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By V. Ramachandran

Over the past 20 years, water treatment plants have been built at various Asarco facilities to effectively handle the process waste streams that need to be bled from the system. The current paper review the several operations with reference to (a) waste streams processed, (b) process chemistry, (c) discharge options and recovery of treated water, and (d) sludge disposal.

Jan 1, 1994

The mineralogy of the crocidolite (blue asbestos) veins at Wittenoom Gorge was examined to determine the cause of failure to recover soma of the fibre by the ore-dressing methods currently being practised. As a, result of this yamina.tion, several fo.Ctors pertinent to the problem were found to be a function of the pa.ragenosis of the veins. The occurrenceof magnetite from tho'cap rock within the veins was thought to be preventing fiborisation during troo.tment. Several petrologic features are described and their relation to the ore genesis is discussed, Comparison with the crocidolite deposits of the Union of South Africa is also considered.

Jan 1, 1963

By Heinz W. Duddeck, Hans-Konstantin Nipp

The design of storage space or deep mining in rock salt should take into account not only time dependency of the rock salt behavior but also temperature effects. For deep mining of potassium salt the natural increase of temperature with depth may no longer be negligible. For the storage of cryogenic liquid gas in salt caverns more knowledge is nezded about the propagation of deep temperatures and their effects on the stress-strain-creep behavior of the surrounding salt. High temperature problems arise for nuclear waste storages in caverns or drill holes emitting radiation. A numerical model is proposed for the analysis of displacements and stresses including their time and temperature induced change. For the material behavior of salt constitutive equations are chosen composed of a combination of Hooke-Kelvin-Bingham-Newton-model based on experimental results (excluding at present deep cooling), Langer 1980. The parameters involved are depending on the stress level and the temperature. The finite-element-method is applied to rotationally symmetrical three-dimensional problems. The non-linear calculation method is based on an implicit method with respect to time. A modified Newton-Raphson-method and the initial strain approach are employed. Along with some experiences on suitable numerical procedures, examples are shown for the characteristical effects of time-temperature dependency. Having achieved convergency and reliability a method is now available for practical design and parametric sensibility studies.

Jan 1, 1982

By Malcolm Ross

The Reserve Mining Co., in the processing of taconite iron ore quarried from the Peter Mitchell Pit, deposited the finely crushed waste rock into Lake Superior near Silver Bay Minnesota. In the early 1970s The U.S. Environmental Protection agency filed a lawsuit against Reserve Mining Co., asking the court to force the company to stop dumping into the lake. On April 20, 1974, after a lengthy court battle, the U.S. District Court concluded that the Reserve Mining discharge into Lake Superior violated federal and state pollution laws and thus ordered Reserve Mining Co., to halt the lake disposal of taconite tailings. At the time many feared that some of the mineral particles contained in the tailings (alleged to be asbestos or asbestos-like) would cause human health problems. This Conference was thus convened to readdress the problem of the mineral content of the Biwabik Iron Formation and to whether any minerals contained in the ore could cause human disease. The four papers given in this session address the nature of the mineral particles in the taconite rock, the definition of the term ??asbestos?? and the history of the legal controversy over the possible health effects of certain mineral particles contained in the Biwabik iron range ores. Paper 1?Geology of the Biwabik Iron Formation and Duluth Complex Mark A. Jirsa, James D. Miller, Jr., G.B. Morey The Biwabik Iron Formation was a principal source of ore for the American steel industry during the 20th Century. The unaltered iron deposits, called taconite, contain approximately 30% iron and 50% SiO2. About 75% of the iron in taconite resides in the mineral magnetite, the remainder is largely in iron carbonate and several iron-silicate minerals.

Jan 1, 2007

By L. C. Glenn

The account of oil and gas production in Tennessee, and of the geological factors related to such production, as given by the writer' a few years ago needs to be supplemented by brief statements as to production and development to bring it up to date. Activity in searching for favorable geological structures or in drilling given areas has never been comparable to the intensive work done in states of large production. It is not possible, therefore, to prepare a statement giving the details that may be readily available in such states, but instead one must be content with more general statements. In the past 10 or 12 years there has been a moderate amount of drilling for both oil and gas widely scattered over the state. Of much of this there is no available record. Morgan, Clay, Scott and Pickett counties have had more oil-drilling activity than any other counties, and likewise they have had almost all of the oil production. In Scott and Morgan counties production centers about Sunbright and Glenmary, the oil coming from the St. Louis limestone at a depth of 1200 to 1500 ft. Wells usually are small but generally hold up well. In Clay, Pickett, Fentress, Overton, Macon and Sumner counties there is a large area in which there are many small structural domes, some of which have been drilled. Wells vary from a few barrels to several hundred flush production and last for some years. The oil comes from porous weathered zones, mostly in the Trenton division of the Ordovician, though some comes from lower horizons beneath one or more bentonite beds that serve as horizon markers and are known as the "pencil cave." Wells recently drilled in the Central Basin and in the Western Highland Rim have been dry or have had only shows of oil. The horizons tested are also usually Ordovician in the Central Basin and usually either Ordovician or Mississippian; occasionally also Devonian on the Highland Rim. In the Gulf Embayment area of West Tennessee there has been but little activity. A well near Ridgely said to be over 2200 ft. deep is supposed to have entered Upper Cretaceous sands and clays in the lower

Jan 1, 1934

By A M. Purba and A Sjadat, A D. Wilson

Ongoing mining of the East Ertsberg Skarn System orebody below the Gunung Bijih Timur and Intermediate Ore Zone caves has been relatively successful and a ramp up to 80 000 t/d was achieved in the Deep Ore Zone Mine. However, the distribution of production, the overall drawpoint availability as well as the rate of change of the cave back profile has not followed the anticipated path. Several key factors influencing cave growth and progress, grade variation, fragmentation, wet muck and surface subsidence have been recognised over the life-of-mine that now have to be taken into account for planning the later stages of mining.The paper will discuss the influence of geological controls of lithology and structure – how this as well as other contributing aspects have impacted ore flow, contributing to some of the widespread panel damage, and been a key factor in compacted draw columns and caused an accelerated appearance of water ingress. This in turn has rapidly changed the distribution of wet drawpoints requiring remote mucking and special controls that also affect the call from the remaining dry drawpoints. Comment is also made on the potential final cave profile if it continues along the current trend and some discussion is offered about possible mitigation measures if this were to come about.CITATION:Wilson, A D, Purba, A M and Sjadat, A, 2016. Progressing cave performance into the later stages of the Deep Ore Zone mine, in Proceedings Seventh International Conference and Exhibition on Mass Mining (MassMin 2016), pp 285–292 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2016

By T. F. Witherbee

That the single charging-bell, properly proportioned, is a good all-around device for distributing material in a blast-furnace can scarcely be questioned; yet it is equally true that, in some cases, it has not given perfect satisfaction; as has been demonstrated by the substitution of double bells, at furnaces under the beat management—generally in cases where anthracite, either alone, or with a portion of coke, was used as fuel. The defect of the single bell seems to be that it does not permit, beyond very narrow limits, such changes in charging as may be required by the temporary conditioil of the furnace. Modern furnaces using Connellsville or other good coke and Lake Superior ores seem to be well served with a single bell. At least, up to a certain size, somewhere about 18 by 85 ft. to 19 by 90 feet, these furnaces make low-silicon pig-iron with about 1,800 lb. of fuel, or in some cases very much less. The following instances occur to me, in which other forms of charging-apparatus have been employed with advantage: 1. A charcoal-furnace, 61 ft. high, 11 ft. in diameter at bosh, and 8 ft. 2 in. at stock-line, with a rectangular crucible, 42 by

Jan 1, 1905

By V. Lessels, D. J. Buckwalter, D. H. Rose

At White Pine Copper Co.'s operation in the Upper Peninsula of Michigan, the company has been losing more than four lbs of copper in each ton of sand tailings. With an average rate of 12,000 tpd of sand going to the tailing pond daily, the company has been losing more than 14 million lbs of the red metal annually. With an eye aimed toward lessening this loss, White Pine engineers in 1959 initiated a study on techniques for recovering this "lost" copper from the sands. Inasmuch as the flotation operation was considered to be optimized, a logical approach seemed to be leaching. For various reasons ammonia, ferric chloride, acid, and biological leaching were ruled out as impracticable. This led to a consideration of cyanide leaching as practiced in the precious metals industry.

Jan 8, 1967

By John Pilling

The concept of microstructure, its evolution through materials processing and its effect on the properties of the material is, perhaps, the foundation upon which the science of materials is built. PHAUST, a computer aided learning program, attempts to provide instruction in establishing the relationships between phase diagrams, thermal processing and microstructure. Using phase diagrams derived from a database or created by the user, the evolution of microstructure during processing is quantified using the lever rule and/or the Scheil equation and tracked through a doubly linked list (a form of binary tree). Microstructures, in the form of full colour cartoons are then drawn using the quantitative and logical information contained within the linked list using bitmapped templates and logigal operators such as NOT. AND, OR and XOR, giving the student a view of the structure as it would be seen under the optical microscope. The software provides complete diagnostics of student answers, locates errors and misconceptions as well as providing tutoring towards the correct solution method and answer.

Jan 1, 1991

By Howard A. Smith

Of late considerable experimental and theoretical interest has been shown in the rates of transformation from a single phase, usually a supercooled solid solution, into one or more phases. Such reactions may involve both diffusion and transformation of the major constituent, as in iron alloys, or it may simply involve diffusion, as in superstructure formation and in age-hardening systems. Most of the work has been confined to ferrous alloy1-9† although two investigations have been made on copper alloys10*". That such work may be of considerable practical importance has been demonstrated by Bain12, by the workers at the Kaiser Wilhelm Institut fur Eisen-for~chung'13, 14, and by the everyday use of precipitation and age-hardening principles15. Experiments in this country have generally followed Davenport and Bain's technique of rapid supercooling followed by isothermal treatment. In Germany16, 17 the work has been extended to the study of the influence of accurately controlled and measured rates of cooling. The work on steel indicates that there are two subcritical temperature ranges where reaction starts sooner after quenching and proceeds at a more rapid rate than at other temperatures. At suberitical temperatures above Ar" (temperature of martensite formation) where reaction is dependent upon atomic migration there is a period of time of which the length depends upon the alloy content and the temperature, before which no reaction has been detected. Davenport and Bain' find that different sorts of atoms in solid solution in gamma iron affect the length of this " prereaction" period differently, manganese probably being the most effective in lengthening it. It is very difficult to believe that nothing occurs within these "prereaction" regions, for if this were so there is no reason why any reaction at all should be observed. In the light of experimental facts and theoretical considerations it is certainly

Jan 1, 1935

By Gary Brieley

Until well into the 20th century, most construction work was performed under the auspices of a master builder or in a manner that would be described today as design-build. In addition, many civil engineers served as ?interns? under the tutelage of a master builder in order to learn how to design and construct a certain type of structure. This was certainly the case for tunneling projects with various individuals having been identified as tunneling experts as a result of successfully completed projects The master builder approach began to change in the early 1900s to a model that would be referred to today as design-bid-build. A design-bid-build approach to project procurement gives the owner more control over the final product and al-lows the contractor to know exactly what is expected of them before the work is constructed. As a result of this transition in project procurement, civil engineering schools placed a greater emphasis on the training of ?design? professionals. This article will document how the training of tunnel design professionals progressed within the United States. Although it is difficult to generalize about the hundreds of tunnels that were constructed in the first four decades of the 20th century, there is one project that stands out as having resulted in a university program related directly to tunneling and that is the Chicago Subway. During a visit to the United States in 1938, Dr. Karl Terzaghi met a student named Ralph Peck who was then studying at Harvard University in a pro-gram established by Arthur Casagrande. Shortly thereafter, Terzaghi traveled to Chicago for a lecture and was asked to consult on the Chicago subway project that was then under construction. The Chicago subway was being constructed in clay, and the owners were worried about possible settlements to nearby buildings. Terzaghi asked Peck to serve as his field engineer for that project. Thus was established one of the most productive relationships in the history of civil engineering in the United States. Peck, who would become Dr. Peck, moved to Chicago in 1939 to participate in an extensive research project that con-tinued until subway construction was halted in 1941 because of World War II. During that time, the cost of subway construction in Chicago was reduced substantially as a result of Peck?s observations and Terzaghi?s recommendations. In fact, it was reported that subway construction in Chicago cost less than one-half of similar projects in London even though the clay in London is considerably stiffer compared to Chicago. Upon the completion of his work on the Chicago Subway, Peck accepted a professorship with the University of Illinois in Champaign/Urbana.

Jun 1, 2010

By C. F. Park

Hog Mountain is in the north central part of Tallapoosa County, Alabama, about 13 miles northeast from Alexander City. The Hog Mountain Mining and Milling Co. controls 1658 acres of land and is the only company operating in the district. The principal mine workings are in sections 10 and 15, T.24N., R.22E. The region has been visited by geologists many times, has been briefly described in several papers,' and mentioned in many others. No detailed map of the mine or vicinity has been published. The field work for this report was started in March, 1934, as part of the Public Works reemployment program. About a month and a half was spent mapping both the surface and underground geology. The mine owners and operators have cooperated in every way possible to facilitate the work. N. 0. Johnson, the mine engineer, E. W. Ellsworth, J. E. McCoy and J. G. Englebert have acted as assistants for part of the work. The University of Alabama and the State Geologist's office have aided materially by permitting free use of their libraries and laboratory equipment. Geography Hog Mountain forms a conspicuous ridge that rises to a height of a little more than 1000 ft. above sea level, and about 400 to 500 ft. above the adjacent country. The ridge is composed of granitoid intrusive rock and silicified schist that are more resistant to erosion than the surrounding softer schist. The topography of the area around the ridge is gently rolling and is typical of the subdued forms of the deeply eroded Southern

Jan 1, 1935

By A. H. Daane, W. J. Wunderlin, B. J. Beaudry

In an earlier study at this laboratory,' the authors investigated the solid solubility of holmium in copper, silver, and gold, and also the melting point of the first eutectic on the noble-metal-rich side in these systems. In a more recent study of the solubility of rare-earth metals in gold at this laboratory. Rider, Gschneidner, and McMasters2 noted that the reported eutectic temperature in the Ho-Au system was lower than the corresponding eutectics in systems of dysprosium and erbium with gold. A redetermination of the eutectic temperature in the Ho-Au system with the same alloy used in the original study showed the eutectic temperature to be 810°C instead of 778°C as originally reported. (The eutectic temperatures in the Ho-Ag and Ho-Cu systems were also redetermined and were found to be 795" and 864°C compared to 787° and 868°C, respectively, which were reported originally.) Since this large change in eutectic temperature made the solubility data appear questionable, new alloys were prepared, heat-treated, and examined metallographically. The procedure of sample preparation and heat treatment used in the original work' was followed except longer heat treatments were used ranging from 7 days at 600°C to 6 hr at 900°C. The results obtained are shown in Fig. 1. There is good agreement between the two studies in the maximum solubility of holmium in gold. Since the slope of the solvus is less pronounced in the present study, the extrapolation to 550°C shows a solubility of 1.6 wt pct Ho in gold compared with 1.0 wt pct in the original work. Since additional data were obtained and longer heat treatments were used in the present study, the larger value is believed to be more accurate. The authors wish to express their appreciation to P. Rider and K. A. Gschneidner. Jr., for bringing this discrepancy to their attention, and also to D. Thompson for assisting in the present study.

Jan 1, 1965

By Gerardo Fuentes

The stoichiometry and kinetics of the hydrothermal reaction of enargite in copper sulphate solutions was investigated in the range 140–300 °C, and particle size under 15 and 50 μm. The stoichiometric experiment was performed at 300 °C, using one gram of sample (96% enargite, 4% tennantite) and 100 mL of copper sulphate solution (10 gpl) at 1.2 pH. Enargite reacted completely after 80 min. A solid product was obtained and characterized by XRD. The main product was chalcocite (M) and some traces of djurleite and chalcocite (Q). Tennantite did not react under these conditions. The kinetic experiments were conducted at 140 °C, 190 °C, 250 °C and 300 °C. From fitted data and Arrhenius equation the calculated activation energy (Ea) was 51 kJ/mol. According to the hydrothermal transformations studied, the reactivity of different phases found in the copper concentrates was bornite > chalcopyrite > covellite > sphalerite > pyrite > enargite > tennantite.

By Hamilton Wingate

In view of the fact that the fineness of the resultant bullion varies with the particular treatment to which the zinc-precipitate is subjected, and since there are considerable losses attributed to both methods, the following notes on the results obtained at the Waitekauri Extended mine, Maratoto, N. Z., may be of interest. The ordinary method of roasting the vacuum-dried precipitate was adopted instead of the treatment with sulphuric acid, the necessary facilities for the latter method not being available. Moreover, provided the ordinary method is carried out with the necessary care, it is questionable if it is not the most satisfactory where large quantities of precipitate have to be handled, and where (as is generally the case in this district) a considerable amount of silver is present. All the precipitate was first washed through a 40-mesh sieve. If it was necessary to recover the bullion at once from the accumulated short zinc, it was oxidized and melted separately; but, as a general rule, being heavily charged with bullion, it was placed on the bottom of the trays at, the top end of the extractor-boxes, where it acted as an excellent precipitant, the bullion being recovered at the next clean-up. After drying on a filter with the aid of a vacuum-pump, the precipitate was weighed and removed to the oxidizing furnace, which is similar to that generally in use in New Zealand, consisting essentially of an ordinary square tray of cast-iron, with 6-in. sides, built over a brick furnace. Wood is used as fuel. The tray is hooded over with sheet-iron, fitted with a sliding-door, and the fumes pass through a flue at the top into a dust-chamber, then into the open air. Oxidation of the Precipitate.—The oxidation was conducted first at a low temperature, which was gradually raised, until

Jan 1, 1903

By L. R. Fisher

The purpose of this investigation was twofold: (1) To devise a rapid method for determining quantitatively the porphyrin-carboxylic acid content of a particular crude-oil porphyrin aggregate, and (2) to isolate porphyrins in the crystalline state from crude-oil porphyrin aggregates. The first purpose was accomplished by applying adsorption chromatography. In fulfillment of the second aim three different crystalline porphyries were isolated by methods which involved both adsorption chromatography and fractionation of benzene solutions with hydrochloric acid of varying strength. The three porphyrins had etio, rhodo-, and phyllo-type absorption spectra, respectively. INTRODUCTION Many samples of petroleum have, as interesting minor constituents, chemical compounds known as metalloporphyrins. Their presence in crude oil and other bituminous materials was first discovered by Treibs a quarter century ago. Much experimental work has been done on metalloporphyrins because of their importance to the petroleum industry. They have a deleterious effect on refining catalysts. The ash resulting from the burning of heavy fuel oil is very reactive, We to the presence of metallic constituents, particularly vanadium. In oil-fired gas turbines, the ash may build up on the blades, causing imbalance of the rotors and, in addition, severe corrosion. In industrial boilers, the ash residue is responsible for severe damage to boiler tubes and to the refractory brickwork (15).4 Through study of the chemical constitution of the various metalloporphyrins found in petroleum, much can be learned concerning the origin, migration, and history of crude oils.

Jan 1, 1961

By H. Shaw

GRAVITATIONAL measurements made by means of the Eötvös torsion balance over any area enable a representation to be obtained of the total gravitational effects over the surface of that area arising from the combination of all sources of gravitational disturbance. The investigation of gravitational anomalies occurring in the upper layers of the earth's crust, in this way, has been attended with considerable success, and, especially in areas in which no undesirable disturbing factors were present, it has been possible to locate geological structures and mineral deposits with remarkable accuracy and also to delineate their confines and to indicate their depth below the surface with a certain amount of precision. Before this can be done successfully, however, it is necessary to determine the gravitational effect arising from all other extraneous .anomalies in order that these may be satisfactorily eliminated. Disturbing features giving rise to these gravitational anomalies may be divided into two classes, according to whether they are situated at or below the surface. The former are determined readily by a detailed leveling of the ground surface, and may be satisfactorily eliminated provided the specific gravity of the terrain material is known, but the latter are generally unknown, and can only be ascertained with difficulty. When, therefore, the observations obtained by means of the Eötvös torsion balance have been corrected for all surface irregularities, known as terrain and topographical effects, there remain residual gravitational values which are due entirely to subterranean conditions. The task of interpreting these results consists in disentangling the various subsurface anomalies, and subsequently in computing and recombining the effects of these various masses in order to verify the interpretation. When the gravitational anomalies are due to large and comparatively simple structures it is a matter of little difficulty to arrive at a satisfactory interpretation of the subterranean conditions, but in more complex areas, where the geological conditions are more complicated and several irregular features exist, the process of disentangling the various constituents of the complex mass arrangement is more difficult and requires the expenditure of considerable time and labor.

Jan 1, 1929

By Jaime Adasme, Héctor González, Benjamín Celada

"INTRODUCTION Santiago de Chile is a 7 million inhabitant city which has a 103 Km long subway network operated since 1975 by Metro S.A. This network is used on a daily basis by 2.3 million people. In 2012 Metro S.A. started the biggest enlargement of the network in its history, through the design and construction of the new Line 3 (21.7 Km) and Line 6 (16.5 Km). The detailed engineering contract for civil underground works of Line 6 (L6) was awarded to the Consortium integrated by ZAÑARTU Ingenieros Consultores and GEOCONTROL S.A., in which Geocontrol was in charge of the design of 11 stations and 14.5 Km of tunnel. L6 crosses L3 in Ñuble and Ñuñoa Station, L2 at Franklin Station and ends, intersecting L1, at Los Leones Station as shown in Figure 1. LOS LEONES STATION DESIGN Location and Characteristics Los Leones Station is placed at the North end of the L6, next to the same named station of the L1 and it has four construction units, as is shown in Figure 2: I. Access Shaft (49 m x 47 m). II. Access Gallery (34 m long). III. Station Tunnel (120 m long). IV. Connection Gallery with L1 (104 m long). A singular feature of Los Leones is that the western section of the station tunnel, built from the access gallery, is located below an underground parking lot which is located in Providencia Avenue, as shown in Figure 3. It is important to highlight that the distance between the vault of Los Leones Station Tunnel and the foundations of the underground parking lot is only 6 m."

Jan 1, 2016

By Sirayanone S, Rashad MZ

An important problem occurring in the iron and steel industry of Egypt is the presence of manganese oxide and chlorine with different percentages in the Bahariya Iron Ore Deposit, Western Desert, Egypt. In this work we used a geostatistical method known as the Volume- Variance Relationship to predict grade fluctua- tions of Fe% , Mn% and Cl% in the ore after blasting a certain volume from the ore deposit, on the other hand, if we have a certain limit for each of these chemical components, we can select the bench blasting dimension to give these limits.

Jan 1, 1986

By Julian Johnson

The effect of changing redox potential (Eh) on the high temperature sulfuric acid leaching of Western Australian dry-land nickel laterite ores has been investigated. In particular, the effect of added reductant (sulfur, sodium sulfite) or oxidant (potassium chromate) on Eh, leaching kinetics, metal extractions, acid utilisation and leach residues has been determined. Three separate ores - nonhonitic ores from Murrin Mumn and Bulong, and limonitic ore from Cawse - were used in the study. Sulfur addition varied from 0 to 7.8 kg/t ore. The total acid loading was kept constant at 430 kg/t (Murrin Murrin ore) and 330 kglt (Cawse ore), whilst acid loading for Bulong ore was varied according to the presence of either reductant or oxidant. The extraction of both nickel and cobalt from limonite ore remained unaffected when small amounts of sulfkr were added, but addition of even small amounts of reductant to nontronitic ore decreased both nickel and cobalt extraction. Increased manganese and iron dissolution were observed as the levels of reductant increased, accompanied by a decrease in chromium dissolution. As the iron dissolution increased, free acidity decreased, with a subsequent decrease in nickel extraction. In contrast, addition of oxidant lead to reduced iron and manganese dissolution and slower extraction of nickel and cobalt. Keywords: Limonite, Nonhonite, Eh, Nickel Extraction

Jan 1, 2004