Search Documents

By William Petruk, J. R. Schnarr

The behaviour of minerals during flotation of a fine-grained pyrite-rich base metal ore was investigated by studying the feeds. concentrate and tailings from every flotation cell in the mill of Brunswick Mining and Smelting Corp. Ltd. Bathurst. New Brunswick. The samples were analyzed for Zn, Pb, Cu. Fe, Ag. Sb, Sn, Bi, In. Hg, Mo and As. Mass balances were computed and recoveries of all metals from each cell. from each circuit and from the mill were calculated. The percentages of sphalerite. galena and chalcopyrite occurring as free grains in each product were determined with an image analyser, as were size analyses for free mineral grains and middling particles, and compared with screen analyses. The results show that the behaviour of minerals is defined much better by the recovery of free mineral grains than by the recovery of elements. The recovery of free sphalerite in the zinc circuit is 96 wt %, whereas Zn recovery from the same circuit is 88 wt %. the difference being due to unliberated sphalerite. The recovery of free sphalerite from the mill feed is 88 wt % and Zn 78 wt %. The recovery of free galenafrom the mill feed is 88 wt % and Pb 64 wt %. The recovery of free chalcopyrite is 75 wt % and Cu 45 wt %. Size analyses show that more sphalerite and chalcopyrite can be liberated by regrinding. but the galena is so fine grained that regrinding would not necessarily improve liberation. Silver occurs mainly in tetrahedrite and galena; the main loss in the tailings is due to large (+ 26 um) and small (-1 um} free and unliberated tetrahedrite grains.

Jan 1, 1981

By G. Swiatnicki, w. Chruscielewski, T. Domanski

INTRODUCTION The inherent errors of simple passive track detectors /SPTD/ used for estimation of exposure to the radon daughters /RnDP/ amount to about 30% /Do75/ while for active detectors only reach about 3 - 4% /Ph78, Du79/. The large error inherent in SPTD is the result of strong dependence of its calibration coefficient on the equilibrium Rn RnDP in the vicinity of detector /0r80/. Nevertheless the SPTD shows many advantages and seems to be very useful for to the estimation of individual exposure of miners to RnDP /Do81a/. For this reason the investigations are undertaken to improve SPTD so that it might provide information about the equilibrium Rn : RnDP during exposure. If the equilibrium would be known then one could use a suitable calibration coefficient yielding a better precision of the measurement. So far, some investigations of the improved type of SPTD have been conducted. One was based on the concept of using the so called diffusion barrier permitting to differentiate the tracks originating from Rn and RnDP /Fr77/. Such improved detector has been named a passive differentiating track detector /PDTD/. However, own investigations have shown /Do81b/ that this type of detector cannot provide precise informations about equilibrium Rn : RnDP. For this reason the investigations of the new idea of PDTD have been carried out. The new model presented below is based on the use of the absorbers of alpha particles. THEORETICAL CONSIDERATIONS The first variant of the concept is as follows: The differentiating detector consists of two portions of detective foil /track detector/ but only one is covered with an aluminium absorber. Thickness of the absorber is carefully selected so that only RaC' particles /7.7 MeV/ can pass the barrier. The second portion of the detective foil records all alpha particles originated from Rn and RnDP i.e. works like a SPTD. The scheme of such a detector, the so called two-fields passive differentiating track detector /PDTD-2/ is shown in the Fig. 1. It is possible to introduce a parameter that can characterize the equilibrium Rn RnDP, namely, the so called track density ratio /TDR/. The definition of this parameter for the considered type of detector is TDR2 = D1•D2-1. One can expect the simple proportion to hold: [ ]

Jan 1, 1981

By Don B. Shupe, John K. Berry

The handling and disposal of mine water is a much larger problem than is apparent at first glance. Many more tons of water are removed from underground coal mines in the United States each year than tons of coal. In the old anthracite region of Pennsylvania the average was around 32.7 t (36 st) of water for each ton of coal produced, while bituminous mines average about 4.5 or 5.4 t (5 or 6 st). Water encountered in the mines may come from several different sources. In mines with light cover and without a firm solid roof, rain may seep directly into the workings. This is also true of deeper mines where pillar falls have broken the roof to the surface. The top under creek beds is generally faulty and broken and water comes through the roof at this point. Deeper mines are frequently overlain by water-bearing strata and pillar breaks and faulty top can admit water, while places running to the dip often accumulate water which comes up through the bottom. In all cases, except where passing under a year-round stream, the amount of water made is usually pretty closely connected with the weather-more water during the rainy season, less in the dry, although the deeper a mine is, the longer it is before changes in rainfall are felt. Another source of water, not connected with seasonal changes, is old water, accumulated over a period of time in abandoned workings of the mine, or from flooded adjacent mines. Here the water filters through the coal, the parting, or comes up through cracks in the bottom. Similarly, core holes, drilled to prospect the property, can be a source of unexpected water and modern safety requirements for dust-allaying water at the working faces can turn a pleasant working area into a soggy mess over the weekend if the system is not properly maintained and operated. Why water must be disposed of is obvious. If allowed to accumulate, sooner or later the mine will fill up, or at least it will become "roofed" in low places, blocking ventilation and traffic. It must be controlled long before it reaches this stage. Water standing in the working faces is

Jan 1, 1981

By Robert J. Clarke

Reflections on over ten years experience handling bituminous coal from railroad cars to ground storage and lake vessels. The arrangement of the facilities is described but the basic theme of the discussion is the experience gained and lessons learned from facility operation. The Great Lakes provide the maritime environment for the economical transport of vast quantities of raw materials from their source in the Upper Lakes (the Mesabi Range, for instance) to Lower Lake Ports. Lake Erie, because of its proximity to the steel centers , blossomed with the great ports that now line its southern shore - Toledo, Sandusky, Lorain, Cleveland, Huron, Ashtabula, Conneaut and Erie.

Jan 1, 1981

By G. V. Henderson

Limestone and Dolomite quarries located near Salto-De-Pirapora, Arroia Grande Gaucho, Conde Francisco and Candioita probably represent the closest, major sources of high quality lime and cement grade carbonate rocks to the major population center of Sao Paulo Brazil. The nearest major city to most of the limestone - dolomite sources is Sorocaba and Palma. All of the mining properties visited during this study are located in the state of Rio Grande Do Sul at approximately -32 degrees south latitude and -52 degrees west longitude, southwest of the major port city of Porto Alegre.

Jan 1, 1981

By H. D. Freeman

The Pacific Northwest Laboratory (PNL) is developing cover technology for uranium mill tailings that will inhibit the diffusion of radon to the atmosphere. As part of this cover program, an improved radon flux measurement system has been developed. The radon measurement system is a recirculating, pressure-balanced, flow-through system that uses activated carbon at ambient temperatures to collect the radon. With the system, an area of 0.93 m2 is sampled for periods ranging from 1 to 12 h. The activated carbon is removed from the radon trap and the collected radon is determined by counting the 214Bi daughter product. Development of the system included studies to determine the efficiency of activated carbon, relative calibration measurements and field measurements made during 1980 at the inactive tailings pile in Grand Junction, Colorado. Results of these studies are presented.

Jan 1, 1981

Canada is a major producer of chrysotile asbestos. In fact, Canada accounts for approximately one third of the world chrysotile asbestos production. Deposits are mined and the fiber processed in Québec, in British Columbia on the West Coast and in Newfoundland in the Atlantic region. Foremost among the Canadian provinces is obviously Québec. Some 85% of Canadian deliveries come from mines located in the Eastern Townships, a region which lies along the southshore of the St. Lawrence River, between Montreal and Québec City. At the heart of this vast territory, five (5) mining towns make up what is called the Québec asbestos region. Total capacity of the five (5) mining producers of Québec is about 1 366 000 tonnes.

Jan 1, 1981

By Harald F. Solberg

A preliminary study of the performance of a 4-inch Krebs cyclone at near rope conditions and different feed slurry temperatures was completed. Results suggest that temperature influences the x50c size which, in turn, did not depend upon spigot diameter. The bypass correction to a reduced efficiency equation incorporating the concept of a critical size xo was a function of fractional water recovery to underflow and may depend on feed size and feed percent solids. Further experimentation is required to develop an accurate model at near rope conditions.

Jan 1, 1981

By I. Jashnani, J. R. Lawter, D. B. Lindsay

INTRODUCTION It is a generally recognized obligation of owners and operators of underground mines in the United States to protect the health of miners against the potential carcinogenic effect of airborne alphaemitting radionuclides, in particular the shortlived radioactive daughter-products of 222Rn. In meeting this obligation, a number of strategies are available, and it is largely up to the operator to decide what combination of methods he will use. Because the officially accepted theory of the mechanism by which radon and its short-lived progeny cause cancer of the respiratory system, the objective in controlling this health hazard is to limit as far as possible the inhalation of the three daughter products, 218Po, 214Pb, and 214Bi. (214Po, the fourth nuclide in the chain, is so short-lived that its alpha-decay occurs almost instantaneously after the beta-decay of its parent, 214Bi.) The reasoning in this theory leads to the conclusion that the alphadecay of radon itself causes essentially negligible physiological damage, and that the amount of daughter product activity attributable to decay of radon within the respiratory system is also very small. As every ventilation engineer in this business knows, however, focusing remedial actions exclusively on the daughter products themselves is choosing the hard way, and will probably never lead to effective control of this health hazard in underground mining activities. The reason for this troublesome fact can be seen in Figure 1. Let us say that we have air containing 222Rn and its short-lived daughters in near-equilibrium, a not-uncommon condition in the air of a poorly ventilated underground mine, and that we wish to purify it by removing only the toxic daughter products. If we have been very thorough in our purification efforts, we might expect to achieve a 99% reduction of the Working Level (WL) measurement. Figure 2 allows us to examine closely the early regrowth of WL's in this freshly cleaned air. Within the first five minutes, for instance, the WL's are back to 10% of their full equilibrium value, and ten minutes later the level has more than doubled and is on its way to an almost complete defeat of the clean-up effort by the end of the next hour. It is quite clear from this simple illustration that no matter how effective an air-cleaning system may be if it is directed only at the selective removal of the toxic trio, 218Po, 214Pb and 214Bi, its beneficial effect will be quite temporary. A truly effective attack on the problem must always include methods aimed at the control of the unruly parent, radon. Then, even if its progeny have an inalienable "right to life", their brief lives will not be spent in the miners' lungs. The object of the present paper is to show how state-of-the-art environmental air

Jan 1, 1981

By J. E. Oberholtzer, M. G. Fernald

INTRODUCTION Approximately six years ago the U.S. Bureau of Mines (USBM) developed a data acquisition system (DAS) specifically designed for measuring radon levels and other environmental parameters during studies of means to control radiation hazards in underground uranium mines. The DAS system records data in machine readable form using a paper tape punch, which represented the state-of-the-art at that time for a moderate cost output device. However, the use of paper tape as a recording medium for field studies is somewhat unwieldy. Reducing the raw data required either that the tape be shipped to a computer center equipped with a high-speed paper tape reader or that the tape be transmitted at low speed over the telephone lines to a remote computer. Transmitting, at ten characters per second, the data from a 10-channel DAS taking Four readings per hour would require about 30 minutes For each 24-hour day's data. Telephone lines from remote mine sites are often of marginal quality and data errors can be introduced during transmission. Paper tape punches are also prone to occasional punching errors. Both problems make it necessary to carefully check for and correct data errors, a process which is possible because each DAS produces an independent printed data record, but the error checking and correction process can be quite laborious. Aware of recent advances in microcomputer technology which have brought the price of a personal computer down to about the cost of a paper tape punch 5-10 years ago, the Bureau decided to explore the feasibility of using a low-cost personal computer in the field to process DAS data in real time. On behalf of the Bureau, Arthur D. Little, Inc., developed a simple interface circuit which permits an Apple II computer to accept data from one or two DAS units as it is being transmitted to the paper tape punches. Computer software converts each measurement to appropriate engineering units, e.g., radon concentration, Working Levels, air velocity, temperature, or barometric pressure. The computer also calculates 1-hour and 8-hour running averages of all converted data and prints those results as soon as they are obtained on a line printer located at the test site for immediate inspection. After development, the system was used continuously and successfully for a 5-month period at a Utah uranium mine. DAS DESIGN AND MODIFICATION Each of the two USBM data acquisition systems used in this work consists of two separate modules. A multiplexer module located below ground near the measurement transducers acquires signals from each of nine tranducers. Six input channels were devoted to measurements of radon or Working Level. The outputs of those transducers, photomultiplier tubes or G-M tubes, respectively, are digital pulse trains which are accepted directly by the mutliplexer. Three channels were used for environmental parameters--air velocity, temperature, and/or barometric pressure. Each of the environmental tranducers is fitted with dedicated linearizing and voltage-to-frequency conversion circuitry so that the outputs to the multiplexer are also pulse trains having frequencies of one tenth of the value of the measured parameter expressed in the appropriate engineering units. A 100-Hz reference signal was input into the tenth channel for use in monitoring system integrity and performance. All ten pulse trains are then timeseries multiplexed into a signal line for transmission to the above-ground data acquisition module. Above ground, the composite signal is de-multiplexed into ten separate lines, each of which is connected to a digital counter which converts the pulse train to a numerical value. The acquisition of each set of readings is initiated by an adjustable "scan cycle comparator" timer. The acquisition process proceeds in three phases. First, radon and Working Level channels are counted for an extended period of time, typically 5-10 minutes depending on activity, because of the low pulse rates involved. Then the other four channels are counted for ten seconds, and finally, all ten readings, along with the Julian day and time of day are output serially onto paper tape and printed on a strip printer. When the scan cycle comparator reaches its preset time (15-minute cycle times were used in this work), it resets itself, initiates another readout cycle, and begins timing again. The only modification made to the data acquisition systems used in this work was to disconnect the scan cycle comparator in one unit, which became the "slave" and bring in the scan cycle comparator signal from the other unit, the "master", to initiate data acquisition cycles in the slave. Synchronizing the two data acquisitions in this fashion and using two slightly different radon counting times insured that the two systems never attempted to output data to the Apple II at the same time. THE APPLE II COMPUTER The Apple II computer used in this work was equipped with 48 KBytes of semiconductor random access memory (RAM), two floppy diskette drives, a Centronics Model 730 impact matrix printer and a modulator for driving an ordinary color television as a video display device. A single California Computer Systems Model 7720A dual 8-bit bidirectional parallel input/output (I/O) card was installed in the Apple to accept the digital data from both data acquisition systems. This card is

Jan 1, 1981

By Everson P. T, Moyle F. J

Magnesite-rich and dolomite-rich ores from the Savage River region of Tasmania are being considered as potential feed material for a commercial process for production of magnesia.Two selected samples have been characterized by chemical analysis, X-ray diffraction, and differential thermal and thermogravimetric analysis. The materials differ in calcination behaviour, with magnesite decomposing at a significantly lower temperature than dolomite. Calcination conditions have a marked effect on the rate and percentage of magnesium dissolved as the bicarbonate when slurries of the calcine are leached with carbon dioxide. From a process point of view, the feed should have the highest possible magnesite/dolomite ratio, while the optimum calcination conditions are determined by the behaviour of the magnesite component of the feed.From batch calcination tests, it is apparent that the optimum calcination conditions for magnesite-rich ore are a temperature in the vicinity of 700°C and a calcination time of one hour.

Jan 1, 1981

By W. G. Prast

The role of governments as a factor in the international non-metallic minerals industry can take several forms. Classically, the government acts as a taxing agent, collecting part of the economic rent on behalf of the country from private-sector mine operators. In addition to its taxation policies, the state can and does provide the practical commercial framework of regulatory and fiscal incentives and restraints that shape the activities of the mining firms. In addition to its functions as an agent of the public interest, the government can choose to take a more direct stake in the mining industry, and has done so in the instance of several industrial minerals that are actively traded on world markets. In this paper, the actions of three governments are reviewed and the consequences of their actions are examined.

Jan 1, 1981

By Lloyd W. Trevoy

Commercial production of heavy minerals from plant tailings streams is undergoing study by Syncrude Canada Lrd. When tar sand from an open pit mine is processed and up- graded to synthetic crude oil, heavy minerals can be recovered from the extraction circuit and can be upgraded to provide concentrates of zircon and titanium minerals. The titanium minerals concentrate consisting of a mixture of ilmenite, leucoxene and rutile, could be utilized as recovered or could be upgraded to synthetic rutile. With the construction of further synthetic crude oil plants in Western Canada a large reserve of heavy minerals will become available for utilization.

Jan 1, 1981

By Nicholas P. Kripakov

The U.S. Bureau of Mines examined the applicability of existing material models to solve practical geotechnical mining-related problems by solving a yielding pillar stability problem considering confining effects on strength. Numerical difficulties normally encountered with modeling strain softening behavior were eased with a simplified computational procedure using a quasi-elastic approach to account for residual strength after initial failure. Although in agreement with a confined-core pillar design method using actual mine conditions that include mine layout geometry, overburden geology, and rock properties of the deposit and surrounding structure, the results cannot be verified because measured field data are not available at this writing.

Jan 1, 1981

By Hoskings R

Conceptual studies of the run of mine stockpiling and reclaiming requirements at Thiess Bros Pty Ltd South Blackwater coal mine commenced in 1975.Final selection of equipment was made in 1978 and the equipment was commissioncd in June 1979. Equipment selection was made after extensive investigation and visits to existing facilities throughout the world.The equipment selected is described and compared with the alternatives. Foundations were designed to minimise clean up effort and to ensure stabilily of equipment under design wind loading without storm bays. Programmable logic control enables the stacking and reclaiming facility to provide a blended feed to the coal preparation plant.

Jan 1, 1981

By William H. Wiese

Anecdotal reports of high rates of congenital malformations and spontaneous abortions at the Shiprock Indian Health Service Hospital in San Juan County, New Mexico prompted an interview survey, obtaining data from families of 26 former uranium miners and 30 controls. Results supported the possibility of increased fetal wastage and congenital malformations. However, definitive conclusions were obviated by methodologic limitations in terms of selection of cases and controls and interviewing technique, as well as very low numbers and lack of statistical significance. The Council of Environmental Quality (1980) published a report which singled out San Juan County, nationally, as having an extra-ordinary high rate of congenital anomalies reported from birth certificates in the years 1973-75. San Juan County is in the northwest corner of New Mexico and includes the northeastern edge of the Navajo Indian Reservation. It has been the site of uranium mining and milling and also of coal mining (Clement Associates, 1980). While much attention has been focused on lung cancer and chronic lung disease as health hazards to uranium miners, virtually no attention has been focused upon possible reproductive effects that may result from exposure to radiation. Could these reports indicate such an additional arena of health effect either on miners or on others living in the vicinity of the mines and mills? The biologic and epidemiologic literature does not lend much support for adverse genetic outcome. The UNSCEAR report (UNSCEAR, 1977) summarizes much of the existing data. For example, on the basis of many animal studies and what has been observed in atom bomb survivers in Japan, it has been estimated that mutation rates resulting from low LET radiation to paternal germ cells would be 60 X 10-6 recessive and 20 X 10-6 dominant mutations per gamete per rad. There would be a five-fold increase in the number of recognizable abortions. The doubling dose for genetic disorders in mice is estimated at 100 rads. The assumption has been that low levels of exposure, such as might be received occupationally from uranium mines and mills or environmentally will produce reproductive effects that would defy distinction from background rates. However, the possibility can not be dismissed. In man, spermatogonia are thought to be three-fold more sensitive than in the mouse. Also, the high LET radiation from alpha particles is as much as 20-fold more effective in inducing changes in meiotic and post meiotic stages of cells, compared with low LET radiation. There is some degree of localization of alpha emitters in testicular tissue after inhalation of radon and radon daughters (Blanchard, R.L. and Moore, J.B., 1971; Pohl, E., 1964). The slopes of doseeffect curves are affected by type radiation and rate of administration. Data on such curves are poorly defined and debated as to whether there may be increased or decreased effect per unit dose at low levels of high LET radiation. Increased rates of aberrations of chromosomes in peripheral lymphocytes cultured from uranium miners have been reported (Brandom, W.F., et al., 1978). At cumulative exposures of 100 working level months (WLM) or less, a range of exposure lower than the limit of current occupational standards, the aberrations were increased more than two-fold. Our interest has led us to pursue the question of reproductive effects along three separate paths of inquiry: studies of the secondary sex ratio, cytogenetic study of human sperm, and studies of rates of congenital anomalies. I will present the thrust of our findings, most of which remain preliminary, comment on their interpretation and limitations, and indicate directions needed for future research. The secondary sex ratio is the ratio of males to females at birth. In the U.S., the ratio averages around 1.05. Ratios in blacks are somewhat lower (1.025) than in whites (1.053). For American Indians, the data are less definite. Values from Oklahoma and California are similar to whites (1.05). Southwestern tribes have, as we shall see, varying levels. The theoretical effects on sex ratio resulting from irradiation of the zygote are based on the principles of sex-linked genetics, including differential effects of lethal dominant and recessive mutations on the sex chromosomes, complicated by possible non-disjunctional events. Observations have done little to clarify, confirm or refute the theories. The sex ratio of progeny of survivers of the atomic bomb showed little change (Schull, W.J., Otake, M., and Neel, J.V., 1981). Observations in children of uranium miners having been inconsistent. Most frequently cited is a study of miners in Czechoslovakia (Müller, C., Razicka, L., and Bakstein, J., 1967). Compared with children born to miners prior to the start of mining, the sex ratios of children born after the start of mining were decreased -statistically significant after correcting for birth order. The ratios in first-born children were, before the start of mining, 1.118, and, after the start of mining, .713. In the interview survey at Shiprock, the sex ratio in families of non-miners was 1.03, and in families of miners it was 0.73 (p < .05). Dr. Alan Goodman at the University of New Mexico has studied trends in the sex ratio in the general population in New Mexico and Arizona with particular reference to counties in the Four Corners area and the Navajo Indian Reservation, areas where uranium mining has been active_ His findings (unpublished) are as follows: (1) Beginning in the early 1950&apos;s, there has been a modest, but persistant and statistically significant decline in the secondary sex ratio for the state of New Mexico compared with the U.S., a decline that roughly parallels the emergence of uranium mining in the Grants mineral belt in northwestern New Mexico. (2) Data available for the 11 years since 1969 show that among the five counties with ratios significantly lower than the state

Jan 1, 1981

By James E. McNulty

The planning and development of new coal mines is requiring the increased use of geologic, geologic engineering and hydrogeologic investigations. This is caused in part by the fact that new mines must deal with less favorable conditions than existing mines as well as higher costs of development and in part by the dictates of regulatory authority. High costs of new mines require greater reliability of geologic assessment using best available geotechnical and geophysical methods and technology. Although the increased cost of additional subsurface data is significant, the more important factor may be the impact on project lead time.

Jan 1, 1981

By J. J. deBarbadillo

This Bureau of Mines report describes a process for recovering chromium and other metals from superalloy scrap. Laboratory-scale experiments were conducted to test a complex flowsheet utilizing a wide range of extractive metallurgical operations. The novel basis for the process is the fonnation of a sulfide matte in which chromium is concentrated in a discrete chromium sulfide phase. Mineral processing and hydrometallurgical procedures are used to separate chromium sulfide from the other matte constituents. The products of the process are a chromium-nickel alloy suitable for reuse in the superalloy industry, electrolytic nickel, electrolytic cobalt, and iron-molybdenum residue. Recovery of the principal elements contained in the scrap is chromium--93 percent, nickel--99 percent, cobalt--96 percent, and molybdenum--92 percent.

Jan 1, 1981

By Noel Jarrett

Energy consumption and distribution in aluminum production, conservation accomplishments, and future goals are presented. Electrolysis and electrode manufacture show the greatest promise for major improvements. Means are proposed for reducing waste heat generation in smelting and for conserving energy in anode manufacture by furnace design and substitution of other materials for petroleum coke. Hall-Heroult Process modifications, alternative designs, and the Alcoa Smelting Process are discussed as energy savers. Scrap recycling, more use of aluminum in transportation, and the installation of offshore smelters in less developed countries are shown to be additional means of coping with possible energy dislocations.

Jan 1, 1981

By David M. Shaw, John C. Franklin

A 32-channel warning system for high working level, fan operation, and airlock-doors has been constructed. The working level monitors have a microcomputer for accumulating the pulses, converting to working level, and triggering an alarm at a variable set point and at one working level. The system also detects when underground fans lose power or air doors are open. The system can detect changes in air velocity which indicate surface fan failures or changes in the ventilation system. Using this alarm system, the ventilation engineer will be alerted prior to excessive levels of radon daughters being reached so corrective action can be taken.

Jan 1, 1981