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Jan 1, 1907

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Jan 1, 1907

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Jan 1, 1907

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Jan 1, 1907

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Jan 1, 1907

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Jan 1, 1907

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Jan 1, 1907

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Jan 1, 1907

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Jan 1, 1907

By W. M. Morris

THE volumetric behavior of isobutane at temperatures below its critical temperature has been studied by several investigators. Seibert and Burrell1 measured the vapor pressure of isobutane from the ice point to the critical temperature. Dana and co-workers2 determined among other thermodynamic quantities the density of the saturated liquid and the saturated gas and the vapor pressure from approximately 0° to 130° F. Sage and Lacey3 studied a number of the thermodynamic properties of this hydrocarbon from 70° to 250° F. The specific volume in the gas and liquid region was determined at pressures up to 3000 lb. per sq. in. ? throughout this temperature interval. In addition, the vapor pressures were measured at 30° intervals. These data taken together serve to establish the thermodynamic behavior of isobutane at temperatures between 0° and 250° F. with reasonable accuracy. However, apparently there are no data available at the higher temperatures. For this reason an investigation of the volumetric behavior of isobutane at temperatures between 100° and 460° F. was carried out with apparatus that has been described in another paper (A.I.M.E. Tech. Pub. 1127).

Jan 1, 1939

By B. H. Sage

ATTEMPTS have been made to predict the volumetric and phase behavior of naturally occurring hydrocarbon mix-tures1-5 but these methods have not been extended to the higher pressures and tem-peratures that are currently encountered in some producing formations. Furthermore, the methods of prediction at present avail-able have not been tested in a sufficient number of cases to ensure their applica-bility to all naturally occurring hydrocar-bon mixtures, even at the lower pressures and temperatures. For these reasons the behavior of a number of hydrocarbon mix-tures from a field in which the subsurface pressures are above 4500 lb. per sq. in.? and the temperatures are in the neighbor-hood of 250°F. was investigated.

Jan 1, 1940

THE reduction of iron from the ferric to the ferrous state prior to its titration by permanganate or dichromate may give erroneous results in the presence of other reducible metals such as titanium. Stannous chloride and metallic zinc both reduce tetravalent titanium to a lower form, and so increase the consumption of the oxidizing standard: solution. Sulphuretted hydrogen and sulphurous acid do not reduce titanium, but are slow in action and troublesome to manipulate.Sulphuretted hydrogen is considered to be the best reducing agent for iron in the presence of titanium.* In the method to be described the advantages of the H 2S reduction are retained without the disadvantages of using the gas. The reduction is carried out by the action of a metallic sulphide having a solubility product of such a value that the sulphide iom, are utilized as fast as they are formed, and but little free sulphuretted hydrogen is given off.Cadmium sulphide was the first to be tried, but its solubility product (3.6 x 10 - 2~)t was apparently too low. The reduction was satisfactory, but the excess was very difficult to remove. Zinc sulphide (S.P. = 1.2 x 10 - 23) was found to be quite satisfactoryin both respects. The zinc sulphide is preferably used in the form of an emulsion prepared from pure zinc sulphate as follows: About 100 grm. of ZnS047H20 is dissolved in 2 litres of water. H2S is passed until no further precipitate is obtained, the acid formed being barely neutralized from time to time by the addition of ammonia. The precipitation of the sulphide in a slightly acid solution gives a finer emulsion than that prepared in an alkaline solution, and any iron present remains dissolved. The precipitate is allowed to settle and the clear liquid decanted. The precipitate is then shaken up with more water, acidified with a little sulphuric acid, allowed to...

Jan 1, 1922

By J. W. Leonard, D. A. Newman

By using physical and chemical means to increase the bulk density of newly broken coal freed from the mine face, the potential to improve coal mine productivity is significantly enhanced. It is estimated that by increasing bulk density, greater tonnages can be placed in fixed volume scoops and shuttles cars to improve production by as much as 10% to 20%. Such improved packaging to achieve new levels of volumetric efficiency might require only small and easy to implement changes to present downstream mining operations. Opportunities exist for improving broken coal bulk density from the moment of breakage, during transport across the continuous miner or loading machine, during discharge into the haulage unit, and after placement in the haulage unit. Physical/chemical methods for broken coal compaction in mobile, fixed volume units in underground operations are discussed.

Jan 1, 1990

By J. W. Leonard

Breakage, handling and treatment techniques that result in the placement of greater quantities of coal in fixed volume haulage units such as ships, railroad cars, trucks, mine cars, shuttle cars and scoops can do much to increase productivity by improving bulk density to reduce delivered cost, surprisingly enough, only in steel industry by-product coking has this subject been investigated and applied to practice, where as much as 20% or more productivity has been achieved. Research at UK Mining using popular coal mine loading cycle simulators shows that for typical Central Appalachian mining conditions a 10 to 20 percent gain in bulk density can produce a 15 to 30 percent increase in the loading cycle time of fixed volume shuttle-car/scoop based mining systems.

Jan 1, 1989

By Ramarao Inguva

Feasibility studies being conducted to investigate the use of electromagnetic methods for insitu volumetric heating of oil shales will be discussed. A two dimensional numerical model which describes eletromagnetic heating of oil shales is outlines. The model includes equations for temperature, pressure, saturations, chemical reactions, mass conservation, and source terms. The gases are all assumed to form one bulk species and the oil is assumed to remain in liquid form. The chemical reactions include pryolysis of kerogen and char, release of bound water, coking, and decomposition if carbonates. Porosity and permeability are dynamic functions of the organic materials. Calibration of the model is accomplished by comparison of the model results with experimental data obtained by IITRI. Nonlinear relationships for viscosity, thermal properties, and source terms and used as inputs to the model. A finite difference approximation to the differential equations is derived and solved using Newton's iteration technique. For the cases studied the solutions are quite stable. Numerical resultes are included and a preliminary study of the optimization of the heating process is presented.

Jan 1, 1984

By Stephen R. Iverson, Jeffrey C. Johnson, Donovan J. Benton, Michael J. Raffaldi, Lewis A. Martin

"The NIOSH ground control safety research program at Spokane, Washington, is exploring applications of photogrammetry to rock mass and support monitoring. This paper describes two ways photogrammetric techniques are being used. First, photogrammetric data of laboratory testing is being used to correlate energy input and support deformation. This information can be used to infer remaining support toughness after ground deformation events. This technique is also demonstrated in a field application. Second, field photogrammetric data is compared to crackmeter data from a deep underground mine. Accuracies were found to average 8 mm, but have produced results within 0.2 mm of true displacement, as measured by crackmeters. Application of these techniques consists of monitoring overall fault activity by monitoring multiple points around the crackmeter. A case study is provided in which a crackmeter is clearly shown to have provided insufficient information regarding overall fault ground deformation. Photogrammetry is proving to be a useful ground monitoring tool due to its unobtrusiveness and ease of use.INTRODUCTIONNIOSH Mine Safety ResearchPhotogrammetry systems have been implemented by the National Institute for Occupational Safety and Health (NIOSH) as part of its ground control research to improve mine safety. Conventional monitoring of ground movement has typically focused on movement of a few discrete points that are marked or anchored to instruments. Loss of a designated point or anchor, or the ability to identify a stable point in an unstable area, have often frustrated monitoring efforts. NIOSH researchers are using photogrammetry to conduct full-field measurements of rock surfaces underground. Periodic measurements of the entire surface of a ramp allow patterns of displacement to be observed. Full-field measurements provide much more insight into ground behavior than point measurements.BackgroundPrevious work by Benton, et al. (2014) discussed laboratory calibration and verification testing of two photogrammetry systems being used by NIOSH researchers. Both systems utilize stereoscopic image pairing techniques for photogrammetric reconstruction. This paper discusses how a laboratory system was used to conduct volumetric analyses of testing of shotcrete panels with varying types of reinforcement. The laboratory system was found to be accurate to within 2 mm. Additionally, a field photogrammetry system was found to produce linear measurements within 1 mm of known lengths in laboratory conditions. This system is currently being used at a deep underground mine to observe ground support conditions and deformations that have occurred. This paper discusses comparison of preliminary volumetric measurements of rib deformation to laboratory tests, as well as comparison of the field system against a crackmeter installed across a fault surface where it intersects the ramp."

Jan 1, 2015

By Stewart W. J

The volumetric method of estimating hydrocarbon resources and recoverable reserves is and probably will remain a dominant method in petroleum engineering. The method is technically very simple, but has one main problem: how to express, measure and properly handle the variable and complex uncertainty of each estimate. The computer age brought in the Monte Carlo Simulation method which enables correct arithmetic operation using data with specified probability distribution. However, several problems are still not solved uniquely and still exist. For instance, the determination and description of the distribution of single parameters, the determination of the degree of dependency between parameters (e.g. hydrocarbon saturation-porosity), and standard probabilist- ic definition of generally used categories (e.g. proved, probable, possible). Methods for handling these problems are discussed.

Jan 1, 1979

By Lauri Gregg

How Can Man Meet the Carbon-Free Energy Challenge ? ? Increases in Energy Efficiency can displace 1/2 to 2/3 of the Carbon-Free Energy required to stabilize at 550 ppmv ? Renewable Energies require too much land and thus can displace 5 to 10 % of the energy requirement ? Large new sources of carbon free energy are needed ? Conservation is desirable but provides only a small and variable contribution ? People will have to adjust to higher levels of CO2 in the atmosphere as energy demand continues to grow

Nov 1, 2002

By C. Beul, R. Schipper, L. Santisteban

The Garfield Mine is a legacy vanadium mine in western Colorado with multiple mine openings, waste rock piles, and adit seepages that Cyprus Climax Metals Company (a Freeport-McMoRan Inc. subsidiary) voluntarily remediated through the Colorado Voluntary Cleanup Program (VCUP). The process to obtain a No Further Action determination from the VCUP is presented. Water treatment of the adit discharge, which is not part of the VCUP, is also presented. The remedial action objectives (RAOs) included preventing direct human or biotic exposure to the waste rock and radiation emitting from the waste rock; reducing metal concentrations and radionuclide activities in adit discharge and keeping the discharge from leaving the site; maintaining the existing undeveloped character of the surrounding landscape; and eliminating the need for a stormwater permit. The design included regrading, installation of an infiltration barrier and rock cover, a diversion channel, and a biologically based passive remediation water treatment system. An initial lab-scale evaluation provided design criteria for the full-scale system, which consists of a sulfate-reducing biochemical reactor and post-treatment aerobic polishing cells. The system has been operational since construction was completed in late 2016. Results indicate that the treatment objective of 90% bulk removal of constituents of potential concern (COPCs) is largely being met. The system also provides year-round operation and non-point discharge of effluent. After 20 plus years of site investigations, the remedial action was completed in 2016 with all RAOs met and a No Further Action determination granted in 2018. INTRODUCTION The Garfield Mine is a legacy vanadium mine located approximately 11 miles north-northeast of Rifle, in Garfield County, Colorado. It was leased and operated intermittently from 1929 to 1975 but was never operated by Cyprus Climax Metals Company (Cyprus) (a Freeport-McMoRan Inc. subsidiary). Prior to reclamation, site features included: • six mine openings—five adits and a vertical opening; • two adits discharging mining-influenced water (MIW)— Adit 1 at less than 4 liters per minute (L/min) and Adit 2 at 7 to 10 L/min; • main waste rock pile (13,500 m3) and small waste rock pile (minimal volume); • debris (small structure, mattress, bottles, shells, etc.) indicating site used for recreational purposes; and, • unimproved road, which has been used to access forest fires.

Jan 1, 2019

By K. Chotruangprasert

This paper explores Global Reporting Initiative (GRI) reporting practices within the mining industry. Specifically, this paper investigates how and why a mining company makes voluntary reporting decisions to include the GRI indicators that may be considered ?negative? to the company?s reputation. Due to the voluntary nature of the GRI Guidelines, a GRI adopter is not legally obligated to report every GRI indicator. Not surprisingly, empirical studies that evaluated the extent to which companies? sustainability reports meet the GRI requirements (Guenther, Hoppe, & Poser, 2006; Morhardt, Baird, & Freeman, 2002; Samy, Odemilin, & Bampton, 2010; Skouloudis, Evangelinos, & Kourmousis, 2009) have found that reporting practices of the companies under their studies are well below the standards reflected in the GRI Guidelines. An influential study by Clarkson et al (2008) uses economic-based and socio-political theories to explain variation in companies? environmental disclosure. They have found that, as predicted by economic-based theory, superior environmental performers disclosed more ?hard? (i.e. verifiable) environmental information. Inferior environmental performers are found to disclose more ?soft? (i.e., not easily verifiable) claims, which is consistent with socio-political theories (Clarkson, Li, Richardson, & Vasvari, 2008). However, this study and the existing literature do not adequately explain why a company may act in a way that cannot be explained by economic-based and socio-political theories, for example, why it would report some negative soft data that it is not required to report. This paper intends to address this literature gap. GRI reporting by a Canadian mining company, which I would like to call ?Company C?, is used as a case study for this paper. Company C was selected for this research because in addition to ?positive? information, its GRI-based sustainability report also includes both hard and soft ?negative? information such as grievances. Research methods include interviewing Company C?s employees who are involved in preparing GRI reports and reviewing documents prepared both by the company and by external parties. I find that integrative social contracts theory (ISCT) offers a valuable explanation to Company C?s reporting practices. From the ISCT perspective, Company C?s management appears to feel that the company is obligated under social contracts to be transparent. Therefore, Company C disclosed both positive and negative social and environmental information to the public because the management appeared to think that it is the right thing to do. At the same time, being transparent about the bad news gave the company an opportunity to conclude that it had done something to avoid future occurrence of the negative incidents. Therefore, I propose that, in addition to the economic and socio-political theories that are more often used in literature, insights from ISCT are instrumental in improving our understanding of the corporate non-financial reporting practices phenomenon.

Aug 1, 2013