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By Willie Manfrey, Richard Klimpel

This paper describes the effects of slurry viscosity on the selection-for-breakage and breakage distribution parameters in the wet grinding of cres. A series of experimental tests were run on laboratory scale ball mills. Slurry viscosities were modified by varying the solids/water ratio with and without the presence of selected chemicals. Very consistent and predictable correlations are shown to exist. The grinding parameters were calculated using a computerized back -calculation technique developed by Klimpel and Austin. Industrial scale circuit calculations and preliminary plant trial data suggest that considerable increases in throughput and/or fineness of grind can he achieved through the judicious use of chemical additives.

Jan 1, 1977

By H. A. Kuhn

The Pittsburgh coal field in Western Pennsylvania is conceded to be the most important in the world.

Jan 1, 1915

By A. L. Holley

THE intention of this paper is not to discuss this important subject in all its bearings, but merely to point out why mechanical tests of steel, as ordinarily made, are not, alone, of any special value to engineers-certainly not to general mechanical engineers. The agents of the Barrow Hematite Steel Company, one of the largest and most successful Bessemer establishments in England, have recently distributed a report, made by Sir William Fairbairn,

Jan 1, 1874

Automation Defined ?Using self-operating equipment to reduce human exposure to the mining environment and routine or repetitive work.?-Atlas Copco Terminology: ?Manual Operation ?A vehicle being operated by a person ?in the cab?. ?Radio Remote Control (RRC) ?A vehicle being physically operated by a person through a Line Of Sight (LOS) or Video-Remote equipment. ?Tele-Remote Control ?A vehicle being physically operated by a person at an operator station which is not necessarily located near the vehicle?s working area. ?Autonomous Operation ?A vehicle under self control with the possibility of human supervision and override.

Oct 1, 2010

By F. F. Roberto, E. Kirby, A. R. Marchbank

The application of biologically assisted methods for metal extraction in the mining industry has a long history, but development of modern techniques has been relatively slow. There is, however, a resurgence of interest in the industry with the recent development of methods to successfully treat base metals concentrates. Two major pilot plant programs for treatment of chalcopyrite concentrates have been initiated in the past year and results from one are beginning to be released. This paper provides an overview of methods that have been applied in the past, from the earliest deliberate applications of the technology, through the copper and uranium heap and dump leach applications, the more highly engineered agitated tank leach gold applications and the developments currently taking place in the industry.

Jan 1, 2003

By L. A. Cisternas, R. I. Jeldres, C. Cruz, P. A. Robles

"Previous studies have shown that the floatability of chalcopyrite in seawater at highly alkaline conditions is significantly affected by the presence of clays. The reason is that the species of calcium and magnesium present in seawater under those conditions may act as a bridge between the surfaces of clay and chalcopyrite, generating massive aggregates that then depress. In this context, the objective of this work is to analyze the impact of pretreated seawater with low amount of calcium and magnesium ions on the recovery of a sulphide copper mineral with high kaolinite content as clay. The seawater pre-treatment is done by the addition of sodium hydroxide in a high carbon dioxide environment. The chemical reactions realized under these conditions lead to the formation and precipitation of calcium and magnesium species that are subsequently removed by vacuum filtration. The pre-treated seawater is then used in flotation tests at pH 11 for copper sulphide, where the mineral is synthetically prepared by mixtures of chalcopyrite, kaolinite, and quartz. When comparing the flotation results for different types of water, including seawater and pre-treated seawater, a significant effect is observed: as the seawater hardness decreases, which comprises the calcium and magnesium ions, the recovery of chalcopyrite is increased. However, the effect is markedly enhanced in the presence of kaolinite. Therefore, the results indicate that sodium hydroxide and carbon dioxide are able to remove different species of calcium and magnesium from seawater and could improve the chalcopyrite recovery with high kaolinite content. INTRODUCTIONIn many cases, mineral deposits are found in arid areas with little access to water resources. Water is a fundamental element to carry out the unit operations that achieved the separation of valuable minerals (especially in concentration operations). Seawater has acquired an interesting role in recent years (Cisternas and Moreno, 2014); in fact, it seems to be one of the few viable options to ensure the sustainability of the mining industry in arid zones. At present, there are numerous experiences of industries that use or have used this resource, either by submitting the seawater to a desalination treatment by reverse osmosis or by applying it directly, without desalting. The latter case may involve significant economic benefits (for example, by avoiding the investment of building a desalination plant) and in some cases some operational benefits. A positive aspect is that in general terms the foaming in the saline medium is much more efficient compared to fresh water (Quinn et al., 2014; Castro et al., 2010). Some reports show that the foaming doses required to achieve a certain quality of bubbles are remarkably reduced, reaching exceptional cases such as Xstrata's Raglan concentrator, where it did not even include foaming to carry out the operation. This fact is quite promising, considering that some researchers have stated that controlling the quality of bubbles and foam could float minerals through coarse particles. This would lead to multiple benefits, such as energy savings by avoiding excessive grinding and a lower presence of fine ore that causes major problems in water recovery operations by gravitation (such as thickening) and in tailings management. However, seawater also causes significant challenges in multiple operations (Jeldres et al., 2017, 2016; Castro et al., 2010), as for example in minerals with high clay content (Uribe et al., 2017). In fresh water, the presence of clays minerals in ores is already a major problem in the flotation stages since the operation becomes difficult to be controlled, and operators are commonly forced to increase the consumption of reagents because the collectors are deposited on the clays' surfaces reducing froth stability (Farrokhpay and Bradshaw, 2012). Sometimes the use of rheology-modifying reagents should also be incorporated since the pulps become more visc"

Jan 1, 2018

By X. Y. Yu, X. A. Wei, A. Zeng

"The flotation behaviors of diaspore and three kinds of silicate minerals - kaolinite, illite and pyrophyllite - using an organosilicon cationic surfactant as collector were investigated as functions of reagent concentration and pulp pH. The results show that the organosilicon cationic collector QAS122 is a suitable collector for the flotation of aluminosilicate minerals but has weak collecting ability with regard to diaspore, enabling the flotation separation of diaspore from silicate minerals using QAS122 as collector. The flotation of a bauxite ore was then studied in detail. Finally, a reverse flotation separation process was used to process a low-grade bauxite ore. It was concluded that use of the organosilicon cationic collector is effective. A concentrate with aluminum oxide (Al2O3) to silicon dioxide (SiO2) mass ratio, or A/S, of 9.67 was obtained from natural bauxite ore with A/S of 6.07 at pH of around 11. The Al2O3 recovery rate was 81.72 percent. IntroductionChina has abundant bauxite ore resources, but more than 98 percent of the bauxite ores are the diasporic type, with the characteristics of complex mineral composition, low aluminum oxide (Al2O3) to silicon dioxide (SiO2) mass ratio, or A/S, and difficulty of processing. The gangue minerals in bauxite ores are mainly kaolinite, pyrophyllite and illite, containing titanium and iron impurities (Zong et al., 2008). It is known that high-grade bauxite ore, with A/S greater than 8, can be processed directly by the Bayer process (Papanastassiou et al., 2002; Ma et al., 1996). However, Chinese diasporic ores have been processed mainly by the sintering process, which is environmentally damaging and energy intensive. Increasing the A/S of the diasporic ores using a flotation method is needed (Xia et al., 2010).Froth flotation is one of the most widely used processes to concentrate valuable minerals in beneficiation ores. It is particularly useful for separating finely ground ores from their associated gangue minerals. For diasporic bauxite ores, flotation is applied to obtain high-quality material for the Bayer process by increasing the A/S. Direct flotation has been shown to be an efficient method for the desilicating of diasporic bauxite ore (Wang et al., 2004; Xu et al., 2004), but reverse flotation has more advantages for this purpose, including less collector consumption, less foaming product and less effect on metallurgy (Liu et al., 2007; Hu et al., 2003; Hu, 2003; Luo et al., 2001)."

Jan 1, 2015

By J. T. Furey

"A pilot plant study was conducted to evaluate the performance of column flotation in the recovery of gold from a gold/tellurides bearing sulphide ore, and to compare the performance of column flotation to conventional ""mechanically agitated"" flotation.Tests were conducted in a 60 liter glass column with ground flotation feed split from a concurrently operating conventional pilot plant, thus permitting direct comparison between the two processes. During the test program, the effects of wash water rate, gas holdup, froth depth, residence time and flow bias were examined in detail.The ore had an average ""as tested"" feed grade of about 5 g/t gold and 1 % sulphur, with the gold occurring primarily as inclusions of montbragite (Au2Te3) in pyrite, with minor amounts of native gold. Conventional flotation using 60 minutes residence time across four roughing stages recovered about 97% of the gold into concentrates grading about 50 g/t Au. A single stage of column flotation roughing using 25 minutes residence time matched the conventional circuit recovery of 97%, but produced grades of+ 150 g/t Au. INTRODUCTIONColumn flotation is the most significant innovation that has occurred in the mineral processing industry in recent years and has become an important alternative to mechanical flotation. Column flotation has been most widely accepted and applied in cleaning service where it has frequently proven to be superior to mechanically agitated flotation. Roughing in columns has not been ignored, but early testing indicated that columns may not be capable of achieving adequate recovery and, to date, columns have not been seen as serious competitors for mechanical roughers."

Jan 1, 1990

By Sherwin Kelly

The prime objective of geophysical exploration is to promote the economical and rapid dis-covery of mineral or oil deposits of commercial value. To a few this concept as applied in min-ing may signify the direct discovery of ore-bodies, but to the geophysical engineer this latter Idea is one of the most insidious and detrimental misapprehensions which he has to combat. The destruction of this annoying obstacle to the progress of geophysical exploration reveals the kernel of truth behind it, that the exploration geophysicist has for the better part of two decades been concerned primarily with the discovery of mineral formations favorable to the occur-rence of commercial ore. There is a very real distinction here, since geophysical methods are capable of discovering certain mineral formations such as sulphide bodies or quartz veins, but are totally incompetent to predict whether or not they constitute ore; that is. whether or not they contain minerals of economic value in the amounts requisite to repay extraction. The art of geophysical exploration is now, however, rapidly outgrowing these early limita-tions. The rate of this growth will in large measure depend on the recognition by the mining industry of the fact that geophysics can play a role far wider and more important than it usual-ly does now, in guiding the future exploration and development of mineral deposits. It is my own firm conviction that as time marches on we will see the methods of applied geophysics turned more and more to the delineation of both minor and major structural features. The outlining of such features having a bearing on the probable loci of mineral deposition will be of inestimable value in guiding the development of a mining district. It is in this field that there will In-evitably occur a meeting and overlapping of the activities of the exploration geophysicists and

Jan 1, 1940

By Allan E. Martin, Harold M. Feder, Irving Johnson

The cadmium-uranium system was studied by thermal, metallographic, X-7-ay and sampling techniques; special emphasis was placed on the establishment of the liquidus lines, The single inter metallic phase, identified as the compound UCd11 melts peritectically at 473°C to form a-umnium and melt containing 2.5 wt pct uranium. The cadmium-rich eutectic (0.07 wt pct uranium) freezes at 320.6°C. Solid solubilities in uraizium and cadmium appear to be negligible. Between 473°C and 600°C the liquidus line is retograde. NO publication relating to the cadmium-uranium phase diagram was found in the literature. The establishment of this diagram was of considerable interest to us because of a possible application of the system to the pyrometallurgical reprocessing of nuclear fuels. Analysis of liquid samples, metallographic examination, thermal analysis, and X-ray diffraction analysis were used to establish the phase diagram from about 300° to 670°C. Particular emphasis was placed on the establishment of the liquidus lines. The same system was concurrently studied in this laboratory by the galvanic cell method.' Both studies benefited from a continual interchange of information. MATERIALS AND EXPERIMENTAL PROCEDURES Stick cadmium (99.95 pct Cd, American Smelting and Refining Co.) contained 140 ppm lead as the major impurity. Reactor grade uranium (99.9 pct U, National Lead Co.) was most often used in the form of 20-meshspheres. This form was particularly suitable because it does not oxidize as readily as finer powder. The liquidus lines were determined by chemical analysis of filtered samples of the saturated melts. The liquid sampling technique is described elsewhere2 alumina crucibles (Morganite Triangle RR), tantalum stirring rods, tantalum thermocouple protecthecadmiumtion tubes, Vycor or Pyrex sampling tubes, and grades 60 or 80 porous graphite filters were used. Uranium dissolves in liquid cadmium rather slowly. In order to achieve saturation of the melts it was necessary to modify the procedure of Ref. 2 by the use of more vigorous stirring and longer holding periods (at least 3 hr) at each sampling temperature. The samples were analyzed for uranium by spectro-photometry (dibenzoyl methane method) or by polar- ography. The analyses are estimated to be accurate to 2 pct. Thermal analysis was performed on alloys contained in Morganite alumina crucibles in helium atmospheres. Standard techniques were employed; heating and cooling rates were about 1°C per min. For the determination of the peritectic temperature, Cd-10 pct U charges were first held for at least 50 hr at temperatures in the range 435° to 460°C to form substantial amounts of the intermediate phase. For the determination of the effect of cadmium on the a-p transformation temperature of uranium, charges of Cd-25 pct U (-140+100 mesh uranium spheres) were first held near the transformation temperature, with stirring, to promote solution of cadmium in the solid uranium. The holding times and temperatures for these treatments were 18 hr at 680°C for the cooling run and 28 hr at 630°C for the heating run. Alloy specimens for X-ray diffraction and metallographic examination of the intermediate phase were prepared in sealed, helium-filled Vycor or Pyrex tubes. Ingots from solubility runs and thermal analysis experiments also were examined metallographically. Crystals of the intermediate phase were recovered from certain cadmium-rich alloys by selective dissolution of the matrix in 20 pct ammonium nitrate solution at room temperature. Temperatures were measured with calibrated Pt/Pt-10 pct Rh thermocouples to an estimated accuracy of 0.3°C. However, the depression of the freezing point of cadmium at the eutectic is estimated to be accurate to 0.05°C because a special calibration of the thermocouple was made in place in the equipment with pure cadmium just prior to the measurement. EXPERIMENTAL RESULTS The results of this study were used to construct the cadmium-uranium phase diagram shown in Fig. 1. This diagram is relatively simple; it is characterized by a single intermediate phase, 6 (UCd11), which decomposes peritectically, and which forms a eutectic system with cadmium. The solid solubilities in the terminal phases appear to be negligible. An unusual feature of the diagram is the retrograde slope of the liquidus line above the peritectic temperature. The Liquidus Lines. The liquidus lines above and below the peritectic temperature are based on three separate solubility experiments. The data are shown in Fig. 1 and are given in Table I. It is apparent from the figure that the solubility data obtained by the approach to saturation from higher temperatures fall on substantially the same lines as those obtained

Jan 1, 1962

By David R. Ray, Arthur J. Pyron, William F. Thomann

"Proterozoic plutonic and volcanic rocks in the Franklin Mountains, west Texas, exhibit similar values in average concentrations of equivalent uranium (eU), equivalent thorium (eTh) and equivalent potassium (eK) when compared to Proterozoic igneous rocks of the southwestern United States. Variations of radioelement concentrations for all Proterozoic igneous rocks of the Franklin Mountains range from 1.1 to 357.1 ppm U, 2.1to 259.1 ppm Th and 2.5 to 10.2% K.Recent geologic mapping of the Proterozoic rocks in the Franklin Mountains revealed several types of granites previously unrecognized, and these warrant further exploration for U and Th resources. Fluorite-bearing granites and riebeckite pegmatites are likely targets for further investigation, as these have the highest U and Th concentrations compared to all other granites.IntroductionThis is a summary of the paper presented at the CIM Geology Division Uranium Symposium held in Saskatoon, Saskatchewan, September 8-13, 1981. The purpose of this study was to evaluate the distribution of uranium (U), thorium (Th) and potassium (K) in Proterozoic igneous rocks in the Franklin Mountains, and compare radioelement concentrations to Proterozoic igneous rocks elsewhere in the southwestern United States.General GeologyThe Franklin Mountains are located in west Texas and southcentral New Mexico, within the southeastern part of the Basin and Range Province o f the southwestern United States. The Franklins are a complex fault-block range trending northsouth with strata dipping toward the west. Ages of the rocks range from Proterozoic to Cretaceous. Harbour (1972, 1960) provides the most recent account of the general geology of the Franklin Mountains. Most recent accounts of the detailed Pro Proterozoic geology o f the Franklins are provided by Hoffer (1976), Thomann (1980, 1981), Pyron (1980), Ray (1982) and McCutcheon (1982)."

Jan 1, 1983

By Garrett May

We present a periodic technique for measuring the thermal conductivity of thin, disk-shaped samples. In samples of this type, temperature measurements must be made across the sample faces and are therefore subject to large error due to the interface resistance between the temperature sensor and the sample. The technique uses measurements of the amplitude and phase of the periodic temperature across both a reference sample and the unknown material at several different frequencies. Modeling of the heat flow in the sample allows the simultaneous determination of the thermal parameters of the sample as well as the interface resistance. The technique is demonstrated on nanocomposite samples less than 1.0 mm thick.

Jan 1, 2008

By Kang N. Zhong, Hui H. Luo, Yi H. Wei, Yu L. Wang

"More than 85% of phosphorous reserves in China occur as middle-low grade phosphate of sedimentary origin. The main gangues are dolomite, quartz, silicates, and clays. The characteristics of minerals are finely disseminated. Flotation results have shown that the floatability of apatite of this kind of ore is much worse than that of igneous and metasedimentary origin because of its high specific surface area. Although some effective depressants, such as naphthalene sulfonate and phenanthrene sulfonate, are used to decrease the MgO content in the P2O5 concentrate, its presence is still high (about 2%) in the Chinese concentrates. Meanwhile, the wastewater may cause some environmental problems. Batch flotation results and measurements of specific surface area and CO3 2- have revealed that there is a relationship between the floatability of apatite and the surface area.A two-stage flotation flowsheet, which includes a combination of direct and reverse flotation, was developed for beneficiating sedimentary phosphate ores. The direct flotation was conducted in an alkaline medium and most of the apatite and carbonate minerals floated leaving quartz and siliceous gangue in the sink. In the reverse flotation circuit, the floated product was further beneficiated in an acidic medium to eliminate the carbonate as a float product. Apart from the high quality of concentrate, the two-stage flotation also facilitated the treatment and the recycling of wastewater. A wastewater recycling procedure was developed and tested in a continuous flotation process. The key factor was the careful selection of effective and non-toxic reagents."

Jan 1, 2003

By E. H. Ahrens

This paper deals with the responsibilities of an operating geologists and the relationship of operations to exploration. It should be of interest to those soon to enter the profession, those new to mining geology and as a review to more experienced geologists. Subjects discussed include detailed geologic mapping, sampling, core logging, assaying, selection of proper map scale, posting geological and assay data, section preparation, identification of ore controls, delineation of development drill targets and geologic hazards, models and the very important topic of salesmanship. Methods and ideas, proven valid in vein, pyrometasomatic replacement and porphyry copper deposits are presented. Hopefully, these will smooth the path for new members of our profession.

Jan 1, 1984

By C. J. Dungey

INTRODUCTION The County of Cornwall is situated in the South Western extremity of England, see Fig. 1, and has for hundreds of years been an historical centre of mining activity. In the last century many thousands of Cornish miners emigrated to Canada, U.S.A., Australia and numerous other countries throughout the world to form the nucleii of mining industries in those lands. At present there are four active underground mines within the county, all mining tin, together with a relatively large china clay industry. All the operations are directly or indirectly associated with the three main granite intrusions, namely the Land's End Granite, the Carnmenellis Granite and the Bodmin Moor Granite. The report which follows relates to two mines, owned by the South Crafty Group of Companies, namely the South Crofty Mine itself and its smaller subsidiary, Wheal Pendarves. Both these mines are adjacent to the Carn Brea Granite ridge, see Fig. 2, which is an off-shoot of the main Carnmenellis Granite mass. The Carn Brea Granite has provided one of the most intensive areas of copper and tin mineralisation anywhere in the world. Many of the mines worked during the last two centuries and the early part of this century were situated close to the metamorphic aureole surrounding the granite intrusion. Both South Crofty and Wheal Pendarves have their shafts collared in the overlying slate, locally known as killas, but the major part of their workings are in the granite beneath. The ore bodies, or lodes, of both mines are generally steeply dipping and approximately one to four metres in width. They have been, and continue to be, worked by either back or under-hand stoping with the major level interval being approximately 37 metres. A feature of both stoping systems is that they require no back filling and in many cases the completed working areas have remained open for many years due to the competent wall rock conditions. The stoping operation necessitates having box-holes or draw points at regular intervals along the strike length at 4 to 7 metres centres; thus a stope some 50 metres long may typically have ten box-holes or draw points through which air can percolate into the empty stopes above. The granite country rock contains traces of uranium minerals, namely pitchblende or uraninite, and it is the decay of this uranium mineral which leads to the formation of the mobile radon gas which, together with its short lived daughters, may create a hazard. The presence of uranium minerals has long been known, but the quantities being so minute, it was not appreciated until some ten to fifteen years ago that these might present a hazard. The Mines and Quarries Inspectorate approached Management approximately ten years ago with a view to taking samples in areas of the mine that they felt might contain the highest concentrations of radon. Samples were thus taken in several areas of both mines, normally well away from working areas and where there was no through ventilation. The results of these initial tests were published by the National Radiological Protection Board in a paper entitled "Radon and Its Daughters in Various British Mines". The results of the initial surveys made it apparent that improved ventilation was the most important factor in reducing radon daughter concentrations within the mine atmosphere, with increased flow rates having three beneficial functions, viz. (1) To dilute radon daughter concentrations. (2) To prevent radon and its daughters reaching a state of equilibrium. It is not uncommon for radon and its daughters to have a disequilibrium factor of 1,000 in some uranium mines.

Jan 1, 1981

By William R. Webster

An investigation has been made of 500 samples of universal and sheared plates of basic Bessemer and basic open-hearth steel manufactured by the Pottstown Iron Company, the carbon-limits being 0.07 to 0.18 per cent. Through the courtesy of Mr. W. H. Morris, President, I am able to lag before the Institute the results of these tests. The samples tested were all taken from the finished material, and the chemical determinations were made on drillings from the broken test-pieces, which were sent to the chemist without giving him the heat-numbers. The results are such as to encourage me to keep on with the work, and, if possible, to have it carried out on other steels. It is kith this view that I now offer my tables in their incomplete form. My first table mas constructed by grouping the tests according to chemical analysis in various. ways, and making a rough tabulated statement, from which the ultimate strengths were worked out and carefully compared with the actual results of the tension-tests. From data thus obtained, one table after another was worked out, and by this method of "cutting and trying" I finally arrived at the results which I now present in Table I. (p. 771). I do not claim absolute accuracy, but my approximations have proved to be so close that the figures are practical data for current use at the works. The indications are that a pure iron, without carbon, phosphorus, manganese, or silicon, if it could be obtained, would give 38,000 pounds ultimate strength. This is assumed as a base, and to it is added the effect of each of the above elements, as explained below. The upper part of Table I. gives the ultimate strength due to carbon and phosphorus, and is the same for both basic Bessemer and basic open-hearth steels. The lower part gives the increase in ultimate strength due to manganese. By adding this to the amount obtained from the upper part, we have the ultimate strength of basic Bessemer

Jan 1, 1893

By Helen L. Cannon

BOTANICAL methods of prospecting for metalliferous ores are based on the premise that deposits at depth may be reflected chemically in surface vegetation. For the past several years, on behalf of the Atomic Energy Commission, the U. S. Geological Survey has investigated on the Colorado Plateau the application of botanical methods to uranium prospecting. Results suggest that orebodies may be found under a considerable cover of barren sandstone through the absorption of uranium and associated trace elements by plants growing at the ground surface. Plant physiologists have demonstrated that uranium is a necessary nutrient for plant growth and therefore is present in all plants.' The amount present is small but measurable. The absorption of uranium by plants growing over ore deposits forms the basis, therefore, for a method of prospecting by plant analysis.

Jan 2, 1954

By Fiorella Polanco Martínez

El presente trabajo describe una forma de financiamiento en la minería a través del mercado de valores. Es decir, que desde un análisis del sector minero se busca convertir las reservas minerales probadas en un patrimonio fideicometido que avale una emisión de bonos titulizados. En este sentido, las reservas minerales por sí mismas carecen de valor económico pero se pueden valorizar con un proyecto de factibilidad futuro, cuya titulización de reservas minerales, se convertirá en una herramienta de financiamiento alternativa o complementaria a la BVL Venture Exchange. Po ello, el financiamiento que se obtenga a través del mercado de valores se destinaría a la ejecución del proyecto minero junior o para expandir uno en producción.

Sep 12, 2005

By A B. Bayooke, A C. Robertson

In terms of underground tunnelling in metres advance per capita, Australasia compares well with the best world performers. This is because of the large number of metalliferous mines, coalmines and civil tunnelling projects, with the Australian tunnel advance for civil and mining projects exceeding 625?km/a. In terms of hard rock quarry extraction, Australia produces approximately 200?Mt/a of aggregates, roadbase, fill material and specialist rock products from its quarries, which equates to approximately 8?t/capita. Australian mining and tunnelling contractors are also of world standard and are used to excavating in a variable range of ground conditions in a competitive environment. One author has been involved in tunnel and underground space planning and quarrying in Australia for the past 25 years and predicts that, over the next 20 years, there will be a major swing towards underground space for commercial uses. This paper identifies the potential uses of underground commercial excavation and the planning and geotechnical challenges for the future. Underground quarrying creates new opportunities to extend existing quarries within their urban footprint with minimum impact on the surrounding community. Investigations by the authors reveal that there are very few cities in the world that actually incorporate underground space planning in their city plans. However, cities such as Helsinki have been planned in detail to utilise the rock resources beneath them. Brisbane is used as a case study for a practical application of commercial underground space and underground quarrying in Australia.CITATION:Bayooke, A B and Robertson, A C, 2014. Geotechnical challenges for underground commercial space and quarrying in Australia, in Proceedings AusRock 2014: Third Australasian Ground Control in Mining Conference , pp 317–322 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 5, 2014

By M. S. Moats

"The effects of commercial copper electrorefining additives (glue and thiourea) on the electrochemical removal of bismuth are of importance in copper production. It was found that Bi(III) electrodeposition occurs readily from acidic sulfate solution via a diffusion-controlled quasi-reversible reduction. The diffusion coefficient of Bi(III) was measured and found to be less than reported values of copper in similar solutions. The presence of thiourea and/or glue was found to accelerate or de-polarize Bi(III) reduction on stainless steel as compared to the inhibition or polarization of Cu(II) reduction. The additives also inhibited the dissolution of the Bi-Cu co-deposit during cyclic voltammetry. During short term deposition studies, the additives increased the concentration of Bi in co-deposited Cu-Bi products from solutions with low concentrations of Cu (<2 g/L). Bi deposition was significantly suppressed by increasing the Cu(II) concentration in the solution. The formation of a copper layer on the stainless steel electrode appeared to significantly suppress the reduction of Bi(III). This study demonstrates that glue and thiourea depolarize the deposition of bismuth on stainless steel. Therefore, the additives could be used to improve Bi impurity removal during third stage liberation.INTRODUCTIONThe production of high purity copper has been steadily increasing due to the wide application of the metal and its alloys in electrical and electronic products, infrastructure construction, industrial machinery and equipment, general products and transportation (Moskalyk et al., 2003). Most high purity copper is manufactured from copper sulfide mineral concentrates and/or scrap via a pyrometallurgical process followed by electrorefining (Navarro et al., 1999). During the electrorefining process, cast anodes of 99-99.5% purity are electrochemically dissolved into an acidified copper sulfate solution while high purity copper (>99.99%) is plated on stainless steel blanks or copper starter sheets (Davenport et al., 2002). The control of cathode deposit growth (purity and morphology) while maintaining a high current efficiency is of significant importance for copper refining (Ilkhchi et al., 2007). At typically applied current densities for industrial copper electrorefining, mass and charge transfer play important roles in the quality of cathodic products (Hiskey et al., 1998). If the real current density at some surface points is substantially higher owing to uneven current distribution, then rough spots can and will grow faster leading to nodules (Suarez et al., 1992). Nodulated deposits tend to capture solution and anode impurities (slimes) resulting in unacceptable cathode quality (Afifi et al., 1987). Furthermore, these nodules can grow until they eventually contact the anode leading to short circuits and current efficiency reduction (Ilkhchi et al. 2007)."

Jan 1, 2016