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By R. W. Snyder, H. J. Ramey

This paper presents the results of applying the Buckley-Leverett' displacement theory to petroleum reservoirs consisting of a finite number of layers. The layers are assumed to communicate only in the wellbores, and the reservoir may be represented as a linear system. Most previous investigations of this nature were limited by assumptions and by inconsistent calculation techniques. This study improves on previous work by applying the Buckley-Lev-erett displacement theory to a noncommunicating layered system where permeability, porosity, initial saturation, residual saturation and relative permeability vary from layer to layer in a logical and consistent manner. Gravity and capillary-pressure effects are neglected. A modification of the Higgins-Leighton calculation method was used in this study. Waterflood predictions were made with all properties varying, and then with only permeability varying using several inability ratios. These results were compared with the Stiles and Dykstra-Parsons predictions. It is shown that the latter methods generally give poor values for the breakthrough recovery and pessimistic predictions for the performance after breakthrough. Similar results were obtained for a gas-displacement case. lNTRODUCTION Field experience with immiscible displacement usually shows constant producing conditions until breakthrough of the displacing fluid. Then oil production continues at increasing displacing-to-displaced fluid ratios until the economic limit is reached. Three different ideal mechanisms are known that will produce this behavior: (1) relative permeability effects as described by Buckley-Leverett frontal advance theory,' (2) vertical stratification as considered by Stiles,2 Dykstra and Parsons5 and others and (3) different path lengths involved in areal (two-dimensional) flow between wells as described by Dyes et al.4 Without question, a combination of these factors modified by formation heterogeneity and other known and unknown factors actually does control the behavior of real systems. This paper presents results of an investigation of certain factors that should affect performance but which have received little attention to date. In 1944, Law5 demonstrated that porosity and perme- ability are often found to have normal and logarithmic-normal distributions, respectively. throughout cored intervals in natural formations. This led to the concept of the noncommunicating, multilayered reservoir model for immiscible displacement. This model assumes that the reservoir is composed of a number of layers that communicate only at the wellbores. Each layer is individually homogeneous, but may be different from every other layer. Stiles' presented one of the earliest applications of this model to waterflood performance. In addition, Stiles assumed that the initial saturations and relative permeabilities were the same for each layer, porosity was the same. displacement was piston-like, fluids were incompressible and injection into each layer was proportional to that layer's permeability capacity (permeability-thickness product). The last assumption would be true if the mobility ratio for the displacement were unity.21 Dykstra and Parsons" used the same model as Stiles, but rigorously included mobility ratios other than unity for piston-like displacement. Dykstra and Parsons used their general result to produce charts for log-normal permeability distributions between layers. Similarly, Muskat6 Pub1ished analytical solutions for linear and exponential permeability distributions. In 1959, Roberts' described a scheme for calculating water-drive performance for the noncommunicating, layered reservoir model which considered two-phase flow in the displaced region. Roberts used the same model and assumed that the injection rate into a layer was proportional to that layer's permeability capacity, but that flood front locations could be evaluated from the Dykstra-Parsons results. These assumptions are inconsistent, and a material balance cannot be maintained except for a mobility ratio of unity. At the same time, Kufus and Lynch8 coupled Buckley-Leverett displacement theory with the layered model to provide an improvement of the Dykstra-Parsons method that was consistent. In 1960, Higgins and Leighton9 resented a numerical method for calculating waterflood performance also considering two-phase flow in the displaced region. The result was used to investigate variation in absolute permeability and oil viscosity. An excellent, detailed history of using the noncomrnunicating, layered reservoir model was presented by Nielsen.'" The preceding techniques (and many related ones) were similar in that differences in initial saturations, residual saturations and relative permeabilities from layer to layer were neglected. It is well known that the irreducible water saturation is an important function of absolute permeability. Calhoun11 showed that the irreducible water saturation

By L. M. Gould

"Syncrude Canada operates the largest oil sands crude oil production facility in the world and produces over 13% of Canada’s total oil requirements. To achieve this, Syncrude mines the oil sands in open pits, extracts the raw oil known as bitumen from the sand using water-based processes and upgrades it into sweet light crude oil by fluid coking, hydroprocessing, hydrotreating and reblending. The final product, Syncrude Sweet Blend (SSB), is sent by pipeline to three Edmonton area refineries and then to pipeline terminals which ship the SSB to refineries in Canada and the United States.As parts of the Mildred Lake base mine reached their economic life, they were replaced with new facilities at the Aurora Satellite mine. Aurora is situated on Oilsand Leases 10, 12 and 34, 35 km northeast of the Mildred Lake facility (Fig. 1).In 2000, the first hydrotransport low-energy extraction production train started up at Aurora. A second production train is scheduled for start-up in 2003. Open pit mining at Aurora occurs using two hydraulic shovels, two cable shovels, and trucks ranging from 320-ton to 380-ton payload capacities (Fig. 2).Once the oil sands is excavated, the trucks dump the ore into a crusher designed to break up the big lumps of oil sands and rock at peak rates of 11 000 t/hr. The ore is then transferred by conveyor to a surge pile and then to a mixing box which combines the oil sands with hot water. Following bitumen separation in the primary separation vessel, froth is delivered to Mildred Lake for processing via the intersite pipeline (Fig. 3).The goal of this paper is to illustrate how high precision shovel GPS (HPGPS) is being used at the Aurora mine to aid in mine planning. This can be accomplished by first describing the function of the mine planning department, describing the Aurora orebody, and finally explaining how the HPGPS system functions and how it is employed at Aurora.The short range mine planning department ensures a steady supply of ore is delivered to the plant at the desired grade in a sequenced and economical manner. This is done by creating a mine plan that consists of shovel dig locations that require the shovels to mine in a specified area at a specified elevation."

Jan 1, 2002

By R. J. Leary

Significant improvements in surface conditions or mechanical properties of steels have been attributed by several investigators to ladle additions of small quantities of rare-earth metals or their oxides. To investigate systematically these effects in wrought and in cast plain carbon and alloy mechanical steels containing approximately 0.35 percent carbon, heats of four representative compositions were melted by the Bureau of Mines in a 4-ton open-hearth furnace. Each heat was cast into three sets of ingots to exemplify respectively, treatments with (1) rare-earth metals, (2) rare-earth metal oxides, and (3) an untreated set as a control. The development of melting, casting and rolling practices is described and discussed. Lance injection of oxygen shortly after melt raised the temperature of the metal immediately as much as 500° F., principally because mechanical agitation exposed the high-carbon metal to the flame and furnace root. An exceptional degree of superheat in the metal at the termination of the refining period was attributed to oxygen injection during the refining period. Bath temperatures higher than industrial practice were permitted by the all-basic furnace lining. Rates of carbon elimination as high as 0.036 percent carbon per minute were achieved by oxygen injections.

Jan 1, 1961

By G. T. Lineberry

A systematic, comprehensive, balanced approach is presented for underground coal mine design, capable of being standardized and generalized. This approach epitomizes professionalism and must preceed the physical product. Design involves a varied senior staff and requires extensive selective input data. Engineering follows a total systems approach, operating in and for a constricting geologic setting, heavily constrained for safety, health, and environmental protection. It must also anticipate execution and operation. Engineering prominence and momentum are maintained, with sub-optimizations balanced by judgments--the "art and science" of engineering. The flow-chart starts with organized input data: Company Capabilities, Property Description, Geologic Analysis and Reserve Analysis. Engineering combines Ground Control with Excavating and Bulk Handling to map feasible Mining Methods, the crucial Milestone Diagram. Layout and Sequencing follow, with numerous alternatives examined. Scheduling is performed on the best designs, using predicted advance (performance) rates. Active and mined-out areas are isolated into time-related parcels, or increments, for the mine life. Bulk Handling, Life Support (especially ventilation and drainage), and Normal Support systems occupy each parcel. Regulations are then checked. Management concerns are covered, and an Economic Analysis is performed for profitability. This and the design represent an Initial Tentative Solution. Continued iterations produce multiple and improved choices.

Jan 1, 1987

By Lynn B. Hales

The Supervisory Computer System at Cities Service copper mine and concentrator at Miami, Arizona was installed at Pinto Valley in the spring of 1975. Design and specification [l] of the digital system was initiated jointly by key plant personnel at Pinto Valley and staff of Cities Service Research and Development Company. The Pinto Valley digital system [2] may be classified as a supervisory control system of hierarchical design. There are three fully independent satellite computers which retrieve and reduce the raw plant data from each of the three main operating areas - the primary crushing plant, the fine crushing plant, and the grinding and flotation plant. While the three satellite computers are core resident systems, the master computer is a disc-based operating system which also interfaces with a computer controlled on-stream x-ray analyzer system. Figure 1 illustrates the basic system configuration [3]. The software systems required to support a large system are quite diverse and vary greatly in function. The philosophy followed in dividing the software into three categories was designed to: 1) fully utilize existing process knowledge of technical staff; 2) delegate certain software tasks to outside sources already skilled and trained in software development; and 3) maintain final control over the design and operation of each system.

Jan 1, 1976

By Edward Keller

GOLD MOVEMENT ON SURFACE OF AURIFEROUS COPPER WHEN LATTER IS SUBJECTED TO OXIDATION SOME years ago the writer's attention was called to the fact that rolling-mill scales from auriferous copper do not have the gold content proportional to the gold contained in the copper from which they are derived. I So, later, he made a few simple experiments, which are described herewith. In: order to test the gold movement on the changing surface of a copper plate under the influence of oxidation, plates 6 in. by 8 in. by I in. (15.2 cm. by 20.3 cm. by 2.5 cm.) of converter copper, refined, of 99.29 per cent. purity, and leaded copper with a content of 95.65 per cent. copper, were obtained. Ten cuts were made through the thickness of the plates along the longitudinal center and the silver and gold content ascertained in each of the 10 samples in both plates, as shown in the accompanying illustration. The assay results, recorded in Tables 1 and 2, show that the gold distribution is relatively uniform in both plates, while silver has greater variations, especially in the leaded plate. The plates subjected to oxidation were placed in a red-hot muffle for about 2 hr., two small scorifiers being used as supports. Arranged alongside each other, they nearly filled the width of the muffle, and so were practically under equal conditions of heat and draft. The accurate observance of the time was not possible, however, because of other work, but the time of the exposure of each plate in a pair was identical. At the end of each period, each plate was plunged into water and completely freed of scale, which was carefully collected, dried, weighed, and analyzed. Samples of the plates had also been taken of the molten metal and duly analyzed. Table 3 contains the analytical data for the two plates and their several sheets, or layers, of oxide scales. These figures show that in the oxidations of the converter copper the silver is fairly uniform, while

Jan 1, 1919

By Adrian L. Moodie

Austar Coal Mine (formerly Southlands and Ellalong Collieries) has had a long association with difficult strata control conditions associated with mining depth and a highly jointed/cleated coal seam. The conditions include poor longwall face conditions, cyclic loading, heavy tailgate (TG) roadway conditions, and difficulties in maintaining stable roadways on development at 5.2 m (17 ft), as well as the geotechnical challenges of an 8.5-m (27.9 ft) -wide roadway required for installation faces. The introduction of Longwall Top Coal Caving (LTCC) to this environment has aided in the management of some of these issues, but LTCC has also given rise to other geotechnical considerations. Additional geotechnical issues associated with LTCC not only require management during operations, but also require consideration when evaluating new mining areas at Austar Coal Mine or potential LTCC extractable resources throughout Australia and the world. In September 2006, LTCC commenced at Austar Coal Mine in longwall panel A1. Since this point the LTCC face has been increased from 147 to 216 m (482 to 709 ft)and finally to 227 m (745 ft) in width, and it has also been rehanded and modified in the three fully extracted panels to date. The application of LTCC in panels A1, A2, A3, and now A4 has been very successful, both from a coal resource recovery point of view and in the management of the principal hazards of spontaneous combustion and strata control. This paper focuses on the geotechnical aspects of the application of LTCC at Austar Coal Mine and also reviews some advances in general strata control management at the mine.

Jan 1, 2011

Jan 1, 1949

By D. T. Kirkwood

The practice of impounding mine water and liquid fine waste in underground mines is increasing. Often these underground impoundments are created by constructing seals or bulkheads designed to withstand the expected hydraulic pressures. Occasionally seals are built for another purpose, usually to act as explosion-resistant ventilation barriers. Due to factors such as clogged drain pipes or unexpectedly high inflow rates, these explosion-resistant seals sometimes become subjected to hydraulic pressures. The incidence of seal failures due to inadequate design and/or construction is also on the increase. Fortunately, to date, no lives have been lost by water seal failures, but a clearer understanding of the design and construction considerations specific to water seals is vital to keep this from occurring in the future. This paper presents technical considerations for the design and construction of seals which will specifically be required to withstand hydraulic pressures in underground mines.

Jan 1, 1995

By Lloyd R. Nelson

Experimental results of three-phase mixing in a physical model of a CCRL for metals refining are presented. The system was operated above a critical lower liquid height-to- width ratio (H,/W) of unity, with adequate bottom gas injection through a line of central, single tuyeres (Q,/A = 7.5 cm/min, or c = 17 W/m3) to sustain levels of interphase transport considered appropriate to an industrial pyrometallurgical refining operation. The application of a thermal tracer technique to elucidate both longitudinal mixing and interphase heat transfer is discussed. The results indicate that even under conditions of significant bottom gas injection, it should be possible to maintain acceptably low longitudinal mixing 1 (D, < 20 cm /s and D,/uL < 0.1) in the CCRL. Interphase mass transfer coefficients of the order of 0.004 cm/s are predicted from the measured interphase heat transfer coefficients (h = 1.3 to 2.0 kW/m2K), using the heat and mass transfer analogy. Adequate rates of rehning are predicted for an industrial CCRL operated under such conditions.

Jan 1, 1995

By William L. Crentz

In a Nation-wide appraisal of coking-coal reserves and of the practicability of upgrading marginal deposits to metallurgical standards, this study of the preparation characteristics of the coals in Cambria County, Pa. , was undertaken. Over 90 percent of the coal remaining in Cambria Comity is found in the Upper Freeport, Lower Freeport, Upper Kittanning, and Lower Kittanning beds. The Middle Kittanning bed, although mined on a commercial scale in the past, is not an important bed now, as most of the remaining reserves are too thin to be mined over wide areas. For many years, Cambria County has been an important source of coal for industrial and metallurgical purposes. The) principal production comes from the Lower Kittanning bed, which accounts for almost .60 percent of the Cambria County coal output. Table 1 shows the county&apos;s coal production, by beds, during 1948.

Jan 1, 1950

By M. G. Corson

Until recently, the characteristics of cast copper have seldom been studied and such study as has been made has been inadequate. The prevailing idea seems to be that since pure copper is infrequently used in the cast stlate, there is no reason for trying to establish precise data regarding the properties of the metal in that condition. On the other hand, wrought copper either in the shape of sheets or wire rarely fails in service, except as a result of the action of reducing gases at the annealing temperatures, so there is little incentive to study the properties of the cast shapes —cakes, bars, ingots and billets—for the sake of tracing the causes of failures of the wrought metal to the cast stock. However, about a decade ago, wirebars of American origin often cracked badly while being hot-rolled in mills in Germany. This Icd to four investigations: by E. Seidl and E. Schieboldll by P. Siebe12 by 0. Bauer and G. Sachs,3 and by G. Welter.4 These authors came to the conclusion that failures in hot-rolling were due essentially to the presence of a wide zone of columnar crystals between t&apos;he thin layer of fine crystal5 near the surfaces of the bars and the large but more nearly equiaxed grains of the central core. This macrostructural defect was explained in turn by the probable upward deviation in the temperature of the metal while it was being poured into the molds of the castling machine. More recently, cast shapes of copper were investigated by X. 1&apos;. Allenh and by C. Blazey. Allen examined vertically cast wirebars and hori-zontally cast wedge cakes of electrolytic tough-pitch copper, but only for the distribution of densities; i.e., porosity. Blazey was interested mainly in the mechanism of the variations in electrical conductivity due to cold-work and anneal, but gave introductively an account of the composi-tion and average densities of the tough-pitch horizontally cast Wirebars used. As far as the present writer can tell, no investigation mas under-taken for the sake of presenting a picture of the distribution of mechanical characteristics in the wirebars of copper, or otherwise.

Jan 1, 1938

By M. J. Gula, S. S. Xue, E. P. Horwitz

A study has been conducted to remove iron from sulfate solutions using Eichrom&apos;s Dipexo® extractant, P,P&apos;-di(2ethylhexyl) methanediphosponic acid (H2DEH[MDP]). It is found that this extractant can effectively and selectively extract ferric ion from highly acidic solutions. Ninety-nine percent of the iron was extracted from a simulated feed solution in a single stage. The separation factor, Fe/Zn, was 106. Over 90% of the iron in a loaded organic can be recovered in an aqueous solution by reductive stripping. This paper presents the experimental results. A new process for iron removal using Dipex extractant is described and discussed.

Jan 1, 1999

The Federal Mine Safety and Health Act of 1977* defines respirable dust as dust measured with a device approved by the Secretary of Labor and the Secretary of Health and Human Services [30 USC 842(e)]. The approved sampler for respirable coal mine dust is the coal mine dust personal sampler unit (CPSU) [30 CFR 74; Jacobson 1971; Jacobson and Lamonica 1969]. The CPSU is generally called the 10-mm nylon cyclone, although the 10-mm nylon cyclone is actually just one component of the CPSU. The CPSU may either be mounted on a worker (with the sampling head positioned in the breathing zone for personal exposure monitoring) or in a fixed location for area sampling [Tomb 1990]. The CPSU consists of a pump unit, a sampling head assembly, and a battery charger if rechargeable batteries are used in the pump unit [30 CFR 74.2]. The sampling head assembly contains two stages. The first stage is a 10-mm nylon cyclone, which has collection characteristics similar to an elutriator. The amount of dust penetration depends on the flow rate [Jacobson and Lamonica 1969]. The second stage is a membrane filter (vinyl, pore size 5 pm) that collects the dust passing through the cyclone. The dust collected on the membrane filter is weighed to a precision (standard deviation) of 81 pg [Parobeck et al. 1981], and the respirable dust concentration in the mine atmosphere is then determined from the mass of dust collected and the volume of air sampled [Tomb 1990].

Jan 1, 1997

By J. P. Burland

The paper describes a number of recent case histories in the United Kingdom where field instrumentation and measurements have played a major role in the design and construction of excavations, piles and foundations. It is shown that the design and construction procedures for deep excavations in London Clay are based almost entirely on the results of field measurements. Examples are given of successful application of such measurements. The present understanding of the behaviour of bored piles in stiff clays and their design is based on a number of instrumented pile loading tests. The results of these tests have led to a radically new concept of pile design in which the piles operate at their full shaft capacity under working loads thereby resulting in considerable savings in design and construction. Some examples of the successful application of this concept are given. Finally it is shown that the present knowledge of the stiffness properties of chalk is based entirely on field observations. An example is given of how direct field measurements were used to solve a foundation problem at the base of a coffer-dam in chalk.

Jan 1, 2010

By L. Schlink

Impacted waters, often complex, are created in mining which at some point in the mine life cycle will need to be attended. The simplest and most cost effective method of handling impacted water is to reuse it as makeup water for operations. At the end of mine life, operational reuse will not be an option and the impacted water will require treatment to achieve alternative reuse goals. Conventional mine impacted water treatment is successful in removing unwanted constituents but create brine and sludge that may require special handling or additional treatment, resulting in additional liabilities and costs. Freeport-McMoRan Copper & Gold has taken an approach to water treatment that focuses on transformation not concentration. The Water Treatment Test Facility located at Sierrita Mine has three test plants that are piloting the mine impacted water transformation process. Two plants have been designed for the removal of calcium and sulfate with products of gypsum and sulfur. The third plant removes metals from process water and transforms them into marketable metal sulfides. The transformation, rather than concentration, of mine impacted water solutes greatly reduce long term risks.

Feb 23, 2014

Discussion of the paper of CHESTER W. WASHBURNE, presented at the New York meeting, February, 1915, and printed in Bulletin No. 9S, February, 1915, pp. 469 to 471. ROSWELL H. JOHNSON, Pittsburgh, Pa.-I hope that this contribution of Mr. Washburne&apos;s is only the first of a series dealing more in detail with the very important problems involved. Pores are of two kinds: Those which are entirely inclosed, so that they do not belong to a system of communicating pores tapped by the bore hole or shot hole; second, those which do so communicate. Porosity, of course, includes both. But since pores of the first class are valueless to us, we should confine our attention to the latter, for which I propose the term "effective porosity." This should be measured by the Wisconsin method, based on the quantity of fluid that can be introduced by the aid of vacuum. Another factor which requires attention in this connection is the dependence of the extractability upon the rate of loss of pressure, as affected by the number of holes, and the rapidity of their completion, the existence of uncontrolled wells, the use by other operators of vacuum pumps upon the casing head, the exhaustion of a gas field in the same reservoir prior to the discovery of the oil, etc. The extractability depends upon the pressure available for the exclusion of the oil from the reservoir into the hole. The action of gravity in bringing oil into the hole is relatively small where the pores are very small, as is so frequently the case.

Jan 5, 1915

By Howard S. Bryant

The year 1928 has recently.passed from the picture and it is at this time that the various divisions of the oil industry are giving thought to plans for the present year. The outstanding characteristic of the industry in 1928 was the successful curtailment of oil production to the market&apos;s needs. It has been thought advisable to look ahead and endeavor to anticipate the oil demand for the coming year, and thus determine the volume of oil that can be safely produced without causing major additions to surface stocks. The year has been one of smaller additions to stocks than in 1927, a record demand for oil products, and a further developed spirit of cooperation among oil producers, as well as various other achievements. It is well to pause and take stock of ourselves. Present Status of Crude Oil Supply and Demand The total daily new supply of oil is at this time1 about 2,960,000 bbl. per day, made up of 2,585,000 bbl. domestic crude production, 125,000 bbl. casinghead gasoline, and 250,000 bbl. of imports. With the present low consumption, due to the falling off in the winter season demand, it is estimated that about 150,000 bbl. a day are now being run to storage, and that the first three months in 1929 will see large-sized additions to storage. Consumption plus exports of oil have increased at a regular rate from year to year, and although oil production in 1928 passed the 1,000,000,-000 bbl. mark for the second time in the history of the United States, with a production of 25,000,000 bbl. more than in 1927, only 30,000,000 bbl. were added to storage during 1928. This is compared to an addition of 65,500,000 bbl. in 1927.

Jan 1, 1929

By P. F. Gnirk, J. B. Cheatham

The results of combined analytical and experimental studies involving simulated multiple bit-tooth penetration into mck are incorporated into a drilling rate equation for roller-cone bits assuming rather idealized downhole conditions. In particular, it is assumed that the rock behaves statically in a ductile fashion during bit-tooth penetration and that the rock chips are instantaneously removed from the bottom of the drill hole. The general analysis demonstrates an application of plasticity theory for the rock/bit-tooth interaction to the formulation of an upper limit on rotary drilling rate. INTRODUCTION Extensive experimentation involving single and indexed bit-tooth penetration into rock in a confining pressure environment has demonstrated that the chip formation process is of a ductile, or pseudoplastic, nature at sufficiently low differential pressures so as to be of interest in rotary drilling. Coincident with the experimentation, analytical consideration has been given to the theoretical problems of single and indexed bit-tooth penetration into rock. In general, the analyses have assumed that the rock behaves statically in a rigid-plastic fashion and obeys the Mohr-Coulomb yield criterion. The quantitative comparison between experimental and calculated values of bit-tooth load required for chip formation has been remarkably good for a variety of rocks commonly encountered in drilling and at simulated differential pressures as low as 500 to 1,000 psi. Results obtained recently for indexed bit-tooth penetration indicate that the work (or energy) required to produce a unit volume of rock chip can be minimized by a proper combination of bit-tooth spacing and bit-tooth load for a given rock type and differential pressure. By utilizing this information, it is possible to formulate a drilling rate equation, at least in a preliminary fashion, for a roller-cone bit performing under rather idealized downhole conditions. In particular, through the use of characteristic dimensionless quantities pertinent to a roller-cone bit and to indexed bit-tooth penetration, interrelationships among bit weight, rotary speed, rotary power, bit diameter, rock strength and bit-tooth shape and spacing can be explicitly expressed. In the formulation of the equations, however, it is assumed that the rock chips are instantaneously removed from the bottom of the drill hole and- that the rock behaves in a ductile manner during bit-tooth penetration. In addition, the effects of bit-tooth load application and penetration by a yawed tooth at an oblique angle are neglected. Although the analysis is presented in the light of some rather restrictive conditions, it does demonstrate a method of applying fundamental rock/bit-tooth interaction data, obtained by combining the results of analysis and experiment to the formulation of a drilling rate equation for rotary drilling. JNDEXED BIT-TOOTH/ROCK INTERACTION PREVIOUS RESULTS The mechanics of bit-tooth/rock interaction under simulated conditions of borehole environment have been extensively described in a number of papers.l-ll In particular, the effects of differential pressure, mechanical properties of rock, pore fluid, bit-tooth shape and spacing, rate of bit-tooth load application and dynamic filtration below the bit-tooth have been investigated experimentally. From a sequence of experiments.1-4 it was demonstrated that, for dry rock at atmospheric pore pressure, the mode of chip formation exhibits a transition, with increasing confining pressure, from predominantly brittle to predominantly ductile. This transition

Jan 1, 1970

By Jerry L. Huiatt

An accurate and reproducible procedure was developed using the gas-liquid chromatograph to quantitatively measure oleic acid on flotation products and in flotation water phases. The method comprised extraction of the oleic acid from the mineral surfaces with alcoholic NaOH, esterification of the extracted oleate, and chromatography of the methyl ester with an internal standard. Quantitative analysis of oleic acid on flotation products from test tube and bench-scale flotation tests with pure minerals and with natural ores proved the applicability of the method on a variety of minerals. The accountability of oleic acid added was 100 percent, ±5 percent.

Jan 1, 1968