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By Sheng-hai Yang

The ultrafine, monodispersed, spherical cobalt powder has been fabricated by reducing cobalt hydroxide with glycol. It were investigated that the effect of NaOH concentration on the reaction rate and the effects of the concentration of cobalt hydroxide and surfactant on the morphology and particle size. The particles were characterized by the X-ray diffraction(XRD), scanning electron microscope(SEM), laser diffraction particle size analyzer and BET specific surface analyzer respectively. The XRD shows that the cobalt powders exist mostly in face centered cubic (fcc) structure, a little in simple hexagonal. The cobalt powders prepared at Co(OH)2150g/L, NaOH 40 g/L and surfactant 30g/L, its average particle size, specific surface area and cobalt content, were 0.88µm, 2.705m2/g. and more than 99.5% respectively.

Jan 1, 2006

A number of factors have resulted in the widespread use of computer simulation as a day to day tool in the mineral processing industry, as is the case in most engineering disciplines. A number of simulation packages, both steady-state and dynamic are now available commercially. The developers of such software face an enormous challenge in maintaining and improving the packages due to the complexity inherent in such systems. This problem known as the software crisis faces all developers of complex software. Object-oriented (OOP) and design is a methodology which has been developed to try and minimise this problem. The use of the OOP paradigm in the devlopment of simulation software for mineral processing systems is explored in this paper and it is found that OOP techniques have major benefits for the design and development of such software.

Jan 1, 1992

Analyze variably saturated flow in mining and other environmentally sensitive settings through the use of personal computer (PC) based software. The Problem There is an increasing need for mining companies to quantify water contaminants and their migration in the unsaturated zone. New and innovative computer models are therefore necessary to more accurately assess the potential impact of mining activities on groundwater resources and the environment. Applications for unsaturated flow modeling include (1) assessment of the impact of surface or underground extraction mining on flow conditions; (2) assessment of various hydrologic designs for resource recovery, such as in heap leaching or in situ leach mining; (3) assessment of the transport of conservative nonrcactive constituents in response to migration from spoil piles, or acid mine drainage; and (4) assessment of any combination of the above to facilitate expeditious permitting for mining operations. Since the mid 1970's there has been a proliferation of mathematical models and procedures for solving unsaturated now problems; however, few of these approaches have been integrated into software for public use. Commercially available unsaturated flow software models typically are limited to a single application and have restricted approaches. For example, computer codes that solve the unsaturated flow problem based on an analytic expression arc restricted to a simple geometric shape, homogeneous and isotropic materials, and provide only information regarding pressure and flow conditions in specified wells. The variably saturated computer codes that take advantage of the finite difference or finite element approach arc often restricted to either steady state or transient solutions; utilize one specific moisture-retention relationship and moisture-dependent permeability function; do not account for hysteresis; and are used with specific hardware such as a mainframe or work station. This restricts their use because they arc hard to interface, and arc often poorly documented, support dependent, and expensive. The mining community needs a flexible, more broadly based, variably saturated fluid flow simulator for the PC-platform to more accurately predict fluid movement in the mining environment.

Jan 1, 1991

By Takahiko Okura, Satoshi Okano, Hiromichi Takebe

"Fine zinc concentrates tend to become sticky when roasted in a fluidized-bed reactor. The oxidation of high-purity ZnS powders and ZnS concentrates with different particle sizes were studied in terms of phase changes and particle morphologies. The sample materials were directly oxidized to ZnO in a roasting process performed over 700°C. Zinc oxide particles with diameters less than 0.5 ìðé formed at 700°C; the particle size increased by grain growth at 900°C. The coarse ZnS concentrate formed the oxysulfate ZnO2ZnS04 when roasted at 700°C; the sulfate transformed to ZnO at higher temperature.1. IntroductionRoasting is an important step in zinc extractive metallurgy because more than 80% of the world's zinc is produced from zinc sulfide concentrates using the roast-leach-electrowinning [1,2]. Currently, zinc concentrates with a finer particle size distribution are used to enhance recovery rate. However, the finer zinc concentrates tend to produce a sticky calcine in a fluidized-bed roaster [3].The factors that affect products in a fluidized-bed roaster include particle size, contaminant, O2 and SO2 partial pressures, and the feeding method of ore to the roaster. This study examined roasting behavior of high-purity ZnS powders and ZnS concentrates with different particle sizes. The phase changes and particle morphologies of the calcine samples producted from theZnS powders were studied."

Jan 1, 2012

By Quast K. B, Newell R, Caterford J. H

The most common reason for gold-bearing deposits being refractory is the presence of sulphides; in many cases these interfering minerals contain arsenic, antimony, or other environmentally-sensitive elements. A number of processes have been proposed or developed for pre-oxidation of interfering minerals. In most cases developers have focussed on gold recovery and capital costs, with relatively little data on the deportment or form of these potentially harmful elements. This paper surveys recent work connected with pressure pre-oxidation processes. Data from pilot plant treatment of refractory gold materials, using the nitric acid Redox process, is discussed along with the attendant flowsheet and engineering implications. Four refractory gold-bearing materials have also been tested at the University of South Australia for arsenic and antimony deportments.

Jan 1, 1991

By Reza M. Rahman

The froth phase plays an important role in the flotation and upgrading of the final concentrate. At present, the techniques that have been used in the mineral industry to measure the froth recovery have limitations. The aim of this paper is to investigate the performance of the froth in an industrial flotation cell. A unique device has been developed which is capable of decoupling the froth zone from the pulp zone. It consists of two concentric tubes. The inner tube acts as a dropback collection chamber or catcher. The particles that detach from the froth phase fall directly into the catcher and are collected as froth dropback. The froth recovery measurements were carried out in a rougher bank of a copper concentrator treating sulphide minerals. The dropback device is designed so that it can be immersed into a plant size flotation cell and plant froth recovery measurements can be taken at any given time. During the experiments, the bubbles laden with valuable mineral particles entered the device from the plant flotation cell, subsequently rising to form a froth layer at the top of the device. The particles that detached from the froth zone were collected in the dropback collection chamber whereas the concentrate sample was collected by a launder. By drying, sizing and chemical analysis of the concentrate and dropback samples, the froth recovery, was estimated on the basis of the valuable component. The effect of air rate on froth recovery was also investigated. Keywords: flotation, froth, dropback, froth recovery

Sep 1, 2012

By Richard C. Banting

Excessive vibration is known to have an adverse affect on soft body tissue and operators of heavy mining equipment can be exposed to vibration that exceeds levels recommended in international guidelines (ISO 2631-1, for example). Research has found that many of the seat and suspension systems currently used in mine haul trucks and load haul dump vehicles are actually amplifying the vibration. This overview presentation will outline the current research being conducted at Laurentian University and the University of Western Ontario, and the roles of partners in rating the ability of a number of commonly used mine vehicle seats to isolate harmful vibration.

Oct 1, 2010

By J. Olsson

Introduction Stainless steel has by tradition been a common construction material for hydrometallurgy processes and the most common grades can be found amongst the ASTM 300-series, i.e. austenitic grades of type 304L, 316L and 317L. However, there are a number of new grades available today, which imply more cost effective solutions for those designing plants where good resistance to acids, containing the desired metal ions, often contaminated with chlorides and other halides, is the key issue. There are austenitic-ferritic or duplex grades having the same or even better corrosion resistance than the austenitic grades and approximately twice the strength, which enables design in thinner gauges, which in turn implies less weight and less cost. They have also excellent engineering properties, enabling fabrication of process equipment, machinery and different types of tanks. On top of that, they contain less nickel and molybdenum than their austenitic counterparts, which implies not only lower cost for alloying elements, but also a more stable price when considering the price fluctuations for these alloying elements during the last years. This paper describes briefly the family of duplex stainless steel and it presents a number of relevant corrosion tests where duplex grades have been compared with austenitic grades. The results have in several cases been verified by in-plant exposures in zinc and copper production plants. It also describes applications and experience of duplex grades within a variety of hydrometallurgy plants. Installations of highly alloyed austenitic grades will be described as well. The corrosion tests and service experience reported cover hydrometallurgical processes based on sulphuric acid.

Jan 1, 2007

By J. J. Bodmer

In 1855, Franz Uchatius patented, in England, his process of manufacturing cast steel. The first experiments, on a practical scale, were made at the Ebbw Vale Iron Works, Monmouthshire. The charge consisted of a mixture of cast iron with about 20 per cent. of a pure iron ore, and with or without other ingredients. In order to obtain the cast iron in a subdivided condition, Uchatius granulated molten pig-metal by running it into water, which during the operation was kept well agitated, and found that "the finer the iron is granulated, the softer will be the resulting steel." The writer is not aware that granulated iron has been used practically, otherwise than in the above-named process; and until 1866 no other process of subdividing iron than by granulation was known. In April, 1866, an English patent was obtained by the writer for subdividing blast-furnace and other slags and metals in a molten condition, by passing the same through one or more pairs of rolls. In reference to iron the idea was, in following up the direction pointed out by the Uchatius process, to obtain better results in the puddling process by means of a thorough amalgamation (not simply a mixture) of the iron with the oxides and other ingredients in the charge itself. Experiments were made. A quantity of iron direct from the blastfurnace was subdivided (or laminated) by passing it through a pair of plain rolls. The rolls were hollow, and water was made to pass through them to keep them sufficiently cool. Without giving differential speed to the rolls, sheets were obtained about one-sixteenth inches thick, and from about one hundred square inches surface, downwards. With differential speed, the iron falls from the rolls in

By S. J. Pearce

One phase of the work of the Bureau of Mines in health and safety is promotion of the use of safe, satisfactory, and reliable respiratory-protective devices. To insure that such devices will be available, the Bureau has established schedules of minimum requirements for self-contained breathing apparatus,3/ gas masks,4/ supplied-air respirators (hose masks, air-line respirators, and abrasive-blasting helmets, hoods, or masks),5/ dispersoid (dust, fume, and mist) respirators,6/ and nonemergency gas respirators (chemical-cartridge respirators).7/ Approval tests of self-contained breathing apparatus are conducted under the supervision of mining engineers of the Accident Prevention and Health Division} Region VIII; approval tests of other types of respiratory-protective devices are conducted by the Health Branch.

Jan 1, 1952

By M-C. Lee, Shomaker, R. Turcotte, B. Short

This research program was undertaken to better understand the factors causing abnormal NOx fumes generation from blasting operations in surface coal mining. More specifically, unusual quantities of nitrogen dioxide and nitric oxide have been observed at several surface coal mines in the Powder River Basin, Wyoming. All these mining operations have several points in common: (i) Blasting is performed using gravity loaded emulsions or emulsion/ANFO blends (ii) Unusual NOx (Oxides of Nitrogen) emissions are observed mostly when blasting is conducted in the overburden as opposed to the coal seam itself (iii) The overburden consists of very weakly consolidated ground strata, providing relatively weak confinement conditions for the explosives, and (iv) Significant ground water is observed.

Jan 1, 2002

By J. J. Schwoebel

Resource Enterprises Inc. (REI) is exploiting the coalbed gas resource by working in unison with active underground mining operations. At REZ7s pilot project at the Soldier Canyon mine, Carbon County, UT, RE1 has drilled nearly 15.25 km (50,000 ft) of horizontal in-seam and slant boreholes during the initial two years of drilling activity. Produced gas has been sold to a natural gas transmission company on a continuous basis since mid 1983.

Jan 1, 1988

By Anand Kumar, Pradeep kumar Jha, Suman Kant, Pradeep Kumar

"It has been a major challenge to reduce the intermixed grade formation during ladle change-over operation in continuous casting process of tundish steelmaking. The F-curve generated by step input of the tracer (new grade steel) tells about the intermixed grade amount for different grade specifications. Use of flow modifiers is beneficial in reducing the intermixed grade because of the change in slope (in different time zones) and position of the F-curve due to their placement at tundish bottom. Present study aims at investigating the role of dam placed before the outlet in a multi-strand tundish with reference to the slope behavior of F-curve in different time zones during the teeming operation plays an important role in determining the intermixed amount.Introduction In Continuous casting process, the old grade steel remaining in the tundish (reservoir between ladle and mould) from the old ladle gets mixed with new grade steel from new ladle and leads to intermixed grade which is considered to be of inferior quality. Although formation of intermixed grade is inevitable with the sequential method of casting, its amount can be controlled by changing the flow behavior of steel inside the steel. Intermixing in a slab caster tundish was simulated using 3-D numerical model based on k-å turbulence equation and compared their result with that of water model experiment Yeh and Hwang [1]. Huang and Thomas [2] reported that quantity of residual fluid in tundish affects the composition distribution in the transitional slab and thus the intermixed length. Huang and Thomas [3] developed three sub models to predict mixing in tundish, liquid core of strand and solidification. Thomas [4] developed a one dimensional model to simulate the final composition distributions in slab caster of continuous casting and investigated the effect of process variables on the intermixing. Alizadeh mehdi et al., [5] simulated of the intermixing phenomenon for slab casting for three different sub models. Goldschmidt et al. [6] developed a numerical model that predicted the location of the intermixed steel in a four line round caster. Lan and Khodadadi [7] studied for the transient fluid flow of liquid steel, heat transfer and solidification during the flying tundish change process. Cho and Kim [8] developed a mixing model to predict the outlet concentration of the tundish during grade transition. Most of the work reported in the literature has dealt with intermixing in slab caster tundish. Billet caster units are more often being used by steel industries due to growing demand of billets. The multiple outlets lead to varying degree of intermixing with time owing to their different distance (location) from the inlet. Use of flow modifier to minimize the intermixed amount, however has also not been discussed in detail so far. Further no work has been reported regarding effect of slope of F-curves obtained through different outlets on intermixing. Hence keeping these objectives in mind attempt has been made by authors to analyze the slope of Fcurves after dividing them into three different time zones and the effect of these time zones on intermixing."

Jan 1, 2012

By Robert K. Linn

The New ldria Mining District is in the southern part of the Diablo mountains of the California Coast Range, 140 miles southeast of San Francisco. The district, noted primarily for quicksilver, also has become important recently as a producer of short-fiber chrysotile asbestos. Between 1853 and 1966, the New Idria district produced 568,092 flasks of quicksilver valued at about $55,600,000, 99 per cent of which was recovered from one deposit, the New Idria mine. In 1944, the district was ranked third in all-time production of North American quicksilver districts, and, since that time, the New Idria mine produced an additional 129,045 flasks, placing the district and the New Idria mine second in all-time production. The major structure of the region is the northwest-trending Coalinga anticline consisting of an asymmetric dome of sedimentary beds ranging in age from Jurassic to Quaternary and marked at its northwest end by an oval body of sheared serpentine 14 miles long by 4 miles wide. The serpentine core, rimmed by Franciscan sandstone of probable Jurassic age, was uplifted in stages between Jurassic and Quaternary time and was intruded along a ring of faults into beds of the Panoche Formation of upper Cretaceous age. The core of serpentine and Franciscan rocks is the locus of about 20 quicksilver mines that rim the faultbounded core and lie within the serpentine mass. The host rock of the most productive deposits is altered Panoche shale and sandstone that lies intermittently along the perimeter of the core. Deposits of the New Idria group of mines and those of a few other small mines lie along the northeast contact in the footwall of the New ldria thrust fault, and a few others occur on steep normal faults around the south and southwest. The chief ore mineral in all quicksilver mines is cinnabar, but minor amounts of metacinnabar and native mercury are found in some of the mines. Ore shoots were deposited in fracture zones and stockworks in altered Panoche shale and sandstone and in definite fissure veins in Franciscan sandstone. Rocks made highly amenable to fracturing by hydrothermal alteration were fractured extensively by late faults. The resulting fracture zones, located along the late faults and at changes in strike or dip of the hanging wall or footwall, are the principal controls of most ore shoots. The largest and richest ore shoots are those of the New Idria mine. The major ore bodies occur in fractured shale and sandstone beneath the New ldria thrust fault at its junction with major tear faults.

Jan 1, 1968

Difficult ground conditions in the area planned for placement of vent rises to the surface at the Porgera Goldmine led engineers directing the project to chose blind shaft boring methods of shaft construction from the available alternatives. Zeni Drilling Pty Ltd was first contracted in 1988 to install a group of three closely-spaced, steel lined shafts. The success of these led to an order for a fourth hole in the same group followed by two more, less than a kilometre. away, under a separate contract in 1992. All of the shafts were completed on.schedule to within one day. The only significant difficulty arose during commencement of the last shaft when the strata collapsed trapping the drilling tools and jeopardising the stability of the surface collar pad. The situation was corrected by innovative lining techniques and the project went on to finish on schedule. This paper discusses the application of various technologies associated with the project including aspects of geotechnical input, drilling fluid chemistry, mining engineering and logistics.

Jan 1, 1993

Performance testing is often used by project owners and financiers to provide protection from, or assessment of, technical aspects of project design, procurement, construction and commissioning. The performance tests can range from comprehensive performance warranties relating to process performance and production in the case of lump sum turn key (LSTK) projects to less onerous demonstration tests for cost reimbursable contracts. This paper will discuss performance testing from both the contractor's and owner's perspectives and focuses on: ? when performance tests are required, ? what type of performance test/warranty is optimum for each type of project, and ? how project performance should be evaluated. The requirement for performance testing can be driven by the project financiers, particularly in the case of smaller resource development companies. In such cases, differentiation between owner's risk and contractor's risk can become contentious. At the other end of the spectrum, larger mining houses may choose to heavily influence the engineering and design process with the contractor supplying services on a reimbursable basis. In that case, the performance testing process is often limited to demonstration tests that validate performance for the owner's corporate governance requirements. This paper was prepared due to the lack of published benchmarking of performance testing and the resultant differences in expectations between a contractor and a project owner that often surface late in the contract negotiation process. The paper provides a checklist of requirements for both the owner and the contractor that may be used to provide `common purpose' early in the contract negotiation process.

Jan 1, 2007

By R. Floyd Farris

A method is presented for determining minimum waiting-on-cement time, which takes into account the differences that exist between types and brands of cements and such individual well conditions as depth, temperature, and pressure. The basis for the method was determined by laboratory tests. Being a laboratory development, several steps were required to prove its merit. The first step consisted of laboratory tests designed to determine the minimum cement strength required in wells. Basis was found for setting a minimum value of 8 Ib. per sq. in. tensile strength. Next, it was shown by laboratory tests that the time to 8 Ib. per sq. in. tensile strength may be expressed as a function of consistometer stirring time to loo "poises," the approximate relation being "the time to 8 Ib. per sq. in. tensile strength equals the time to I00 'poises' times three." Next, it was shown that the time of maximum temperature development in cement slurries, due to heat of hydration, is also related to consistometer stirring time to loo poises, but only by a factor of approximately two. It was shown also that the shut-in casing pressure will build up after cement is placed and register a maximum pressure at approximately the same time the slurry down the hole attains maximum temperature. From this and the relationships listed above, the general rule was established that minimum waiting-on-cement time (time to 8 Ib. per sq. in.) after casing cement jobs in any well is equal to the time when the shut-in casing pressure reaches a maximum, as measured from the initial mixing of cement, times a factor of 1.5. Cement plugs drilled in the field at the time prescribed by this formula were found to drill "firm to hard," thus confirming the laboratory tests. These tests prove that many of the present regulations for waiting on cement require a longer time than is absolutely necessary. Use of the method herein proposed offers the possibility of a saving of $1200 per well. Introduction The length of time allowed for cement to set after casing is determined either by state-wide rules, field rules, or self-imposed rules written into drilling contracts. In general, the time is dictated by experience and common practice. However, owing to differences in opinion and in experience of the various groups involved, waiting-on-cement time often varies from one area to the next. For example, an operator in an area where no rules exist may drill out of surface pipe at 24 to 36 hr., while another operator in another area may wait 48 hr. or more to comply with state or field rules, although the depth of the well, hole size, type of cement, and other data are identical. An even greater difference in practices will be found by making similar comparisons with respect to oil-string cement jobs. Differences in waiting-on-cement times of 36 to 48 hr. are common. Further complicating the picture is the rather common practice of allowing more waiting time for cement to set at the greater depths than is allowed at the shallow depths. This practice has existed for years in spite of the common knowl-edge1,2,3 that the temperature of the earth at the usual setting depths of surface

Jan 1, 1946

By John O. Galloway

"The year 1947 was a momentous one in the history of the petroleum industry in Canada. It was in that year that Imperial Oil Limited made its discovery at Leduc, the forerunner of other discoveries, large and small, and the spark wl1ich started a most intensive exploration and development programme there.If, to use boxing parlance, Leduc was the first blow of a one-two combination which left doubting Thomases groggy, then Redwater was the number two blow which achieved the knockout. The oil industry's exploration leaders did about-face without delay and the rush of oil operators of all classifications to western Canada began. It is still continuing, and the influx of capital which the operators have brought in and are bringing in has a bouyant effect upon the over-all economy. The boom is on, but it is a sound one, and it is difficult to conceive that it will have anything but the most beneficial effect on Canada, and particularly western Canada.The petroleum industry is an important segment of the general economy. Its activities call for tremendous amounts of capital; its employees are well paid; it is a large customer for a wide range of products of other industries; its commodities are essential to the citizens and the nation.The industry is carried on by highly aggressive and independent groups and individuals, of which a small minority are integrated while the majority are relatively small operators engaged in only one or two phases of the business. Competition is the rule and, since the nature of the business is mass production, the industry is faced from time to time with serious problems, many of which are peculiar to it."

Jan 1, 1950

By Francis Martino

There are numerous techniques and predictive models used by geologists and mining engineers to define coal reserves and plan mines. The traditional reserve estimation methods commonly used include the isopach, triangular, polygonal, inverse-distance weighting, weighted-moving-average, and trend-surface methods. Geostatistically-based estimation techniques are now being examined by many geologists and mine planners as a superior alternative to these traditional methods. With today's coal mine development costs often exceeding $100 million, and power generation $1 billion, it is logical that a technique that can indicate the degree of confidence associated with a reserve estimate (fuel supply), and thus also the degree of risk, is highly desirable to the coal producer, the financiers, and those desiring to commit to coal utilization under short or long-term supply arrangements.

Jan 1, 1983

The use of scrapers in mining and earthmoving operations is not new; in fact they are one of the earliest methods of bulk earthmoving. A single machine, which can load, haul, and dump material with a minimum of ancillary support is a highly productive and cost-efficient method of earthmoving. In recent times scrapers have been unpopular due to perceived problems and operational limitations, but the last couple of years have seen a resurgence in the use of scrapers in the Bowen Basin as a primary prestripping tool. The main operational limitation of scrapers is the economic operating range. Maximum productivity and lowest cost per bcm is achieved on short leads, as the lead distance increases the cost per bcm quickly reaches and then overtakes that of an truck-excavator fleet. The geometry of a ætraditionalÆ coal mine does not readily allow short leads for prestrip fleets due to the nature of dragline stripping operations. The strip arrangement means that material has to be taken around the end of the pit, meaning a longer haul distance than the actual point-to-point distance between load and dump. This can be alleviated by using pit bridges, however these can cause spoil problems for draglines if not properly planned and have been avoided by many mines. Due to the economic haul distance limitation of scrapers, truck-excavator fleets have become the normal method utilised. Currently more geologically complex mines are opening up, which do not allow traditional down-dip strip mining to occur. Cross-dip mining methods allow for short leads between prestrip loading and dumping areas, hence scrapers and bulk doze are realistic alternatives to a truck-excavator fleet in the prestrip environment. Keeping the lead distance to a minimum a fleet of 657Æs can move material at a very low cost. The other main operational limitation of scrapers is the type of material that can be economically excavated. Hard material can lead to damage to the bowl, free-flowing sand will not readily stay in the bowl leading to reduced load factors. Ripping the material with a dozer prior to excavating can lead to improved loading time, and greatly reduced GET consumption. When considering scrapers for prestrip operations a number of things must be considered: is the lead distance within the economic haul distance? should twin power (push-pull) or single power (dozer pushed) scrapers be used? do I need to rip, what should I rip with? what ancillary support is required? is there another system already available on-site which is currently under utilised? This paper considers the parameters under which large twin power scrapers are the most effective way of undertaking prestrip operations.

Jan 1, 2003