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By B. C. Allen

Liquid surface tensions of copper and 18 Group IV-A to VIII transition metals (Ti, Zr, Hf, V, Cb, Ta, Mo, W, Re, Ru, Rh, Pd, Os, Ir, Pt, Fe, Ni. Co) have been measured by the static pendant-drop and dynamic drop-weight methods on the same rod sample. The drops were formed by electron-bombardment heating in high vacuum. Application of necessary corrections enabled determination of surface tensions to k2 pct and agreement between methods to * 1 to 4 pct for all the metals studied. Evidence is presented that the liquid surface was well screened by metal vapor, suggesting negligible adsorption of gaseous impurities and that the surface tensions measured are characteristic of the metals involved. Correlations between liquid surface tension and melting point, molar volume, heat of vaporization, and atomic number are presented and discussed. Temperature coefficients of surface tension were calculated using Eötvös' law. SURFACE tension and interface energies of metals are the result of incomplete atomic coordination resulting in a force perpendicular to the boundary, tending to minimize its area. These energies are important in many phases of metallurgy, including microstructure, sintering, joining, electronic emission, and lubrication, which in turn affect many physical and mechanical properties of metals. Liquid surface tension refers to the interface between the liquid and its own vapor or nonreactive atmosphere, and is considered a physical property of the liquid. Since equilibrium shapes can be readily obtained with liquids, the units of surface tension (force per length) and interface energy (energy per area) are interchangeable. Thermo-dynamically, the surface tension ?LV is given by the change in free energy F with surface area A at constant pressure P, temperature T, and composition N: for commercially important refractory metals, vanadium, columbium, tantalum,13,14 molybdenum,14 and tungsten,l5 and none for the rare platinum-group metals and rhenium. Measuring the surface tensions of transition metals is difficult because of their high reactivity and melting points. Of the many techniques available,16-18 the pendant-drop 19-21 and drop-weight methods17,22 are considered superior because they can be modified to eliminate persistent sources of contamination such as supports and capillaries necessary in the popular sessile drop, capillary rise, and maximum-bubble-pressure techniques. The necessary modification is to melt a drop on the tip of a vertical rod, which provides support through a solid of the same composition.13,15 The object of the work was to study the surface-tension behavior of copper and transition metals, having reasonably low vapor pressures. Liquid surface tension of each pure metal was systematically determined by using a combination of the static pendant-drop and dynamic drop-weight methods on the same rod. Liquid drops were formed by electron-bombardment heating in high vacuum. EXPERIMENTAL WORK As indicated in Table I, the metals studied were high purity and generally were obtained in rod form. The exceptions were titanium and zirconium, which were machined from crystal bars, and molybdenum (tot 11, osmium, and ruthenium, which were sintered and arc cast into rods. All the metals were ground or swaged to desired sizes between 1- and 7-mm diam, and centerless ground round and smooth to a finish better than 50 µ in., rms. Each rod was thoroughly cleaned with steel wool, degreased, acid etched, and dried. In a typical run, the rod was vertically clamped in a modified floating-zone electron-bombardment furnace designed after Calverley23 and Carlson.24 The specimen was outgassed and maintained positive at several kilovolts in a dynamic vacuum of 10-5 to 10-7 mm. The bottom end was enclosed by a tantalum pillbox and heated by electrons emitted from a hot concentric tungsten filament mounted on a movable bracket. The bombardment power was slowly raised until melting was observed. Power requirements ranged from 30 w for copper to 1300 w for 4-mm tungsten. The stabilized and out-gassed drop of near-maximum size was photographed at 4. 1X on panchromatic film at desired time inter-

Jan 1, 1963

By Ben A. Kornhauser

The mineral industry consisted primarily of natural gas production and of urea fertilizer, which was manufactured for domestic agriculture. Copper and iron deposits were being developed. Information regarding the mineral industry of Afghanistan was sparse. The Government continued to emphasize the development of mineral resources that could benefit the economy of the U.S.S.R. and repay Soviet grants. The northern half of the country, north of the Hindu Kush mountain range and adjacent to the U.S.S.R., received considerable Soviet aid to develop mineral resources.

Jan 1, 1986

By Takeshi Ohgai, Hisaaki Fukushima, Tetsuya Akiyama, Joon-Seo Ki

"Recently, an intensive attention has been paid to the electrodeposition of Zn-Cr alloy in the field of the production of super-highly corrosion-resistant alloy plated steel sheets for the next generation. In this study the electrodeposition of Zn-Cr alloys from the sulfate baths was conducted to investigate the codeposition mechanism of Cr with Zn. As a result, Cr was codeposited with Zn at higher current densities in both polyethyleneglycol(PEG)-free and PEG- containing baths. However, PEG made it possible to reduce Cr+ to the metallic state and Cr existed in the form of Cr(III) hydroxide in the deposits obtained from PEG-free bath. The measurements of the partial polarization curve of Zn and the pH in the cathode layer revealed that PEG acted as a polarizer to shift the cathode potential to the reduction potential of the composited hydroxides of Zn and Cr formed due to the pH rise in the cathode layer.1. IntroductionRecently, much attention has been paid to the electrodeposition of Zn-Cr alloys because of its application to the production of super-highly corrosion-resistant alloy plated steel sheets for the next generation1Hl_ Some researches have already tried to commercialize this type of steel sheet. High corrosion-resistance of this steel sheet is brought about by codeposited Cr in the alloys. According to Piontelli's classification5l concerned with metal deposition from aqueous solution, Cr belong; to an inert metal and its deposition is associated with a large amount of hydrogen evolution. Therefore the current efficiency for Cr deposition is extremely poor. It has been also reported that Cr is unable to codeposit in the electrodeposited Zn film in the absence of a certain additive in the solution. 0-compounds group colloids7l, ether group organic compounds8), 9>, peptide based compounds10l, etc., have been found to be effective additives to induce the codeposition of Cr with Zn. However, few studies have been made on the codeposition mechanism of Cr with Zn. In this research, the fundamental electrodeposition behavior of Zn-Cr alloys from sulfate baths was investigated to clarify the codeposition mechanism."

Jan 1, 1998

By Joseph P. Nugent

The new combination gypsum plaster and gypsum wallboard plant of Compania Industrial Kaiser S.A., the first of its kind in Mexico went into production in April of 1969. This was approximately fourteen months from the signing of the formal order for the plant and equipment. Compania Industrial Kaiser S.A. is an affiliate of the Kaiser Gypsum Company in the United States and will market practically the same line of products and to the same standards as those produced in American plants. Located in the City of Puebla, the plant will readily service the major Mexican sales areas. It is approximately 85 miles away from Mexico City on a modern, four-lane, divided highway and distribution to other major consumer areas can be readily effected by the use of a good highway system, as well as, by rail. This, plant is the, sixteenth Gypsum Wallboard Mill supplied abroad by my company, United States Wallboard Machinery Company. Other installations are in Australia, New Zealand, Chile, England, Scotland, Ireland, Finland, South Africa, Latvia and Germany. Two new mills are on order; a small unit for Brazil and a comparatively large unit for New Zealand. All these mills have one thing in common with plants in the United States and Canada; they are equipped with standard, time-proven and tested equipment and they are designed in accor¬dance with the latest engineering thinking in order to produce efficiently, the highest quality product at lowest cost. They differ generally in the size of plant, the factors that brought them into being and in the market that they supply. I believe that these differences will be of interest to you.

Jan 1, 1969

Environmental considerations were key factors in the design of the Ranger Uranium Mines treatment plant. The mine is located adjacent to the Kakadu National Park and has an average rainfall of 1.6m per annum. Initially, no contaminated water or liquid effluents are to be released from the project area and thus water management is a key design and operating fact. Particulate and gas emission criteria influenced design as did occupational hygiene factors (dust, radon, housekeeping, maintenance access). Equipment selection and engineering standards were conservative and resulted in the plant attaining design performance in less than three months from the date of commissioning. A number of mechanical and operational problems were experienced and are discussed in the paper, however none of these problems have had a significant effect on production.

Jan 1, 1984

It's my privilege to welcome you here this afternoon on behalf of the Sydney Branch of the Australasian Institute of Mining and Metallurgy. This is a most important gathering. You, the delegates, represent what is probably the most influential cross-section of the mining investment community and the oil and gas investment community to meet as a group during the last decade. We are meeting today and tomorrow to review two related issues that will have far reaching implications for the effective use of capital by the natural resources sector in the 1990's. The views which will emerge over the two days will almost certainly 'influence the availability of new capital to the companies in the natural resources sector for the decade ahead. The two principal themes of Minval '89 are, first, the valuation of mining and oil and gas assets and securities, and second, disclosure and reporting requirements in the capital markets which relate specifically to natural resources companies. This conference is taking place at a time when further consolidation and rationalisation appears likely within the mining industry. Although the base metals and other sectors of the industry are enjoying profitability not seen since the early 1980's there is caution about committing to new capacity which could bring about a return to the low prices and excess supply which prevailed during much of the last ten years. These conditions have led to increased takeover activity within the mining industry overseas, and similar trends are as evident here in Australia as they are elsewhere. Recognition of value is therefore likely to become more important than ever before in preserving shareholder wealth, for creating new wealth and for preserving the financial health of the resources industry in the future. Valuation therefore is the first theme of the conference.

Jan 1, 1989

By Thomas Rupp, Michael Siegwart

The paper presents the vibration and sound emission measurement campaigns carried out in 2007 in preparation for the Ceneri-Basistunnel construction. We also present the vibration measurement campaign conducted during the construction of the Zimmerberg-Basistunnel. Both tunnels form an integral part of the Swiss Federal Railway Company Neue Eisenbahn Alpentransversale project (NEAT). This strategic project comprised the construction of several new tunnels. Its aim is the improvement of the existing infrastructure. The improved infrastructure will be able to accommodate a larger volume of railway traffic that is also crossing the Alps at higher speeds. The construction of the Ceneri-Basistunnel commenced in 2006. Both the Zimmerberg-Basistunnel and the Ceneri- Basistunnel are located underneath densely populated areas. Therefore, noise and vibration emissions have to be kept to a minimum and must not exceed applicable codes of practice. In order to identify the most appropriate blasting strategy for the yet to be constructed Ceneri-Basistunnel, blasting trials were conducted. The paper presents the findings of these trials and identifies ways to reduce both noise and vibration emissions from blasting. The construction of the first phase of the Zimmerberg-Basistunnel took place between 1999 and 2003. While the first phase is already in operation, the construction of the second phase has been postponed (commencement originally due in 2007). The Zimmerberg-Basistunnel connects the outskirts of Zürich with the city centre. As the tunnel site was not located close to the surface near populated grounds, no special measures were needed to reduce the noise emissions from blasting. However during the construction of the tunnel, the vibration emissions from blasting were monitored on more than 50 locations on the surface. The paper presents the analysis of some of the data. An emphasis is placed on the appropriate synopsis and presentation of data for documentation purposes.

Jan 1, 2009

By Vadim J. Jabotinski

This paper describes several areas of application for electron beam processing of materials. The technology and use of electron beam systems in gas phase synthesis reactions are described. Gas phase reactions may be used to generate ultra- fine metal or ceramic powder that are very pure and crystalline. Among the examples presented are: the generation of nanometer sized metal powders and the gas phase synthesis of silicon carbide for silica and methane. The experimental system is described and future theoretical and experimental objectives are identified.

Jan 1, 1998

A brief description of the mining method and ventilation system of the San Manuel Mine?s first presented; this is necessary to an understanding of the heat problem and cooling system. The problem of heat at San Manuel is discussed. Charts and graphs showing the relationships between ambient surface air and underground temperature conditions are given. A history of attempts to cool air at San Manuel is presented, starting with the first refrigeration type air coolers which were used in development headings, and followed by the underground water chillers that were used in conjunction with cooling coils. Goals for design of a centralized cooling system with ultimate heat rejection through surface cooling towers are presented. The problems found with using the centralized system in main cooling coils are discussed. Plans for modification of the centralized system as utilized is the summer of 1987 are given, along with results obtained and problems with the system. Plans for subsequent modifications are presented.

Jan 1, 1988

The exploitation of mineral deposits for economical recovery of the contained minerals has many aspects differing from other industrial or manufacturing operations. However, generally accepted principles of good organization and management applicable to industrial plants are similarly effective for mineral processing plants. A more detailed coverage of organizational structures and management techniques than is possible in this section can be obtained from many good books devoted wholly to these subjects. A few of the more readily available examples are included in the general references at the beginning of this section. The field of mineral processing encompass a wide variety of minerals, processes, flowsheets, equipment, and end products. Mineral deposits, mines, and related beneficiation plants are found in all parts of the globe, often in remote locations with no nearby support for supplies and maintenance. Available labor is frequently unskilled, sometimes primitive, and often untrained without machine and hand tools or heavy equipment experience. Such situations call for well- planned and conducted training programs covering the full range of mining-type job skills. Climates can range from arctic to tropical and from arid to extremes of rain or snow, and the mine and plant sites can be almost anywhere. However, it is often possible and sometimes necessary for

Jan 1, 1985

By Forssberg KSE

Purification of GAsgruvan Limestone is carried out by anionic, cationic and cationic followed by anionic flotations in order to obtain a calcite concentrate that is acceptable to the paper industry. The results indicate that such a concentrate could be achieved by first carrying out the separation of siliceous gangue minerals by cationic flotation followed by the separation of carbonate during the anionic flotation. Stearylamine acetate (Flotigam SA) and a modified fatty acid (OMC 357) are found to be selective during cationic and anionic flotation, respectively. A final product containing 99.25 per cent calcite with a recovery of around 80 per cent is obtained. It is hoped that these results could be further improved by the follow-up process variable studies, in particular, the effect of reagent dosages and conditioning time at each stage of cationic and anionic flotation steps.

Jan 1, 1993

By P. E. Doherty, R. S. Davis

Sub boundaries and micropores, as well as certain other imperfections, may be revealed in aluminum by the formation of pits on the surface during cooling from elevated temperatures. The pits are attributed to the condensation of vacancies from supersaturated solution. This "vacancy pit" phenomenon has been used as an etching technique for studying the structure of aluminum specimens grown from the melt. Three fundamental structures were studied: stria-tions, cells, and dendrites. Two types of striations, as well as a crosswise structure are reported. Mic-roporosity is observed to occur in the cell walls on freezing. Subboundaries between primary, secondary, and tertiary branches are observed in dendritic growth. A special case is cited in which cellular growth suppresses the formation of striations. SMALL, well-defined pits have been observed to form on the surfaces of electropolished aluminum specimens during cooling from elevated temperatures.' This phenomenon was attributed to the condensation, from supersaturated solution, of vacancies at particular points on the surface. It was shown that the amount of cooling required for the formation of pits increased exponentially with decreasing holding temperatures in a way that was consistent with the thesis that a critical supersaturation of vacancies was required for the pits to form. Pits do not form in the vicinity of certain imperfections, namely, subgrain or normal graind boundaries, phase boundaries, certain surface irregularities, and pores. The width of the pit-free region increases with decreasing cooling rate. This observation suggests that the imperfections in question are effective sinks for vacancies and that the pit-free region around them is material that is not sufficiently supersaturated with respect to vacancies to nucleate the surface pits during cooling.

Jan 1, 1962

By A Sellgren, M R. Carstens, R Visintainer

There is a wide variety of industrial pastes or non-settling slurries pumped in mining, dredging and reclamation projects as products, refuse and tails. The types and/or names of some of the common ones are alumina red mud, phosphate clays, tar sands mature fine tails, tar sands (CT) consolidated clays and fly ash. The pipeline performance or friction of these varies dramatically with the type, its concentration and the particulars of the actual slurry making it difficult to select pumping equipment and to design associated pipelines. The GIW Hydraulic Laboratory in Grovetown Georgia has tested a number of these slurries over the last 30 years for various mining customers. Where available in the public domain and/or where permission has been obtained, the results of those tests are presented in this paper in a form usable for pipeline and pump system designers and users.

Jan 1, 2005

By G. McIsaac

"This paper discusses the formulation of a linear program with the objective of maximizing the cash flow of the long-term plan of an underground operation. A mine is split into eleven independent ore zones, each characterized by its reserves, required development, and mining method. Based on practical considerations, maximum rates are set for each zone’s development and production capacity. For the total mine plan, a minimum daily production rate is set along with a minimum feed grade to the mill. A maximum daily development capacity is set based on the equipment and labour available. Proven and probable ore is mined preferentially over possible ore in the early years of the plan. Also, the fixed cost of operating the mine is taken into consideration whenever mining activities take place.Once the linear program is solved, it can be critically reviewed, and unrealistic results can be identified. Some resource allocations constraints can then be changed in certain sectors, and new results can be analyzed. “Whatif” scenarios can also be examined, such as determining the impact of hiring a contractor to develop a given sector, or dropping an ore zone completely from the plan."

Jan 1, 2005

By R H. Stevenson

This paper deals with a new variation of the cast blasting technique, where-in the object is to cast the economic deposit out front under the overburden, while avoiding dilution from the floor material. To date, the technique has been successfully applied at two cement quarries in Iowa and at a granite quarry in Minnesota.

Jan 1, 1991

By K. E. Tame

The Bureau of Mines is studying possible modifications in conventional uranium ore-processing steps to confine and permit controlled disposal of radioactive wastes. A potential method of minimizing pollution from radio-active nuclides, principally radium 226, in uranium mill waste streams is to reuse the waste solutions within the mill. Such reuse of waste solution in the Kerr-McGee Shiprock-type process was investigated in the laboratory. The Shiprock mill employs a two-stage acid-leaching process for dissolution of the uranium, countercurrent decantation for liquid-solid separation and washing, and organophosphorus solvent extraction for recovery of the uranium and vanadium from solution. The simulated use of barren raffinate instead of fresh water in the mill circuit was carried through a laboratory campaign of 28 interlocked leaching, washing, and solvent extraction cycles. About 99 percent of the uranium and 91 percent of the vanadium were dissolved from the are, Washing efficiency in the thickener circuit averaged about 99.5 percent when the pulp was washed with enough barren raffinate and makeup water to recover 2.5 tons of pregnant solution per ton of ore. The only solution discarded was that contained in the washed and thickened leach residue. A buildup of salts due to recycling of solutions did not adversely affect operation of the washing circuit.

Jan 1, 1962

Develop a user-friendly computer program that permits those interested in mine health and safety to access and analyze on a personal computer (PC) employment, production, and accident data for U.S. coal and metal-nonmetal mines. This software is being designed with a major focus on flexibility and case of use. The Mine Accident Decision Support System (MADSS) will be available for distribution in mid-1994. Currently, the U.S. Bureau of Mines (USBM) is seeking volunteers willing to pilot test a preliminary version of the software and to provide suggestions for its improvement. Background Since 1975, the Mine Safety and Health Administration (MSHA) has compiled large data bases of information about U.S. mines and the reportable accidents, injuries, and illnesses that have occurred in those mines. Employment and production data arc collected on a quarterly basis from each mine and accident information is collected on an incident -by-incident basis. The USBM has compiled estimated costs for each of these accidents using computer models. All of this information is potentially useful to mine health and safety researchers. However, it has been underutilized because it is stored in large mainframe data bases that arc inaccessible to many users and/or are cumbersome and difficult to use.

Jan 1, 1993

By George M. Enos, Robert J. Anderson

An impoRtant factor affecting the rate and nature of corrosion of metals and alloys is the film, or coating, formed on the surface; and this may accelerate or retard corrosive action once started. The formation of films and coatings is intimately associated with the chemical composition and physical constitution of both the metal and the corroding medium. A film or coating may be either the corrosion product resulting from oxidation; that is, an oxide or salt, or a deposition of suspended matter from the corroding media upon the surface of the metal, or a mixture of both. The coating may adhere tightly or loosely to the surface of the corroded metal. In short, a film or coating is the reaction product of the corroding medium and the metal, which adheres to the surface of the metal and with which may be intermingled material from the attacking media not concerned in the chemical reactions. As the terms film and coating are used by different writers for very different things, distinction is made between the two, by the present writers, on the basis of thickness. Thus, a film is defined as a corrosion product or deposition, on the surface of a corroded metal, that is of such thickness that it cannot be measured by the metallurgical microscope. A coating, on the other hand, is of such thickness that it can be measured. If the resolving power of the 2-mm. (equivalent focal length) apochro-matic oil immersion objective (N.A. 1.4) is taken as the limit of the microscope, the limiting resolution is two lines that are 0.0002 to 0.0004 mm. apart. It is thus possible to measure coatings that are greater than 0.0002 to 0.0004 mm. thick. This thickness is equivalent to 50,000-

Jan 1, 1925

Underground mine designs typically try to avoid extraction beneath streams and rivers of any significant size, especially when the overburden rock thickness between the stream bed and the mine is thin. Potential issues with mining beneath streams include excessive groundwater inflow to the mine; weak ground (roof, floor, and pillar) conditions; horizontal stress effects; as well as stream loss and other potential adverse environmental effects. However, there are times when crossing beneath a stream or river is necessary to move into a new area of mineral reserve without creating additional mine access points from the ground surface. Often, stream crossings are completed without thorough assessment, potentially resulting in increased costs, decreased safety, and, in some cases, failure to advance the mine. Selection of the most favorable location(s) to cross the stream must account for numerous factors and the associated assessment often requires a multidisciplinary approach. Stream crossing investigations often require geological, hydrogeological, geotechnical, and geophysical expertise. Phases of stream crossing investigations include desktop evaluation of maps and aerial photography, stream bed observations, drilling, detailed rock core logging, downhole geophysical surveying, hydraulic conductivity testing (packer testing), geotechnical laboratory testing, assessment, and reporting. The deliverables from a stream crossing assessment typically include geological, geotechnical, and hydrogeological characterization of potential stream crossing locations; classification of favorable and unfavorable crossing locations; recommendations for entry design and pillar sizing; and recommendations for if, and how, to conduct pre-grouting activities. Examples of technical aspects of data collection and assessment are provided based on decades of industry experience conducting stream crossing assessments in various underground mining scenarios.

Jul 28, 2020

By Anne-Laure Bonnet

Les connaissances acquises au cours des dernières décennies sur les gîtes de métaux de base et précieux intensément métamorphisés (p. ex. Vokes, 1991; Cornell et al., 1992; Zaleski et Peterson, 1995) ont permis d?élaborer des guides d?exploration pour de tels gisements dans les terrains de haut-grade métamorphique (Spry et Scott, 1986; Rubin et al., 1993; Hand et al., 1994; Spry, 2000; Spry et al., 2000). Un transfert de ces connaissances à la cartographie des vastes terrains gneissiques non différentiés de la province de Grenville permet d?affiner l?approche cartographique nécessaire pour reconnaître les systèmes hydrothermaux métamorphisés en terrains vierges et peu diagnostiques puis d?en discriminer les divers halos d?altération (Corriveau et al.,1996, 1997, 1998, 2003; Williamson et al., ce volume). Cette approche prend en compte les « empreintes métamorphiques » observées sur le terrain, telles que les variations des assemblages minéralogiques, du mode et de la composition des minéraux métamorphiques, pour reconnaître des roches présentant une composition inhabituelle caractéristiques de protolites altérés par hydrothermalisme. Ces empreintes citées cidessus sont facilement reconnaissables dans les terrains de haut-grade où la recristallisation induit un grossissement des grains qui permet de déterminer la nature et le mode des minéraux dès les levés de terrain. Cette approche raffine la compréhension des terrains de haut-grade métamorphique et illustre que leur complexité (i.e. polyphasage de la déformation et du métamorphisme) n?est pas forcément une limite à leur exploration. Elle a donc été utilisée systématiquement lors des levés de terrain réalisés dans le cadre d?un projet de l?Initiative géoscientifique ciblée de RNCan. La zone cartographiée se situe le long de la marge sudest du Groupe de Wakeham dans le secteur est de la Province de Grenville. Deux régions ont été plus particulièrement étudiées, celle du lac Musquaro (SNRC 12K10, 11 et 14) et la région côtière comprise entre Kégashka, La Romaine et Baie des Loups (SNRC 12K1, 2, 3 et 7) (fig. 1).

May 1, 2003