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By Prasad S. Mulukutla

INTRODUCTION The use of specialty chemicals In mining Is an Important consideration In determining the economic efficiency of a floatation plant. The plant metallurgist would like to maximize the recovery of valuable minerals while maintaining an acceptable grade product. The direct cost of the reagents, while significant, Is only a part of their economic effect. Reagents determine the flotation rates and the selectivity of the mineral separation. In flotation practice, mineral selectivity can be achieved through the addition of various reagents that can control the wettablllty of a particular mineral In the flotation pulp. The reagents which will generally optimize the flotation process are commonly classified Into three distinctive categories: collectors frothers and modifiers. Large tonnages of metal sulphide concentrates which are the source of most of the common base metals are produced economically by fairly standard flotation techniques. The advent of modern technology coupled with the necessity of processing finely disseminated and complex ores of low grade has Increased the need for utilization of non traditional and high selective chemicals reagents for the economic recovery of metals and raw materials. Mining operations in developing countries continue to progress at a rapid growth as many countries mine and process both metallic and nonmetallic ores. The total mine production of base metals, precious metals, Iron ores and coal In developing countries In Africa, Asia and South America has been much higher as compared to the western world production In terms of tonnage and dollar value. Global capital Investments In mining during 1991-95 Is $ 55.1 billion and It Is anticipated that the development of new and specialty reagents may be concentrated In the processing of aluminum , copper, precious metals and Industrial minerals with special reference to potash, phosphates, kaolin and silica sands.(1) The challenge for the design and development of new specialty chemicals Is dependent on Its cost performance and environmental acceptability. Information on the theory and application on the development of mining chemicals has been reviewed In several conference proceedlngs,(2-4) publications(5) and also discussed by several Individual authors.(1,6-10) These publications serve as a comprehensive reference source on the reagents used In several flotation processes. This paper discusses the present trend in the use of specialty mining chemicals In diversified mining operations on several mineral systems with particular reference to sulfide ore systems. The necessity to expose these specialty chemicals through aggressive marketing techniques In mining operations In many developing countries Is also presented. SPECIALTY CHEMICALS Specialty mining chemicals, like other specialty chemicals, share common business characteristics that transcend geographic boundaries. They are manufactured 1n a few selected areas, generally expensive relative to commodity chemicals, shipped and compete globally and usually require specialized knowledge for proper use. Specialty mining chemicals are relative newcomers to chemical markets. The vast majority of mining chemicals are derived from products that are less than two decades old. Traditional collectors and frothers have been available for a considerably longer time. The emphasis on adding value to existing products and byproducts Is responsible for several characteristic features of the mining chemicals business. Most raw materials for these chemicals are related to oil and gas byproducts, chemical refineries, pulp and paper mills and all chemical manufacturers. Until the last several years these operations were located In Industrialized countries, while a significant number of mining chemical users were In developing countries. Therefore International trade In mining chemicals developed through agencies or agents in each particular country.

Jan 1, 1993

By B. E. Davis

Over 80 pct of domestic phosphate rock, which is the starting material for phosphorus-containing fertilizers, comes from central Florida deposits. As K-her grade deposits are depleted, lower grade phosphate ores containing 'Mg0 in the form of dolomite are encountered. Treating high MgO ores with present beneficiation technology will not yield a concentrate meeting specifications for acidulation. The Bureau of Mines conducted research on three high-MgO phosphate samples from south Florida. The sales contained, in percent, 5.4 to 10.2 P205, 1.9 to 7.6 MgO, and 35.3 to 60.1 acid insolubles. A technique of sizing, grinding, desliming, scrubbing, and redesliming was used to produce a feed suitable for continuous flotation studies, A conventional fatty acid-fuel oil rougher flotation followed by two to three cleaner stages resulted in concentrates containing, in percent, 30.7 to 31.3 P205, 0.6 to 1.3 MgO, and 2.5 to 4.8 acid insolubles. The P205 recovery from the flotation feed ranged from 55.1 to 89.7 pct.

Jan 1, 1984

"Dada la dificultad de ajustar el tonelaje de extracción de mineral a la demanda de la manufactura, puesto que crea una sobrecarga en el equipo de transporte minero, el objetivo de nuestro trabajo, estriba en solucionar los inconvenientes derivados de extracción irregular a través de un dispositivo de capacidad de reservas en tolvas que permita al personal técnico trabajar con un margen en el tonelaje dentro de una explotación sistemática. Para ello, es necesario la ampliación de las tolvas de madera actuales y asi aumentar la capacidad de 1000 T,M. hasta. 4,000 T.M, que pudieran absorver posteriormente cualquier ampliación de la concentradora y regular la extracción del mineral. Entre otros recursos complementarios al proceso, tenemos el uso de las tolvas de gruesos en roca, las tolvas cilíndrico-cónicas, socavón de carga (de descarga e inclinado), desatrague, la ejecución de los trabajos en roca y el diseño, construcción e instalación de los transportadores de caja. "

Jul 20, 1957

By Thomas V. Falkie, R. Venkataramani

Table

Jan 1, 1972

The Colorado portion of the Rio Grande rift is clearly defined physiographically from the south in the San Luis valley northward to the latitude of Leadville where sediments of the Dry Union Formation (Tweto, 1961) accumulated within the subsiding rift zone. To the north of Leadville is a system of faults active in the late Tertiary, including the Mosquito fault that offset a portion of the Climax mineralization (Wallace et al., 1968). Tweto (197B) describes remnants of Dry Union Formation against the Mosquito fault north of Dillon in the Blue River valley, so it is apparent that the rift and associated sediments extended well to the north of Leadville. Kelley (1952, 1954, 1956) and Chapin (1971) have noted in New Mexico that the Rio Grande rift is a series of en echelon basins, offset to the east, with constrictions connecting them (Fig. 1). In Colorado the structural basins are offset to the west. The net effect of all the rift zone basins in New Mexico and Colorado is an arcuate pattern (Fig. 1) abutting the Colorado Plateau and Sari Juan Volcanic Province on the west. The width of the rift system gradually decreases northward to about Leadville where rift definition is not apparent.

Jan 1, 1987

Jan 1, 1883

By M Chiquito, R Castedo, P Segarra, L M. López, J A. Sanchidrián, J Navarro

The aim of this work is to assess the performance of different constructive solutions against explosions on the strength of masonry walls. The solutions tested, namely an external metal mesh, a glass fibre film on the external face of the wall and a basalt fibre film located on the inner face of the wall, have low to medium cost and are originally designed for other purposes, like seismic protection. Four cubic boxes 3 × 3 × 3 m were built using each of the solutions and typical masonry blocks. In the tests, a spherical plastic explosive initiated in the centre was placed at scaled distance of 2.9 m/kg1/3, so that moderate damage would be caused on the wall. In order to assess the performance of the explosive, pressure gauges were placed at the wall and at different distances from the explosion. Additionally, vibrations were monitored with seismographs in the far field and a high-speed camera was used to estimate the shock wave velocity during the tests. The resulting damage has been evaluated on 13 points of the external wall of each box using a rebound hammer. Damage maps have been drawn for each wall based on these measurements and damage has been assessed inside the box considering the fragments mass launched during the test. The use of external metal mess leads to a decrease of 34 per cent on damage of the external wall and 38 per cent reduction of spalling. The use of a film in the inner wall provides a strong reduction on spalling.CITATION:López, L M, Segarra, P, Castedo, R, Sanchidrián, J A, Navarro, J, Santos, A P and Chiquito, M, 2015. Performance of different constructive solutions against explosions in full-scale masonry walls, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 819–824 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By Richard W. Smith

KYANITE, long known to occur in Georgia, did not excite commercial interest until about 1930. Investigations revealed two main types of deposits: (1) separate kyanite crystals embedded in mica schist; and (2) crystal aggregates of kyanite associated with quartz in small and very irregular veins. The second kind at first sight appeared to be the best source of supply. Large boulders or dornicks of kyanite with more or less quartz were found on the surface at many places throughout the Piedmont and Highland sections of the state, but prospecting failed to disclose a sizable vein. These dornicks seem to be a surface accumula-tion from small veins or lens-shaped masses not more than one or two feet thick, and with a horizontal extent of not' more than a few feet. The larger surface accumulation of kyanite dornicks, where not too badly stained by iron oxide, may prove to be marketable, but it is extremely doubtful whether a vein large enough to mine will ever be found. In 1932 deposits of the kyanite-mica schist were known to occur in two places northwest of Clarkesville, in Habersham County. In 1934, at the request of and in cooperation with the Georgia Geological Survey, the United States Geological Survey made a thorough investigation2 of the deposits and found that the two known areas of kyanite-mica schist in Habersham County were but a part of an unsymmetrical, U-shaped belt (Fig. 1) with a western limb extending into Rabun County and somewhat longer than the eastern limb. The total length of the belt is about 30 miles. The width of outcrop ranges from 100 ft. to 1/4 mile or more. Deposits of kyanite-mica schist of very doubtful commercial importance were found in several other counties. Only the deposits of this kyanite-mica schist belt in Habersham and Rabun counties will be discussed in this paper.

Jan 1, 1936

Minute of the Board of Directors, Jan. 26, 1917 In the name of all the members of the American Institute of Mining Engineers, this Board extends to. Mr. Herbert C. Hoover, an honored Vice-President of the Institute, on the occasion of his present temporary return to his native land, the cordial welcome of his colleagues, and their congratulations upon the noble work splendidly done by the Commission for Relief in Belgium of which he is the head. It is understood that a leading purpose of Mr. Hoover's visit to America at this time is the collection of additional funds, to be administered by his Commission in the care of the destitute children of Belgium. To this enterprise endorsed by both the belligerent parties, as well as inspired by the purest and tenderest sentiments of humanity, contributions are solicited from engineers, especially through an organization known as the "Belgian Kiddies Limited," which this Board, heartily approving its object and method, recommends to the consideration of the members of the Institute. On motion duly seconded it was unanimously VOTED.-That this minute be spread upon the record of the Board, and published in the Bulletin, and that a copy thereof be transmitted to Mr. Hoover, and to the San Francisco Section of the Institute.

Jan 3, 1917

By Georgy Cherkashov, Tamara Stepanova, Anna Firstova

INTRODUCTION High tellurium contents in the ancient volcanogenic massive sulfides (VMS) and modern seafloor massive sulfides (SMS) have been reported by V.Maslennikov (Maslennikov et al., 2013). However findings of tellurium minerals in SMS are rather rare. The only reported coloradoite and bi-melonite, have been found in massive sulfides from Rainbow hydrothermal field (Fouquet, 2010). Here we present data about Te - minerals in sulfide chimneys of different ages (up to 84.7 kyr - Cherkashov et al., 2010 ) from Semyenov-2 hydrothermal field. The obtained results The Semyenov hydrothermal cluster was discovered and studied in the course of cruises 30 and 32 of R/V Professor Logachev (2007 and 2009) at 13º31´ N, MAR. This area is associated with an oceanic core complex and associated with serpentinized gabbro- peridotites and basalts. Plagiogranites and tonalites have been dredged on seafloor in the Semyenov cluster area (Cherkashov et al., 2013; Pertsev et al., 2012). In total, 25 sulfides samples have been studied. The major and minor mineralogical phases were identified using reflected light microscope. Major element compositions of ore- forming minerals were analyzed on a Hitachi S3400N scanning electron microscope at the Geomodel Center, St. Petersburg State University (St. Petersburg, Russia) with an AzTec Energy 350 (EDX) detector and an INCA 500 (WDX) detector.

Jan 1, 2018

By Kenneth L. Bickel

During an underground mine fire, the importance of controlling the spread of smoke and toxic gases with suitable ventilation structures has been proven. However, under certain conditions, control of the propagation of the fire itself may be even more critical in insuring a safe mine evacuation. Fire doors offer the means for accomplishing both objectives. In 1978, the Bureau of Mines initiated research to evaluate the state of fire-door technology and develop and test a fire door suitable for large openings (10 by 12 ft or larger) in noncoal underground mines. This report discusses current fire-door technology in the context of the underground mine environment and the design, fabrication, lab testing, and in-mine field testing of a mineworthy fire door. This door has a 1.5-h fire resistance rating and limits temperature rise across the door to 2500 F during the first 30 min of fire exposure.

Jan 1, 1987

By Carla A. Kertis

Because coalbed discontinuities often pose serious economic and safety problems in underground coal mines, criteria were documented for the recognition and prediction of discontinuities in advance of mining. Pennsylvanian strata in Indiana and Armstrong Counties, PA, were deposited as part of fluvio-deltaic complexes with channel-phase sandstones as the predominant type of coalbed discontinuity. Coalbed isopach maps constructed for this study delineated numerous want areas (areas of no coal) with elongate to linear geometries. A comparison of coalbed isopach and corresponding sandstone isolith maps of the study area revealed many examples of a thick-sandstone, thin-subjacent-coalbed relationship. Nearly 60 pct of the want areas in the study area were found to lie subjacent to thick (> 20 ft [6 m]) sandstone accumulations. In addition to erosion of the coalbed, channels may contribute to coalbed splitting, coalbed thinning over paleotopographic highs, abnormal coalbed thick- nesses, and deterioration of coal quality. If these features are considered, then approximately 80 pct of all interruptions in the economic coalbeds in this area result from channel activity. By using the criteria developed in this study and described in this Bureau of Mines report, the occurrence of coalbed discontinuities may be predicted and anticipated in advance of mining.

Jan 1, 1985

By A. Yehia, J. S. Hu, J. D. Miller, M. Misra

Fluoride activation has been evaluated by Hallimond tube flotation of collophanite in terms of fluoride concentration, conditioning time, pH, and temperature. The results reveal that efficient oleate flotation of collophanite can be achieved by fluoride activation. Experimental results of fluoride adsorption by collophanite suggest that, at low fluoride concentration, a fluoroapatite-type compound may form on the collophanite surface by chemisorption of fluoride ions at calcium sites. At high fluoride concentration, calcium fluoride appears to form at the collophanite surface involving a surface precipitation phenomenon. The formation of CaF2 on the surface of fluoride-treated collophanite is further substantiated by the FTIR spectroscopic measurements, which suggest a metathetic exchange with phosphate from the collophanite lattice during the surface precipitation process.

Jan 1, 1988

By J. T. McCartney

Thin sections of coal have been prepared for many years either by cutting on a microtome (1,2)5 or by grinding and polishing (2,1). Specimens of most coals had to be demineralized in hydrofluoric acid and softened in caustic solutions before they could be successfully cut with a conventional microtome. Some lignites could be cut without pretreatment. Jeffrey (1) obtained sections from coals of all ranks, although long and tedious pretreatment was required for anthracite. His sections were less than 1 cm.2 in area (probably much less for high rank coals) and about 5 microns thick. Thiessen (2) also cut sections of softened coals, mostly of low rank. His sections were a few square millimeters in area and about 3 microns thick. However, Thiessen preferred ground and polished sections for detailed studies because they were larger and had not been chemically attacked by softening media. He prepared ground sections as large as 4 cm.2 in area and usually 5 to 10 microns thick. Thousands of such sections, covering complete column samples of many coal beds, were studied for a number of years (4). With the development of the electron microscope and increased interest in quantitative optical studies of coals, a need for much thinner sections arose. However, no suitable technique for preparing such sections was known until Fernández-Morán developed a diamond knife for cutting ultrathin sections of hard materials (5). Workers at the Centre d'Etudes et Recherches de Charbonnages de France applied this new tool to the cutting of coal sections and have recently described their technique to the Burg, of Mines. Using their methods, with some modifications, researchers of the Bureau of Mines have succeeded in cutting ultrathin sections of coals ranging in rank from lignite to

Jan 1, 1961

By Z. T. Bieniawski

This paper presents the results of a survey of room and pillar dimensions and design practice in U.S. coal mines aimed at improving the design procedures in room and pillar mining. A review is given of the current pillar strength formulas and suggestions are made for better utilization of research results in engineering practice.

Jan 1, 1981

By J. D. Galloways

The northern part of the P. G. E. railway traverses and opens up that part of the province known as the Cariboo district, comprising the Cariboo and Quesnel Mining Divisions, which are a part of the Northeastern Mineral Survey District. Williams lake, a divisional point on the P. G. E. is near the southern boundary of the Quesnel Division and from this point the railway runs northerly to Quesnel, its present terminus. From Quesnel the railway is projected and partially constructed to Prince George on the Canadian National railway; therefore its general trend is northerly through the heart of the Cariboo district. Early History There is no need to outline at any length the early history of mining in the Cariboo. It is sufficient to say that the great gold rush to the Cariboo, in the early sixties, was practically the commencement of mining in British Columbia. These early placer mining operations centred around the old towns of Quesnel Forks, Keithley Creek, Barkerville and Van Winkle, the latter now called Stanley. Many millions of dollars of placer gold have been taken out and the end of production is not in sight yet. The maximum yearly production was reached about 1863, after which there was a gradual decline in output. During the war years production was at a very low figure but a steady, even if small, increase has occurred in the last three years and prospects are encouraging for a much greater output.

Jan 1, 1925

By A. B. Young

THE difficulties encountered in the preparation of. the lead smelter charge for the blast furnace and in the roasting and sintering of the ores, and the expert means taken for the preparation of these materials since the introduction of flotation concentrates into the lead smelter charge, have been described by W. H. Eardley1 and R. A. Wagstaff.2 FUNCTION OF ROASTERS AND BLAST FURNACES The lead smelter has first its roasters and its sintering devices, of which the primary object is the removal of sulfur from the ore or from the charge. The blast furnace follows; its function being the elimination of the gangue material left in the charge-the elimination of the insoluble, the iron, the zinc and the lime from the metallic lead. The secondary object is the separation of copper from the lead. A lead blast furnace is a sensitive apparatus. The materials composing the charge must be marshalled inn certain proportions before they will, make a fluid slag which will separate from the metallic lead. The silica, iron, lime and zinc must be put together in proportions that usually do not exist naturally in the ores, therefore fluxes are necessary. FUNCTION OF THE FLOTATION CELL The flotation cell-speaking from the standpoint of a lead concentrate-has taken over part of the work hitherto performed entirely by either gravity concentration or the lead blast furnace. It has eliminated gangue from the concentrate and separated waste products from the lead. In so far as it has done that, it has usurped some of the function of the lead blast furnace; and it is much cheaper to run a flotation cell than a lead blast furnace. The effect in Utah, and it will be similar to effects in other districts, has been to remove a great deal of the gangue by means of flotation, whereas in the old days it was eliminated by means of smelting. In this district, as in others, the insoluble content of the ores has been greatly out of proportion to the iron and lime content to make a proper slag

Jan 1, 1928

By S. A. Falconer

This paper deals with the practical application of the Dutch State Mines cyclone separator for fine-coal cleaning. The more important operating variables are discussed, and results of a number of continuous- scale tests on various fine coals with a 6-in. cyclone separator are given. Descriptions of the Cyanamid Pilot Plant and the 50 tph Cyclone Separator Plant at the Emma Washery in Holland are included.

Jan 7, 1950

By Hll J. K, Zhang Y. G

The wear mechanisms of impregnated diamond drill bit matrices are complex and believed to be the key point in solving drill bit self-sharpening problems. A method has been developed to find the change in c,, the wear rate of matrices having different fracture toughness K_ at the increment of drill pressure P. The worn surfaces of specimens were placed under a scanning electron microscope to examine the wear patterns and wear mechanisms at different pressures, and were compared with the worn surface of a practical drill bit. A model is proposed that within a wide range of pressures there exist two different wear mechanisms and three wear regions for cemented car- bide matrix materials. In region one (linear region), at low pressure, the major wear mechanism is plastic deformation in which the preferential wear of the binder phase of the matrix results in the loss of WC, tung- sten carbide particles. Wear rate is controlled by hardness, H as Archard's formula predicts. Wear enters region two and three (non-linear region) simultaneously as pressure is being increased. Consequently, wear transfers to fracture mechanism in which micro-fracture occurs at the root of wear grooves and the material is removed mainly in piece and mass. It has been shown fracture toughness K,, plays a more important role than hard- ness H. It is concluded that for a specific drilling condition, the pressure on the matrix should be carefully controlled and a balance between hard- ness and toughness of the material is essential for a steady drilling Condition.

Jan 1, 1989

By Ennio Bonetti

The technological applications of MgH2 hydrides for hydrogen storage demand the overcoming of some critical issues: an improvement of the reaction kinetics and a reduction of the desorption temperature. The synthesis of nanocrystalline MgH2 by reactive milling and inert gas condensation and a proper metal catalyst addition, constitute recently employed strategies. In the investigation of the hydrogen short and long-range dynamics, sorption kinetics and nanostructure stability, the mechanical spectroscopy offers some specific advantages. In the present research this technique was employed with other experimental approaches (XRD DSC) to investigate relaxational and structural damping processes in nanocrystalline MgH2 with added catalysts (Fe). Time/temperature variation of the dynamic elasticity moduli and mechanical quality factor are correlated to hydrogen anelastic relaxation processes and concomitant structural transformation of MgH2 to Mg associated to long range H diffusion. Results are discussed with reference to microstructural modification strategies able to assist hydrogen release.

Jan 1, 2006