Search Documents

By D. Tao

Froth flotation is widely used in the coal industry to clean -28 mesh or -100 mesh fine coal. A successful recovery of particles by flotation depends on efficient particle-bubble collision and attachment with minimal subsequent particle detachment from bubble. Flotation is effective in a narrow size range outside which the flotation efficiency drops sharply. A fundamental analysis has shown that use of picobubbles can significantly improve the flotation recovery of particles by increasing the probability of collision and attachment and reducing the probability of detachment. A specially designed column with a picobubble generator has been developed for enhanced recovery of fine coal particles. Picobubbles were produced based on the hydrodynamic cavitation principle. Experimental results with one metallurgical coal and one steam coal have shown that the use of picobubbles in a 2" column flotation increased fine coal recovery by 10-30%, depending on the feed rate, collector dosage, and other flotation conditions. Picobubbles also acted as a secondary collector and reduced the collector dosage by one third to one half.

Jan 1, 2006

By John B. Rigg

The title of my paper today is "public relations challenges for the pending minerals crunch". There isn't anyone in this room who would dispute. That the minerals industry has always had public relations challenges . . . No matter what the circumstances, mineral shortage or abundance. The industry suffers from an image that is second to none in longevity. It defies all actuarial formulas of the past or the future. Never mind that such an image is outdated, distorted, overstated, and reiterated. I submit that the minerals industry had public relations challenges long before there was anything called public relations. This account of egyptian mining practices, recorded for posterity by Diodorus Suculus at the end of the second century, b.c., is indicative. "On the confines of Egypt . . . And Ethiopia is a place which has many great mines of gold, where the gold is got together with much suffering and expense. The kings of Egypt collect together and consign to the gold-mines those who have been combined for crime, and who have been made captive in way . . . Sometimes only themselves, but sometimes likewise their kindred. "Those who have been consigned to the mines, being maw in number and bound with fetters, toil their tasks continuously both by day and all night long, getting no rest and jealously kept from all escape.

Jan 1, 1975

By Felipe P. D. Lopes, Jr. dos Santos, Sergio N. Monteiro, Frederico M. Margem

"Continuous and aligned fiber composites provide the highest possible reinforcement for a polymeric matrix. In particular, the impact resistance is significantly increased in comparison with a low energy absorbed brittle polymer. For this reason, investigations have been carried out with both synthetic and natural fibers as a way to improve the toughness of polymeric composites. Among the natural fibers, ramie was not yet been studied for its reinforcement effect to make tougher polyester composites. Thus, the present work assesses the impact toughness of polyester composites incorporated with different amounts of ramie waste fibers.IntroductionIn most engineering and other technological areas, the use of materials associated with low energy processing conditions is gaining attention for the possible environmental benefits. This offered an incentive towards the substitution of natural renewable and biodegradable materials for the traditional energy intensive synthetic materials [1]. Natural fibers from both origins: animal, such as silk and wool, and vegetable, such as cotton and jute, are typical examples of those environmentally friendly materials. Low cost and highly reduced processing machinery wear are important advantages of the natural fibers over the most common synthetic ones such as glass fiber and nylon. For these reasons, polymeric composites reinforced with natural lignocellulosic fibers have nowadays been the subject of investigation [2,3].The mechanical strength is one important property of lignocellulosic composites to access the possibility of uses like structural materials for building parts such as doors and panels, as well as furniture. In this case, mechanically strong fibers like sisal, jute, curaua and ramie [4-7] are most convenient. Moreover, the relatively low fiber/matrix interfacial shear stress in these composites is associated with higher impact energy. In fact, a greater energy has to be expended for the rupture of a weak interface. The many cracks that are formed by impact tend to branch during the fiber pullout from the matrix [8]. A larger number of cracks correspond to a greater fracture surface and consequently higher toughness."

Jan 1, 2008

By Wai Ng, Fluquer Peña, Elvis Sanchez, Inés Trinidad

Las unidades sedimentarias mesozoicas que afloran en las subcuencas Apurímac, Vilcabamba y Santo Tomás se encuentran asociadas a una clasificación hidrogeológica (acuíferos o acuitardos fisurados sedimentarios). La caracterización litogeoquímica de estas unidades sedimentarias se basó en los 15 elementos (As, Cr, Cu, Fe, Mn, Ni, Se, Zn, Be, Cd, Hg, Pb, Sb, Sn, Ti) que utilizan los estudios de línea base geoambiental del Ingenmet. Los resultados han sido comparados con los valores de la UCC (Wedepohl, 1995), lo cual ha permitido caracterizar el comportamiento químico de las unidades hidrogeológicas asociadas a las unidades sedimentarias. Se determinó que son tres los factores que controlan el comportamiento químico de las unidades hidrogeológicas: tiempo geológico, espacio y litología. Estos factores son importantes para la integración de información con los análisis de sedimentos y aguas de los estudios de línea base geoambiental, porque permitirán comprender el origen de posibles zonas anómalas de los elementos descritos en los sedimentos y aguas.

Sep 20, 2019

By Mark K. Larson, Douglas R. Tesarik, Heather E. Lawson

"Load transfer distance (LTD) is simple in concept and usually evident in underground coal mines. Many people in the mining industry recognize LTD as the distance from the panel to where the mine ribs and pillars show evidence of renewed spalling, floor heave, or other effects of increased weight due to longwall mining or pillaring. Barrier pillars, in particular, are designed to shield mains and other relatively permanent facilities from this loading. LTD is also important in determining the extent and degree to which mining increases the load on pillars and ribs in the gate roads. Generally, a long LTD reduces loads in gate roads, but may require larger barrier pillar widths to protect mains or adjacent panels from excessive loads. Therefore, a long LTD may make it easy or difficult to meet various objectives of mine layout design . LTD reflects overburden geology in two ways: First, overburden that is weak and readily caves will limit both the amount and distance of load transfer. Second, stronger, stiffer, sandier, and more massive overburden increases both the amount and distance of load transfer. As such, LTD is central to coal mine layout design and calibration of numerical models that seek to anticipate these transfers of load during mining. However, the term does not have a consistent definition in the literature, and various instruments and observational techniques with varying sensitivities and thresholds have been used to indicate the onset of mining-induced stress increase and, subsequently, to determine an LTD. Consistency is important for meaningful comparison of ground response between mining sites and for accurate calibration of models.This paper adds to the body of observed and reported LTDs by presenting cases with relatively sandy and massive overburden at two western coal mines. These two cases include observation and measurement of LTD with multiple methods and provide insight into how distances reported relative to different criteria and instrumentation could be adjusted for comparison against a common base. This base is the criteria used by Peng and Chiang (1984) to determine their empirical equation. In one of these two cases, LTD was recently measured at a western U.S. coal mine (Mine A) to be approximately four times that calculated using the Peng and Chiang empirical equation. LTD measurements were examined using various instruments at Mine A and at adjacent Mine B. The measurements at Mine B showed that LTD was significantly greater than that calculated by the Peng and Chiang equation. Difficulties with BPC installation and fittings at Mine B permitted only ranges of LTD to be determined from some BPCs. Even so, the LTDs and ranges of LTDs determined were consistent with the LTDs determined at Mine A."

Jan 1, 2015

By R. K. Mehta, U. Cetin

The Nevada Test Site is located approximately 100 km (65 miles) northwest of Las Vegas, NV. The site was primarily used by the Department of Energy for the field testing of nuclear weapons and has been contaminated by several million cubic feet of low-level radioactive wastes, heavy metals, explosive materials, and volatile and nonvolatile organics. The transportation and leaching of these contaminants are creating serious environmental problems. The purpose of this study is to examine pozzolan, a natural alumina-silicate mineral, as a possible replacement for the existing impermeable clay barriers. In the first phase of this study, radionuclide sorption characteristics of pozzolan were investigated. This paper presents the results of the adsorption tests for the target radionuclides.

Jan 1, 2000

By Walter H. Voskuil

Illinois supplies coal to seven states in the Upper Mississippi Valley —Illinois, Missouri, Iowa, Minnesota, Wisconsin, and portions of the Dakotas, Nebraska and Kansas. In this same area are marketed large quantities of coal from West Virginia, Kentucky, Pennsylvania, and elsewhere; fuel oil from the crude petroleum supplies of the Mid-Continent fields, and natural gas from Louisiana, Kansas and the Texas Panhandle. The boundaries of this "Illinois coal-market area" are determined by competition from other coal fields and from other forms of fuel. Within the area so described 90 per cent of Illinois coal is marketed. Thus in the Southwest, an abundance of fuel-oil supplies and natural gas dominates the market almost to the exclusion of coal. The westward movement of Illinois coal in Kansas, Nebraska and the Dakotas is met by an eastward flow of high-grade coals from Colorado, Wyoming and Montana. In the lake-shore counties of Minnesota and Wisconsin, the market is dominated by Appalachian coals, cheaply carried over the Great Lakes and reaching the ports of Lake Michigan and at the head of Lake Superior. Illinois coals find their largest market in the southern and western sections of these two lake states. Only small quantities of Illinois coals are shipped east of the state line. This market area is occupied entirely by the neighboring coal fields of Indiana and the Appalachian coal fields in Ohio, West Virginia, Kentucky and Pennsylvania. Illinois Coal-makket Area , With these factors in mind, the map of the Illinois coal-market area may be drawn. Within this boundary is the area that is logically and economically served by Illinois coal. However, this area is by no means exclusively dependent upon coal from Illinois mines. The preponderance. of Appalachian coal in Wisconsin and Minnesota has been mentioned. Appalachian coal, also, moves in large tonnages into Illinois itself, particularly the Chicago district. The Iowa and Missouri local coals share the market with imported coal from Illinois; throughout the market area, fuel oil and natural gas are important factors in the total energy supply.

Jan 1, 1936

By T. E. Gray

This report describes the preparation characteristics of the three significant coal beds in Greene County, Pa. It is one of a series planned to determine which coals are suitable for the production of metallurgical coke, either as mined or after beneficiation. Over 12.5 million tons of coal was produced in Greene County in 1956, of which approximately 10 million tons was cleaned mechanically in 8 cleaning plants. The Bureau of Mines has estimated that 3.5 billion tons of recoverable coal remained in the county as of January 1, 1954.

Jan 1, 1958

By M. S. Badollet

"IntroductionASBESTOS FLOATS may be defined briefly as blends of air-borne particles of fibrous asbestos and dusts produced during the milling stages and collected by Cottrell precipitators, dust sheds, or bag-houses.The various grades of asbestos floats on the market contain fibrous asbestos particles ranging in length from microscopic to approximately 1/4-inch. The fines or dusts present in the floats are from 40 microns to 2 microns or less in cross-section.Airborne asbestos particles are of diverse length because they are collected at numerous places in the mill. There are: (1) dusts removed from dry rock storage bins, (2) dusts removed from rock and fiber screens, (3) particles from the tops of collectors, and (4) fines removed by suction from the processing equipment. Sometimes the airborne particles are kept segregated, so that there is a partial separation by gravity. This is accomplished by a series of dust chambers enclosed in a long, rectangular building. The longest and heaviest particles fall nearest to the air flow entrance, the smallest at a point farthest away and nearest the exit. Sometimes the air from the dust chamber building is passed through a series of bag-houses or electric :precipitators ,to collect the extremely fine particles which normally escape to the atmosphere."

Jan 1, 1952

By H. C. Verakis, T. E. Lobb

During the past decade, approximately 5 billion pounds of explosives were used annually in the United States. Most of this quantity of explosives was used by the mining industry, with coalmining being the dominant application for explosives. Considering the large amount of explosives used, the accident safety record for the mining industry has improved significantly over the past several decades. Although blasting accidents usually represent a small percentage of the total number of mining accidents, they continue to occur and the severity of these accidents is disproportionately high compared to the other mining accidents. This paper is an analysis and summary of mine blasting accidents over the past several decades as they relate to surface coal mine operations. A compilation and review of surface mine blasting accidents from1978 through 2001 was made. The accident data was examined to identify the trends and primary causes, which continue to be blast area security, fly rock, premature blast, and misfires. Approximately 46percent of the causes of surface coal mine blasting accidents are attributed to blast area security, while fly rock, premature blast, and misfires represented an additional 50 percent of the causes. Accident categories were established based on the cause of the accident or the activity that was taking place when the accident happened. A discussion of the accident data is presented to increase hazard awareness and to emphasize safe blasting practices and MSHA requirements concerning mine blasting operations.

Jan 1, 2003

By Anis Farah, Khosrow Aref

Pull-out tests were conducted on cable bolts grouted with concrete, and cement paste. The influence of several parameters on the performance of these cables were studied under loading rates varying from very slow to relatively fast. These parameters include water-cement ratio, cable surface conditions, curing time and embedded length. In addition to being more economical, the results indicate that cables grouted with concrete have higher ductility and ultimate bond strength as compared to those with cement paste only.

Jan 1, 1986

By William A. Vogely, Lawrence J. MacDonnell

This section begins with an introduction to several key environmental laws. This is followed by a discussion of some of the issues raised by such environmental regulation. Finally the subject of regulatory reform is addressed. Overview of Selected Major Environmental Laws The number, type and complexity of environmental laws and regulations affecting mineral resources development have grown at an astonishing rate since the 1960s. The most significant laws and regulations are those addressing the use of the public lands; those concerned with air quality, water quality, and surface reclamation; and those defining government responsibility for its actions having important environmental consequences. The laws and regulations governing activities on the public lands will be taken up in the section 5.15C, "Minerals and Land Management." In this section we will concentrate on five primary laws: the Clean Air Act, the Clean Water Act, the Surface Mining Control and Reclamation Act, the Endangered Species Act, and the National Environmental Policy Act. The Clean Air Act: The legislative and regulatory framework for controlling air pollution has developed in a series of steps. Most important for present purposes are the Clean Air Act of 1970 (P.L. 9 1-604) and the 1977 Amendments (P.L. 95-95). The rather complex air quality control scheme includes four key elements-national ambient air quality standards, state implementation plans, the prevention of significant deterioration program, and the non- attainment program. National Air Quality Standards. The 1970 Clean Air Act is a landmark law because it contains the first explicit recognition that pollution is a nationwide problem requiring a national control program. The federal government through the Environmental Protection Agency (EPA) was to establish national air quality standards for at least the six pollutants named in the Act (sulfur dioxide, carbon monoxide, total suspended particulates, photochemical oxidants, hydrocarbons, and nitrogen dioxide). These standards were to be established so as to protect public health, "allowing an adequate margin of safety." The cost of achieving these standards is not to be considered. The 1970 Act unrealistically required that these standards be achieved in all areas of the country by 1975. As the program has developed, the air quality control regions are now to be designated as "attainment" or "nonattainment" with respect to each of the national standards. State Implementation Plans. Under the Act the states are given the primary role in achieving the ambient standards. States are to develop and implement control plans governing emissions from all existing and new sources. These plans can include emission limitations for existing stationary sources, transportation control plans to reduce emissions from mobile sources, and pre- construction review of new stationary sources to assure compliance with new source performance standards. The EPA must approve all state implementation plans. Sanctions are given to the EPA to be applied if states fail to submit acceptable

Jan 1, 1985

By R. Woods

"Comments on the paper ""Formation of hydrogen peroxide by chalcopyrite and its influence on flotation,""by A. Javadi Nooshabadi and K. Hanumantha Rao (Minerals & Metallurgical Processing, 2013, Vol. 30,No. 4, pp. 212-219)The formation of hydrogen peroxide from water during the grinding of chalcopyrite in a nitrogen-sparged environment, as reported by Javadi Nooshabadi and Rao (Minerals & Metallurgical Processing, 2013, Vol. 30, No. 4, pp. 212-219), is questioned on the grounds that oxidation of water by the mineral is unlikely to be thermodynamically feasible. It is argued that it is more likely that any peroxide that had been formed would have been generated from residual oxygen in the nitrogen-flushed system than from the oxidation of water.The formation of hydrogen peroxide by finely divided pyrite had been reported by a number of authors (Borda et al., 2001; Borda et al., 2003; Cohn et al., 2006; Schoonen et al., 2006; Schoonen et al., 2010; Jones et al., 2011; Javadi Nooshabadi et al., 2013). That hydrogen peroxide is formed in the presence of oxygen in solution can be comprehended from wellestablished mechanisms. Pyrite in aerated solution is known to oxidize by an anodic process that is coupled with the cathodic reduction of oxygen (Holmes and Crundwell, 2000). The latter process has been shown to occur through the formation of hydrogen peroxide (Biegler et al., 1975; Ahlberg and Broo, 1996). The pH dependence of cathodic oxygen reduction at other sulfide minerals, including chalcopyrite (Biegler et al., 1977; Rand, 1977), implies a similar mechanism at these surfaces."

Jan 1, 2015

By F. V. Hicks

THE similarity of mining practices in bituminous coal fields through-out America is due to the fact that certain fundamental conditions are encountered in all fields. The problems of labor, housing and mining are somewhat similar whether the mine is in Pennsylvania, Illinois, Wyoming or the State of Washington. Each field has had its particular problems, resulting in advantages or disadvantages over a competing field. This might take the form of a wage differential, a better natural condition more favorable to cheap production, or proximity to a market that allows freight rate advantages, etc. In any event, no matter how favorably situated, the mining companies that have been slow to recog-nize and accept the advantage of mechanization, clinging too long to the old hand methods, have found themselves unable to meet competition. Throughout the Wyoming coal fields, production methods have so changed in the last decade as to be almost unrecognizable to an old-time coal miner who has had no connection with the industry during; that period. The old contract system, with its peculiar labor relationship between employer and employee, based upon the long-established custom that the miner's working place was his castle, and that it was his privilege to carry on operations within that place largely in his own way and to his own liking, is a condition that has passed away. The present-day, 100 per cent mechanized mine bears but little resemblance to the old. A change -in system has naturally altered the old-time labor relationship. Contract labor has been almost entirely eliminated and a straight day-wage basis established, with certain classes of work calling for different rates, which places the entire personnel of the underground operating force more directly under the direction and supervision of the mine foreman and his assistants. The transition from the old order to the new has gradually done away with the system of penalties, personal- rights and privileges existing under the contract system, which were so controversial in the past that the average mine management was constantly involved in labor disputes in fields where organized labor was employed.

Jan 1, 1936

By T. Wennberg

An elevated location of a paste thickener on a ridge close to the disposal area is considered at a Swedish iron ore mine. About 0.7 M tonnes of thickened tailings are planned to be layered as paste in the vicinity of the thickener over several years with pipeline lengths of up to 900 m after about 20 years. In order to clarify the pipeline pumping characteristics of the tailings product for volumetric solids concentration from 40 to 50%, experiments in loop systems with pipeline inner diameters from 0.063 to 0.152 m have been carried out with various types of pumps. The results and comparisons carried out here showed that the performance of centrifugal pumps cannot simply be related to the rheology, but factors related to pump design and build-up tendencies of material within the pump and other particle properties may be of equal importance. During the first years of operation only one thickener underflow pump is required. The reliability and performance for various pump configurations are planned to be investigated systematically in order to meet the most effective long-term solution for paste thickener operation, pipeline distribution and placement in the disposal area as the discharge point advances over the life of the project.

Jan 1, 2007

By M. Kumaran, A. Vetriselvan, A. Purantharan

"This paper presents a case history of evaluating the stability of a distressed earth bund and rectification measures carried out. A 5.45 km long, 7m high earth bund for drinking water storage was constructed in Andhra Pradesh. During construction of the bund following were observed – (a) a longitudinal crack at the downstream side (b) Bund on the downstream side along the crack settled to a max of 700 mm and (c) downstream rock toe level area raised by heave up to 175 mm. Investigation of the events made important contributions to the fundamental understanding of the behaviour of large earthworks of this type. It was found that the variation in subsoil strata was not addressed during the execution.After careful evaluation, stone columns were recommended as a suitable ground improvement technique. Stone columns were used as a reinforcement to improve the shearing resistance of foundation and in turn ensure stability. By using and applying advanced geotechnical engineering analysis tools and modelling techniques, earth bund and its foundation was analysed and examined against failure by slope instability. Stone column design was carried out using in-house computer program GEOSTONECOL and stability of earth bund was analysed using TALREN software. Earth bund construction was completed after ground improvement and is performing satisfactorily.INTRODUCTIONIn order to supply water during summer season, Government of Andhra Pradesh decided to construct a 7m high and 5.45km long earth bund summer storage tank. It was one of the largest earth bund summer storage tanks in whole of South India at the time of its construction. During construction, the earth bund has undergone sudden distresses. Investigation of the series of events occurred during construction has made important contributions to the fundamental understanding of the behaviour of large earthworks of this type. This paper presents the reasons for earth bund failure, slope stability assessment of the distressed earth bund and recommendation of stone column as a suitable ground improvement remediation technique.DESCRIPTION OF STUDY SITEThe characteristics of the original construction are briefly described as follows. A shallow cut-off trench was excavated below existing ground level at the centreline of bund as shown in Fig. 1. Below the base of the trench a cut-off grout curtain was installed. Upstream and downstream shell earth filling was carried out using Clayey Sand ‘SC’ type soil. At some locations, bottom of cut-off trench has reached as deep as 12m from the existing ground level."

Jan 1, 2017

By F. Castelli

A simplified non-linear method to predict the behaviour of a single pile and/or pile group under horizontal loads is presented in the paper. The evaluation of the non-linear lateral deflection is based on a procedure taking into account the decrease of the model stiffness with the increasing of the applied load. The solution derived firstly for the single pile, was extended to the case of a pile group introducing the p-multiplier (fm) concept proposed by Brown et al. (1988).

Jan 1, 2006

By Slobodan B. Vujic

"For the requirements of the mining company “Rudnik-Rudnik”, engaged in undergr-ound exploitation of polymetallic ore and lead, zinc and copper concentrates production, the Department of Computer Application of the Faculty of Mining and Geology, University of Belgrade, designed a computer supported and integrated information-management system. This paper presents a concept of this system covering both monitoring and management of production in ""Rudnik-Rudnik"".The ""Rudnik"" Rudnik, Yugoslavia is a mining company, engaged in underground exploitation of polymetallic ore and production of ore, zinc and copper concentrate as well as other metals such as silver, bismuth and cadmium. This mining company runs stable business activities and undergoes a permanent growth of valuable production volume.The basic characteristics of production-technical system of ""Rudnik"" company are: uniform and up-todate technical-technological solutions: linking of production chain from underground exploitation of ore to flotation, namely final product - concentrate of lead, zinc and copper; complete mechanization of production; relatively low level of computer technics implementation; namely, ununiformed implementation of different application of computer-supported information technologies in production and business activities of the Company.These are the assumptions on the basis of which the management of the Company made a decision, in 1999, to upgrade information-management functions through development and application of modern integrated and computer-supported production-business information-management system (hereinafter: IMS, namely IMS Rudnik). For this purpose the Company requested the Department of Computer Application, Faculty of Mining and Geology, University of Belgrade to make the Project on IMS for their needs."

Jan 1, 2003

By Robert Stefanko

Transients are results of sudden changes which take place in power systems and can be created by the opening and closing of switches and circuit breakers or the occurrence of a fault anywhere in the complex. Transients are of short duration, and the time during which they occur is an extremely small percentage of the total operating time. However, it is during these short periods that the greatest electrical stresses occur, mainly due to excessive currents or voltages. In extreme cases, system parts are damaged, and equipment failure follows. Safety can be further compromised because anomalous voltages can exist at machine frames. For several years, the electric utilities have been well aware of the serious nature of transients on their systems, but problems firmly believed to directly result from these phenomena are just now becoming apparent to the coal mining industry. The situation became discernible after the underground introduction of high voltage distribution systems (along with vacuum circuit breakers) and sensitive solid state electronic apparatus. In order to protect against such transients, knowledge about their characteristics and origin must be obtained.

Jan 1, 1974

By P. Greenfield, P. A. Beck

RECENT work by J. Darby, Jr. in this laboratory has shown that the reported vanadium-rich limit of the s phase in the Co-V system at 1200°C is in error. The appearance of a second phase in s actually is restricted to alloys containing over 68 atomic pct V. The error in the original value is due apparently to a reaction that takes place along the numerous cracks in the s specimens between the alloy and the impurities present in the He + 8 pct H atmosphere in the annealing furnace. Such a reaction and the consequent appearance of a second phase can be suppressed if the alloys are sealed under vacuum in Vycor tubing. The new value of 68 atomic pct V for the vana-dium-rich limit of the s phase in the Co-V system effects slightly the s compositions calculated from average values of N, and N,. for various s phases. The standard deviation between experimental mean compositions and those calculated from the assumption that s is characterized by a constant number of 3d + 4s electrons per atom (N,), is slightly reduced from 9.1 to 8.8 pct. The maximum divergence for the V-Mn s phase is reduced from 15.5 to 14 atomic pct. The standard deviation calculated from constant electron vacancy numbers given by N.. = 4.66 (Mo + Cr + V) + 3.2 (Mn) + 2.2(Fe) + 1.71(Co) + 1.6(Ni) is now greatly reduced, as the maximum divergence for this correlation previously occurred in the V-Co system. This maximum divergence is reduced from 7.6 to 2.3 pct, and the standard deviation for all s- phases is reduced from 4.1 to only 2.9 pct. The correlation for electron vacancy numbers given by N. 5.66 (V when with Ni or Co) + 4.88 (V when with Mn or Fe) + 4.66 (Cr + Mn) + 3.3 (Mn) + 2.66 (Fe) + 1.71 (Co) + 0.61 (Ni) is made slightly worse, and the standard deviation increases from 2.8 to 3.9 pct. These changes, however, do not affect the conclusions of the paper.' The deviation between calculated and experimental s compositions is much less for either one of the electron vacancy correlations than for the correlation with the number of 3d + 4s electrons.

Jan 1, 1955