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By Charles B. Dudley

DEAR SIR: It is now nearly three years since my first report to you on the subject of steel rails was written. That report, as you will remember, dealt principally with the question of the relation between the chemical composition and physical properties of steel rails end their power to resist crushing and fracture in actual service. Other matters were referred to or touched upon in that report, but the main question was, Why do some rails crush or break in service while others do not? Yon will doubtless remember that the principal conclusion arrived at was, that the softer rails are less liable to Crush or break in service than the hard ones. Or, in other words, so far as conclusions could be drawn from the chemical analysis and physical test of 25 samples of steel rails which had actually been in service, these conclusions were that those rails which have the smaller amounts of carbon, phosphorus, silicon, and manganese are less liable to crush or break in service than those which have larger amounts of these elements. Or, again, looked at in the light

Jan 1, 1881

By Peter N. Holtham, Mary M. Ng

"Resistivity measurements of minerals in the laboratory are commonly made with a low DC voltage source. Common test voltages specified in the ASTM Standard D257 are 100, 250, 500, 1000, 2500, 5000, 10000 and 15000 V, however 100 and 500 V are the most frequently used. Resistivity results obtained in the laboratory have been used to infer the electrical behaviour of minerals undergoing electrostatic separation. However because the voltages employed in electrostatic separation in the plant are of the order of thousands of volts, typically greater than 15000 V, whether the laboratory results are applicable as a predictor of plant performance is a critical question. It is unclear whether resistivity values taken at a low voltage are characteristic of those seen in electrostatic separation, in which the minerals are exposed to a much higher voltage. No definitive answer could be found in the literature.In this work, the resistivities of zircon, rutile and ilmenite were measured in a corona field for the first time. The measurement principle was based on a technique developed to measure fly ash resistivity in electrostatic precipitators, however the test apparatus and findings are novel.Resistivities of rutile and zircon were found to be easy to measure. The values measured in a corona field were several orders of magnitude less than those obtained with a dc voltage of 100 V. Evidence of back corona was observed with zircon. When the voltage drop was greater than the sample layer could withstand a localised electrical stress developed, resulting in a voltage breakdown, at which point a sudden surge of corona current (back corona) was detected in the sample layer. Rutile, on the other hand, exposed to the same conditions as that of zircon (i.e. same temperature and applied voltage) did not exhibit any sign of back corona. Its resistivity across the range of test voltages (14 to 33 kV) remained fairly constant."

Jan 1, 2003

By T Leach, I Pringle

The Bowdens Silver Deposit is a low sulfidation epithermal silver-base metal deposit that has formed on the northern margin of a hydrothermal system within air-fall breccias, ignimbrites and crystal tuffs of rhyolitic composition. The deposit lies near the north-eastern margin of the Lachlan Fold Belt and the rhyolitic host rocks are of Early Permian age. The silver mineralisation occurs as flat-lying zones of disseminations and silicic fracture-filling within the Rylstone Volcanics and is closely associated with sulfides of iron, arsenic, lead and zinc. High-grade silver mineralisation is also found in steeply-dipping fracture zones which host banded sulfide veins. Studies of the alteration products indicate that high temperature fluids, flowing from south of the current project area, resulted in quartz (¦adularia) û illite/sericite alteration. Cool, low pH steam-heated waters on the northern and eastern margins of the prospect area resulted in siderite û smectite-illite clay û Fe-carbonate û marcasite û kaolinite alteration. Mixing of the two fluid types resulted in the deposition of iron and base metal sulfides, a decrease in both sulfur activity and pH of the mineralising fluid, and subsequent silver mineralisation.

Jan 1, 2004

By D. Allan Coutts

Demonstration projects using hydrogen as a fuel are becoming very common. Often these projects rely on project-specific risk evaluations to support project safety decisions. This is necessary because regulations, codes, and standards (hereafter referred to as standards) are just being developed. This paper will review some of the approaches being used in these evolving standards, and techniques which demonstration projects can implement to bridge the gap between current requirements and stakeholder desires. Many of the evolving standards for hydrogen-fuel use performance-based language, which establishes minimum performance and safety objectives, as compared with prescriptive-based language that prescribes specific design solutions. This is being done for several reasons including: (1) concern that establishing specific design solutions too early will stifle invention, (2) sparse performance data necessary to support selection of design approaches, and (3) a risk-adverse public which is unwilling to accept losses that were incurred in developing previous prescriptive design standards. The evolving standards often contain words such as: ?The manufacturer shall implement the measures and provide the information necessary to minimize the risk of endangering a person?s safety or health.? This typically implies that the manufacturer or project manager must produce and document an acceptable level of risk. If accomplished using comprehensive and systematic process the demonstration project risk assessment can ease the transition to widespread commercialization. An approach to adequately evaluate and document the safety risk will be presented.

May 1, 2007

By Diego Benites

El presente texto señala los resultados de la caracterización mineralógica de 28 muestras con importante contenido en sulfosales de plomo y cobre de origen hidrotermal provenientes de la Sierra Central del Perú. El principal objetivo fue caracterizar la mineralogía de la zona con énfasis en las sulfosales y el aporte de plata que éstas podían contener. Así, las sulfosales identificadas por microscopia óptica en conjunto con microscopia electrónica de barrido son: tetraedrita, tennantita, boulangerita, bournonita, fizélyita, jamesonita, semseyita, zinkenita; entre otros. Para determinar qué minerales aportaban plata y en qué porcentaje, se realizaron estudios puntuales por microscopia electrónica. Así también se verificó que la plata se aprecia en pequeñas cantidades en sulfosales de plomo, mientras que éstas aparecen en mayor abundancia con respecto a las sulfosales de plata y de cobre.

Oct 21, 2015

By A. T. Yu

On March 18, 1964, the 52,000 dwt ore carrier M/S Houn Maru called at the port of Coquimbo, Chile, on its maiden voyage to take iron ore to Japan. This marked the first time a vessel of this size ever arrived at Coquimbo, and the event promises to drastically accelerate henceforth iron ore exports from Coquimbo province. This was made possible by the use of a versatile shiploading system recently installed by Cia. Minera Santa Fe. Coquimbo has no mechanized loading facilities other than six conventional 5-ton cargo cranes. Limited space on shore further complicates the stocking problems. To make the best of what is available, a meticulously organized semi-hand-loading system has been developed through the years.

Jan 5, 1964

K. T. Aust and J. W. Rutter (General Electric Research Laboratory)—We find it difficult to reconcile the activation energies determined by Gifkins with his general conclusion that "migration during both creep and grain growth can thus be treated on the basis of the same model" (that of Lucke and Detert). Gifkins finds the activation energy for grain boundary migration during creep to be 24.5 kcal per rnol and that for grain boundary migration during grain growth to be 7.5 kcal per mol. The calculation carried out by Gifkins of the activation energy for grain boundary migration during grain growth, using the Lucke and Detert model, gives a value of 20 to 24.5 kcal per mol, rather than his experimental value of 7.5 kcal per mol. The theory of Lucke and Detert was developed to account for the rates of migration of grain boundaries in the presence of impurities during grain growth. The theory does not take into account the effect on the boundary migration of another, simultaneous process such as creep deformation and would be expected, therefore, to be applicable only to migration during grain growth. The fact that Gifkins measured a different activation energy for boundary migration during grain growth (7.5 kcal per mol) from that during creep (24.5 kcal per mol), although the specimens were of the same composition, shows clearly that such an effect exists under his experimental conditions; the presence of a simultaneous creep deformation markedly affects the boundary migration process in comparison with what would be observed under the same conditions but without the creep deformation. The failure of McLean's equation (Eq. [4] of Gifkins' paper) to give a satisfactory dislocation density difference for boundary migration during creep is not surprising, since the activation energy which must be used in this equation refers only to the elementary atom transfer process of grain boundary migration. This activation energy value is approximately 6 kcal per mol for zone-refined lead, as determined in both the grain boundary migration experiments of Aust and Rutter31, 32 and the grain growth experiments of Bolling and Winegard.33 Using this activation energy value, McLean's equation gives reasonable agreement with observed migration rates for grain boundaries moving free of the influence of impurities.31, 32 The value of 24.5 kcal per mol is probably associated with the presence of impurity atoms, as Gifkins suggests. It should be noted, however, that this value was obtained using lead of only one composition and measurements at only two temperatures. The work of Aust and Rutter3"' on the effects of tin, silver, and gold on grain boundary migration in zone-refined lead in the temperature range from 320" to 200°C, as well as the work of Bolling and Winegard34 on the effect of silver and gold on grain growth in zone-refined lead, shows that the measured activation energy is markedly dependent upon the kind and amount of solute present. Gifkins' work does not permit evaluation of the effect of the 8 ppm of impurities other than oxygen present in his specimens. One incidental point: the symbols used to designate the experimental points of Fig. 6 appear to be in incorrect order in the figure caption. As the caption is printed, it would indicate that larger grain sizes were obtained after annealing at 47°C than at 100°C, which does not agree with the text (point M, p. 1019). Finally, it seems clear from Gifkins' results that any serious attempt to determine whether grain boundary migration and grain boundary sliding during creep occur with the same activation energy, as Gifkins suggests and McLean rejects, must take into account the effects of impurities on these two processes, Although the work of Weinberg35 indicated that adding small amounts of copper, iron and silicon to aluminum did not affect the grain boundary shear behavior, it should be noted that his starting material contained approximately 60 ppm of impurities. Gifkins' results indicate impurity effects at an impurity level of 8 ppm, suggesting strongly that the most significant impurity range to be investigated lies substantially below that value. R. C. Gifkins (author's reply) — As Drs. Aust and Rutter suggest, the results under discussion may have to be reinterpreted in the light of their own work on grain boundary migration, which was not available to me when the paper was written. Because of their work, Aust and Rutter attach more importance than I did to the activation energy for grain boundary migration during annealing (7.5 kcal per mol) obtained from a "direct" plot of log-rate against the reciprocal of absolute temperature. At the time it was obtained, this value seemed rather low, although it was similar to the value obtained by Bolling and Winegard.36 It was then, and still is, difficult to accept this value because of the low value of the index in the power law for grain growth, which seemed to indicate the influence of impurities. It was also concluded that the low value of the activation energy might have arisen from the manner of selecting rates of grain growth which were truly comparable at the two temperatures. There were many other indications in these experiments and those on recrystallization during creep3? that an impurity, probably oxygen, was of importance. The model for grain-boundary migration which Lucke and Detert had proposed was an obvious possibility and its use yielded an activation energy for boundary migration during annealing of 20 to 25 kcal per mol.

Jan 1, 1961

By Pierre Hines

THESE notes are based on observations made while on a recent trip through the West, for the purpose of studying the practical operation of the ball-mill. The writer takes this opportunity to express his thanks for courtesies extended at the many plants visited as well as for the valuable data received. While there are several types of ball-mill on the market, particular attention will here be given to the diaphragm type, as the open-trunnion type, especially the conical mill, has been thoroughly discussed in the Transactions. There is a prevailing impression that the ball-mill is a recent development; however, ball-mills were used extensively in Montana and other western states for crushing ores for concentration as far back as 1898. Its present prominence is due in part to its recent successful application by one of the large copper companies. Without any reference to dry grinding, the first successful ball-mill for wet crushing, which is still in operation, was built 10 years ago.1 This mill, designed by Erminio Ferraris for crushing Sardinian ores for concentration, is of more than passing interest. It embodies the peripheral discharge with grates, large forged-steel balls, and the principal features of the modern ball-mill. The results approach present-clay practice, the chief differences being that the mechanical construction has been improved in the modern types.

Jan 2, 1918

By T. Xin

A vertical grain boundary intercepting a horizontal free surface forms a groove to reduce the combined surface energy of the system. We study grooving by surface diffusion with anisotropic surface energy. A recently developed delta-function model of facets is used to describe the surface energy with three or four fold symmetry. It is found that the groove grows following a similarity law. The self-similar groove profile is solved numerically by a shooting method. Even with strong anisotropy, the groove profile can be smooth if the exposed surface orientations do not include a facet orientation. The smooth self-similar groove shape is the same as an isotropic groove, but the size is reduced by a factor that depends on the degree of anisotropy. This induces a large error on the value of surface diffusivity if the isotropic model is used for an anisotropic system. In this talk. we will describe how to correct for this error.1 I Xin, T. and H. Wong, "Grain-Boundary Grooving by Surface Diffusion with Strong Surface Energy Anisotropy," Acta Materialia 51, 2305-2317 (2003). Keynotes: Grain growth, Surface Diffusion, Surface energy, Anisotropy

Jan 1, 2003

The problems of using comparatively simple x-ray diffraction equipment for quantitative analysis are examined. Internal standard and direct calibration procedures based upon the measurement of integrated diffraction energy (diffractometer peak area) have been developed for the determination of quartz in Broken Hill dusts. By these methods an accuracy of ± 10 per cent of the true value can be obtained and this can be improved to ±2 1/2 per cent by statistical methods if necessary.Rapid analysis for the components quartz, muscovite, rhodonite, galena, fluorite, sphalerite, calcite, and garnet has been developed by adaptation of direct calibration procedures and use of maximum diffraction energies (diffractometer peak height). Until more is know!) about the pathological effects of multi-component dusts of the Broken Hill type it seems undesirable to fix theIr allowable concentrations in terms of the quartz content.

Jan 1, 1968

By Yagesh N. Bhambhani, Rammohan V. Maikala

Landstrom et al. (1985) suggested the possibility of cortical activation during exposure to WBV, however, it is not known how cerebral physiology (oxygenation and blood volume) responds in healthy women during different vibration frequencies. This study examined the role of backrest support and handgrip work on cerebral oxygenation and blood volume responses, during exposure to seated WBV. Methods Fourteen women (age: 23.9 ± 3.5 years) were randomly exposed to three frequencies of WBV (3, 4.5 and 6 Hz at approximately 0.9gr.m.s in the vertical direction) on a customized vibrating base (Advanced Therapy Products, Inc., USA) in a seated posture on three separate days. On the first day, the subjects completed an aerobic fitness test until volitional exhaustion on an arm cranking ergometer (Cybex, MET 300, USA). Each WBV session lasted 30 min (6 min baseline without WBV, 8 min WBV ‘with’ or ‘without’ backrest support, and 4 min recovery from WBV, 8 min WBV with ‘opposite’ backrest condition, and 4 min recovery following WBV). During 8 min WBV exposure ‘with’ and ‘without’ backrest support, subjects performed maximal voluntary rhythmic handgrip contractions with their right hand for 1 min using a dynamometer. To obtain regional oxygenation and blood volume responses, a NIRS sensor (MicroRunman, NIM, Inc., PA, USA) was placed on the anterior right frontal lobe just below the hair and close to fronto-temporalis region (Maikala et al. 2005). Results Baseline oxygenation and blood volume values were recorded during recovery from each WBV session of ‘with’ and ‘without’ backrest support. The physiological change in oxygenation and blood volume during each frequency (3, 4.5, and 6 Hz) for both backrest (‘with’ and ‘without’ a backrest) and workload (WBV only and WBV combined with rhythmic handgrip contractions) was calculated as the difference between the maximum values identified for each WBV condition of backrest and workload and baseline values (Maikala et al. 2005). Three-way analysis of covariance with repeated measures (frequency, backrest, and workload) with a fully crossed design was used to evaluate the differences in the oxygenation and blood volume responses (measured in optical density [od] units). Peak oxygen uptake during

Jan 6, 2006

By Williams Morales

En el presente trabajo se encuentra una innovadora forma de almacenamiento de relaves en la industria minera, al aprovechar las sinergias de operaciones combinadas de lixiviación y planta Gold Mill. Se muestra el diseño, construcción, operación y los controles para dar estabilidad y solidez al almacenamiento de relaves en el pad La Quinua de Minera Yanacocha. Entre sus beneficios, destacan la reducción en los costos de construcción y protección del medio ambiente a través de la captación de agua directa hacia las plantas de EWTP.

Sep 20, 2019

By L. D. Smith

"This paper examines the impact of the various assumptions that go into an economic evaluation, and shows how these can be combined to show an exciting result that may not really exist. An example of an embellished case (the kind that one frequently sees when projects are being promoted) is developed and the cumulative impact is analyzed to show the actual project underneath. The paper also points out some areas to watch for overly optimistic assumptions such as prices, inflation, and debt. The concept of a “bare bones” base case is proposed (constant metal prices, constant dollars, no inflation, no debt, no interest, on a project basis, after tax) as a common reference point.As well, the discount rate is examined as one of the fundamental means of reflecting risk in discounted cash flow evaluations. Current industry practice is discussed, and a methodology for the analysis of risk levels is proposed that assesses the constituent components of the discount rate: real interest, mineral project risks, and country risk."

Jan 1, 2002

By Stephen C. Tadolini, Colton Cook, Cody Hildreth, Frederick Cybulski

"Broken and jointed ground is extremely hazardous and requires unique stabilization techniques to protect worker and critical entries. Bolting techniques, even the most advanced with pre-load to create roof compression, can leave large gaps of unconfined and separated roof. This roof can also be susceptible to water inflows which only exacerbate the support problem. These types of conditions existed on long term development main entry accessing several future longwall panels. The geotechnical assessment identified well-defined jointing systems that also permitted water to flow between the roof separations, which “lubricated” the roof material and minimized any frictional advantages. Chemical injection of a Polyurethane material, Minova Carbopur WS, was placed beyond the bolted horizon to move the water to the rib lines and reinforce the fractured and broken roof. The injection material permitted the effective use of bolting patterns and helped ensure long-term stability of these critical entries. The paper describes the evaluation techniques, design patterns, basis for chemical selection and application, and results and recommendations.BACKGROUNDThe injection of mine and underground civil structures using polyurethane (PUR) has been ongoing for over 50 years. The applications in mining have included gate road stabilizations, longwall set-up and tear-down entries, and simple consolidation of coal mine roofs. PURs have also been used for roof stabilization during longwall shield recoveries. Polyurethane injection was initially developed by the Bergbau-Forshung GmbH, a German coal mine research institute, in the early 1960s (Jankowski, 1972). The product became a standard stabilization method in Germany after its commercial introduction in 1971 (Knoblauch, 1994), and was successfully manufactured at the Minova Essen, Germany location for over 50 years. With the recent closing of the German underground mines, that manufacturing facility has been closed and moved to Katowice, Poland, where production continues today Injection products are also being successfully manufactured by Minova in Australia and the United States.Polyurethane injection in underground coal mines is used in difficult ground conditions in fractured immediate and main roofs. It is also common as a rock stabilization remedy to prevent longwall face caving during shield removal. As presented in the case study, polyurethane was applied to minimize the inflow of water from beneath a stream channel while providing reinforcement and consolidation of the fractured roof that had lost confinement. Polyurethane is a two-component system (Part A and Part B) that is injected into a borehole and can chemically bond to the rock, not relying on friction or mechanical interlock to provide support. The material is injected under pressure, coupled with a low viscosity and small particle size; it flows into roof fractures and separations, which are the paths of least resistance. New developments in low viscosity PUR materials allows penetration of cracks as tight as 0.002 inch (0.05 mm) wide. This also allows for the closures of extremely small cracks to minimize the inflow of water, even if the water is under pressure. Combinations of designed expansion properties and low viscosities make the materials ideal for minimizing and stopping flows of water from underground structures."

Jan 1, 2019

By D. D. Macdonald, G. Engelhardt

The accumulation of damage due to localized corrosion [pitting, stress corrosion cracking (SCC), corrosion fatigue (CF), crevice corrosion (CC), and erosion-corrosion (EC)] in complex industrial systems, such as power plants, refineries, desalination systems, etc., poses a threat to continued safe and economic operation, primarily because of the sudden, catastrophic nature of the resulting failures. Of particular interest in managing these forms of damage is the development of robust algorithms that can be used to predict the integrated damage as a function of time and as a function of the operating conditions of the system. Because complex systems of the same design rapidly become unique, due to differences in operating histories, and because failures are rare events, there is generally insufficient data on any given system to derive reliable empirical models that capture the impact of all (or even some) of the important independent variables. Accordingly, empirical models have generally failed to provide a robust basis for predicting the accumulation of corrosion damage in complex systems under realistic operating conditions. The alternative prediction philosophy is determinism, in which the development of damage is described in terms of valid, physico-electrochemical mechanisms with the output being constrained by the natural laws. The differential damage is then integrated along the corrosion evolutionary path for the system (i.e., over the future operating "history") to yield the desired integrated damage, which is the quantity that is most useful to an operator. In this paper, we review the theory of predicting corrosion damage within the framework of Damage Function Analysis (DFA), with particular emphasis on the pitting of aluminum in chloride solutions and on the accumulation of damage from SCC in Type 304 SS components in the primary coolant circuits of Boiling Water (Nuclear) Reactors (BWRs). These cases have been selected to illustrate the various phases through which localized corrosion damage occurs.

Jan 1, 2005

By D. Raicevic

After more than 93% of the uranium is extracted from Elliot Lake uranium ores by a sulphuric acid leaching process, the leach residue (tailings) contains small amounts of uranium and radioactive isotopes, particularly radium-226, which is the most serious health hazard. Heavy metal components and pyrite are also present, along with the gangue minerals. Currently, over /000 acres of the Elliot Lake area are covered with these tailings, which contain over five million tons of pyrite. Because of constant oxidation of the pyrite by bacteria (thiobacillus) and the presence of moisture, pyrite slowly generates sulphuric acid, which steadily leaches the metal-bearing constituents from the tailings. The seepage-flows of the dissolved contaminants, although often quite low in volume, have an environmental impact on the Elliot Lake area. Although these seepages are treated and most of the contaminants removed and impounded, a small amount of the radioactive contaminants reaches Lake Huron via the Serpent River. This paper describes a flotation approach for treatment of the Elliot Lake uranium tailings to produce new, decontaminated tailings practically free of pyrite, with radium, thorium and uranium contents considerably reduced. The decontaminated tailing produced, which comprises about 75% by weight of the current uranium tailings, appears to be suitable for mine backfill. Because mine backfilling normally uses about 50% of the plant tailings, the surface storage of about half of the uranium tailings, therefore, would be eliminated by this process. Mine backfilling would also increase the mine production and thus enlarge the over-all uranium resources due to recovery of the ore from pillars. The pyrite concentrate produced from the current uranium tailings would be suitable for sulphuric acid production. The possibility of uranium recovery, and disposal of radium and thorium from the concentrates produced, is now being studied at CANMET.

Jan 1, 1979

By R. A. Davidson, L. Silverman

RESIDENTS of many urban centers are becoming increasingly aware of the obscuring effect of fume and smoke discharge from power, metallurgical, chemical, and other industries; and they, as well as the legislatures of these affected cities, are agitating for cleaner air. Management's most pressing problem is to find an economical way to reduce process effluents in response to the growing pressure from population and legislative demands. The removal must be done, if possible, without handicap to the current operation, since the costs of relocating are often excessive or prohibitive. In fume recovery or disposal, an important item to consider is whether or not the material being discharged has any value. If it has commercial value, the cost of its recovery may offset or aid amortization. For this reason, in making a study of the specific problem in hand, a major factor was the nature of the material emanating from the stack: in particular, its particle size, size range, and its chemical and physical composition, as well as its potential value and utility when recovered (in either a wet or dry state). Should the product have no commercial value, it must be disposed of at minimum cost in a way to prevent recontamination. Initial studies were therefore made to determine stack concentrations and volumes of material evolved from the operations. The next phase of the study concerned the physical and chemical nature of the collected fume. The third portion of this paper describes the wet and dry collector studies undertaken to recover the fume. Cleaning Requirements for Ferroalloy Furnace Operation The basic need for any effluent collection equipment is the highest possible efficiency and the lowest tolerable resistance when the power consumption involved is considered. Since the electric furnace effluent is largely composed of fume of small size (less than 0.5u), it has high light obscuring properties, and even low concentrations will cause some loss of visibility and be evident to nearby residents. The permissible limit for fly ash emission in many cities is based on a weight value (viz, approximately 0.4 grains per cu ft), but the smoke density values are dependent upon a shade of color. In the case of the Los Angeles County code, emission is restricted to pounds per pound of material processed per hour basis (but not exceeding 40 lb per hr for any one given plant operation). If an average particle size of the fume from ferro-silicon alloy electric furnaces is assumed to be 0.4u (as shown later, this is the approximate mean size) and an average loading of 1 grain per cu ft (stp), each cubic foot of stack gas will contain approximately 75x10 10 particles (based on assumed, and confirmed, spherical shape and a standard deviation of unity). When it is realized that the air in metropolitan areas, which are also general industrial areas, contains approximately 5x108 particles, the tremendous light scattering effect of this concentration becomes apparent. Consequently, nearly 100 pct collection would be necessary to equal the average concentration. Fortunately, however, discharge from a high point above ground (50 to 100 ft) will result in at least a thousandfold dilution, or the stack concentration reaching the ground in the foregoing case might result in a ground concentration of ' particles. If the concentration at the source could be reduced by a factor of 100 (99 pct efficiency of collection), then a concentration of 75x10" particles would be diluted to 7.5x10' which would be very satisfactory. An efficiency of 90 pct (factor of 10 decontamination) at the source would result in a discharge of 75x109 articles which upon dilution yields 75x10 which is still 15 times the general air value. Another approach to this consideration is to use the value of concentration of 0.005 grains per cu ft for the value of a visible effluent as cited by Kayse.1 To attain this value with an average loading of 1 grain per cu ft would require an efficiency of 99.5 pct. Since the foregoing value is not based on any reported size of fume particles, it is felt that the numbers' approach given previously is more reliable. These calculations serve to indicate the desirability of thorough cleaning, preferably at the source, and with efficiencies well above 90 pct, preferably above 95 pct (dilution 1:20). One of the most important items in any control program is to reduce the concentrations as close to their sources as possible. The use of better furnace design, deeper coverage over the electrodes, and the prevention of blows or breaks in the surface all help to reduce dissemination; consequently, all of these improvements should be made, if possible, to cut down the effluent load. In addition, in order to minimize the volume of contaminated air that has to be cleaned, the furnace should be enclosed as much as possible. Test Arrangements Before fundamental studies with collectors were made, a furnace stack selected for the test program was sampled to determine the gas temperatures and

Jan 1, 1956

By Bland Z. Richardson

Jan 1, 1985

By Bora Derin

The synthesis of titanium diboride (TiB2) by carbothermal reductions of TiO2 and B2O3 was investigated. For this aim, TiO2, B2O3 and carbon black powders were dried, weighed out and mixed in stoichiometric molar proportions (TiO2:B2O3:C = 1:1:5). The experiments were carried out in a graphite resistance furnace in argon media using different range of temperature (1400- 1700 °C) and time (0 and 15 min). The phase analyses observation of the products were examined by using XRD.

Jan 1, 2008

By B. R. T. Simoneit

The formation of petroleum is normally thought of as a geologically lengthy process, involving the accumulation of organic matter, its gradual burial, diagenetic breakdown via geochemical reactions, maturation, heating within a 75-150'C "oil window" induced by normal geothermal gradients in the subsiding basin, and slow product migration into structural traps (Tissot and Welte, 1984, Hunt, 1979). The entire process can take millions of years and, indeed, most oil reservoirs probably formed in this manner. How-ever, today in sedimented, submarine rift basins (Fig. 1), Cl to >C40 hydrocarbons with the chemical and physical properties of crude oil are forming in demonstrably much shorter time by rapid thermal maturation of immature organic matter in hydrothermal regimes that are unusually high for sedimentary basins (Brault and Simoneit, 1988a, b; Didyk and Simoneit, 1988; Kawka and Simoneit, 1987; Peter et al., 1988; Simoneit, 1983; 1984; 1985a,b; 1988; Simoneit et al., 1984; 1987; 1988).

Jan 1, 1989