption of these species decreased the flotation since the alkyl chains are in chaotical orientation with a conceivable number of head groups directing towards the solution phase. Keywords: quartz, hematite, adsorption, mixed collector system, flotation, zeta-potential

Sep 1, 2012

By M. E. Poad

Structural properties of steel-fiber-reinforced shotcrete and polymer-impregnated shotcrete, both plain and fiber-reinforced, were investigated by the Federal Bureau of Mines, Spokane Mining Research Center. The research center has found that flexural strengths can be increased by as much as 106 percent, and splitting-tensile strength by 50 percent, by introducing randomly oriented steel fibers. A slight decrease of compressive strength was found in the fiber-reinforced shotcrete. Polymer-impregnated shotcrete exhibited a threefold to fourfold increase in compressive and splitting-tensile strength. The techniques of preparing shotcrete with the dry process, using both fast-set agents and regulated-set cement, are described, along with the results of physical-property testing. Physical properties include compressive and splitting-tensile strengths, tangent and secant moduli, and stress-strain curves for plain shotcrete, fiber-reinforced shotcrete, and polymer-impregnated plain and fiber-reinforced shotcrete. Flexural strengths for plain and fiber-reinforced shotcrete are also reported. Steel-fiber shotcrete is the more promising of the new structural materials for ground support, and additional research is recommended.

Jan 1, 1975

By J Widjaja, E Hermawan, M Muharam, L Damanik

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. The island of Java lies within the Sunda-Banda magmatic arc, which is characterised by multiple phases of volcanic activity and extensive compressional deformation. Along this zone, significant gold and copper mineralisation occurs, including some of the world’s largest deposits. In West Java, epithermal gold mineralisation is typically located in a series of extensional and strike-slip faults that cut Miocene to Pliocene volcanic rocks. These are all low-sulfidation, epithermal, vein-stockwork-style deposits developed in Miocene to Pliocene calc-alkaline volcanic rocks, which have been intruded by shallow-level plutons.This paper discusses an example of epithermal mineralisation at Mt Subang, West Java. Gold mineralisation was originally identified from stream sediment, panned concentrate and rock geochemistry sampling in the early 1990s. Geophysical surveys (magnetics and induced polarisation resistivity/chargeability), trenching, pitting and diamond hole drilling has subsequently revealed silicified-quartz vein epithermal gold mineralisation hosted within fault structures. It is clear that these structures acted as hydrothermal fluid pathways leading to the development of mineralised offshoots along north–south extensional and en-echelon arrays of north-east–south-west and transtensional faults. A number of vertical offshoots also occur in flexures and fault jogs. Post-mineral faulting has subsequently dissected and offset a number of the offshoots. Therefore, a detailed knowledge of structure and fault kinematics and displacement magnitudes is required in order to understand the geometry and continuity of mineralisation across major structures and maximise the resource potential. A range of exploration targets were modelled, indicating a minimum and maximum of 0.2 and 1.8 Moz of gold respectively.CITATION:Cunningham, M J M, Muharam, M, Damanik, L, Hermawan, E and Widjaja, J, 2015. Structural controls on the localisation of low-sulfidation epithermal mineralisation in West Java, Indonesia , in Proceedings PACRIM 2015 Congress, pp 227–234 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By G. P. Saseen, R. A. Haney

The US Mine Safety and Health Administration (MSHA) developed a model to estimate diesel particu¬late (dp) exposures in underground mines. The estimator uses in-mine measured dp concentrations or engine manufacturers' standardized emission data. Through a series of calculations, full-shift dp concentrations are estimated by applying standard engineering principles of ventilation, control technology and work cycle. This model, in the form of a computer spreadsheet, provides the mining industry with a method for estimating dp levels and determining the impact of various diesel particulate controls on occupational exposures to dp in underground mines. A detailed description of the estimator and several examples demonstrating the results are provided.

Jan 1, 2000

By William Brewster

DATING back some five years ago, various foundries made inquiries as to the probable total carbon content in a given specification and grade of pig iron. Up to that time we had no data, and except for a few occasional determinations of total carbon, no attempt had ever been made to set up routine determinations of total carbon. In fact, at that time, a cast analysis was considered sufficient, without examining at further length into possible variations of analysis between ladles of the same cast. In view of the various inquiries as to total carbon, we sampled all piles of all grades of pig iron, making complete analyses. Finding some variation in carbon content, we secured more samples and plotted the carbon content with respect to silicon in each grade of iron except for the higher phosphorus foundry iron, where it was necessary to divide the group into twenty-point phosphorus ranges. This is easily understood, owing to the falling off of carbon content with the increase in phosphorus con-tent, silicon in each case being the same. In addition, these curves clearly demonstrate the lowering of the carbon content as the silicon is increased. In order to insure accuracy and reliable determinations the following method of sampling and analysis was employed: Two pigs selected from each end of the car, each car containing iron from one 50-ton ladle, are drilled with a 5/16-in. drill all the way through from top to bottom in the center of one section of the pig. The drillings are collected and transferred to an 80-mesh sieve; the portion passing through and the portion retained are placed in separate envelopes and labeled accordingly. The amount of sample in each envelope is weighed to obtain the proportionate amount of coarse and fine drillings, then a factor weight of sample (1.3636 grams) made up of proportionate

Jan 1, 1936

By J. S. Edwards

The ISASMELT? process is recognized worldwide as a modem, flexible, environmentally-friendly and low capital cost smelting technology. Due to the inherent simplicity, and the advanced process control that has been developed, personnel become competent within weeks of being introduced to the ISASMELT? technology. This compares with the years required to become proficient with alternative technologies. Copper smelters in Australia, USA, India, China, Peru and Zambia have installed ISASMELT? technology under licence from Xstrata Technology. In the secondary copper business, plants in Belgium and Germany are processing copper and/or lead materials in ISASMELT? furnaces in a two stage process. In a single furnace smelting is followed by converting. Both plants have exceeded design capacities and are continuously improving their performance. The next evolutionary step for the technology is the implementation of the continuous copper converting process on a commercial scale. The present work describes the design status of the continuous converting process - ISACONVERT?.

Jan 1, 2007

By J. J. Egan

ADVANCES in the production of quality steel have emphasized the need for greater knowledge of the amount and distribution of oxygen in the steel. Control of inclusion content and quality is largely dependent on such knowledge. While many analytical methods have been de-vised for the accomplishment of this end, few are without serious limita-tions in accuracy, convenience, or skill required in application. Usually at least two methods are necessary to determine total oxygen and constituent oxides. Because of the great importance of this problem and the specific interest in the application of such methods of analysis, the various procedures were carefully reviewed at the Union Carbide and Carbon Research Laboratories, with the view of developing a method free from the limitations mentioned above. Intensive experimentation finally led to an improved iodine extraction analysis described by Cunningham and Price. I After this had been thoroughly checked from the standpoint of the analytical chemist, it was rechecked from that of the metallurgist. This involved preparation of a number of small heats of varying composition with determination of total oxygen in the molten metal by the alumina method2 and an analysis of the solidified material without the aluminum addition by means of iodine extraction; the oxides of iron, manganese, silicon and aluminum also being determined by the iodine analysis. The report of this work constitutes the subject of this paper.

Jan 1, 1933

Mining Automation By Professor Hugh Durrant-Whyte, Australian Centre for Field Robotics and Centre for Mining Technology and Equipment, Department of Mechanical and Mechatronic Engineering, The University of Sydney Professor Hugh Durrant-Whyte summarised why the mining industry needs to automate and reviewed the current automation technology - its risks, costs and benefits. Why automate? The drivers for automation include: safety, productivity, quality control and reduced manning, equipment utilisation, maintenance, and organisation and planning. Durrant-Whyte recommended starting out with a picture of a fully automated mine and working backwards through a systematic analysis of benefit and risk. This also involves looking at the impact of the total automation on current mine design, and identifying the key technologies.

Jan 1, 1997

By R. A. Harris

In this study Pt-Al thin films were prepared via electron beam physical vapour deposition (EB-PVD) with an atomic concentration ratio of Pt25:Al75. These films were heat treated at temperatures ranging from 150°C to 650°C for annealing times from 4 to 60 minutes. The resulting microstructure of these thin films were obtained via secondary electron imaging used in conjunction with depth profiling with the aid of scanning auger microscopy (PHI 700).Elemental maps of the micrographs were obtained. Simulations, based on a chemical potential Monte Carlo method1, were run for various interaction parameters. From these simulations theoretical depth-profiles and proposed microstructures were obtained. These were compared to the experimentally measured depth profiles and elemental maps. Keywords Monte Carlo, chemical potential, depth profile, Pt-Al thin films.

Jan 1, 2011

By A. Iannacchione

Longwall mining began within the Pittsburgh coalbed of Pennsylvania (PA) in the early 1970?s. Originally, longwall mine layouts were designed to fit within existing room-and-pillar operations, where panels were limited to that of typical production panels, e.g. a few hundred feet wide by a few thousand feet long. In these early designs, the gate entries were comprised of chain pillars similar to those found along main entry systems or within pillar recovery sections. The modern longwall mine has little in common with their 1970?s predecessors. Today the entire mine layout is designed around the longwall mining method. The longwall panels have grown to well over one thousand feet in width with lengths now measured in miles. In addition, development pillar sizes and shapes are matched to specific performance requirements.

Feb 27, 2013

By G. N. Goldberg, Robert A. Rapp

The steady-state kinetics and microstructures of simultaneous internal oxidation and external scale formation were investigated for the oxidation of Cb-Zr and Ch-Zr-Re alloys in pure oxygen at 1000°C. For each binary alloy, a constant rate of scale formation was observed at steady state; the internal oxidatton zone reached a steady-state, time-independent thickness. The dependence of the scaling rate on zirconium content exhibited a maximum at a low zirconium colttent; more concentrated alloys oxidized at a slower rate than pure columbium. This composition dependence of the scaling rate may be partially attributed to the effect of the internal oxidation process as an intenla1 sink for oxygen, with the formation of voluminous, and relatively impermeable ZrO2 precipitates. However, the morphologies of the ZrO2 internal oxide precipitates also affected the scaling rate. The internal oxide precipitates were distributed uniformly in the external scale. The steady-state thicknesses of the internal oxidation zones were not in agreement with those predicted theoretically from an idealized simple model. However, in this particular alloy systen1 the ideal model is not satisfied experitmentally. For ternary Cb- Zr - Re alloys with Nr10e = 0.02 or 0.05, the steady-state thicknesses of the internal oxidation zones were less than those for the corresponding binary Cb-Zr alloys. For ternary alloys with NRe(0) - 0.05, a more adherent and much less porous external scale was formed, and a reduction in the kinetics of scale formation was observed. A number of authors'-7 have reported linear oxidation kinetics for the reaction of pure columbium at 1000°C in air or in oxygen of about 1 atm pressure. A thin and tightly adherent oxide layer is found at the metal/oxide interface beneath a porous external layer of scale. Although the suboxides CbO and CbO2 represent thermodynamically stable phases at 100O°C, generally only Cb2O5* is identified as a reaction product in quenched specimens. Studies at 1000°C at lower oxygen pressures8,10 (Po2 - 10-4 Torr) show that both CbO and CbO2 do form and that CbO2 is a protective oxide. The growth of CbO2 results in parabolic kinetics until Cb2O5 is nucleated and grows. Apparently because of the large volume change associated with its formation, Cb2O5 is porous and does not serve as a diffusion barrier; linear kinetics prevail after the surface is covered with Cb2o5. On the basis of these observations, several authors5,9,10 have suggested that the linear oxidation of pure columbium at 1000°C in air or oxygen of 1 atm is limited by a Loriers-type mechanism,11 whereby the total rate or reaction is controlled by ionic diffusion through a thin layer of CbO2 which is maintained at a constant thickness throughout the linear oxidation. However, the concept of a Loriers model for a three-phase CbOlCbO2 Cb2O5 scale, with the only oxygen activity gradient across the NbO2 phase, is not self-consistent. Further, the suboxides CbO and CbO2 were not observed in the high-temperature X-ray diffraction study of columbium oxidation by Goldschmidt.8 From investigations in which the large PO2, dependence of the linear scaling rate was demonstrated, the importance of an oxygen adsorption or dissolution step has been suggested.4,5,7,10,12 Thus the mechanism for the linear oxidation of pure columbium remains quite controversial. Since further insight into the oxidation mechanism of pure columbium is not provided by this investigation, the authors wish to emphasize at the outset that their experimental results are not interpreted in terms of a particular rate controlling step for the oxidation of pure columbium. Previous investigations13-18 of the oxidation of Cb-Zr solid-solution alloys in air or oxygen at 1000°C suggest a remarkable dependence upon zirconium content. For an alloy of bulk zirconium mole fraction, N2r(0) equal to 0.05 or 0.10, the oxygen uptake is reported to be as high as four times greater than that for pure columbium;13,14 for alloys with NZr(0) 0.05 or 0.10 the oxygen uptake is reported to decrease with increasing NZr(0); to a minimum uptake of about one quarter that for pure columbium at NZr(0): = 0.50.13-15Since zirconium forms a more stable oxide (ZrO2) than the lowest columbium oxide (CbO), and since columbium exhibits a high solubility19,20 and diffusivity21,23 for oxygen, the internal oxidation of the zirconium component to ZrO2 is expected at a reaction front ahead of the advancing metal/scale interface. The external scale is then formed at the metal/scale interface by the inward migration of oxygen through the scale, probably through a series combination of molecular and ionic diffusion. Internal oxidation in conjunction with external scale formation has been investigated by Maak24 for the oxidation of dilute Cu-Be alloys in pure oxygen at 850°C. For cu-Be and many other binary alloys,24-27 very small, essentially uniaxial internal oxide particles are formed in the most dilute compositions; for somewhat more concentrated alloys. the internal oxide particles precipitate as platelets or needles. From pertinent solutions to the diffusion equation, Maak28

Jan 1, 1967

The extraction of minerals and coal at greater depth, employing higher-powered machinery to improve production levels, imposes an increased burden on the ability of a ventilation system to maintain an acceptable mine climate. Hence, mechanical mine cooling systems are often adopted, which can be expensive in terms of both their associated capital and operating costs. Consequently, in order to optimize the total mining costs, it is essential to provide the mine operator with a method with which to determine the most cost effective and efficient mine cooling system. In a previous paper1a novel energy analysis employing the concept of exergy was proposed and applied to cooling systems applied to two conceptual model mines, representative of UK deep coal operations, and their resultant subsurface thermal environ-mental conditions predicted. This paper presents an analysis of the results obtained from the application of this novel technique to assess the performance of various cooling systems applied to a current UK colliery that is experiencing climatic problems due to its depth and highly mechanized production and development workings. To perform this analysis, ventilation and climatic data collected at the case study mine were used to construct balanced mine ventilation and climatic network models to replicate the subsurface environment. Where air conditions exceeded specified climatic limits within identified climatically control zones, mechanical mine cooling systems were employed. A number of cooling system configurations were applied to these model to investigate the potential to satisfactorily regulate the thermal environment. The heat energy transferred out of the air stream by the various cooling methods was absorbed using a variety of chilled water systems, which were designed to operate at various water flow rates and temperatures. Models of various cooling system were developed and applied to control the underground climate within this mine network to within pre-set climatic limits. The results of a comparative analysis of the energy transfers that were produced by the application of the different cooling systems are presented in the form of exergy performance indices. The results produced by simulation models constructed to represent chilled water distribution networks to supply the various air coolers, are designed and balanced. The results of the exergy analyses applied to the operation of the various chilled water pipe networks are discussed and used to assess the exergetic performance of the application of each proposed cooling system to the mine ventilation network.

Jan 1, 2004

By G. Richard Dreese, Harold L. Bryant

The coal mining industry has had a long history of successfully externalizing part of its costs. Thus the private or internal costs of coal mining have been minimized and the social or external costs have been ignored. The externalized costs have largely taken the form of water pollution from acid mine drainage and sedimentation of stream channels from eroding spoil banks and gob piles. The environmental problems created by strip mining are very conspicuous, so the public demand for legisla-

Jan 1, 1975

By Edgar Bain

OF THE important phenomenon of the hardening of steel, Professor Sauveur1 says: "It would seem as if the methods used to date for the elucidation of this complex problem have yielded all they are capable of yielding and that further straining of these methods will only serve to confuse the issue, the point having been reached when this juggling, no matter how skilfully done, with allotropy, solid solutions, and strains is causing weariness without advancing the solution of the problem.. The tendency of late has been to abandon the safer road of experimental facts and to enter the maze of excessive speculations, in which there is great danger of some becoming hopelessly lost. The conclusion seems warranted that new avenues of approach must be found if we are to obtain a correct answer to this apparent enigma. With some degree of fitness we may say, this of other problems. It seems likely that one of the new avenues of approach to many metallographic problems is the study-of crystal structure, or more accurately, the atomic arrangement by means of the X-ray spectrometer. The crystal structure of some materials has been carefully worked out by the mineralogist, but his methods are, in general, unsuited to commercial metals and a method that yields even better information is at hand as the result of work on the diffraction of X-rays by Laue and the Braggs2 and later by Hull,3 St. John, and others. It should be understood that the contour of free crystals, which is the subject of measurements by the crystallographer, is the result of the atomic structure and, in general, bears a simple and obvious relation to it. The use of the X-ray spectrometer4 has been described frequently, so the procedure will not be given here.

Jan 2, 1922

By J. S. Peterson, G. P. Cole

The National Institute for Occupational Safety and Health (NIOSH), Pittsburgh Research Center (PRC), has conducted research to improve electrical fault detection on coal mine direct current (dc) trolley systems. Present circuit breaker protection systems are current-magnitude-based and cannot discern between normal traffic and high resistance electrical faults. Tests were conducted at cooperating mines to assist in developing a neural-network-based detection algorithm for distinguishing between electrical faults and normal operation. The Fast Fourier Transform of the trolley rectifier current signature served as baseline data for the neural network. During field tests, the algorithm performed with greater than 90% accuracy.

Feb 24, 1997

By Lynn B. Hales, Randy Ynchausti, Jeffrey D. Mckay

Many consider rougher flotation control to be more of an art than a science. Some have even thought it impossible to make process control decisions and changes without human interaction. Controlling flotation bank pulp levels to maintain consistent pulling rates in the face of changing feed slurry flow rates, varying mineral types, and inconsistent reagent additions can be daunting. However, an advanced supervisory control strategy was installed on the plant floor to control an industrial rougher flotation circuit with little or no operator interaction. Plant staff monitored the flotation circuit under supervisory control and reported benefits of up to 4% improvement in copper recovery above that achieved with an older supervisory control strategy. To accomplish this work, a novel use of instrumentation to solve a flotation bank pulp level control problem was employed, a new implementation approach was used to correct some flaws in the older approach, and careful attention was paid to a few key process control principles. This paper discusses important aspects of these activities.

Jan 1, 2000

By W. A. Backofen, G. Mayer

Single crystals of iron, copper, and a Cu-7 wt pct A1 alloy were pulled through conical dies to simulate the constraint in a polycrystalline aggregate undergoing axisymmetric reduction. With Taylor-type hardening, dependence of the drawing stress, od, on the Taylor orientation factor, M, is predictable from the polycrystal stress-strain curve; in particular, for a power-law relationship, it should follow that d log od/d log M = (1 + n). A first-order agreement with analysis was found in the data from iron. For copper, the implied n from the observed d log od/d l°g M was -0, while for Cu-7Al it was negative. The trend was in the direction of random polycrystal behavior. Thus the idea of hardening only in response to the amount of prior slip loses validity as stacking fault energy (SFE) is lowered. Two possible explanations have been suggested: as stacking fault ribbons are widened, barriers from dislocation reactions become increasingly effective in dispersing slip and reducing the orientation dependence of the total glide strain dm that appears in alternatively, or conjointly, the polyslip shear stress, 7, acquires an orientation dependence of a kind which has the same leveling effect on M. The problem of relating the strain hardening of polycrystalline material to that of an isolated single crystal is still largely unsolved. In a new experimental approach from recent work, single crystals of different orientations have been deformed under the constraints found in an aggregate while measuring their deformation resistance. Procedures have involved drawing cylindrical crystals through conical dies1 and compressing slab-shaped crystals in plane strain.2'3 Predictions for the outcome of such experiments were made first by Taylor~ and later, in more general form, by Bishop and Hill.5'6 Taylor's example was the axisymmetric extension of an fcc crystal slipping on the usual {111}(110) systems or, equivalently, a bcc crystal undergoing 'kestricted" slip on {110}(111). In his solution, the deformation work supplied was equated to that dissipated internally in slip on all active systems. With o the single applied tensile stress, dc the resulting axial strain, and dyT the total glide strain on systems operating at resolved shear stress, 7: The orientation dependence of M was found by minimizing dyT for each orientation while activating five independent systems, Fig. l(a).? The Bishop and Hill analysis, based on a principle of maximum work, leads to essentially the same conclusion; the need for at least five active systems is recognized in the finding that either six or eight are actually brought into operation. The mean value from the entire stereo-graphic triangle in either case is M - 3.06. More recently, Hutchinson8 made a Taylor-type analysis for pencil glide in a bcc structure, from which piehlerg prepared Fig. l(b) as the counterpart in Fig. l(a); here M = 2.75. The obvious weakness in such analyses is the indifference to slip-system interactions. A condition of what might be termed "independent"

Jan 1, 1969

By Paul Lynch

"Since being reported to the 2012 UMI in Shanghai, the Cook Islands has been steadily developing for the commencement of it Seabed Minerals sector in its large Exclusive Economic Zone which contain a vast and unique Manganese Nodule resource, estimated at 10 billion tonnes1. At the 2013 UMI in Brazil, it was reported that the Seabed Minerals Act had commenced and all the necessary complex Technical aspects of this developmental work was being undertaken. At the 2014 UMI in Portugal, full details of the final developments leading to the opening of the Tender of Exploration Blocks in the Cook Islands EEZ will be presented in a brief but comprehensive method, using Poster displays, Powerpoint and active Website interaction. This will show the drafted Regulations, prepared on best international standards, to address both Licencing and Environmental requirements, to give clarity and security to the Resources Owner, industry and stakeholders. This work in being coordinated by the Cook Islands Seabed Minerals Authority, with the valuable collaboration of many international, regional and national stakeholders, including the Cook Islands NGOs, Marine Resources, Marine Park and National Environment Service."

Sep 1, 2014

By F. H. Cornet, D. Ask, O. Stephansson

We have conducted a stress analysis of overcoring stress measurements undertaken at the Zedex Test Site (ZTS) in the Äspö HRL, Sweden. Two different types of overcoring cells have been used at the site: the 9-gauge Borre Probe (CSIR-type) and the 12-gauge CSIRO HI cell. Inversion programs based on the least-squares criterion were developed and calibrated. The primary and secondary stress field in the ZTS were back-calculated using strain data from individual cells as well as from combining data from both cells. We propose that the combination of strain data from the two cells significantly improves the determination of the stress field. A striking result is the good agreement between the re-analysed overcoring data and the existing hydraulic fracturing data. The deviations for the horizontal stresses between the re-analyzed overcoring data and the existing hydraulic fracturing data are approximately 3 MPa. The deviation in the orientation of maximum horizontal stress is approximately 10-20°. Nous avons analysé les résultats de mesures de contrainte par surcarottage réalisées sur le site Zedex, du laboratoire souterrain HRL d’Aspö, en suède. Deux types de cellule de mesure ont été utilisés sur ce site : la cellule à 9 jauges (du type CSIR) et la cellule à 12 jauges (du type CSIRO HI). Un programme d’inversion mettant en œuvre une norme par moindres carrés a été développé et validé. Les champs de contrainte primaires et secondaires du site Zedex ont été évalués d’une part en considérant chaque mesure isolément, d’autre part en intégrant l’ensemble des données de déformation dans une inversion unique. Nos résultats suggèrent que l‘association des diverses mesures dans une intégration unique améliore nettement la détermination du champ de contrainte. Un résultat intéressant est le bon accord entre ces nouveaux résultats et les résultats des mesures par fracturation hydraulique. Les écarts sur l’amplitude des contraintes horizontales est de l’ordre de 3 Mpa, les écarts sur les orientations de l’ordre de 10-20°. Auf dem Zedex Test Gelände im Äspö Festgesteinslabor (HRL) wurde eine Spannungsanalyse mittels Overcoring Spannungsmessungen durchgeführt. Hierzu wurden zwei verschiedene Methoden verwendet: das 9-kanal Borre Gerät (CSIR- Ausführung) und die 12-Kanal CSIRO HI Zelle. Inversionsprogramme, die auf dem “least-squares”- Kriterium basieren, wurden entwickelt und kalibriert. Das primäre und sekundäre Spannungsfeld des Zedex Test Geländes wurde sowohl aus Verformungsdaten individueller Zellen als auch aus Kombination beider Zellen ermittelt. Wir nehmen an, daß die Kombination der Messergebnisse beider Geräte die Bestimmung des Spannungsfeldes signifikant verbessert. Überzeugender Beweis hierfür ist die gute Übereinstimmung der überprüften Overcoring Daten und Ergebnisse aus existierenden Hydraulic Fracturing Versuchen. Die Abweichungen der horizontalen Spannungen aus beiden Datensätzen ist etwa 3 MPa und Abweichungen der Orientierung der größten Horizontalspannung liegen bei etwa 10-20°.

Jan 1, 2003

By A. A. Collins

OF widespread interest to all lead metal¬lurgists is a dross smelting process that will consistently give mattes and speiss of low lead and high copper contents. It is -a problem that has intrigued operators through the years. In the past few years, with increased amounts of copper and overcrowded metallurgical furnaces, it has been almost imperative to evolve some method. Experience at El Paso has shown that high copper-to-lead ratios can be consistently attained by use of the new soda process.* OLDER METHODS Three older methods; i.e., I. Dross plus siliceous ore and limestone, 2. Dross plus one fourth blast-furnace speiss and siliceous ore, 3. Dross plus sulphides and siliceous ore and scrap iron, do not give consistent results and the products are higher in lead and lower in copper than those produced with the soda process. Any radical changes in the blast-furnace drosses will throw any of these older methods into a tailspin. For almost ten years, El Paso used the third method, with varying results. It was noted that as the arsenic and antimony contents of the dross increased, the speiss and matte steadily increased in lead and decreased in copper. A dross containing four parts of copper to one part of arsenic was considered to be ideal. At times this balance of copper to arsenic was almost impossible to obtain, especially when handling copper Cottrell dusts, which vary so greatly in copper and arsenic. Custom smelters like El Paso, handling a great variety of dusts, concentrates and ores, are apt to have anywhere from 1 to 15 pct copper on charge, with a variable in arsenic of from 0.5 to 2 pct. With such conditions, and drosses varying from 12 to 40 pct copper, an operator using the older dross reverberatory practices would find it just about im¬possible to control the reverberatory operations and to produce a good product low in lead and high in copper. These conditions prevailed at El Paso from the year 1940 to the present. In May 1942 it, was decided to experiment with the soda process. THE SODA PROCESS After considerable work the soda method was finally evolved to the present state. It has never failed to produce a good product even under the most adverse conditions. It might be well to remember that many men of thought in the smelting industry have at one time or other suggested the removal of all copper, arsenic and antimony from the lead blast-furnace charge as an aid to better metallurgy.

Jan 1, 1947