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By H. L. Paterson, R. R. Keays, M. J. Donaldson, D. J. Boyack, M. F. Smith, J. J. Gresham

"Albite-rich sedimentary rocks that contain abundant Fe sulphides occur in the lower portion of the ultramafic sequence at Kambalda and their broadly antipathetic relationship to most of the nickel orebodies is well documented. These sediments generally contain less than 0.1% Ni, but nickeliferous equivalents with 0.3 to >6% Ni occur locally in close spatial association with more typical volcanic peridotite-associated massive, matrix and disseminated ores. Nickeliferous sediments have been mined at several locations at Kambalda but, collectively, they constitute less than 2% of the total Kambalda nickel reserve. The nickeliferous sediments occur both on the ultramafic-footwall basalt contact and within the lower part of the ultramafic sequence, and are usually less than 5 m thick. They are commonly finely laminated rocks with a cherty appearance, composed essentially of layers of albite+quartz±amphibole, alternating with pyrrhotite+pentlandite±pyrite layers. Some contain a minor amount of carbon. The sediments are only of ore grade (> 1% Ni) immediately adjacent to massive Fe-Ni-Cu sulphides, which are interpreted as normal magmatic ores on the basis of geochemistry and the presence of distinctive ferrochromites. The nickel content of the sediments decreases to background levels (<0.1%) within about 20 m of the massive sulphides. In most locations the massive sulphides clearly have been emplaced tectonically within or adjacent to the sediments, which are commonly highly deformed. Typical nickeliferous sediments contain about 1% Ni, 0.1% Cu, 0.1% Zn, 400 ppb Pd, <0.2 ppb Ir and 10-200 ppb Au. They have lower Ni/Cu (average 10), higher S/Ni (average 6) and higher S/Se (average 11 200) than associated massive sulphides (average 40, 4.8 and 7400, respectively). The Pd/Ir ratio of the nickeliferous sediments (typically > 1000) contrasts markedly with that of associated massive sulphides (average ca 16).The high Pd/Ir values are similar to those which have been reported for hydrothermal Fe-Ni sulphides and barren sulphidic sediments of probable volcanic exhalative origin. They preclude a direct magmatic origin for the sulphides in the nickeliferous sediments, though S/Se and S isotope data indicate a magmatic source for the sulphur. The restriction of nickeliferous sediments to within about 20 m of normal magmatic sulphides and the lack of a widespread Ni dispersion halo suggest local redistribution of originally magmatic Ni. This probably occurred by diffusion and hydrothermal mobilization during deformation and amphibolite-facies metamorphism. Although not totally ruled out, a volcanic exhalative origin for the Ni seems unlikely."

Jan 1, 1984

By Peter W. Harben, Edward M. Dickson

The distribution of metallurgical grade bauxite deposits will be discussed with the aid of a comprehensive table and a reference map. Information will include operating companies, mine locations, ore grade, and chemical analysis, geological environment, and production capacities. General comments will be made on the distribution of production and its relationship with major consuming regions. The pattern for the future will be assessed, including potential new producers, changing specifications and industry structure.

Jan 1, 1984

By Stephen H. E. Phillips

Geological and hydrological conditions in the strata overlying the Salado Formation vary considerably in the Carlsbad, New Mexico area. The first four shafts sunk at international Minerals and Chemical Corporation&apos;s property have been located in competent and essentially dry conditions, while other shafts on adjacent properties have had such adverse conditions that ground freezing has been chosen as the water and ground control technique for shaft sinking. At the location of the IMC No. 5 Shaft there has been extensive-erosion and salt dissolution in the Rustler Formation which has led to collapse of some zones of the strata. Both ground freezing and pregrouting were considered as alternative methods of stabilizing the extremely poor ground conditions and controlling the potentially very heavy water inflows it was decided that pregrouting the shaft was feasible and would offer substantial cost and time saving over a ground freezing technique. This paper describes the pregrouting techniques used and illustrates the requirement for flexibility in a grouting program so that it can be codified to reflect any new or additional information which is obtained during the progress of the grouting.

Jan 1, 1984

By Peter B. Lilly

I appreciate the opportunity to tell you something about Kerr-McGee&apos;s Galatia Mine in Southern Illinois. This new underground mine was a departure for us since our previous experience had been gained in large surface mines in Wyoming. Although we were new, we did have the corporate experience in the operation of deep uranium and potash mines in New Mexico and Wyoming, and an earlier underground coal mine in Southeast Oklahoma. In arriving at our final design, we evaluated numerous concepts and finally settled on a two seam mine sharing a single shaft and slope. The mine, in turn, would be supported by a heavy media processing plant designed to optimize the yield from either seam. Further, we wished to be able to keep the two seams separate so that we could sell either seam separately or in a blend. Due to the thickness of the coal, the practical area dedicated to the mine provided forty to fifty years operations at the selected mine capacities. It was important, therefore, that our design and selection of hardware and systems provide for long life and low maintenance in order to compete in today&apos;s competitive markets.

Jan 1, 1984

By Douglas Talley

This report describes a 4-inch diameter borehole probe which contains a low light level TV camera, magnetic compass, light illumination source, bottom/water detector sensor and a pointing angle sensor. The camera viewing angle is at a right angle to the probe&apos;s body. All data from the sensor is multiplexed into the closed circuit camera video for transmission on a single 50 ohm coaxial cable to a surface control unit. Likewise control of the probe&apos;s power, zoom lens, focus, panning and aperture is accomplished via a down-link multiplexed on the same cable.

Jan 1, 1984

By Montagnon P, Dagois G

The use of activated carbon for gold recovery has been known for years, but came industrially on stream since the years seventies.Despite several years of experience, the criteria for selecting a carbon have not been clearly determined so far.This paper will try to highlight the user through his experience, on the most important factors which should affect his decision.We will develop:- Physical characteristics - Adsorption characteristicsand try to show that slight variations on these characteristics may have important consequences on the plant design and profitability.

Jan 1, 1984

By M. J. Shulman

An algorithm used by the US Coast Guard to find lost objects is utilized to optimally allocate exploration efforts during initial stages of an exploration program. Based on classical search theory, the algorithm assumes a target probability distribution function, a detection function, and a cost function. The three functions are analogous to delineating areas of possible mineralization, choice of exploration methods, and exploration budget. Application of the algorithm is shown for a hypothetical target distribution. Using the maximum number of field day available as the cost function, the optimal allocation of effort is shown for different exploration methods, e.g. electromagnetic survey and induced polarization. The adaption of the algorithm for the exploration process is discussed.

Jan 1, 1984

By A. J. Williams

"Conventional base metal milling practice normally consists of crushing, grinding and cyclone classification followed by flotation. It is the authors' belief that the commencement of flotation after cyclone classification leads to inferior metallurgical results and that implementation of flotation of grinding mill discharges can result in increased recovery due to reduced overgrinding, reduced activation of contaminating minerals and improved dewatering circuit results due to the production of coarser concentrates.The concept of recovering minerals from the discharge of grinding mills is not new! Gold concentrators have utilized jigs and flotation cells while iron ore plants have employed magnetic separators to recover gold and magnetite respectively from the discharge of grinding mills. More recently, a Reichert cone has been used to recover sulphide and oxide base metal minerals from screened rod mill discharge. 1To the authors' knowledge, the first application of flotation of base metal minerals from the discharge of a production plant grinding mill was at the Lake Dufault concentrator of Corpor'1tion Falcon bridge Copper. Located 10 miles north of Noranda, Quebec the Lake Dufault concentrator commenced operations in August, 1964.The installation of flot11tion cells in the Lake Dufault grinding circuit proved so successful that an identical system was installed in the Manibridge concentrator of Falconbridge Nickel Mines Limited. Located 90 miles southwest of Thompson, Manitoba the Mamibridge concentrator commenced operations in June, 1971 and due to exhaustion of economic ore reserves discontinued production in May 1977."

Jan 1, 1984

By Jerry A. Selvaggi, Richard B. Jacob

The High Gradient Magnetic Separator (HGMS), also known as the High Gradient Magnetic Filter (HGMF), is an effective device utilized in magnetic separation. This method of separation is gaining popularity in the separation of submicron material containing feebly magnetics. The most common use of this type of separator is in the removal of iron stained particles to improve the brightness of kaolin clay. Potential areas for use of this magnet include: (1) desulfurization of coal (2) the clean-up of mill effluent (3) removal of fine particulate matter from municipal and indus¬trial waste (4) desulfurization of oil Design, operation, and applications of this separator are further dis¬cussed in papers by R. R. Oder (1975), and R. R. Oder and B. I. Horst (1975). This device is a system composed of an iron enclosure of high per¬mability material housing a set of electrical coils, a canister en¬closing a magnetic matrix (stainless steel wool), an electric power supply and a hydraulic system to maintain specified operating tempera¬ture conditions. See Figure 1.

Jan 1, 1984

By H. J. de Klerk

The metallurgical phenomena in the design and manufacture of high-strength low-alloy (HSLA) steels are reviewed, and some aspects of the production of Supraform TM (thermo-mechanically processed) steel are discussed. . The weldability of Supraform TM is related to changes in the microstructure of its heat-affected zone.

Jan 1, 1984

By R. Y. Wan

Acid ferric sulfate solution has been used for heap and dump leaching of low-grade chalcopyrite ores and is being considered as a possible lixiviant for the hydrometallurgical processing of copper sulfide concentrates. For many years, researchers have attempted to explain the leaching behavior of chalcopyrite, since the reaction rate kinetics are extremely slow and seem to be significantly influenced by the nature of the reaction product. A summary of conclusions drawn from reported literature on chalcopyrite leaching is found in the paper by Munoz, Miller, and Wadsworth(1) and more recently by Dutrizac.(2) Lowe(3) and Jones and Peters (4) attributed rate control to a surface reaction. Linge,(5) Dutrizac,(6) Bauer,(7) and researchers at the University of Utah(1,8) reported that the reaction rate is limited by transport in the chalcopyrite lattice or through the elemental sulfur reaction product layer. Munoz et al.(1) presented a model, derived from the Wagner theory of oxidation, which is based on the formation of a protective sulfur layer with rate control by electron transport through the insulating sulfur layer. By utilizing Wagner&apos;s parabolic oxidation relationships, (9) the following equation was obtained: [ ] where a is the fraction of CuFeS2 reacted at time t, pB is the molar density of CuFeS2, do is the initial diameter of the particle, e is the electronic charge, s is the total electrical conductivity of the sulfur layer, and ?G is the Gibbs free energy for the reaction:

Jan 1, 1984

By Espig D, Standish N

In the paper a stochastic model of the batch sieving procedure is presen- ted resulting in a system of ordinary differential equations to describe the time dependence of the mass fractions on the sieve surfaces being randomly influenced by sampling errors. The coefficients of the system can be interpreted as sieving velocities. Their dependence on the sieving con- ditions is discussed and a special type of functional relationship and methods are suggested to determine this function experimentally. Moreover the applicability of the approach is demonstrated by an example to evaluate the particle size distribution, if only the result of incomplete test sieving is known. For this problem a rough error estimation is performed.

Jan 1, 1984

The results of small-scale resin-in-pulp pilot-plant investigations at Grootvlei Proprietary Mines Ltd, President Brand Gold Mining Co. Ltd, and Western Areas Gold Mine Co. Ltd are reported. At each mine, a pulp was fed simultaneously to a carbon-in-pulp plant, allowing a direct comparison of the metallurgical performance of the two processes. With the Grootvlei pulp, gold was extracted more efficiently by resin than by carbon owing to the Iow concentration of competing base-metal cyanide complexes in solution. With the Western Areas pulp, the reverse was true because of the high concentrations of copper and nickel in solution. Finally, with the President Brand pulp, resin-inpulp was significantly superior to carbon-in-pulp owing mainly to the inherently slow rate of gold extraction from calcine by activated carbon. Results are presented that show the efficiency of the elution of gold and other elements with a variety of reagents from the loaded resins arising from these three campaigns. At Western Areas, a detailed investigation enabled a preliminary cost evaluation to be made of three techniques for the elution of strong-base resins.

Jan 1, 1984

By John B. Goddard

Crystallization of ammonium paratungstate (APT) is frequently the last effective purification step in producing high-purity tungsten. However, crystallizer mother liquors are often several times higher in tungsten than predicted by the solubility of APT. The formation of heteropoly anions, particularly those containing phosphorus and silicon, is largely responsible. Solubility of tungsten in APT mother liquor can be linearly correlated with the concentration of these and other impurities. The problem can be overcome by direct treatment of the crystallizer feed solution with alum. By appropriate treatment, the aluminum hydroxide flocculates and is easily filtered, resulting in a purified low-aluminum crystallizer feed from which high APT yields can be attained.

Jan 1, 1984

By J. E. Rouse, D. L. Buchanan

"During the emplacement of the Bushveld Complex in the Potgietersrus area magma reacted with the original floor rocks— Archaean granite or Malmani dolomite and overlying Penge handed ironstone or sedimentary rocks of the Pretoria Series. The complex sequence of sulphide-rich mafic rocks that formed along the contact is known as the Platreef. Associated with the sul­ phide mineralization are important concentrations of platinum-group metals, copper and nickel. Xenoliths of Malmani dolo­ mite have been incorporated into the Platreef and previous work has suggested that anhydrite is likely to have been present in the dolomite. The sedimentarv-derived sulphur thus introduced into the magma exercised an important control on the forma­ tion of the sulphides.Petrographic studies on the Platreef rocks from the Tweefontein area indicate that the original magma reacted with the banded ironstone to form iron-rich pyroxenites. In the Turfspruit area, to the south, the footwall rocks consist of sediments of the Timeball Hill Series. Original argillaceous rocks have been metamorphosed to cordierite-, corundum- and spinel-bearing hornfelses. Graphite was present in the contact zone in both the Tweefontein and Turfspruit areas. Anhydrite-bearing hornfels rocks are also present on Turfspruit.The Platreef rocks that overlie the corundum- and spinel-bearing hornfelses on Turfspruit are peridotitie, and pyroxenites are present in areas underlain by cordierite-bearing hornfels. The absence of orthopyroxene in the peridotite is probably indicative of low silica activity in the original magma. The pyroxenites have, however, undergone silica contamination from the underlying more siliceous cordierite hornfels.Carbon isotope studies indicate that the graphite in the Tweefontein and Turfspruit samples represents organic material orig­ inally associated with the footwall sediments. Sulphur isotope determinations on the anhydrite-bearing floor rocks indicate that this phase is clearly of sedimentary origin and was probably derived from an evaporitic unit within the carbonate sequence. This provides firm support for a model of ore genesis that involved the introduction of additional sulphur into the Bushveld magma. Isotope studies on sulphides associated with the banded ironstone and graphite indicate that these units were not the source of additional sulphur. Experimental studies predict, however, that a magma contaminated with iron- and carbon-rich material would have a high sulphur-carrying capacity. Where additional sulphur is available the magma would achieve saturation early in its crystallization history and precipitate an immiscible sulphide phase. Experimental work has also shown that sulphide precipi­ tation can be triggered by the introduction of salic material into a magma close to sulphur saturation. This mechanism probably played a role in the control of the sulphide mineralization in the Turfspruit area."

Jan 1, 1984

By M. Adnan Göksel

Pyrite cinder is generated by roasting pyrite for sulfur dioxide production. It contains up to 62% iron, but also may contain other hazardous or toxic materials such as Zn, Pb, As, T1, Cd, Cu, Sn and S. Furthermore, the physical characteristics are not properly suited for conventional sintering. As a result pyrite cinder is considered to be unsuitable for iron and steelmaking or for outside storage because of its potential for causing environmental problems. In recent years industrialized nations have put increasing pressure on the manufacturers to either use such waste products or properly dispose of them. In this study, solutions to both the iron recovery and disposal problem were attempted by pelletizing the pyrite fines with internal carbon. The pellets, after hydrothermal hardening, were reduced and melted in a furnace for hot metal production. Hot metal of usuable quality was produced and the hazardous materials were either collected with the fumes or in the slag.

Jan 1, 1984

[Mr. Jay Abbott Union Sply Co 7458 S Jackson St Littleton. CO 80122 Mr. Ronald H. AchZlger Midwest Rbr 6 Sply Co 6404 E 39th Ave Denver, CO 80207 Mr. Randy Acre Dorchester Coal C 9350 E Arapahoe Rd Englewood, CO 80112 Mr. Dell H. Adams Kenerco Corp 5480 Swanton Dr Lexington, KY 4051 Mr. Robert S. Affleck Anderson Mavor (USA) Ltd RD #1 Box 140-Lake R Bradford Woods, PA 15015]

Jan 1, 1984

Diamonds have been known in Australia for many years, especially in association with alluvial gold and tin occurrences. Exploration for primary sources in the Kimberely area of Western Australia has been carried out since 1968, culminating in the discovery, in 1979, of the Argyle Kimberlite No 1 (AK1) kimberlite pipe. Various techniques have been used in the search for diamonds such as geologic interpretation, aerial photography and Landsat, soil geochenical techniques, geophysics, and stream sediment sampling. Stream sediment sampling, a method developed in South Africa, using the detection of indicator minerals derived from kimberlites in gravel samples, has had wide application and success in Australia. Nevertheless, although Australian diamond bearing kimberlite and lamproite rocks contain some of the classic indicator minerals, their concentrations are generally much lower than in South Africa and Russia. Despite this paucity of indicators, stream sediment sampling is still the best known and most commonly used method of diamond prospecting in Australia. Small samples are treated by hand but larger samples require the use of diamond pans, jigs or heavy media separation plants. Each of these methods has advantages and disadvantages. The final concentrate is passed over a grease table or subjected to x-ray sorting.

Jan 1, 1984

By Omar A. Muhtadi

Experimental statistical designs were used at Zortman Mining Company&apos;s, Zortman, Montana, heap-leach operation to establish functional relationships between key operating parameters and gold/silver recoveries. Zinc feed rate, lead feed rate, and vacuum (CFM/gpm) account for 64% and 67% of the attainable gold and silver recoveries, respectively. Surface response graphs of the resulting polynomials were plotted. These graphs were used to optimize Zortman&apos;s Merrill-Crowe precipitation process.

Jan 1, 1984

Pbo activities have been measured in conventional blast furnace and direct smelting type slags at 1200¦C. Much higher activity coefficients than previously measured have been obtained and attributed to interactions between iron and lead oxides. The behaviour of PbO in the two types of slag reflects their relative silica contents. Simple equations derived from mathematical modelling work are presented for the prediction of Pbo activities in complex industrial slags.

Jan 1, 1984