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By E. R. Cole

This Bureau of Mines investigation was prompted by the need forr a stable anode for electrowinning metals, particularly zinc and copper, from acid solutions. The polarization behavior of Pb-Ag (1 pct Ag) anodes in H2SO4 and fluoride solutions was determined as the first step in the development of such an anode. A Luggin capillary, dc power supply, high-impedance voltmeter, and other equipment standard to an electrochemical laboratory were used in this study. It was determined that during polarization, a relatively hard, stable coating of Pb02 was formed on the surface of the lead-silver anode and the rate of formation of this coating was considerably enhanced by the presence of fluoride ions in solution. Subsequent investigations at the Bureau of Mines Rolla Research Center resulted in the development of a Pb02-coated titanium (Pb02-Ti) anode. Results of this effort were presented in Bureau of Mines Report of Investigations 8111. Additional data resulting from extensive testing of the Pb02-Ti anodes, as well as process improvements and innovations, are included in this report. The anodes were considered generally unsatisfactory for zinc electrowinning because of lower conductivity, higher oxygen overvoltages, and shorter in-cell life as compared with the Pb-Ag anodes now being used in industry. However, the PbO2-Ti anodes were used successfully to oxidize waste chromium solutions and to electrowin copper.

Jan 1, 1981

By Y Peng, D J. Bradshaw, X Chen

At NewcrestÆs Telfer gold mine, a strategy of regrinding pyrite rougher flotation concentrates has been proposed to increase gold recovery and reduce cyanide consumption in the CIL circuit. The regrinding will be followed by an additional copper/gold flotation stage, where copper minerals need to be separated from pyrite. However, although the minerals are well liberated, the separation of chalcopyrite from pyrite in the cleaner stage is not always straightforward. The surfaces of the fine particles, produced during regrinding, are more easily oxidised and contaminated than coarse particles, directly influencing the particle floatability. The depression of pyrite is difficult in the cleaner stage as well due to copper activation, a process which is also highly dependent on the grinding environment. In this study, different grinding media, including mild steel and stainless steel, was used in the regrinding to produce different regrinding chemistry, such as, pH, Eh, and iron hydroxide contamination. The effects of regrinding conditions on chalcopyrite flotation and its separation from pyrite were studied. It was found that the stainless steel grinding media, which produced an oxidising environment, was more beneficial for the separation of chalcopyrite from pyrite after regrinding. The mild steel grinding media had a detrimental effect on both chalcopyrite and pyrite flotation. This study addresses the importance of choosing suitable regrinding conditions in the pyrite and copper flotation circuit.CITATION:Chen, X, Peng, Y and Bradshaw, D J, 2012. Effect of regrinding conditions on the flotation of chalcopyrite and its separation from pyrite in the cleaner stage, in Proceedings 11th AusIMM Mill OperatorsÆ Conference, pp 279-286 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Oct 29, 2012

By D. E. Munson, H. J. Sutherland

Surface subsidence caused by underground mining is described through complementary influence functions. The complementary functions developed here differ from the simple functions previously used in that the surface displacement is the result of the combined contributions of the mined and unmined zones. This eliminates computational difficulties experienced with the simple functions in determining the deflections above the rib side and in the eventual application of influence functions to complex room-and-pillar configurations. Although the analysis framework presented is intended for predicting subsidence over complex mine configurations, use of the complementary functions is illustrated adequately by application to a longwall panel of the Old Ben No. 24 coal mine.

Jan 1, 1982

By Jianliang Li, Xi Peng, Guorong Lu

This paper describes a wind tunnel modelling study on airflow and pollutant concentration in a large open pit mine located in southern China. A 1:1000 scale model of the surface mine was fabricated and placed in a wind tunnel. Airflow velocity in the test section of the wind tunnel can be continuously adjusted from 0.3 m/s to 6.0 m/s. In this study, both the present pit condition and the projected final pit condition were modelled. Airflow direction and velocity profiles were obtained. The impact of wind direction and velocity on airflow was also studied. The pollutant concentration distribution in the open pit was simulated using smoke, and a distribution profile was obtained. Respirable dust concentrations at the mine site were measured, then its concentrations at the projected final pit condition were estimated using the obtained pollutant concentration distribution profile. Under normal meteorological conditions, it is expected that the respirable dust concentration for the final pit should not exceed the government standard. Key Words: wind tunnel modelling, open pit, surface mining, scale model, mine ventilation, airflow profile, point source.

Jan 1, 1993

By D. J. Fitzpatrick

The paper reviews current mining subsidence research at The Department of Mining Engineering, University of Notting- ham. Special attention is being devoted to prediction of ground movements between the mining horizon and the surface using physical and computer-based models. The paper presented discusses linear and non- linear finite element methods and compares results with those from physical models and field observations. Special attention is focussed on the determination of the effect of caved zones on overlying and underlying geological structures. The paper presents data from comparisons with U.K. case histories.

Jan 1, 1986

By Fred C. Bond

MOST investigators are aware of the present unsatisfactory state of information concerning the fundamentals of crushing and grinding. Considerable scattered empirical data exist, which are useful for predicting machine performance and give, acceptable accuracy when the installations and materials compared are quite similar. However, there is no widely accepted unifying principle or theory that can explain satisfactorily the actual energy input necessary in commercial installations, or can greatly extend the range of empirical comparisons. Two mutually contradictory theories have long existed' in the literature, the Rittinger and Kick. They were derived from different viewpoints and logically lead to different results. The Rittinger theory is the older and more widely accepted. In its first form, as stated by P. R. Rittinger, it postulates that the useful work done in crushing and grinding is directly proportional to the new surface area produced and hence inversely proportional to the product diameter. In its second form it has been amplified and enlarged to include .the concept of surface energy; in this form it was precisely stated by A. M. Gaudin2 as follows: "The efficiency of a comminution operation is the ratio of the surface energy produced to the kinetic energy expended. According to the theory in its second form, measurements of the surface areas of the feed and product and determinations of the surface energy per unit of new surface area produced give the useful work accomplished. Computations using the best values of surface energy obtainable indicate that perhaps, 99 pct of the work input in crushing and grinding is wasted. However, no method of comminution has yet been devised which results in a reasonably high mechanical efficiency under this definition. Laboratory tests have been reported' that support the theory in its first form by indicating that the new surface produced in. different grinds is proportional to the work input. However, most of these tests employ an unnatural feed consisting either of screened particles of one sieve size or a scalped feed which has had the fines removed. In these cases the proportion of work" done on. the finer product particles is greatly increased and distorted beyond that to be expected with a normal feed containing the natural fines. Tests on pure crystallized quartz are likely to be misleading since it does not follow the regular breakage pattern of most materials but is relatively harder to grind at the finer sizes, as will be shown later. This theory appears to be indefensible mathematically, since work is the product of force multiplied by distance, and the distance factor (particle deformation before breakage) is ignored. The Kick theory' is based primarily upon the stress-strain diagram of cubes under compression, or the deformation factor. It states that the work required is proportional to the reduction in volume of the particles concerned. Where F represents the diameter of the feed particles and P is the diameter of the product particles, the reduction ratio Rr is F/P, and according to Kick the work input required for reduction to different sizes is proportional to log Rr/log 2.5 The Kick theory is mathematically more tenable than the Rittinger when cubes under compression are considered, but it obviously fails to assign a sufficient proportion of the total work in. reduction to the production of fine particles. According to the Rittinger theory as demonstrated by the theoretical breakage of cubes the new surface produced, and consequently the useful work input, is proportional to Rr-1.5 If a given reduction takes place in two or more stages, the overall reduction ratio is the product of the Rr values for each stage, and the sum of the work accomplished in all stages is proportional to the sum of each Rr-1 value multiplied by the relative surface area before each reduction stage. It appears that neither the Rittinger theory, which is concerned only with surface, nor the Kick theory, which is concerned only with volume, can be completely correct. Crushing and grinding are concerned both with surface and volume; the absorption of evenly applied stresses is proportional to the volume concerned, but breakage starts with a crack tip, usually on the surface, and the concentration of stresses on the surface motivates the formation of the crack tips. The evaluation of grinding results in terms of surface tons per kw-hr, based upon screen analysis, involves an assumption of the surface area of the subsieve product, which may cause important errors. The'evaluation in terms of kw-hr per net ton of 200 mesh produced often leads to erroneous results when grinds of appreciably different fineness are compared, since the amount of -200 mesh material produced varies with the size distribution characteristics of the feed. This paper is concerned primarily with the development, proof, and application of a new Third Theory, which should eliminate the objections to the two old theories and serve as a practical unifying principle for comminution in all size ranges. Both of the old theories have been remarkably barren of practical results when applied to actual crushing and grinding installations. The need for a new satisfactory theory is more acute than those not directly concerned, with crushing and grinding calculations can realize. In developing a new theory it is first necessary to re-examine critically the assumptions underlying

Jan 1, 1952

By M. R. Anderton

"A hierarchical four-character code designed for geological and allied data may be used to log exploration drill-holes and store the information on magnetic media. The code is intended for use in semi-free format and permits the collection of as much, or as little, data as the geologist may require for the purpose in hand. A method of data storage by variable length records is discussed.Information may be retrieved by means of a simple enquiry language. Optional output facilities could allow the retrieval of data in a form suitable for direct input to a contouring package. The enquiry parameters and interrogation program can thus provide the interface between the data bank and associated application systems."

Jan 1, 2014

By E. C. Perkins

This report describes a ferric chloride trap, based on formation of a low-melting sodium chloride-ferric chloride mixture of near-eutectic composition, and its use in chlorination of impure titaniferous materials. The trap is placed in the hot gas stream between the chlorination reactor and the condenser. Virtually all of the iron is removed by the trap. The condensed titanium tetrachloride is free of suspended solids and contains only a trace of iron. Four examples are given of the use of the ferric chloride trap in chlorination of impure titaniferous materials. INTRODUCTION In the Kroll process, ductile titanium metal is produced by reducing titanium tetrachloride with magnesium metal.4/ In commercial practice, titanium tetrachloride is produced by chlorinating titaniferous materials in the presence of carbon.2/ In 1957 most producers were using rutile, and virtually all plants were designed for its use. About four-fifths of the domestic consumption of rutile was imported from Australia. The Bureau of Mines, under provisions of contract DMP-116 with the General Services Administration, studied electrosmelting of domestic ilmenites and titaniferous magnetites to produce high-titanium slags with pig iron as a byproduct. Under the same contract, chlorination studies also were being made of these slags. Smelting was done at the Northwest Electrodevelopment Experiment Station, Albany, Oreg., and chlorination at the Electrometallurgical Experiment Station, Boulder City, Nev.

Jan 1, 1958

By S. R. Krogh, T. O. Olsen

Analytical expressions for the breakage rate as functions of mill charge, mill speed, particle size, ball diameter, and ball load are derived, using idealized models for probability of breakage (Gaudin and Meloy), energy distribution (Mempel), and arithmetic mean of effective ball energy (Langemanns). Computational results using the theoretical equations are compared to experiments. The equations enable simulation of ball mill grinding at different grinding conditions.

Jan 1, 1973

By T. Ito, N. Tokashiki, H. A. Bilgin, Ö. Aydan, T. Akagi

This study is concerned with the electric potential induced by deformation, fracturing and sliding of non-piezoelectric geomaterials. In experiments, the acoustic emissions together with electric potential measurements were also measured in order to see how the so-called seismic electric signals are associated with new fracture occurrence and propagation and sliding in case of existing discontinuities. The outcomes of this experimental study may explain why such electric potential variations may occur during the fracturing and sliding of non-piezoelectric geomaterials. On the basis of these outcomes, their possible implications in geo-engineering and geo-science are discussed. Ce travail concerne 1e potentiel électrique produit par la déformation, 1a fracture ou le glissement du matériel géologique non-piézoélectrique. Aux expérimentations, on a mesuré 1es émissions acoustiques avec le potentiel électrique afin de constater la relation entre les phénomènes de glissement ou de formation et de propagation de nouvelles fractures le long des discontinuités existantes. Les résultats de ce travail expérimental expliquent pourquoi de telles variations de potentiel electrique se produisent durant le glissement ou la fracture du matériel non-piézoélectrique. Sur la base de ces résultats, on a discuté de leurs éventuelles implications dans les domaines de 1a géologie et de 1a géo-ingénierie. Diese Studie befasst sich mit dem elektrischen Potential das durch die Deformation, Bruchbildung und Gleiten von nicht-piezoelektrischen Geomaterialien induziert wird. In Experimenten wurden die akustischen Emissionen zusammen mit elektrischen Potentialmessungen gemessen, um zu sehen, wie die so genannten seismischen elektrischen Signale mit neuer Bruchbildung und Ausbreitung sowie Gleiten im Falle von vorhandenen Diskontinuitäten verbunden sind. Die Ergebnisse dieser experimentellen Untersuchungen könnten erklären warum elektrische Potential Schwankungen während der Bruchbildung und dem Gleiten von nicht-piezoelektrischen Geomaterialien entstehen. Auf der Basis dieser Ergebnisse, wurden ihre möglichen Implikationen in Geoingenieurwissenschaften behandelt.

Jan 1, 2003

By B Ascott, J Kennedy, A White

At mines with low tonnes per vertical metre, like the Jundee Mine in Western Australia, operated by Newmont Asia Pacific, high development rates across multiple mining areas are critical to achieving the delivery outlined, or promised, in the annual business plan. The challenge is to deliver the short-term requirements while keeping in balance with the long-term strategic direction. Newmont Jundee has developed a system called æMine Planning by QuartersÆ that integrates the planning process with the business process in one end-to-end continuum. Short-, medium- and long-term schedules are reviewed and updated by applying four integrated subprocesses, which capture new information as it becomes available. The four subprocesses are: resource development planning û evaluating mineral resource,reserve development planning û preliminary design for new reserves,mine operating planning û final mine design for reserves, andmine production planning û detailed plans for stoping a proved reserve. Commercial mine planning software is used in these subprocesses to facilitate the flow of information into a central storage æhubÆ for uploading into the rolling business plan. A regular and consistent quarterly review helps to identify and qualify areas of business risk at an early stage, allowing time to plan for contingency and minimise the impact of the risk.

Jan 1, 2008

By A. Bartkowiak

The lower flammability limit of methane at 0 p.s.i.g. and ambient temperatures is 5.6 volume percent in chlorine, 5.2 in oxygen, and 5.0 in air. The corresponding upper limit values are 70, 60.5, and 15 volume percent, respectively, so that the range of flammable mixtures is greater in chlorine than in oxygen or air. The lower flammability limit of ethane at 0 p.s.i.g. and ambient temperatures is 6.1 volume percent in chlorine, 3.0 in oxygen, and 2.9 in air. The corresponding upper limits are 58, 66, and 12.5 volume percent, respectively. In this instance the range of flammable mixtures is greater in oxygen than in chlorine or air. Generally, the limits of flammability for both methane-chlorine mixtures and ethane-chlorine mixtures widen with increases in temperature and pressure.

Jan 1, 1960

JESSE L. JONES,* Pittsburgh, Pa. (written discussion?).-As the die-casting process is so very different in character from the process of making sand molds, it is often considered that entirely different methods of pouring, gating, venting, etc. should be used. There is really, however, no essential difference in the making of (lie castings and sand castings, and similar methods should be used in each process. In the matter of gating, the metal should be introduced at a central point, as nearly as possible, so that it will have an equal distance to flow from the point of entrance to the most distant points of the mold. This will cause a uniform rate of congealing of the casting and prevent streaks and cold shuts. The venting should be done in such a way that a free exit of the air in the molds can occur. It should be less difficult to take care of the venting of a die-casting mold than to vent an ordinary sand mold. In the case of a sand mold, the venting is left, to a considerable extent, to the judgment of the molder, and it is possible that no two molds will be vented in a similar manner. Further than this, after a vent has been made in a sand mold, it may become clogged by the sand and for this reason be inefficient. There is also quite a variation in the pressure of the metal entering a sand mold, due to varying heights of the pouring gate. In a die-casting mold these factors can be controlled more closely. The vents should be so disposed that the air in the mold compressed by the entrance of the metal may be able to leave the mold at a uniform rate and by exits located symmetrically. These exits are made quite small on molds at first, as they can he easily enlarged if necessary, and they are tapered so that a free flow is guaranteed without danger of the metal spurting out from the die. Uniformity of pressure of the metal as it enters the mold is very important and, as the pressure is mechanically applied, its control is not difficult. It is true that a sand mold has much less of a chilling effect on the metal poured into it than has the die-casting mold, but, outside of this point, there is a great similarity between the die-casting process and the process of making castings in sand folds. It is suggested that much would be gained by regarding these two processes as not essentially different.

Jan 4, 1919

By Randal J. Barnes

There are many methods available for the estimation of geologic parameters (Popoff, 1966; Barnes, 1980). In the last decade a new and relatively sophisticated technique using statistical theory has emerged: geostatistical kriging (David, 1977; Journal and Huijbregts, 1978; Rendu, 1978). An interesting property of geostatistical estimation is that when a geologic parameter is estimated for a given volume, not only is the estimate generated but an associated measure of certainty is produced as well. This statistical measure of estimation confidence is called the estimation variance. While the concept of an estimation variance is universally considered to be a good idea, mining engineers and geologists do not currently have the tools to incorporate it into their planning and quantitative analysis. This paper attempts to develop and present some of the necessary tools required to incorporate estimation uncertainty into mine planning. Geologic uncertainty is portrayed as an economic business risk. This risk is objectively characterized, and-the associated cost is quantified. Geologic delineation sampling is viewed in this light as an economic commodity with an associated cost and value. A coal mine planning example is used as a focus in this presentation. The data used is real, though it has been modified to maintain data security and project anonymity.

Jan 1, 1986

The McArthur lead-zinc-silver deposit is of the stratiform type. It consists essentially of a mineralized bituminous shale sequence that incorporates tuffites, numerous graded beds, and isolated but massive slump breccia horizons.The principal sulphides are' pyrite, sphalerite, and galena. These occur mostly in the shales. The accompanying turbidites contain only minor mineralization.The geochemistry of the deposit has been investigated in relation to the stratigraphic column and mineralogy of the sediments.A sedimentary origin is proposed for the deposit. Volcanism, thermal spring activity, salinity, regional faulting, and climate are examined as possible factors that may have contributed to sulphide formation and which could be used as criteria for mineral exploration.The metallurgy 'of the McArthur deposit is discussed in terms of its geological history.

Jan 1, 1972

By T Baard, A Pieters

This paper deals with the design and implementation of a 17 MW (nominal) surface cooling installation at Impala Platinum No 14 shaft located in Rustenburg, North West Province, South Africa.The cooling requirements included the installation of a surface ammonia refrigeration plant complete with the storage of hot and cold mine service water for underground use. It was also necessary to install a surface bulk air-cooling facility, which cools 400 kg/s of ventilation air going to the underground workings. Primary cooling is to the surface bulk air cooler. The cooling duty of a surface bulk air cooler is heavily dependent on the ambient wet-bulb temperature. Because of the daily wet-bulb temperature variation in this part of the world, use was made of a cold thermal storage facility of four million litres. The excess chilled water is stored during the night, for use by the main drilling shift during the day. This keeps the refrigeration machines as close as possible to full load during the summer, thus maximising the use of the capital expenditure. This paper discusses the control philosophy used to maximise the cooling output, as well as the thermal process. The project consisted of two phases resulting from the underground development phases of the mine. The first phase started in January 1999 and was commissioned by the end of the same year in record time. The final commissioning of the second phase took place at the end of 2002. The most difficult part of the construction phase was the tunnelling of a subsurface air duct from the bulk air cooler to the operating vertical shaft. This was done without disruption to the hoisting of men, material and ore in the shaft. Owing to the size of the refrigeration machines, the ammonia quantities involved and the application on a mine (no ammonia can go underground, either in the service water or in the mine air) special precautions had to be taken. South Africa has developed high standards for ammonia refrigeration plants used on mines, which will be partially dealt with in this paper.

Jan 1, 2005

By Claude H. P. Lupis, John F. Elliott

IN the recent past, extensive use has been made of the interaction coefficient in treating the thermody-namic behavior of components in solutions at dilute concentrations. The development of this concept by wagner1 and chipman2,3 is sufficiently well-known so that its elucidation here is not necessary. The present discussion is focused on the relationship between E and e. The usual forms of the coefficients are:

Jan 1, 1965

Jan 1, 1906

By EFFC/DFI Concrete Task Group

Concrete technology continues to advance rapidly and modern mixes with five components – cement, additions, aggregates, (chemical) admixtures and water – often have characteristics which differ significantly from the older three component mixes – cement, aggregates and water. Recent trends have favoured higher strength classes and lower water/cement ratios, resulting in greater dependence on admixtures to compensate for reduced workability and to meet the (often competing) demands for workability in the fresh state and setting time. The application of testing methods which reflect the true rheological properties of the concrete has not developed at the same rate as the mixes themselves and it is still not uncommon for the slump or flow table test to be used as the only acceptance test for fresh concrete.A joint review of problems in bored piles (drilled shafts) and diaphragm walls cast using tremie methods by both the European Federation of Foundation Contractors (EFFC) and the Deep Foundations Institute in the United States (DFI) identified a common issue. The review determined that many of the problems were caused by (or in part due to) the use of inadequate concrete mixes with inadequate workability, or insufficient stability or robustness of the mixes. It further identified the primary causes as inadequate concrete specifications and inadequate testing procedures. The consequences of these problems are often significant and it has been recognised that spending more time and money on getting the concrete right is the most cost effective approach.A joint Concrete Task Group was set up by EFFC and DFI in 2014 to look at this issue and this guide is the output from that Task Group. A research and development project, funded by the Sponsors of this guide, is being carried out by the Technical University of Munich in conjunction with the Missouri University of Science and Technology. This project includes desk studies, laboratory testing, and onsite testing at worksites in Europe and the US. The research work will be completed during 2016.

Jan 1, 2016

By R. A. Crouse

The Tanco pegmatite at Bernie Lake, in the Lac du Bonnet mining district of southeastern Manitoba, is a unique deposit of Li, Rb, Cs and Ta, with substantial reserves of Be and several industrial minerals. This paper summarizes the present state of understanding the regional geology, structural setting, zoning, mineralogy and geochemistry of the pegmatite, and the mining and ore-processing methods used in its exploitation.

Jan 1, 1979