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By J. A. Venter

Mineralogical studies indicate the Pt-Pd-Bi-Te class to react poorly on the flotation stimuli and indications are that these minerals are slow floaters. However, recent studies performed on a number of minerals from this class indicated strong interactions with potassium ethyl xanthate resulting in the formation of dixanthogen (only one of several xanthate species). The poor flotation response is not a result of poor interaction of xanthate with the surface. It is proposed that the oxidation products of sulfides in the process water interact with the PGM surface. To test this, the effect of thiosulfate (an important oxidation product of sulfides) was investigated by employing electrochemical measurements and FTIR spectroscopy. The electrochemical investigations indicate no strong effect of thiosulfate on the interaction of xanthate with the minerals surface as well as the reduction of oxygenthiosulfate is likely not responsible for the poor flotation response of these minerals in industrial plants.

Jan 1, 2014

By Thomas M. Keevin, Gregory L. Hempen

Accurate assessment of blasting near an object (organism or structure) requires recording of the damage parameter for low-valued scaled distances. Seismograph recordings of particle velocity are a well established, common procedure for land-based blasting. Similarly, pressure recording of the absolute waveform needs to be a more common procedure for sensitive, underwater resources.

Jan 1, 1997

By Shulin Xu, Moreno Pescara, Nicola Avagnina, Piergiorgio Grasso

The Roreto Tunnel is a shallow, twin-bore, road tunnel on the connection between the A6 and the A21 motorway in NW Italy. The challenges faced the design and construction of this tunnel derive from 1) the presence of groundwater, both phreatic and artesian; 2) excavation in loose and/or little cohesive materials; 3) excavation in cohesive materials containing water-saturated, sand lenses; and 4) surface constraints due to the urban environment. In this paper, these problems are examined and the rationale led to the optimum design choices and construction solutions explained. The experience should be useful to others when tunneling in similar situations.

Jan 1, 2003

By LeRoy R. Curwick

This Bureau of Mines report presents the results of a study conducted to assess the domestic availability of chromium from superalloy and cast heat- and corrosion-resistant alloy scrap material. Six alloy classes included in this survey were investment cast, hardfacing, and wrought nickel- and cobalt-base alloys, wrought nickel-iron-base alloys, and heat- and corrosion-resistant alloy castings. Data were collected for 1976 on metallic scrap generation, use patterns, and production practices for these alloy producing and using industries. A model was developed that allowed an assessment of the materials flow circuits within the industries that produce these alloys. The types, amounts, sources, secondary products, and ultimate destinations of chromium- containing metallic scrap for the six alloy classes were determined. Regarding the overall recycling efficiency of these alloy producing and using industries, of the 580.9 million pounds of scrap generated from these six alloy classes in 1976, about 72 percent (416.8 million pounds) was remelted by the same alloy-producing industries, about 18 percent (104.9 million pounds) was downgraded into stainless and low-alloy steels, about 3 percent (19.7 million pounds) was exported, and about 7 percent (39.5 million pounds) was lost through landfill or other disposal or service wastage. The lost material is primarily contaminated oxides for which recovery is currently uneconomic. However, the 124.6 million pounds of scrap material downgraded or exported in 197b contained potentially recoverable critical strategic elements. The amount of scrap material lost to the six alloy-producing industries in this manner contained 22.1 million pounds of chromium, 53.4 million pounds of nickel, 5.9 million pounds of cobalt, 35.9 million pounds of iron, and 7.3 million pounds of other alloying elements.

Jan 1, 1980

By Mike Ounpuu

"Locked cycle testing has become more common practice in the last 10 years. Reasons vary from a desire to avoid pilot plant testing, demand for more variability testing within deposits, and perhaps most importantly, a request from the financial institutions who invariably finance many of the projects. Surprisingly, many people don’t understand locked cycle testing, analysis and balancing. This paper provides a brief overview of locked cycle testing, and then progresses into a more detailed discussion on the analysis and balancing of locked cycle test data. The paper endeavors to educate CMP personnel on how to determine if the test was good and if a reasonable metallurgical projection was made. The paper uses case studies to illustrate the key points.INTRODUCTIONA locked cycle test is a repetitive batch used to simulate a continuous circuit. The basic procedure has a complete batch test performed in the first cycle which is then followed by similar batch tests which have “intermediate” material from the previous cycle added to the appropriate location in the current cycle. These batch tests, or cycles, are continued in this iterative manner for an arbitrary number of cycles. The final products from each cycle, i.e. final concentrate and final tailings, are filtered and thus removed from further processing. At the end of the test, all the products, final and intermediate, are dried, weighed and subjected to chemical analysis. The test is balanced and a metallurgical projection is made.This description can be found in many of our classical textbooks for the mineral engineer 1, 2, 3,4. Unfortunately, none of these textbooks provide any discussion beyond the basic procedure. Often, they provide comments such as in Taggart’ where he states; “It is questionable whether in any case it approximates mill results any more closely than the standard batch test”. It is truly surprising that our classic textbooks promote that locked cycle tests are more art than science, and suggest that they can be of dubious value. None of the textbooks provide meaningful insight or discussion in how to assess:"

Jan 1, 2001

By J. Font

New approaches for the fire refining process of blister copper have been carried out at the Codelco Norte Smelter. These have been mainly focused on modification and improvement of the process configuration based in fluid-dynamic and metallurgical studies of the oxidation and impurity treatment stages. This paper presents the results of the laboratory simulations and industrial tests performed in the 250 t anode furnace, evaluating two different process configurations: ? Bottom Bath Agitation System in the vessel during the oxidation stage, ? Dual Flux Injection System during the impurity treatment stage. The results show the possibilities of effective removal of high content of sulfur from the melt during the oxidation stage by using the bottom bath agitation. The use of the dual injection system demonstrated the significant improvement in the removal efficiency of impurities. Cu2007

Jan 1, 2007

By R. J. Dippenaar, W. H. Van Niekerk

The relationships between coal properties, the strength of coke, and the performance of a blast furnace were investigated by means of correlation studies, and a linear programming model was developed for the prediction of a coal blend based on these relationships. The unique feature of this approach is that it utilizes a knowledge of the minimum blast-furnace coke requirements, rather than the maximum attainable coke quality. The model predicts the least expensive coal blend that would still comply with the minimum coke-quality requirements of blast furnace. The study also confirms the existence of a relationship between the rank and caking parameters of coal, and the hot strength of coke. The effect of coke-oven operating parameters on coke quality is also discussed.

Jan 1, 1991

By J. Leinart

As is readily apparent, the reliability of the early-stage costs estimated for any mining project are critical to the viability of that project. An estimate too high might leave a potentially profitable deposit undeveloped or worse yet, available to a competitor. One too low might waste investment dollars in a project not yet economically ripe. There are two aspects critical to any estimate: 1. The cost data used to represent the values of the wages, salaries, supplies, and equipment. 2. The design used to determine the engineering parameters upon which the above estimated values are based. Given that all of the information contained in Mining Cost Service is provided by suppliers, equipment manufacturers and mine operators, one wonders why there is any question as to the reliability of cost estimates developed using this information. Given that it is all actual (as opposed to statistically derived) data, where do the problems with estimate reliability lie and what is the impact of the data on that reliability? The following presents a series of analyses designed to assess the reliability of the cost estimating process. Both the actual cost data and the engineering parameters upon which they are based are examined in an attempt to quantify and understand the importance of each. While several sources of cost information are available (Means, Richardson, Primedia?s Equipment Watch, and individual suppliers and manufacturers), the following rely solely on data contained in InfoMine USA, Inc?s, Mining Cost Service and in its Sherpa Mine Cost Estimating Software.

Feb 27, 2013

Council for 2004/2005 President F.M.G. Egerton President-elect W.H. van Niekerk Vice-presidents Senior R.P.H. Willis Junior R.G.B. Pickering Immediate Past-president T.R. Stacey Honorary Treasurer J.A. Cruise

Jan 1, 2005

Gold cyanide equilibrium adsorption isotherms in the loading range typical of operating carbon-in-pulp/carbon-in-leach plants have been established and the effect of various cations and the presence of copper cyanide species quantified. It was found that the equilibrium loading of gold was enhanced by the presence of sodium or calcium, with calcium having an order of magnitude stronger effect. The presence of copper has an adverse effect on the equilibrium loading of gold. A unified model was developed to predict the effect of sodium and calcium concentrations in solution and the competitive carbon adsorption of copper on the equilibrium loading of gold on carbon. A satisfactory agreement between the measured gold equilibrium loadings and the model results was obtained over a wide range of solution conditions.

Jan 1, 2010

By George F. Swindle

This paper discusses a composite of two coal reserve studies, each of which made use of a computer-based modeling system to assist in an evaluation of multi-seam deposits. The model permitted simultaneous consideration of seam thickness, seam structure, overburden thickness, over-burden ratio, and quality parameters for sulphur content, ash content, BTU values and the EPA Compliance index. The model is designed for use by a non-programmer, geologist or mining engineer. It enables the user, from a computer terminal in his office, to specify constraints (for example maximum um sulphur and maximum- ash content, minimum seam thickness and minimum BTU rating), and produces a report showing the volume, quality and location of that part of the total in place deposit satisfying all the constraints.

Jan 1, 1983

By M. Verri

The paper describes the design options available for the simultaneous production of liquid sulphur dioxide, via cryogenic condensation, and sulphuric acid in a sulphur-burning sulphuric acid plant. The impact of the operating conditions of the cryogenic condensation on plant capital and operating costs are discussed, with the main focus on the optimization of the most important economic and operative drivers of the non-ferrous mining industry, such as energy efficiency, reliability, and availability. A case history relevant to an integrated sulphurburning plant producing liquid sulphur dioxide and sulphuric acid, recently started up in the Democratic Republic of Congo, is described. Keywords sulphur burning, sulphuric acid, liquid SO2, cryogenic SO2 condensation, liquid sulphur dioxide, sulphur dioxide.

Aug 1, 2013

By Jeffrey L. Pagnutti

Train derailment can lead to loss of capital, damage to the environment, and loss of life. Machinery condition monitoring techniques can be used to develop a structural health monitoring system for railway track to detect faults at the incipient stage, before catastrophic failure occurs. This study uses vibration measurements from a novel material haulage unit to develop a decision support system for railway track maintenance. A variety of feature sets and classifiers were compared to determine the optimal configuration for fault detection. The results highlight the shortcomings and advantages of certain methods and describe the process in which the optimal result was obtained. The Parzen data descriptor paired with a refined statistical feature set performed the task of fault detection with less than five percent false positive and false negative classification error. Overall, the outcome of these experiments indicated that condition monitoring of railway systems is a promising approach for fault detection and has the potential to avoid catastrophic failure.

May 1, 2013

By A. B. Kinzel

IT is with sincere appreciation and a deep sense of responsibility that I accept the honor of delivering the Howe Memorial Lecture. In our time metallurgical research has delved into phenomena ever more complex in character, so that much of this work must be done by organized teams. We, of the Union Carbide and Carbon Research Laboratories and the Electro Metallurgical Co., are truly a team and the lecture which is to follow is due largely to a few of the outstanding members of that team here cited and well known to you in their own right: John Lamont, whose work deserves special recognition, Walter Crafts, William Forgeng, William Binder, Robert Fowler, and David Swan. Thus it is a fitting pleasure to accept this honor for the research institution which I represent. Henry Marion Howe was truly inspirational and his breadth of view was such that he could use either the method of rigid proof or implied mechanism to further the broad understanding. But perhaps his outstanding characteristic was his sound judgment and his ability to weigh observations. The following is replete with observations and judgment as to their implication. We would like to feel that it is the type of dissertation which Howe, himself, would have enjoyed. Chromium carbides in stainless steel have, in a sense, been a key to the progress of the stainless steel industry. Brearley's first stainless steel, containing approximately 0.30 pct C, was successful because it differed from previous Fe-Cr alloys in that the carbides were present in such amount and form as to provide the stainless and cutting properties. Again, the 12 pct Cr die steels with a carbon content of 1.5 pct or more achieved their properties by virtue of the form and distribution of the chromium carbides. In the straight chromium steels with from 12 to 25 pct Cr, chromium carbide amount and distribution are once more the determinants with respect to physical properties and corrosion resistance. In each of the cases just cited the role of the carbide is in essence similar to that of iron carbide in carbon steel and this story is so well known that we need not dwell on it. In the austenitic stainless steels, the chromium carbide plays only a minor positive role with respect to mechanical properties, and for corrosion resistance the objective is to achieve maximum homogeneity. Thus the tendency has been to ever lower the carbon and correlatively the chromium carbide content of the austenitic steels. Today stainless steels with carbon less than 0.03 pct are beginning to find their true place, and this is being aided in major degree by our Company's introduction of a new type of ferrochromium having negligible carbon. The role of carbon in these austenitic steels has long been recognized, and a truly enormous amount of research has been devoted to the subject. Much has been learned about corrosion resistance, but the attack on the problem from the point of view of carbide precipitation and the nature thereof has left much to be understood. Because of its fundamental importance to the future of stainless steels, further study of the mechanism of carbide formation in austenitic steels is of interest. In the 18-8 Cr-Ni steels, which are typical of the austenitic class of steel, carbon is soluble in the aus-tenite to the extent of approximately 0.15 pct at 1832°F (1000°C). The solubility becomes less with decreasing temperature, so that at 1652°F (900°C) the solubility limit is approximately 0.06 pct, at 1472°F (800°C) it is about 0.03 pct, and at 932°F (500°C) it is approximately 0.01 pct. Obviously this is the ideal situation for the classical precipitation phenomenon. It is true that, in a sense, 18-8 austenite resulting from annealing is in a metastable state, and the phenomenon of ferritic precipitation from this austenite should be considered. However, in a so-called fully austenitic 18-8 steel this is secondary with respect to the carbides and can be neglected. A wide variety of chromium carbides is known. Only one chromium carbide, Cr,,C,,, frequently referred to as Cr,C, has been found in unmodified low carbon 18-8 steel. This, fortunately, simplifies the study of the precipitation phenomena. For this study an A.I.S.I. type 304 stainless steel of commercial quality was selected. Analysis showed C 0.07 pct, Mn 0.49 pct, Si 0.33 pct, Ni 9.34 pct, Cr 18.91 pct, and N 0.033 pct. As expected with this composition the steel was homogeneous after annealing except for a few pools of ferrite, which were disregarded in that their location was not coincident with subsequent carbide precipitation areas. On corrosion testing the steel was normal and typical of good commercial quality. Specimens 1/2xlx4 in. were annealed and subjected to precipitation heat treatment for 100 hr at 100" temperature intervals from 1000° to 1500°F and for ten selected intervals ranging from 5 min to 64 hr at 1300°F. These blocks were then cut into small pieces for metallographic studies. The first problem

Jan 1, 1953

By Carl G. Schwenk

Rocks of the Precambrian Shield of Rusk County, Wis., were recognized as a favorable host for volcanogenic base metal deposits by personnel of Bear Creek Mining Co. Most of the county is covered by a thick layer of glacial drift: consequently, geophysical techniques played a prominent role in the exploration program conceived and initiated there in 1966. The original work on three Precambrian exposures was followed by an airborne electromagnetic survey and subsequent ground follow-up. A geophysical evaluation of air-borne anomaly F-22 defined a target which was interpreted as a massive sulfide body. Numerous potential field and electrical tools were utilized to describe the geometry and physical properties of the target. Drilling confirmed the massive sulfide interpretation and eztentually outlined a 6 million-ton copper deposit.

Jan 1, 1977

By J. F. Myers, F. M. Lewis

The paper reports the development of a large, slow speed ball mill closed circuited with a hvdro-scillator. This increased grinding efficiency 28 pct over conventional units. AS the title indicates, this is a progress report for the first year of experimental operation of a relatively large diameter, slow speed ball mill with 1-in. balls, with and without various classifiers, and including a hydroscillator. Several years ago the authors came to the conclusion that if any further progress were to be made in our flotation process, an understanding of the chemical and physical reactions and the control thereof, in the grinding circuit, was essential. It may be stated, at this point, that the preparation of a correct feed for the flotation process is still the number one objective of our grinding studies. This progress report deals with grinding "per se," and not with the chemical and physical reactions as the result of grinding. Prior to this time we had taken the naive position, that since grinding had been practiced by the industry for some fifty years or more, it had been well exploited and developed by a host of investigators. Consequently, we had given the matter only superficial attention. At the start of our study, we were aware of the fact that some difference in opinion existed, but we were not prepared for the controversial evidence that developed nor for the extent to which the experts differed in their viewpoints. There seemed nothing else to do but to tour the continent and decide for ourselves what was right and what was wrong, read all the published literature and visit with anyone who had ideas about the matter. This we did over the next few ensuing years. Since our study has met with some measure of success, we report, herewith, these data that ultimately they may be of help to other investigators. In 1944 it became necessary to increase our grinding capacity and at the same time to grind the sulphide portion a little finer. This provided the impetus to put our ideas into effect. As has been previously described, our grinding flowsheet at that time consisted of a 6x12 rod mill, followed by two 5x10 ft, and one 6x12 ft trunnion overflow ball mills, with conventional rake classifiers. Naturally, we first considered all the possibilities of altering or adding to the existing equipment. It became evident that if any appreciable increase in grinding efficiency could be obtained, it would pay to scrap the existing small mills and classifiers and install one big mill with adequate classification. Trying to determine just how much more efficient a big mill could be, in which were incorporated all

Jan 1, 1951

By Paul W. Jeran

Subsidence was monitored by the U.S. Bureau of Mines over the ends of longwall panels operating in the Pittsburgh, Kittanning, and No. 2 Gas Coalbeds of the northern Appalachian Coal Basin. The final subsidence over the finishing ends of three panels in the Pittsburgh Coalbed are compared with the subsidence measured over the rib at these panels. The characteristics of subsidence are different. At Mine A, data over the start of a longwall panel shows similar characteristics to the subsidence measured over the rib. Subsidence over the fmishing ends of panels in the Kittanning and No.2 Gas Coalbeds are also different from the subsidence over the rib. The use of a subsidence prediction model based on data gathered over the rib of a panel will not yield accurate results if it is applied to the finishing end of a longwall panel. Acceptable results may be obtained along the centerline over the starting end of a panel.

Jan 1, 1991

By A. Singh, C. Da Corte

"South Africa possess the biggest fluorspar reserves in the world followed closely by China. In light of the current commodity downturn this paper explores the use of Dense Media Separation (DMS) as a coarse pre-concentration method for two fluorspar deposits located in South Africa in which the dominant gangue is carbonate present in the form of dolomite and calcite. Heavy Liquid Separation indicated that conventional pre-concentration of the drill core samples from both deposits would result in unacceptably high fluorite CaF2 losses. At a maximum CaF2 loss to floats of 5% the benefit of DMS would be economically marginal and difficult to justify as a conventional pre-concentrator. In light of cashflow constraints, a twin flowsheet was proposed for the sole purposes of upfront cash generation in which the majority (67-77%) of the CaF2 would report to a high grade flotation plant in 38-41% of the mass whilst the rejects would be stockpiled for flotation at a later stage. Considering the proposed twin flowsheet approach the high grade product split was achieved using DMS and this paper documents the challenges encountered and results achieved. INTRODUCTION Fluorspar is the commercial term for the mineral fluorite (calcium fluoride, CaF2). Worldwide production of fluorspar is dominated by four countries namely China, Mexico, Mongolia and South Africa. Although South Africa is the fourth largest producer, it has the largest fluorspar reserves closely followed by China (U.S. Geological Survey, 2017a). Fluorspar is broadly categorized into two grades namely acid grade also referred to as acidspar (>97% CaF2); and sub-acid grade (ceramic and metallurgical grade) commonly referred to as metspar (=97% CaF2). Acid grade fluorspar is used for the production of hydrofluoric acid (HF) which in turn is used for the manufacture of fluorocarbons and semi-conductors in the electronics industry; metal processing; the production of insecticides, herbicides and cleaning detergents, and the manufacture of uranium tetrafluoride used to concentrate the uranium isotope 235 for use as a nuclear fuel (British Geological Survey 2010; Miller 2001). Ceramic grade fluorspar (85-95% CaF2) is used in the ceramic industry as a flux and opacifier in the production of glass and enamels. Ceramic grade fluorspar is also used to make coatings for welding rods and as a flux in the steel industry. Metallurgical grade fluorspar (60-85% CaF2) is primarily used in the steel industry as flux to reduce the melting temperature and remove impurities in steel making. Similarly metallurgical grade fluorspar is also used as flux in cement production to reduce energy consumption (British Geological Survey 2010; Miller 2001)."

Jan 1, 2018

By Patrick R. Taylor

A non-transferred arc thermal plasma assisted cyclone reactor has been designed, built and operated to evaluate its use in vitrification of wastes. Simulated waste (liquid, slurry or fine particulate) is injected near the plasma flame, where nearly instantaneous dehydration and calcination reactions happen. A non-transferred arc plasma torch was attached tangentially to the cyclone and is utilized as both an enthalpy source and to provide the gas velocities required to generate the cyclonic gas flow patterns. The closed top cyclone flow sends the solid particulates to the wall, where they are captured by a thin film of molten glass that is injected as a powder at a position lower in the reactor. The molten glass is then collected in a crucible. The feasibility of simulant injection directly into the flame zone and its effect on electrode lifetimes has been studied. Several candidate refractory systems have been evaluated for their suitability for extended use under the demanding conditions present in the cyclone reactor.

Jan 1, 2002

By Dalton Fowler

"Pressure vessels used in pressure leaching and pressure oxidation processes in the mining industry are often lined with acid resistant brick and membrane systems. Although the options available when it comes to selecting materials and linings designs for these vessels appear somewhat limited there are, nevertheless? several choices which must be made in order to successfully design, manufacture and construct these linings. These choices require careful evaluation of materials properties which include, among others, thermal conductivity, thermal expansion, chemical swell, and modulus of elasticity, as well as a variety of construction methods.Some of the options available, and some of the means of evaluating them objective of this discussion."

Jan 1, 1999