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By R Badreddine, J Rose, L De Windt, P Chaurand, L Raimbault

Municipal solid waste of incineration (MSWI) bottom ashes are recycled as aggregates in civil engineering. These heterogeneous materials are composed of crystalline and glassy solid phases which contain trace metals, presenting a potential risk to the environment. Secondary ion mass spectrometry (SIMS) can provide quantitative chemical information, in particular the localisation of metals at trace level. Unstable glassy phases formed during incineration are present in relatively high proportions. Their analyses suggest a continuum between melilite-bearing glasses and dark glasses enriched in iron with abundant spinel aggregates. These primary glasses are enriched in zinc (~4500 ppm) but depleted in lead (~800 ppm) by comparison with the bulk chemical composition and reference materials. Heterogeneous cementing and encrusting admixtures on coarse grains are studied in a second step. SIMS imaging suggests a superposition of band zones including an intermediate layer enriched in iron oxyhydroxides and a superficial layer with calcium accumulation. A strong spatial association between lead and iron is systematically observed. Extended X-ray absorption fine structure (EXAFS) supports these observations by demonstrating that lead co-precipitation within iron oxyhydroxides, or sorption on their surfaces, may be a main containment process in the cementing and encrusting admixtures, whereas lead speciation is globally more complex in MSWI bottom ash.

Jan 1, 2008

By Mohammad Mainul Hoque, Linhan Ge, Ai Wang, Geoffrey Evans, Subhasish Mitra

"Dispersed phase interactions involving bubbles and particles in the turbulent environment play a significant role in the flotation process. The conventional collision models only account for the deterministic rather than the stochastic behavior of turbulenct flow. What the bubble-particle collisions would be like remains an open problem due to the complex nature of turbulent flow. To address this research question, the present study aims to quantify the bubble-particle collision efficiency incorporating turbulence using the computational method. Multiple solid particles were released to interact with a single stationary rigid bubble (non-deformable interface). Effect of particles Stokes number, turbulent intensity (TI) and integral length scale on the bubble-particle collision efficiency (Pc) was examined. Large Eddy Simulation method (LES) was used to compute the continuous phase. Fluctuating velocity required at the inlet boundary condition was derived from Gaussian energy spectrum to generate the upstream turbulence. Discrete Phase Model (DPM) is used to simulate particle trajectory. The characteristics of turbulent flow were analyzed through Energy spectrum and energy dissipation rate. The critical initial releasing radius of the annulus, where Pc equals zero, reaches up to 1.5(Rb+Rp) under high turbulent intensity (TI) 20.48% compared to 0.23(Rb+Rp) calculated from the traditional Pc model. Pc decreases as the distance of initial releasing annulus between bubble centre increases. Pc increases as particle Stokes number increase up to 0.66. The collision efficiency for particles of St less than 0.38 is higher under TI 11.78% compared to TI 4%.INTRODUCTION To increase mineral recovery, interactions between bubbles and particles are essential. All flotation devices achieve it through introducing some level of turbulence into the system by increasing specific energy dissipation rate. Figure 1 shows three different flotation equipment, traditional floatation cell, Concorde cell and cyclonic-static micro-bubble flotation column (FCSMC), with different turbulence generation mechanisms – impeller, down-flow liquid jet and pump recirculation, respectively."

Jan 1, 2018

By Martin S. Oudenhoven

This Bureau of Mines report presents the results of a microseismic study conducted in the Climax block cave mine at Climax, Colo. Rock noises created by caving were monitored and their sources located during a 3-month period. A planar array of seven accelerometers, located above the block of ore being caved, detected the rock noise. A computer was used to calculate the location of the microseismic activity, using a traveltime difference method. The accuracy of these locations was estimated to be ±20 feet. An analysis of the data taken during the recording period showed a concentration of microseismic events located in the wall of the cave panel. This concentration of events was found to occur in a "high-silica" geologic forma-tion that cut across the caving panel approximately 200 feet behind the undercut.

Jan 1, 1973

By J. A. Herbst, K. N. Han, P. B. Queneau, S. W. Asihene

As hydrometallurgy matures as a technology, more of its existing process knowledge will continue to be summarized in the form of detailed mathematical models. This development is happening at a time when major improvements in computer hardware have reduced the cost of computing. The opportunity then exists, through the solution of these process models, to design, control, and optimize hydrometallurgical plants on the basis of the physics and chemistry of its processes and less on empiricism. In this paper, a review of the current capabilities of sensors and phenomenological models for selected hydrometallurgical processes is presented. Future trends, in terms of the control and optimization of hydrometallurgical plants, are then explored. The possibility of simultaneously optimizing plant design and associated process control system performance is discussed.

Jan 1, 1993

By Robert I. Jaffee, Walter L. Finlay

IN the broad survey of the nonferrous' metallic elements contained in this book, the reader may well be impressed by the wide range of property combinations offered by the many metals and alloys the metallurgist has prepared since before Kubla Khan. The diversity is great and the overlap is considerable. It is particularly surprising, then, to find the latest structural metal new- comer designated by such extravagant terms as "Cinderella Metal," "Wonder Metal," "Miracle Metal," "The Metal of Tomorrow," "Dream Metal or Nightmare?" and "The Middleweight Champion of the Structural Metals." Of these and others, the most appropriate designation for the metal involved, titanium, appears to be that of The Middleweight Champion. Its intermediate density of 4.5 and elastic modulus of 16 million is a unique combination between the lower density and modulus of magnesium and aluminum and the higher density and modulus of copper, nickel, and iron. It is light, strong, ductile, and corrosion resistant. A chemical neighbor in group IV of the Periodic Table, zirconium, is similar to titanium in many respects but is appreciably denser, 6.5 instead of 4.5, less stiff and relatively much less abundant. On the other hand, the resistance of zirconium to acids and alkalies is better than that of titanium. Also, compensating for its higher density, lower stiffness, and somewhat lower strength level compared with titanium, zirconium has much better permeability to slow neutrons and is much more suitable as a material of construction for nuclear reactors.

Jan 1, 1953

By Doris M. Hyde

The economy of Belize continued to show a very slight but still positive growth during 1986. The gross domestic product (GDP) was estimated to have been about $164 million,2 almost the same as those of 1984 and 1985. Foreign investors looked favorably on Belize because it had remained isolated from the sometimes turbulent political and social strife elsewhere in Central America. Reportedly, in late 1986, Guatemala had decided not to pursue its claim to Belizean territory and to give full recognition to that country. Discussions were to be held regarding any matters of mutual concern. New investment possibilities were oriented toward agriculture or manufacturing endeavors. Except for some interest in petroleum exploration, the minerals sector remained limited to the quarrying of construction-related materials.

Jan 1, 1988

By F. Habashi

Japan was a closed society until 1853 when it was forced to open to the West. Mining, metallurgical, and geological education started there around 1861 when a graduate from Yale University in USA went to Japan to organize the first School of Mines. This was followed by other metallurgists from Great Britain, France, and Germany and thousands from other disciplines. The present report is a summary of the writer's first contact with Japanese metallurgists and his visits to a number of universities and research institutions in the past years.

Jan 1, 2012

By L. Keith Hudson

The purpose of this study is to provide data that demonstrates that the Alcoa flash calciner design can be used for the decomposition of AlCl3?6H2O to A1203. Heat and material valance data for calcination provides data on the partial pressure of HCl in the off-gases. Experimentally determined data for the HCl partial pressure, over solutions expected in producing alumina from clay by the hydrochloric acid process, show that HCl can be absorbed from the off-gases into process solutions to effect crystallization of AlCl3?6H2O.

Jan 1, 1979

By Marc C. Bétournay

Replacing diesel power in underground metal mining vehicles with available clean energy (e.g. hydrogen, lithium-ion batteries) is now a priority due to worker health issues, the increasing price of diesel, ventilation costs and air quality. Hydrogen fuel cells are a known and broadly applied power technology. They have been the focus of a dedicated research program to carry our proof of concept projects as well as regulatory developments for mining application. However, hydrogen remains a demanding energy vector to use in confined, underground applications. Standardization and safety considerations are being addressed in the industrial consortium Hydrogen Mine Introduction Initiative (HMII). Research projects are being carried out to resolve the gaps for regulated use. This article focuses on HMII objectives and Project results. The first has reviewed the relevant codes and standards and mine regulations, indicating that hydrogen and fuel cells could be allowed underground and that current codes, especially the Canadian Hydrogen Installation Code would be sufficient for hydrogen use. The second project established the standard hydrogen storage and distribution architecture along with related risks and safety requirements for its use in the third project, using an underground test chamber to delineate the behaviour of hydrogen leaks in confined conditions with various ventilation regimes and ignition studies. This project will end in 2013. It will be followed by the last project, which will establish best practices in support of regulations development, and develop the ISO standard for mine hydrogen infrastructure and underground application.

Aug 1, 2013

By V. F. Petrov, O. D. Khmelnitskaya, V. M. Lodeischikov

"The processing of copper gold ores is one of the major issues of gold-mining industry in the beginning of 21st century. In this case, application of ammoniacal cyanidation process for this type of mineral raw materials deserves special attention. Irgiredmet Institute has carried out a wide range of studies on ammoniacal cyanidation process and evaluated the possible commercial use of this process for Russian operating plants. Copper gold-bearing ore from a current Russian deposit was studied. The content of gold and copper in the ore is 9.4 g/t and 0.4%, respectively. Based on the results of preliminary test work, a flow sheet was developed. It included gravity concentration followed by cyanidation of the gravity tailings using CIP. The flow sheet provides sufficient total gold recovery (91.5%). However, this technology has disadvantages, such as high specific consumption of reagents: 4.5 kg/t NaCN and 13.5 kg/t Ca(OCl)2 the ore and the increased gold grade in the liquid phase of the tails slurry (0.2 g/t). In order to improve cyanidation process parameters, test work on gravity tails processing using ammoniacal cyanidation was carried out. After the test work was completed, ammoniacal cyanidation flow sheet for copper gold-bearing ores was developed. Leaching conditions were optimized using recycled process solutions. Recommendations on gold recovery from the solutions and tails detoxification are given. The proposed flow sheet provides 91.5% gold recovery. In this case, compared to the conventional option, the consumption of cyanide decreases by 3-4 times.INTRODUCTION The technology of precious metals recovery from gold-bearing ores is based on cyanidation. This accounts for up to 90% gold recovery and the significant portion of silver (Lodeischikov, 1999). However, there exists the category of so called refractory ores. They are not amenable to direct cyanidation (without using additional expensive processes), or they are characterized by low indices of metals recovery and high consumption of reagents. The latter also include copper gold ores. Their deposits can be found extensively both worldwide and in Russian Federation. A feature of these ores is that they contain not only gold but also copper. It is considered not only as a valuable component but also as a harmful mineral impurity that hinders gold cyanidation, gold precipitation from the solutions by cementation onto zinc dust and adsorption onto activated carbon (CIL, CIP-processes), detoxification of cyanide bearing effluents."

Jan 1, 2018

The fundamental objective of mine plans are usually to maximize the mine profit by extracting ore at the lowest possible cost over the mine life while some technical constraints are satisfied. Since the costs associated with the operation of trucks and shovels as resources are significant, determining the optimum number and allocation of these resources is an essential issue. This paper presents a Mixed Integer Linear Programming (MILP) model to determine the optimum number of shovels and trucks required to meet the short-term plan?s goals. Also, the model takes into account the allocation of trucks and shovels to mining faces. This model minimizes operational costs, while attempting to meet the production demand and to satisfy technological constraints. This paper also analyzes the operations of trucks and shovels in an open pit mine using ARENA simulation software.

Jan 1, 2012

Knowledge of coalfield geology has evolved rapidly over the past few years. Recent advances ranging between exploration, mining geology and seam variation studies have enabled application of geological techniques commensurate with technological changes in the coal industry.

Jan 1, 1969

The rights of nations to explore and exploit minerals in the continental shelf were recognized by the 1958 Convention on the Continental Shelf. The Commonwealth Government has expressed the view that, as a party to the Convention, it has, by virtue of its foreign affairs power, full rights to legislate with respect to offshore minerals. States have taken the view that the rights recognized as extending into the continental shelf are land mineral rights, which belong to the States, and the Commonwealth legislative power in this field is strictly limited. Without prejudice to each other's rights, Commonwealth and States agreed to "mirror" legislation in relation to offshore petroleum. Commonwealth and State legislation, of which the operative parts are in identical terms, are both administered, in relation to areas adjacent to each State, by State Ministers of Mines. The legislation has functioned well in practice, though difficulties are encountered by the Commonwealth Government due to lack of direct accountability to Commonwealth Parliament. An alternative scheme designed to overcome this problem is outlined.

Jan 1, 1974

"Placer Dome Inc.'s Dome Mine is located in South Porcupine, Ontario and has been in production since 1910. In the past, the mill leach circuit was preceded by preaeration and primary filtration circuits. These circuits were operated to overcome the effects of pyrrhotite in the ore which reacts with cyanide to form cyanates and thiocyanates and also consumes oxygen.In early 1989, primary filters were by-passed for an extended period. Actual plant results showed no affect on gold recovery or cyanide consumption so the circuit was left off-line permanently with significant cost savings.In 1990 it was determined that considerable savings could be realized underground if backfill storage facilities were located in the mill. It was decided to convert the preaeration pachucas to backfill storage tanks on a trial basis. The trial proved successful with no effect on recovery or significant increase in reagent consumption occurring due to the elimination of the preaeration circuit. The converted pachucas worked well as backfill storage tanks.Modifications such as these have helped to keep the Dome's millings costs among the lowest of Canadian gold producers."

Jan 1, 1992

By Alfred Goldberg

The paper is founded on the results of an investigation on the softening behavior of a cold-rolled low carbon steel. This specimen, originally cold rolled 15 , 30 , 50 and 75% reduction in thickness, were annealed at several temperatures ranging from 481 to 687ªC. A temperature-time range was encountered over which strong competition between these processes was evident. An interpretation on the effect of test variable on determining which one of the competing processes dominated during annealing is presented.

Jul 20, 1961

By B. Burger, T. Bester, S. Deonarain, L. S. Schultz

"This paper details the process followed to raise drill and equip a 6.1 metre diameter vertical service shaft at Glencore’s Mindola Deeps project in Kitwe, Copperbelt Province, Zambia. The project scope comprises a shaft collar, bulk air intake, a pre-sink to -90 metres and raise drilling the shaft from surface to a final depth of 1,892 metres underground, in four separate lifts of approximately 475 metres each. Equipping of the shaft steelwork, headframe erection and commissioning the shaft for hoisting. In addition, the scope included the development of a decline down from 5430’ level underground to the new shaft position on 6205’ level. This paper will provide some insight into the successes and challenges encountered during execution of the shaft works to date and provide some learnings for future projects of a similar nature. INTRODUCTION The Mindola Mine is situated to the west of the city of Kitwe in the Copperbelt Province of the Republic of Zambia (Figure 1). The mine is owned and operated by Mopani Copper Mines Plc (MCM), whose shareholders are Glencore AG (73.1%), First Quantum (17.9%) and ZCCM Holdings Plc (10%).Productivity at the Mindola mine has been adversely affected because of significant ventilation and ore re-handling challenges, which are caused by the dilapidated infrastructure, and design of the existing vertical and sub vertical shaft system. In the circumstances, it was apparent that it was necessary to sink a new vertical shaft that would increase the volume of fresh air down the mine, improving the underground working environment and the current hoisting restrictions, resulting in an increase in productivity and efficiency. Because there were two existing levels ideally situated and perpendicular to one another and because a third level was in close proximity to that perpendicular and because the mine required a ramp down to shaft bottom in any event, consideration was given to raise drilling the shaft as opposed to using conventional blind sinking methodologies."

Jan 1, 2019

By L. F. Willmott

The production operation of a Kerpely gas producer at Louisiana, Mo., is described. This unit, originally designed for airblown operation was modified to permit using oxygen in the blast in place of air. The first runs J for test purposes, were made in June 1950. After this, seven production runs were made and these are the subject of this report. Total gasification time was 245 days. In each run, Nut or Pea coke or mixtures of both at a rate varying from 1,700 to 2,300 pounds per hour was converted with oxygen and saturated steam to produce synthesis gas - primarily carbon monoxide and hydrogen -approximating a predetermined rate of 80,000 to 95,000 cu. ft. per hour and a predetermined hydrogen-carbon monoxide ratio, The requirements per 1,000 std. cu. ft. of (CO + H2) were 21.6 to 30 pounds of coke, 213 to 267 std. cu. ft. of oxygen, and 3L4 to 47.B pounds of steam.

Jan 1, 1955

By H. G. Turner

The coals mined in the area known as the anthracite fields of Pennsylvania have always been recognized commercially as anthracites. In the literature, however, some of these anthracites have been called semi-anthracites by various writers. The coals mined in Sullivan County, especially those from the Bernice field, have been recognized commercially both as anthracites and semi-anthracites. In the literature they have almost always been referred to as typical semianthracites, although Franklin Platt,1 in his report to the Pennsylvania Geological Survey, uses the terms semibituminous, semianthracite, and anthracite in describing them. The purpose of this paper is to endeavor to dispel the confusion of names used to describe these coals and to supply further information that will permit a logical and definite classification. Most of the confusion of the past has been due to the impossibility of securing enough fresh face samples from which to draw sound conclusions; some of it was due, no doubt, to lack of standard methods of analysis, and of course, to the ever-present lack of definition of boundaries from the standpoint of classification. Map Showing Lines of Equal Volatile Matter and Lines of Equal Specific Gravity As a foundation for this work the writer constructed a map showing lines of equal volatile matter and lines of equal specific gravity throughout the anthracite and semianthracite regions. The points on these lines were determined from a study of analyses of 214 face samples from 28 mines and composite analyses from 18 different breakers. These samples were collected through the joint efforts of the U. S. Bureau of Mines and the Anthracite Institute. The Bureau of Mines standard method of sampling was used in all cases. All analyses were made by the Bureau of Mines and are used here with its permission. The

Jan 1, 1934

By J. W. Merks

Applied statistics provides scores of powerful tests and techniques that are widely used and abused in science and engineering. The variance is the basic measure for variability, precision and risk. The formulas for the variances of the arithmetic mean and the weighted average are derived from the variance of a general function, as defined in probability theory. The requirement of functional or mathematical independence in probability theory translates into the concept of degrees of freedom in applied statistics. Geostatistics is the only variant of statistics in which functional dependence and degrees of freedom are irrelevant. This paper examines whether such basic elements of probability and statistics can be ignored with impunity.

Jan 1, 1998

By John W. Walkiewicz

The U.S. Bureau of Mines has conducted studies to utilize rapid microwave heating to stress fracture ore samples. Iron ores containing hematite, magnetite, and goethite were subjected to microwave energy in batch operations at 3 kW and heated to average maximum temperatures between 840 and 940 °C. Standard Bond grindability tests showed that microwave heating reduced the work index of iron ores by 10 to 24 pct. In a microwave chamber designed to simulate a continuous throughput operation at 3 kW, the grindability of a taconite ore was improved by 13 pct at a bulk temperature of 197 °C. Because stress cracking occurred at a lower temperature, less energy was consumed. To further improve the economics of microwave fracturing, higher powers up to 16 kW were used to rapidly heat samples to relatively low temperatures in a continuous, belt-fed applicator. A significant improvement of grindability was obtained with a larger rod mill feed size in comparison to a minus 6-mesh Bond feed.

Jan 1, 2010