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The Mons Cupri Cu-Pb-Zn deposit is situated within a complex Archaean volcanic sequence dominated by rhyolitic fragmental rocks. This sequence is underlain by a 150 m group of rhyolitic ash flow tuffs with minor conglomerate and sandstone, and is overlain by approximately 180 m of dacite and andesite flows. The Mons Cupri sequence itself consists of several elongate or circular rhyolite domes, flanked by rhyolitic fragmental rocks ranging up to 400 m in thickness away from the domes. The lithology of clasts (typically 1 cm to 1.5 m in size) provides strong evidence that the flanking fragmental unit was derived by explosive eruptions associated with the rhyolite domes. An approximately 15 m thick shale horizon, bleached and silicified at its base, overlies both the rhyolite domes and the frag- mental unit. A south-dipping chloritic pipe-like body, with near-surface dimensions of 1,000 by 250 m and narrowing at depth to produce a cone-shaped cross section, lies within the rhyolitic frag- mental rocks about 250 m north of the largest rhyolite'dome in the Mons Cupri vicinity. Its east west elongation parallels that of the rhyolite dome. Ghost fragments indicate that the material in this fissure is a severely chloritized derivative of the rhyolitic frag- mental unit. The chloritic pipe is overlain

Jan 1, 1973

By R L. Brathwaite

In New Zealand, volcanogenic massive sulfide (VMS) deposits are found in three main geological environments associated with: 1.   ophiolitic basalts of Oligocene age in Northland and East Cape (eg Pupuke, Pakotai, Parakao and Lottin Point); 2.   with chert and pillow lava in greywacke sequences of Permian-Jurassic age (Torlesse and Waipapa terranes; eg Kawau Island, Te Kumi and Maharahara) and their metamorphic equivalents (Haast Schist; eg Moke Creek and Waitahuna); and 3.   with greenschists (metabasalts) and metaserpentinite of Permian-Triassic age (Ponamu Ultramafics) in Westland (eg Bowen and Wilberg ranges). The deposits consist of small lenses of disseminated to massive sulfide minerals, mainly pyrite and chalcopyrite. Small quantities of copper ore were mined from some deposits in the 1800s (eg Kawau Island from 1846), with the last mining at Parakao from 1961 to 1966. Several deposits have been recently examined for their gold potential with assays on sulfide rock samples as high as 75 g/t Au (Lottin Point).

Jan 1, 2005

By Harold L. Gibson, David H. Watkinson

"Volcanogenic massive sulphide deposits of the Noranda Camp cur throughout the Noranda Shield Volcano but are concentrated and along the margins of the Noranda Cauldron. The deposits are realized along synvolcanic faults that also accommodated subsince and controlled the location of eruptive centres. Deposits within e 3 000 m thick Mine Sequence formed during a period of active volcanism and subsidence coinciding with the onset of two cauldron subsidence cycles. The Noranda Cauldron was a restricted site of 10malously high heat flow and structural permeability that favoured e development of a high-temperature hydrothermal system. Metals may have been derived from leaching of aquifer rocks by convecting a water or directly from a shallow underlying magma chamber, now presented by the Plavrian Pluton, that was at its highest position !thin the crust during cauldron subsidence. The deposits formed rough a combination of sulphide precipitation from exhaled fluid td replacement at and below the seafloor in a manner analogous to ose on the modern seafloor.RESUMESi les dépôts de sulfures massifs volcano gènes du camp minier de ~uyn-Noranda sont présents dans les différentes parties du volcanluclier de Noranda, ils se trouvent concentres toutefois, en plus ·and nombre, sur le pourtour de la caldeira (cauldron) de Noranda. ~s dépôts sont localises le long des failles synvolcaniques qui ont cilite la subsidence et contrôle la position des centres d’éruption.~dépôts situes dans la séquence des mines (3 000 m d’épaisseur) sont formes durant un épisode d' activité volcanique et de subsiden qui coïncide avec l' amorce de deux cycles d' affaissement de la rldera (cauldron) de Noranda. Celle-ci Jut le site exclusif d’unflux : chaleur anormalement élevé et d’une perméabilité d’origine cucturale qui ont favorise le développement d’un système hydrothermal a haute température. Les métaux proviennent soit directement d’une chambre magmatique situee afaible profondeur, so it d’un lessivage des roches de l’aquifère par l’eau de mer circulant par convection. Cette chambre magmatique, représentée maintenant par le pluton de Flavrian, se trouvait à son niveau le plus élevé dans la croute au moment de l’affaissement de la caldeira (cauldron). Les dépôts se sont constitués par un mecanisme combinant remplacement et précipitation de sulfures à partir des fluides exhalatifs, au niveau ou au-dessous du plancher océanique, de la même manière que se forment de nos jours, les dépôts de sulfures massifs au fond des océans."

Jan 1, 1990

By A. J. Naldrett, N. T. Arndt

In Archean greenstone belts, ultramafic lavas occur interbanded with basalts, commonly at the base of volcanic-sedimentary cycles. The lavas form part of a recently recognized extrusive rock series, the magnesian series, in which liquid compositions range from peridotitic (33 wt-% MgO) to basaltic (8 wt-% MgO). Rocks of this series occur as peridote, pyroxenite and magnesian basalt flows, and intrusive/extrusive bodies of dunite (49 wt-% MgO) grading outwards into a peridotitic marginal zone. The nickel sulfide deposits are of two main types: (1) basal accumulations of massive and disseminated pyrrhotite + pentlandite associated with some of the thickest and most magnesian (<40 wt-% MgO) of the peridotite flows, and (2) widespread zones of disseminated sulfides in the dunite lenses. Massive sulfide segregations may occasionally occur within the dunites.

Jan 1, 1977

By A. J. Naldrett

Over the past six or seven years important new ideas have been developed concerning the origin of nickel sulfide deposits. To a large extent these have been stimulated by the major nickel discoveries of the Eastern Goldfields area of Western Australia (Woodall and Travis, 1969; Ewers and Hudson, 1972). Prior to these finds, the most important nickel camps were regarded as being associated exclusively with intrusive rocks such as the Nickel Irruptive at Sudbury or the intrusive peridotites at Thompson, rocks that were thought to have no close association with volcanism. Study of the Australian discoveries, coupled with work in South Africa (Viljoen and Viljoen, 1969) and Canada (Naldrett and Mason, 1968; Pyke, Naldrett and Eckstrand, 1973), has shown that volcanic rocks with true ultramafic compositions and extrusion temperatures of 1400 to 1600°C were a common feature during the Archean. Under certain circumstances economic concentrations of nickel sulfides have formed from these rocks, either settling to the base of their associated flows or accumulating in shallow intrusive feeders to the flows. The aim of this article is to show how these ultramafic rocks can be recognized, how the nickel deposits, if present, are likely to occur within them, and what special features characterize ore-bearing examples of the rocks.

Jan 1, 1975

By M. Labrie, H. L. Gibson, G. Doiron, J. J. Watkins, D. H. Watkinson

Abstract -The Corbet deposit is one of 17 proximal Cu-Zn massive sulfide deposits located. within the Noranda Cauldron which occurs within the core of the Noranda Volcanic Complex. The deposit is located at the top of the F1avrian Formation, the lowermost formation of the 3000 m thick Mine Sequence; the deposit has yielded 2.75 M tonnes of ore grading 30Jo Cu, 0.96% Zn, 2.06 g/t Ag and 1.0 g/t Au. The multi-lens Corbet deposit formed within a 250 m wide crater that occurs within a localized breccia pile. The Corbet breccia pile was constructed by explosive magmatic and hydrovolcanic eruptions localized along the south flank of a larger andesitic shield volcano that formed during the waning stages of F1avrian volcanism. The breccia footwall of the deposit allowed unfocused and widespread hydrothermal discharge that resulted in the development of a large area of chlorite and fringing sericite alteration that exceeds, by six times, the size of the sulfide lenses and represents a significant exploration target.

Jan 1, 1993

By M. Labrie, H. L. Gibson, G. Doiron, J. J. Watkins, D. H. Watkinson

The Corbet deposit is one of 17 proximal Cu-Zn massive sulfide deposits located. within the Noranda Cauldron which occurs within the core of the Noranda Volcanic Complex. The deposit is located at the top of the Havrian Formation, the lowermost formation of the 3000 m thick Mine Sequence; the deposit has Yielded 2.75 M tonnes of ore grading 3% Cu, 0.96% Zn, 2.06 g/t Ag and 1.0 g/t Au. The multi-lens Corbet deposit formed within a 250 m wide crater that occurs within a localized breccia pile. The Corbet breccia pile was constructed by explosive magmatic and hydrovolcanic eruptions localized along the south flank of a larger andesitic shield volcano that formed during the waning stages of Havrian volcanism. The breccia footwall of the deposit allowed unfocused and widespread hydrothermal discharge that resulted in the development of a large area of chlorite and fringing sericite alteration that exceeds, by six times, the size of the sulfide lenses and represents a significant exploration target.

Jan 1, 1993

By Maria D. Salazar-Villalpando, Anthony Cugini, Bryan Reyes

"The electrochemical reduction of CO2 was performed in a laboratory-made, divided Htype cell. A copper electrode was used as the cathode. An Aldrich Nafion 117-type ion exchange membrane (0.18mm thickness) was used as the diaphragm. NaHCO3 and KHCO3 were studied as the catholytes. Hydrogen evolution from water reduction and products from CO2 electrochemical conversion were recorded. Higher CO2 reduction enhancement was observed by KHCO3 as compared to NaHCO3. The main conclusion of this work is that in fact CO2 can be electrochemically reduced with copper electrodes.1.-INTRODUCTIONThe direct electrochemical reduction of CO2 may allow for a simple process and, by avoiding high temperature reactors, would enable the process production rate to be quickly varied to follow the time of day availability of surplus electricity [1]. Temperature has a major effect on the electrochemical conversion of CO2 since its solubility increases when temperature decreases [2]. The electrical potential applied to the electrochemical reacting system will have an influence on the product distribution, as well. For example, a narrow potential range during cyclo-voltagraphic studies will determine the detection of a lower number of products. A recommended potential range to study the electrochemical reduction of CO2 is -2V to 2V. Moreover, the reaction rate on the electrode is governed by various processes, such as the kinetics of electron transfer, adsorption/desorption at the electrode surface, and diffusion of CO2 to the Cu electrode. The availability of active species, CO2 for electro-reduction, is extremely low at the vicinity of the electrode surface and it seriously interferes with the rate of mass transfer. In batch type electrolytic reactors, depletion of CO2 at the surface takes place first. CO2 from the bulk then has to diffuse to the electrode surface, resulting in mass transfer controlled kinetic phenomena. During the above process, several other competitive side reactions could suppress the primary reaction even though the cathode has good electro catalytic properties for reduction of carbon dioxide. When the dynamic supply of specific active species is ensured to electrode surface, the mass transfer effects are minimized to certain extent. Hence it is envisaged that a continuous flow reactor is more efficient for the electro-reduction of CO2 in CO2 saturated aqueous electrolytes. The primary reactions that occur at the copper electrode during the reduction of CO2 are listed below (with the standard potentials calculated using formation energies [1] :"

Jan 1, 2010

Jan 1, 1965

By Morrison AL

The volume changes occurring during the reduction by hydrogen of single, high-grade hematite pellets under isothermal and non- isothermal conditions were investigated using a time-lapse photographic technique. The major cause of swelling during iso- thermal reduction at temperatures in the range 600-1000¦C, was the disruptive stresses set up during the transformation of hematite to mag- netite. The severity of the disruption was temperature dependent; the degree of swelling increased with increases in the reduction temp erature. Under non-isothermal reduction conditions, in which the pellet temperatures were increased at constant heating rates over the temperature range 500-1000¦C, minor swelling (6-8%) occurred in the initial stages of reduction followed by pellet contractions of up to 15% in the final reduction stages. The low initial swelling and high final pellet shrinkages were due to a com- bination of the temperature dependence of the swelling mechanism, and the sintering of fine pores in the reduced iron in the latter stages of reduction at higher temperatures.

Jan 1, 1980

By Minna Karstunen, Patrick Becker

"Abstract The deformation behaviour of a foundation on deep mixed columns in a natural soft soil is a three-dimensional problem, which has to be considered adequately in numerical modelling. However, simplifications are often made due to the computational costs of fully coupled 3D analyses by either modifying geometry of the problem or material parameters in 2D for plain strain analyses or by modelling the problem as 2D axisymmetric case. The volume averaging technique (VAT) is an enhanced 2D FE technique that enables mapping the 3D problem in two-dimensions, yet modelling the two constituents (column and soft soil) with appropriate different constitutive models within a homogenized material. The performance of the volume averaging technique is demonstrated by considering unit cell simulations of floating and end bearing columns in soft soil. The results with VAT are compared and validated against conventional 2D axisymmetric and fully coupled 3D finite element analyses.IntroductionThe properties of very soft clays, silts and organic soils can be improved by stabilizing agents, such as lime and/or cement that are mixed into the soil in situ by using auger-type mixing tools in situ. Deep mixed columns are extensively used to reduce deformations and to improve the overall stability of embankments and foundations on soft soils. Whilst the most typical applications are embankments, increasingly the method is used under foundations. The first category of applications is very common in Scandinavian countries, whilst the latter application has been pioneered in Poland, as an environmentally friendly (low CO2) and cost effective alternative for piling. Due to economic and environmental reasons there is an increasing interest in the technique elsewhere in Europe. With deep mixing, the strength and deformation properties of the soft soil can be improved, and the risk of unwanted deformations is substantially reduced.Numerical methods, such as finite element (FE) analysis, can be used as an alternative to conventional design methods. They are particularly suitable when considering serviceability limit state, i.e. deformation analyses under working loads. FE analyses allow using advanced constitutive models that take account of the complex stress-strain behaviour of natural soil and stabilized columns, respectively. The problems that involve a grid of circular columns under an embankment or a strip footing are fully three-dimensional problems. As 3D analyses are very laborious and expensive, an enhanced 2D technique using the so-called volume averaging technique (VAT) is utilised. The basic idea is to describe the column-improved ground as a homogenized composite material, and using clever mathematics to map the true 3D problem into 2D. Once the constitutive relations of both composites are defined, the response of the column-improved ground can be simulated in 2D subject to arbitrary loading and boundary conditions."

Jan 1, 2014

By Atulya Verma, Samantha Espley, Nashel Kalaka

Numerical modelling simulations of proposed mining sequences are used to evaluate mining induced stress concentrations and their migration associated with the progress of mining. This analysis is a standard practice for most prospective mining projects at various levels of feasibility study. The studies are usually initiated at the beginning of the mining cycle, on a global scale, and are maintained and updated throughout the life of mine (LoM) to identify or address local issues and the required remedies as and when needed. Developments in numerical modeling techniques along with advancements in computing technology and data storage/management capacity have given rock engineers access to a huge volume of data that needs to be analyzed and assessed. The most common approach to numerically evaluate stress concentrations and migrations in underground mines is to select the points of interest in a given volume such as the back of an excavation or points within pillars around critical infrastructure, and plot the stresses or a derivative of stresses over time to represent life of mine concentrations and migrations of stresses. The problem with this approach is the sharp gradient of stresses close to excavation boundaries. Slight changes in the location of selected points can change the stress concentration and migration patterns substantially and all generalized statements about LoM risk can be challenged in one way or another. For global stresses, the most common current approach of data analysis is by viewing series of pictures representing stress contours. In this approach, it is easy to overlook some critical detail and/or be masked by personal preferences of contour/picture representation. To overcome the problem of representing and analyzing huge volume of stress simulation data, the authors, through their experience at different mining operations, developed a volume-based technique to reliably evaluate mining-induced stress concentrations and migrations. The volume-based approach is for risk-based assessments of adjacent regions in the rockmass, in and around planned stoping excavations. The volume of interest is the entire ore body that is planned to be mined, but it could be just a part of the ore body depending on the specific use case. The risk identifiers are the induced stresses as compared to the strength of the rockmass. Over the LoM, the risk identifiers are tracked versus the corresponding excavation ratio of the zone. This approach is very effective in identifying the stages of mining that are contributing the most to the mining induced stress risk and the results can be used for proactive planning and mitigations measures such as alternative mining sequences, or stope sizes, or extraction methods. The approach has also been very successful in application at mature mines, particularly in assessing the re-initiation of mining in zone that has been dormant for some time. The volume-based approach allows for an assessment of the current state of the rockmass and the identification of future risks when planning resumption of mining activities.

Jan 1, 2023

By M. Kwasniewski, M. Takahashi

Prismatic samples of a medium-grained sandstone from Slask Colliery (Upper Silesian Coal Basin, Poland) were tested under uniaxial compression, conventional triaxial compression and true triaxial compression conditions. The conventional triaxial compression tests were carried out at confining pressure (p) equal to 12.5, 25.0 and 37.5 MPa. In the true triaxial compression tests the minimum principal stress (s3) was equal to 25.0 MPa and the intermediate principal stress (s2) was 1.5, 2 and 2.5 times higher than s3. Results of the studies show that confining pressure strongly inhibited dilatant behavior of rock samples tested under conventional triaxial compression conditions; the increasing confinement resulted in the growing compaction of the rock material. The effect of dilatancy was also highly suppressed by the intermediate principal stress. While important dilatant, negative volumetric strain corresponded to the peak differential stress at low intermediate principal stress conditions, at high intermediate stresses the rock material was damaged to much lesser extent. As a result, faulting of rock samples in the post-peak region was much more violent and was accompanied by a strong acoustic effect. Les échantillons parallélépipédiques du grès à grains moyens de la mine ‘Slask’ (Bassin Houiller de Haute Silésie, Pologne) ont subi les essais de compression monoaxiale (compression simple), de compression triaxiale conventionnelle (compression triaxale de révolution) et de compression triaxiale vraie. Les essais de la compression triaxiale conventionnelle ont été effectués à la pression de confinement de 12,5, 25,0 et 37,5 MPa. Dans les essais de compression triaxiale vraie la contrainte principale minimale (s3) était de 25,0 MPa et la contrainte principale intermédiaire (s2) était 1,5, 2 et 2,5 fois supérieure de s3. Il résulte des essais que la pression de confinement inhibe fortement le processus de dilatance dans les échantillons testés dans les conditions de compression triaxiale conventionnelle; l’augmentation de la pression provoquait l’augmentation du compactage du matériau rocheux. Le phénomène de dilatance était également limité de façon significative par la contrainte principale intermédiaire. Alors que l’importante déformation volumique négative correspondait à la contrainte différentielle ultime avec les faibles contraintes principales intermédiaires, dans les conditions de fortes contraintes intermédiaires, le matériau rocheux subissait l&apos;endommagement de façon beaucoup moins importante. En résultat, la rupture des échantillons rocheux au stade post-maximum était beaucoup plus violente et accompagnée d’un fort effet acoustique. Prismatische Probekörper des mittelkörnigen Sandsteines aus dem Bergwerk ‘Slask’ (das Oberschlesische Kohlengebiet, Polen) wurden unter der einaxialen Druckbeanspruchung, konventionellen dreiaxialen Druckbeanspruchung und der echten dreiaxialen Druckbeanspruchung geprüft. Konventionelle dreiaxiale Druckversuche wurden bei dem Manteldruck von 12,5 25,0 und 37,5 MPa durchgeführt. Bei den echten dreiaxialen Druckversuchen betrug die kleinste Hauptspannung (s3) 25,0 MPa und mittlere Hauptspannung (s2) war 1,5-, 2- und 2,5-mal höher als s3. Aus den durchgeführten Versuchen ergibt sich, dass der Manteldruck die Dilatanzentwicklung bei den Probekörpern unter der konventionellen dreiaxialen Druckbeanspruchung stark bremst; die Erhöhung des Druckes rief die ansteigende Kompaktion des Gesteinsmaterials hervor. Die Dilatanz wurde auch durch die mittlere Hauptspannung beschränkt. Während die wesentlichen volumetrischen, dilatanten Verformungen der Grenzdifferenzspannung bei den niedrigen mittleren Hauptspannungen entsprachen, bei den hohen mittleren Hauptspannungen wurde das Gesteinsmaterial viel weniger beschädigt. Im Ergebnis war der Scherbruch der Gesteinsproben im Post-Peak-Bereich viel heftiger und mit kräftigen akustischen Effekten verbunden.

Jan 1, 2003

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Considerable attention has been given to the restoration of low-level radioactive (<1000 pCl/g) sites contaminated during the early years of the atomic energy program. Current clean-up activities which involve the relocation of contaminated soils to licensed disposal sites have been shown to be very costly due to the large volumes of soils which must be excavated, transported and stored. Recent characterization studies conducted at Virginia Tech suggest that the volume of soil requiring disposal can be greatly reduced using mineral processing techniques such as classification, density separation and froth flotation. This article discusses the application of these technologies for soil remediation and describes a conceptual flowsheet for treating soil samples from two contaminated sites.

Jan 1, 1997

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