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By George H. Roseveare

Early flotation dealt primarily with the bulk concentration of sulphide minerals or the separation of one sulphide from another and was referred to as oil flotation because oils and fats were used as reagents. The separation or concentration of one nonmetallic mineral from another developed later with the use of fatty acids. Fatty acids are organic acids present usually as glycerides in tall oil and oils of fish, peanut, cottenseed, soya beans and ethers of veg¬etable and animal origin. Some, of these oils and their derivatives were used by the Phoenicians as early as 600 B.C. in making soap, and the use of such reagents in mineral dressing is referred to as "soap flotation". The first use of oleic acid for the recovery of minerals was the early agglomeration process.' The coarse particles of ore, from 1/16 to 1/4 inch diameter, were coated with large amounts of soap or oil and after screaming from the gangue were recovered by screening, hydraulic or table classification. In 1886, a patent was issued to Mrs. Carrie Everson in which the essential feature was the constituted commingling of pulverized ore, fat or an oil, either animal, mineral, or vegetable, for the purpose of effecting .a. union of the free metal or metallic portion of the ore with such admixed material whereby the same may be changed in subsequent separation of quartz or other rock therefrom by washing or other suitable means. The patent mentions the use of red, cotton seed, caster, sperm and linseed oils, In the early use of collectors the amount of oil for froth flotation was often 2 to 6 per cent by weight of the ore rather than pounds per ton.

Jan 1, 1959

By Charles M. Brinckerhoff

The Potrerillos mine of the Andes Copper Mining Co., a subsidiary of Anaconda Copper Mining Co., is 100 miles east of the coast town of Chanaral, in the Province of Atacama, Chile. In December 1926, the plant was placed in operation and has operated continuously ever since. Block caving is the only mining method used, as it is especially suited to the grade of ore, the position and shape of the ore bodies, and the character of the ground. At the present time there are three haulage levels, which handle oxide and sulphide ores, and production from them averages 31,000 short tons daily. The purpose of this paper is to describe the layout, equipment and systems used on the gathering or main haulage levels. Haulage Layout Because of the shapes of the ore bodies, their distances from the dumping pockets

Jan 1, 1946

By C. H. Schack

Extractive metallurgy techniques currently employed to recover silver from primary ores and secondary scrap were reviewed and evaluated to identify and delineate metallurgical problems whose resolution would increase the supply of silver from domestic materials. The survey revealed that practically all primary silver is recovered by froth flotation concentration of various types of ores, followed by smelting and refining of the separate lead, copper, and zinc concentrates. Silver losses during the complex processing are, with rare exception, inconsequential. Furthermore, any silver production gain from base metal ores, which contribute about two-thirds of the total primary silver, is directly dependent no improvement in the market for the base metals. Statistical data on new and old silver scrap are wholly inadequate to make reliable conclusions about scrap processing problems and the possibility of increasing the recovery of silver from the many forms of secondary silver-bearing materials. The available information indicates (1) that efficient silver reclamation practices are employed by the larger users of silver, and (2) that recovery of additional secondary silver involves solution of problems of collection rather than of processing. Several possibilities exist for limited increases in silver production from primary ores by improvement in metallurgical practices. Specifically, research is needed to (1) solve the problem of recovering silver from the copper ores of the Copper Range district, Michigan; and (2) devise economically feasible methods for recovery of silver from presently marginal or submarginal ores char because of grade, location, and frequently complex nature cannot presently be exploited by conventional techniques.

Jan 1, 1965

By D. H. Platt

Bauxite, the principal source of aluminum, has been mined from deposits in Saline and Pulaski Counties, Ark., since 1899; war needs have greatly stimulated production. Many of the ore deposits are basin-shaped and either outcrop or are covered by a shallow-depth overburden at their peripheries; these are mined by stripping and open-pit methods. When stripping becomes economically impracticable, incline shafts or slopes are sunk on the dips of the deposits, and underground mining is done on the retreat, using a room-and-pillar method.

Jan 1, 1945

By James M. Barker

Marketing is the linchpin of the industrial-mineral (IM) industry. Without markets and consumers for IM products, all other associated IM activities are superfluous. The simple existence of an IM deposit does not mean that it can be exploited. A dynamic interaction between exploration (geology), mining, processing, transport, marketing, sales, and consumers is required for profits. Geology dictates the existence of a deposit, but markets dictate its development, and transportation provides the connection. This is true to such an extent that marketing commonly is called the exploration phase of IMs. Marketing is strategic and includes long-range market-development and planning activities, whereas selling is tactical and more focused on day-to-day consumer interactions. Each will help the other when properly done. Many producers of IMs have failed because of inadequate marketing skill, information, and practice. Over many years at the Montana Bureau of Mines, the many developers seeking technical assistance to find an IM deposit, but who had no marketing plan, always failed. In contrast, the few who sought assistance first on marketing, with the IM deposit to be found later, always succeeded (Richard Berg, personal communication, 1998). Marketing has many facets helped by geologists who must be aware of what marketing is attempting to do. A geologist needs to understand many aspects of IMs: location (deposits, plants, consumers), processing (specifications), transportation (truck, rail, barge, ship), competition (local, regional, national, international), substitutes, pricing, and new developments and market forces of all kinds. Some needed skills are not taught formally to geologists, so well-rounded self-education and on-the-job training are the way a geologist normally enters into IM marketing. The IM geologist generally is associated with marketing either by helping to prepare a market study or by acting on the results of one. Preparing a market study is a two-part process. The first part is relatively simple but requires a time-consuming collation of data into an IM survey (mostly past-and present-oriented). The more difficult and much more important second part entails expanding the IM survey into a market evaluation (mainly future-oriented) that emphasizes forecasting, timing, location, and specific products. A market evaluation generally boils down to formulating the right questions to ask of the right persons. One very good question to ask is, "What could be the market for this specific IM?" while thinking for yourself without excessive recourse to gossip, rumors, promoters, developers, or (at times) IM experts. The evaluation must prove that market potential exists and suggests a marketing plan. Effective marketing is an ongoing process, with the initial marketing plan modified over time, using wide and continuous input to avoid tunnel vision. Industrial-mineral markets are based either on commodity (lower-priced, basic-processing) minerals or specialty (higher-priced, value-added) minerals. IM marketing methods are either product-driven (commodity minerals), a more traditional approach, or market-driven (specialty minerals), but these are neither mutually exclusive nor is one always better than the other. Focusing too much on specialty minerals can lead to problems. A blend of commodity products with specialty products commonly lowers risk and enhances long-term profits. The highest profits occur in specialty minerals at the cost of higher risk and complexity and require intelligent marketing, versatile technical services, and creative research and development. Industrial minerals are best served by an industrial-marketing approach rather than a consumer approach. Modern industrial marketing emphasizes the consumer using the "marketing concept." The marketing concept focuses all management and operational activities on total consumer management and satisfaction similar to the total quality management approaches to excellence.

Jan 1, 1999

By Allan E. Martin, George Glocker, C. E. Wood

"INTRODUCTION As part of a comprehensive investigation of the mechanism of defurization of iron and steel by slags, the Blast Furnace Studies Section, Metallurgical Division, Bureau of Mines, in cooperation with the Institute of Technology, University of Minnesota, has made a study of the forms in which sulfur occurs in blast-furnace slag. This report presents data on the three sulfides most important in iron smelting, namely, ferrous sulfide, manganous sulfide, and calcium sulfide. The tendency of these sulfides to form colloids in the molten slag was determined by an examination of quenched samples with an ultramicroscope.Vogt/ conducted experiments on sulfide silicate melts and examined synthetic blast-furnace slags in a partly crystallized condition. His conclusions were that FeS, CaS, and MnS, or isomorphous compounds, such as (FexCay)S and (MnxCaa)S, were precipitated from the melt, depending on the composition of the slag. In all specimens sulfides were visible and were spherical.Coloration of glass by sulfur also provides indirect information on the nature of sulfur in blast-furnace slags./ There seems to be a general agreement at present among the workers in the field of colored glasses that ferrous sulfide is a strong color producer. Colors that have been attributed to this compound include yellow, orange, brown, blue, and black. Apparently the ferrous sulfide is considered to be dissolved in these glasses. There is no indication that any of them have been examined for a colloidal phase.Lorenz 7/ investigated a single manganese slag in the glassy state and observed a Tyndall beam in an ultramicroscope. His conclusion was that either a manganese compound had precipitated in a finely divided condition or that metallic manganese had volatilized and penetrated into the slag as a vapor and thus formed colloidal particles."

Feb 1, 1941

By R. V. Ramani, R. D. Zigmond, R. L. Frantz

In this paper, a computer program for determining the capital and operating costs for coal preparation plants is described along with its applications. The logic of the computer program is based upon the results of a survey of existing preparation plants, operators, plant contractors, equipment manufacturers, and consulting firms. This survey provided information on plant performance, order-of-magnitude costs, and costing procedures. Additionally, an extensive cost data file for the major capital equipment in coal preparation plants has been developed. Using the washability data and the computer program out- puts, the cleaning costs per million Btu can be calculated. Details about the program and its applications can be found in a report by the authors (Zigmond et al., 1979).

Jan 1, 1983

By J. L. Reuss

The Bureau of Mines investigated the technical feasibility of smelting copper concentrates containing chalcocite (Cu2S) and native copper using nonpyritic sulfur-bearing materials to aid matte formation. The procedure consisted of combining various proportions of commercial chalcocite concentrate, smelter slag, fluxes, and matte-forming constituents to produce charges of comparable compositions. The mixtures were charged in fire-clay crucibles and smelted in an induction furnace at 1,300° C. The research proved that either sulfur or gypsum can replace pyrite as a matte-forming material, and that gypsum produces an exceptionally high-grade copper matte. The addition of small quantities of metallic iron to the nonpyritic smelting charge furthers the removal of sulfur, improves the recovery of copper, and makes it possible to utilize gypsum as the exclusive flux and matte-forming ingredient, thereby eliminating the necessity of adding limestone.

Jan 1, 1968

By R. W. Olson, A. L. Benham

Viscous fingering was studied as it occurred in an open Hele-Shaw model (1 ft x 4 ft x 1/16 in.); it was also studied in the same model packed with 80-mesh glass beads during miscible displacements under unfavorable viscosity ratio conditions. It was determined that the lengths of 20 elements of the front were distributed normally around the average position of the combined elements under all conditions. Represented by the normal distribution, the length of the viscous fingers grew linearly with the distance traveled from the point of finger formation, increased with displacement velocity, and increased with increasing mobility ratio. Results obtained during the first few inches of displacement were of little or no use in predicting finger growth and/or finger length throughout the 4-ft model since the point of finger initiation cannot be predicted and would often occur several inches from the point of injection with either positive or apparent negative coordinates. The fingering occurring during a miscible slug displacement was much greater than would be predicted based upon the actual mobility ratios between in-place fluid and slug and between slug and following fluid, using the results described above for miscible displacement in the absence of a slug. Many of the experiments in the packed model showed that the rate of growth of the viscous fingers was diminishing toward the end of the displacement in the 4-ft long model, indicating that microscopic mixing, such as diffusion or dispersion, was decreasing the viscous fingering effect. INTRODUCTION Viscous fingering is a manifestation of a finger-shaped interface between displaced and displacing fluids occurring during typical miscible displacement projects for oil recovery. Its cause may be traced to the instability of a viscous fluid being displaced by a more mobile fluid. Viscous fingering takes on important significance in the miscible slug process 1.2 where it may be a dominant factor in determining minimum slug size. Experimental1-3 and theoretical4-7 studies of viscous fingering have been made by other investi- gators. However, an exhaustive study of the variables affecting viscous fingering had not been made. The present study was undertaken in an effort to determine the effects of some of the more obvious variables—such as mobility ratio, displacement velocity, distance displaced, and packing—upon viscous finger length and growth in a small laboratory model. It does not necessarily follow that conclusions reached by studying the results of this model study may be applied to the field. Future studies would have to evaluate the effect of model size on extension of these results. EQUIPMENT AND EXPERIMENTAL PROCEDURES A flow diagram for the equipment used in this study is shown in Fig. 1. Basically, it consisted of (1) a constant-rate pump for the injection of displacing fluid into (2) a model made up of two flat transparent plates spaced a small distance apart and (3) provisions for the production of fluid into a calibrated graduate. The displacing fluid contained a dye which allowed visual observation of finger spacing and length. The pump performed at rates from 2.5 cc/hr to 480 cc/hr, while pumping a light mineral oil into a bladder in a closed glass container holding the displacing fluid. The model was made up of two plates of 1-in. Plexiglass with dimensions 1-ft wide by 4-ft long. These were spaced 1/16 in. apart so that the internal model dimensions were 1-ft wide x 4-ft long x 1/16

By Roger J. Goodman

"Major industrial restructuring, which started to manifest itself in the mature economies of the Western World and Japan in the 1970s, will accelerate in the 1980s and 1990s. Conventional heavy manufacturing industries will continue to lose ground to lighter processing/assembly operations and the new wave of high technology, information and service sectors. The decline in heavy manufacturing has severely impacted on the steel industries of Western Europe, the U.S.A . and Japan.World trade in metallurgical coal has shifted correspondingly, with declining demand in the mature developed countries being only partially offset by large increases in the steel intensity of the newly-industrialized countries (NICs) of the Far East, Latin America and, to a more limited extent, the Middle East and Africa. These trends will be accentuated in future years with direct implications for the distribution of metallurgical coal trade. This paper discusses, in quantitative terms, such changes in the 1980s and 1990s, and examines the implications for, and impacts on, Canadian metallurgical coal exporters.IntroductionThe twenty-year period from the early 1950 s to the early 1970s was characterized by inexorable growth in consumer demand and industrial expansion in most of the advanced countries of the western world. Long- term forecasting during this period typically used linear extrapolation techniques which , despite their simplicity, invariably ended up predicting future demand and production level s with uncanny accuracy. Times have changed!The last decade has been characterized by a n abysmal failure of our economies to respond to simple long-term, linear growth patterns. We appear to have entered a new world in transition, where we can observe a wave of dying or sunset industries reluctantly being submerged by a wave of emerging or sunrise industries.This paper is aimed a t examining the evidence for long-term industrial restructuring trend s. For want of a better word, these so -called, megatrends are then used to predict future demand level s and spatial distribution of steel development and , hence, metallurgical coal trade. It is tempting to correlate the decline in economic activity in the western world with the first Organization of Petroleum Exporting Countries' (OPEC) crisis of 1973. This crisis was probably no more than the straw that broke the camel's back, as the megatrends and embryo s of major industrial restructuring were already evident. Today these megatrends are merely more apparent and transparent than they were ten years ago.While the concept of industrial restructuring is the new economic buzz word, the process was at work, to a lesser degree even throughout the period of strong economic growth of the post-Second World War boom. Many people still remain convinced that our present-day sluggish economy is just part o f the typical , though rather more prolonged, recessionary cycle. Yet, we have always been part of a dynamic economic system and industry throughout history has been the subject of a continuous process of evolution, restructuring and reconstitution . Now the time is ripe to examine the evidence for such restructuring in order to develop coherent policies of adjustment in this transition from one industrial regime to another."

Jan 1, 1985

By Anshumali Gangwar

This paper outlines the chance constrained binary integer program developed by the author in his doctoral dissertation at Columbia University, New York, 1973. The optimum planning of a mining program involves the determination of a production schedule which maximizes the net present value of the mining property. The actual mining process has an inherent stochastic and discrete nature. In particular, the demand for the mined product and the grade of the mineralized material in the ore are the two most important stochastic mining variables. The decision to mine or not to mine any block of a mining property is a binary integer variable. This paper outlines the formulation of pit production scheduling problem as a chance constrained binary integer program. The deterministic equivalents of these chance constraints are nonlinear in binary variables which have subsequently been linearized. The planned objective is to meet with a stipulated high degree of reliability, all the random demands as they materialize with a random supply of the commodity being marketed as determined by the eventuating random grade values of the exposed ore blocks and the mining system's production constraints such that the discounted total production costs over the entire planning horizon are minimized or the profits maximized. The emerging surface of the mine in each scheduling period is determined by the values taken by the binary decision variable associated with each block of material in each scheduling period.

Jan 1, 1982

By Thomas L. Barkley, Steve Salli

In the past, blasters have attempted to evaluate the results of their blast designs and make corrective adjustments to improve the blasts' productivity and value to the mining operation. The methods employed have nearly always been "eyeball" evaluations and "trial and error" corrections.

Jan 1, 1997

By J. W. Evans

ONE possible method for the separation of hafnium from zirconium is by the vapor phase oxidation of the purified mixed chlorides. An important factor for success depends on the difference in free energies of the following reactions: ZrCl(g) + O2 = ZrO2(s) + 2C12 [1] HfCl4(g) + O2 = HfO2(s) + 2C12. [2] Prakash and Sundaram1 have calculated these values from certain data and carried out experimental work with partial success. However, their free energy values for reaction 2 diverge rather widely from other data which are presented here. The possibility of successful separation is briefly considered in the light of these alternative values. Table I shows the free energy values (?F°) for reactions 1 and 2 derived from the recent compilation of data on oxides and chlorides by Glassner.2 The corresponding values of Prakash and Sundaram for the same temperatures are also shown. The alternative values to those of Prakash and Sundaram for reaction 2 are substantially confirmed by the data of Kubaschewski and Evans" and Cough-lin' on heats of formation, entropies, and heats of vaporization. In spite of the considerable uncertainty in the hafnium data it is reasonable to suppose that the oxide-chloride free energy difference for two such chemically similar elements would not be very far apart. These figures indicate clearly that the oxidation of hafnium chloride is appreciable at all temperatures. Nevertheless, there is a significant difference between the values for reactions 1 and 2

Jan 1, 1959

By D. S. Reynolds, K. D. Jacob, H. L. Marshall

All types of commercial phosphate rock produced throughout the world contain fluorine in quantities ranging from approximately 0.4 to 1.3 per cent in the Curacao and Christmas Island phosphates to 3.1 to 4.2 per cent in the phosphates of the United States and North Africa1. For a given type of rock, the fluorine content is usually roughly proportional to the phosphorus content. Significance of Fluorine in Phosphate Rock On the basis of chemical and X-ray diffraction studies, Hendricks and co-workers2 concluded that fluorapatite, Cal10F2(PO4)6, is the essential phosphatic constituent of the commercial types of domestic phosphate rock. On the other hand, Bredig and co-workers3 have recently advanced the opinion, also based on X-ray diffraction studies, that the mineral phosphates usually contain carbon dioxide in the apatite lattice, and that the phosphate rocks of the United States are really fluorcarbonate apatites. However, the domestic types of phosphate rock do not seem to differ greatly from coarsely crystalline fluorapatite in their behavior toward chemical reagents in general, and for the purpose of this paper it will suffice to consider fluorapatite as being the essential phosphatic constituent of these types of rock. The available data1 indicate that the different commercial types of domestic phosphate rock usually contain about 12 to 52 per cent more fluorine than theoretically is required to form fluorapatite with all the phosphorus. Calcium fluoride (fluorite) has been definitely identified in only a very few of the samples that have been examined1,2. Bredig and co-workers4 state that fluorapatite can take into its crystal lattice excess calcium fluoride to the extent of approximately 70 per cent of that theoretically required by the formula Ca10F²(PO4)6 without causing more

Jan 1, 1938

By V. Bredykhin

The efficiency of scrap processing depends firstly on reliability of information about its chemical composition. The paper presents the results of the investigation and development regarding solid copper alloy scrap in the range of lump size 40÷300 mm. Nowadays the sorting of lump scrap is done by two methods: 1. Sorting according to metals and alloys is done at places of scrap generation, and further till metallurgical processing each lot has its "certificate"; 2. Hand sorting of scrap is done according to the marks on solid items in special shops using proximate analyzers or manually by experienced workers. This sorting process is labor - consuming low efficient and involves mistakes. The informational method is a promising trend in the copper scrap sorting. The method is direct, i.e. as a result of sorting the chemical composition of each scrap lump or main elements is determined, and assured data of qualitative and quantitative composition are received.

Jan 1, 2006

By Lye GN

Rock mechanics investigations have shown that some major slopes in the Panguna pit would be stable at angles in excess of 500 providing near-surface instability could be controlled. Excavation of final batters at angles between 55¦ and 60¦ is now being carried out using D10 dozers with berms at 45 to 60 m centres. A trial slope with berms at 90 m centres is planned. Shotcreting of weak zones combined with crest reinforcement, with rock anchors and dowels, is used to provide protection against erosion and toppling of the crests. Overall slopes excavated in this way are of the order of 10¦ steeper than slopes obtained by blast and shovel excavation.

Jan 1, 1986

By Mrs. V. J. DeCarlo, G. P. Salvo, H. W. Schadler, L. M. Osika

The lattice parameter of the inlerrnetallic compound Nb3Sn has been measured as a function of temperature from 80° to 1290°K. The results are compared with published data on the thermal ex- ThE recent interest in the intermetallic compound, Nb3Sn, as an engineering material for the production of superconducting devices has necessitated that certain engineering data be obtained. Because of the difficulty encountered in producing bulk pansion of niobium and indicate that the compound when made by diffusion of tin into niobium at 1000°C, would be subjected to a tensile strain of about 0.1 pct when cooled to room temperature. material which is single phase, the coefficient of thermal expansion has not been measured by dilata-tional methods. Therefore the lattice parameters of fine-grained samples of Nb3Sn produced on the surface of a niobium sheet by heating in molten tin at 950°C have been obtained as a function of temperature. The results are compared with published data on niobium2 and Nb3Sn3 and with lattice-parameter measurements made on small single crystals of Nb3Sn.

Jan 1, 1964

By Brian T. Burch, Paul N. Worsey

When fired, submerged Linear Shaped Charges (LSCs) lose all effectiveness in the cutting of steel. Users in underwater applications have reported having to substantially increase the charge size to the point where brute explosive force shears rather than cuts the target.

Jan 1, 2015

By Nordau R. Goodman

"IntroductionTHE HISTORY of Nova Scotia's gypsum industry goes back about two hundred years. The extensive deposits found in the Windsor formation, which is Lower Carboniferous, were the first discovered in North America and were known to the earliest .settlers. There has been a steady increase in production from these beds, except for minor setbacks in years of wars and depressions, but at the same time there has been a decrease in the number of operating quarries. This decrease reflects the change from the days of horse-and-cart recovery to the modern, large-scale, highly mechanized operations. In the beginning, almost any outcrop could •supply the tonnage requirements and the most •convenient were selected, but the millions of tons needed to meet present-day needs are not easily found.Despite the size and importance of the Nova Scotian deposits there has been little detailed geological work. Sir Charles Lyell, in 1843 ( 10), established that the beds are Lower Carboniferous and this was confirmed by Sir William Dawson (3) a .few years later. Both Lyell and Dawson agreed the calcium sulphate beds were an original part of a bedded series .but did not consider they resulted from a concentration of sea water. Lyell reached the conclusion that the gypsum was related to volcanic action in the form of heated vapours or hot springs. Dawson believed it was formed by the action •of sulphuric acid on calcium carbonate. The acid, derived from the oxidation •of iron pyrites which was abundant in the older formations, was carried by rivers into basins which were rich in shells."

Jan 1, 1954

Jan 1, 1932