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Volume LIV has been shipped to all members whose clues were paid on or before Feb. 10, 1917. The next shipment will be made the latter part of April to all those whose dues were paid on April 1, 1917.

Jan 4, 1917

Vol. LIX will be shipped during December to all Members whose 1918 clues are paid on or before Nov. 15.

Jan 12, 1918

By Américo Zuzunaga Cardich

La voladura de rocas es la operación minera más importante de la producción minera, dado que provee materiales de calidad para el equipo de carguío, transporte y conminución. En este sentido, el presente texto señala el método temporal alternativo para el diseño de malla y carga de la voladura en la mina Cuajone. El diseño de la malla se realizó considerando los parámetros geotécnicos del explosivo y del equipo de perforación, mientras que para el cálculo de carga se utiliza el criterio de "velocidad pico de partícula" que originalmente fue desarrollado para el control de daños a estructuras por efectos de la vibración derivado por la voladura. Finalmente, para minimizar el daño ocasionado a la pared del banco a ser minado, la ejecución debe efectuarse a través de métodos de voladura controlada a través del equipo empleado en voladura de producción normal.

Nov 24, 1986

By Gregorio Llanos Villarreal

Dado que la expansión progresiva de la mina Calera exige una productividad de material detrítico, se ha optado por una alternativa de voladuras a gran escala que controle el desmonte proveniente de los desarrollos de la mina. En esta perspectiva, el presente estudio refiere las experiencias de voladura adquiridas en la mina Calera, a partir de la aplicación de "voladuras de coyote" a gran escala. La eficiencia de sus resultados redujo la utilización de los equipos pesados en la cantera de relleno, así como los costos de los conceptos.

Apr 1, 1991

By Noelia Farías, Luis Lozada

La voladura representa una de las operaciones unitarias más importantes en toda la cadena de producción del proceso minero. Su objetivo es lograr un adecuado grado de fragmentación de la roca, produciendo a la vez el menor daño posible en la proximidad del sector volado como taludes del tajo, botaderos, comunidades cercanas, estructuras y/o edificaciones. Tal es el caso de un proyecto de desarrollo de minado en un sector adyacente a una faja transportadora que ha sido ejecutado con éxito. Este proyecto incluyó realizar voladuras a una distancia menor de 40 metros a la estructura en mención, así como a 20 metros de una tubería de combustible.

Sep 29, 2023

By Rolando Fuentes

El artículo discute la importancia de cada uno de estos 5 elementos, que son: (1) control y aseguramiento de la calidad, (2) distribución de la carga explosiva en la columna; (3) técnicas de múltiples iniciaciones de carga; (4) energía explosiva y (5) Secuencia de iniciación. Finalmente, aplicando técnicas de modelamiento numérico, se pone a prueba un par de elementos de esta técnica, al comparar un diseño estándar de carga explosiva para voladuras de mineral, en rocas de alta competencia con un diseño de VAD. Las curvas de DTP se comparan para cuantificar el impacto que una mejor distribución de tamaños, con mayores contenidos de tamaños finos, genera en el tratamiento de minerales y, por lo tanto, en una mejora sustantiva del negocio minero.

Sep 29, 2023

By Marcos Rojas

El método Sub Level Stoping con taladros largos; está intrínsecamente ligado a la producción de grandes cantidades de material fragmentado, y dependiendo de las características del terreno donde se aplica puede tener envergaduras realmente importantes. En los cuerpos de la Unidad Minera Cerro Lindo este método se emplaza en secciones de 30 metros de altura por 25 de ancho; y los abanicos enmarcados en éstas; producen hasta 8000 toneladas de mineral cada uno, aun así; la necesidad de producción creciente en nuestra realidad, la presencia de nuevos problemas como efecto del método y la posibilidad de obtener nuevas y mejores ventajas, nos ha llevado a trabajar en la viabilidad de ejecutar voladuras masivas en los tajos donde se puedan disparar de 40000 a 50000 toneladas unitariamente

Sep 1, 2017

By Martín E. Mendoza

En 2010 se identificó un peligro potencial en la pared Norte del Tajo Chaquicocha, donde existía fallas pre-existentes, catch bench reducidos (subestándar) y bloques colgados que presuponían condiciones de mala voladura de control. Por ello, se planteó la modificación del diseño Final del Tajo Chaquicocha, ya que la continuidad de estos malos resultados arriesgaba el minado de los Bancos inferiores. En ese sentido, el objetivo del presente texto estriba en lograr voladuras masivas, sin afectar la estabilidad de las paredes del Tajo Chaquicocha, así como tener beneficios económicos en la reducción de tiempo de minado por cada banco, y en la productividad (Dig Rate) de los equipos de carguío.

Sep 12, 2011

J. W. RICHARDS*(South Bethlehem; Pa.).-The brass industry would find it very profitable to subsidize researches on the purely scientific determination of the thermophysical properties of the brasses. The data we need most in connection with the brasses are the vapor tension of the zinc from the brasses at different temperatures, the heat of combination of zinc With copper to form different kinds of brasses, and the latent heat of fusion of these brasses at the melting temperature.

Jan 1, 1919

By Behram H. Wadia

El presente estudio describe el proceso de volitización de plata-plomo y otros valores metálicos como cloruros en la Cerro de Pasco Corporation. La aplicación de este procedimiento busca recuperar metales como la plata y el oro, así como los metales menores: bismuto, cadmio, teluro, etc., los cuales se perciben en los humos, producto de la volatización de los valores metálicos. En este sentido, el proceso de volatilización de plata y plomo como cloruros aplicado en altas temperatura, es metalúrgicamente fac¡tible, ya que logra una eficacia de plata entre 80 y 84% y no menos de 95% de plomo. Asimismo, el uso de la cama fluidizada como reactor usado en la experimentación, es el más conveniente dado que se puede obtener mayor concentración de valores en los productos de condensación de los cloruros volatilizados.

Nov 20, 1967

By Qian Li, Li-chen Hou, Yong-bin Yang, Tao Jiang, Jian-jun Hu, Bing Xu

Extraction of gold from refractory gold concentrates usually requires an oxidation step to remove arsenides、sulphides and carbonaceous matter. In this investigation, the gold concentrates were two-stage roasted under different atmospheres and temperatures. Results indicated that at the first stage, under neutral atmosphere, the removal rate of arsenic increases as the temperature rises. Under the oxidizing atmosphere, with the increase of temperature, arsenic content in the residued calcine increases, in addition, the volatilization of arsenic is also affected by the oxidation of carbon that generated CO, which is advantageous to the decomposition of arsenate decomposition. At the second stage of roasting, it is the higher temperature and stronger oxidizing atmosphere, the faster sulfur and carbon oxidated rate is, but at the same time, the calcine appears the phenomenon of consolidation because of the phase of silicate compounds generate.

Jan 1, 2015

By Ho-Sang Sohn

Copper concentrate particles of 200 to 300 mesh size were fed from the top of vertical reaction tube of 2.8 cm ID and 2 m long with an O2-N2 gas mixture. The reaction tube was heated to 900 K to 1100 K. The residence time of the particles in the reaction tube was about 1 second. The copper concentrate particles were very rapidly oxidized and melted down during their descent in the reaction tube. The particle temperature were calculated by combining an un-reacted core model, mass transfer between gas and particles, and heat transfer between gas, particles and tube wall. The particle temperature reached its maximum within a distance of 60 cm from the top of reaction tube, and it attained at 2000 K at higher oxygen partial pressure. The most particles were melted at the oxygen partial pressure above 20 kPa. An appreciable amount of As, Sb and Pb in the concentrate particles was eliminated in the upper portion of the reaction tube and the rate of elimination are explained by the rate of mass transfer of volatilized species through the gas film on the particle surface and the variation of particle temperature during the descent.

Jan 1, 2006

By K. Sugawaral, W. Tongampl, K. Hiruta, Takasaki Y., A. Hosoi, T. Katol, A. Shibayamal

Printed circuit boards of discarded personal computers, televisions, mobile phones and so on contain a significant amount of valuable metals. For the recycle of valuable metals contained in the printed circuit board wastes (P CB W), the effect of temperature on chlorination-volatilization of metals under chlorine gas flow was studied. The experimental sample used was powder of two types: crushed PCBW (Sample 1) made from PC and industrial machines, and crushed-combusted PCBW (Sample 2) made from Sample 1. The principal element in Sample 1 and Sample 2 was copper, about 13 wt% and 20 wt% respectively. Sample 1 was composed of pure metals such as copper, tin and lead. In comparison, Sample 2 consisted of oxide metals such as copper oxide, tin dioxide and silicon dioxide. The two samples were heated at predefined temperatures (ranging from 300 °C to 900 °C) in chlorine gas. The chlorine gas flow into the furnace was set at a rate of 100 mL/min. As a result, copper in Sample 1 began to volatilize at 600 °C and completely vaporized at 700 °C. While in Sample 2, copper started to volatilize at 600 °C and reached 100% vaporization at 800 °C. For Sample 1, zinc finished volatilizing at 500 °C, while for Sample 2, zinc volatilization reached only about 80% (maximum). Also, lead, nickel and titanium showed similar results. Consequently the volatilization rate of Sample 1 is higher than Sample 2 and the temperature dependency was verified for copper, lead, zinc, nickel, antimony, titanium and chromium. In fact, the volatilization rate of these metals increased with the temperature. This result reflects the difference between pure metal and metal oxide, as Sample 2 was combusted before the chlorination-volatilization test. Moreover, the chlorination reaction may be accelerated by a reductive atmosphere because Sample 1 contains carbon. In this study, the volatilization behavior of some valuable metals in PCBW by chlorine gas was observed. Further improvement in the rate of volatilization can be achieved by optimizing the experimental conditions.

Jan 1, 2011

By Frederic Dewey

IT IS common to blame irregular assay results upon volatilization and much has been written upon the subject, but there is no. real evidence that, in a properly conducted assay, the loss of either gold or silver by volatilization is sufficient to affect appreciably the result, even when, arsenic or antimony may be present. Bulk assays of flue dust from assay muffles have been published, but the data given are totally insufficient to even approximate the volatilization from a single assay; and such figures as we have indicate the volatilization to be extremely small. Diligent search in the literature and wide inquiry among assayers and instructors have failed to produce a single case where the litharge volatilized in making an assay has been collected and assayed for gold and silver. Having attempted to do this, with most indifferent success, I am not surprised that this has not been done. While various textbooks give volatilization as a cause of loss in cupellation, it may safely be said that in the rare cases where this volatilization is sufficient to affect appreciably the result it is due to excessive temperature. Percy1 says "The loss of silver by volatilization during cupellation is very slight (unless the temperature has been much too high), and may be disregarded." This statement is repeated by the Beringers2 and Smith,3 who includes gold with silver. Mitchell4 says the litharge fume rarely contains over one ten-thousandth of silver. Campredon5 says that at a proper temperature no silver is lost by volatilization.

Jan 2, 1920

By Xu Zhong

The theoretical limit to smelting rate and possibly the size of a smelter is dependent on the rate of heat transfer, and the chemical kinetics of both sulfur removal and minor element volatilization. The fundamental kinetics of volatilization of minor elements such as As, Sb, Bi, and Pb from matte and white metal is being investigated. It has been shown that the molecular form of trace elements in matte depends on the chemical potential of sulfur and the propensity for the minor element to form a sulfide. The impact of the variable molecular form of the minor elements on the volatilization kinetics is unknown and is under investigation in this study. The experimental technique is reviewed and preliminary results are reported in this manuscript.

Jan 1, 1995

By D. Y. Wang, G. Y. Sha, X. L. Shen, D. R. Gu

The study of the volatilization kinetics of zinc and lead in pellets made of zinc-leadbearing dust mixed with coal powder, in a nitrogen atmosphere and at a temperature range between 1100 °C and 1300 °C, shows that the reduction temperature has a significant effect on the volatilization rates of zinc and lead, and that both the particle size of the coal powder and the extra carbon content has no effect on the volatilization rates. The obtained activation energies for the volatilization of zinc and lead are 79.42kJ/mol and 88.74kJ/mol respectively. The volatilization rate of zinc is controlled by the reaction between the zinc oxide and carbon monoxide while that of lead is controlled by the lead evaporation reaction, and the diffusion of gaseous lead through the gas boundary layer covering the surface of the reduced liquid lead.

Jan 1, 2000

By Alex Moyano

At present, the Codelco Norte smelter processes in the Teniente Converter and the Flash smelting Furnace 1,420,000 t/y of its Chuquicamata concentrate with an arsenic content of up to 1.5%. In a near future Codelco-Chile is considering different processing options for a new projected concentrates from the Alejandro Hales mine (former Mansa Mina mine with an arsenic content of up to 6%). The main option is the possibility to process 3,000 t/d of mixing concentrates from the Alejandro Hales and the Chuquicamata mines, in the Teniente Converter. The main feature of this smelting unit will be high volatilization of arsenic when processing high arsenic-bearing concentrates. The CN smelter staff carried out a technical feasibility study to evaluate the processing of high arsenic-bearing concentrates directly in the Teniente Converter, thus the low arsenic-bearing concentrates can be processed in the FSF. Accordingly, laboratory scale tests were carried out at the Tohoku University facilities. The lab-scale results allowed an industrial scale test at the Codelco Norte smelter to smelt 2,300 tpd of high arsenic-bearing concentrates in the TC and evaluate the metallurgical impact in the smelting, converting and refining areas of the smelter. The main industrial-scale result confirmed the stabilization of the arsenic content at 0.5% in the 70% Cu produced white metal at the test condition.

Jan 1, 2006

By S. Skowronski

PURPOSE OF INVESTIGATION Since cuprous chloride melts at 418° C., boils at 954° C. to 1033° C.,1 and is known to be volatile at a much lower temperature, the presence of chlorine in any form in or on copper to be melted has always been looked upon by copper refiners as a possible source of-serious copper loss. Although this fact has been known for some time, the copper literature contains little or no information regarding it and the field seems .never to have been properly investigated from a metallurgical standpoint. According to Greenawalt,2 cupric chloride, CuCl2, when ignited gives cuprous chloride; therefore cuprous chloride is always formed when copper enters into reaction with chlorine at a high temperature. Cuprous chloride melts somewhat below a dull red heat, and does not volatilize in closed vessels, even if strongly heated, but if heated in the air it goes off as a white vapor. Hofman3 gives the melting point of cuprous chloride

Jan 2, 1919

By Linfeng Zhou, Yuanbo Zhang, Rong Sun, Guanghui Li, Zhiwei Peng

The volatilization behavior of rhenium in the process of oxidative roasting of a molybdenite concentrate with 43.55 wt.% Mo and 321 g/t Re is explored based on identifying the relationship between volatilization of sulfur and rhenium. The results show that rhenium volatizes after sulfur and precise control of operating variables plays an important role in separating rhenium from molybdenite concentrate. When the roasting parameters are optimized as follows: roasting temperature 600 oC, roasting time 2 h, roasting atmosphere air, the volatilization rate of rhenium reaches 89.26%. In the process of solidification roasting, the volatilization rate of rhenium decreased almost to zero when the ratio of slaked lime/molybdenum concentrate was 10% excess to the stoichiometric requirement at 600 oC for 2 h.

Jan 1, 2016

By Edgar Peek

Lixiviant regeneration is by definition a precondition for any hydrometallurgical process. In chloride hydrometallurgy either HCl or Cl2 has to be regenerated in order to establish an economically viable metallurgical process. One such regeneration process is widely used with steel pickling where HC1 is regenerated through the thermal decomposition of ferrous chloride in either spray roasters or fluid bed pyrohydrolyzers. This standard HC1 regeneration process deserves to be considered as a potential separation process, since thermodynamic calculations show that a fluid bed pyrohydrolyzer can function as a ferrous-nonferrous separator. Several nonferrous,metals such as zinc, lead and cadmium can be volatilized as a chloride under ferrous chloride pyrohydrolysis conditions. If such a nonferrous metal volatilization could be achieved in the case of slurry feeding of "contaminated" iron oxides, then this would increase the Fe/H2O ratio of the (process) feed and thus save on fuel per ton of iron, while yielding a marketable iron oxide product. Previous test work on synthetic materials revealed that the near-complete separation of zinc, lead and cadmium from iron oxide was possible in a pyrohydrolytic atmosphere, even if zinc was present as zinc ferrite (more than 99.5%). This investigation, which was carried out in a tube furnace at 1100 K has now been extended to treat synthetic zinc minerals and also franklinite ore. For the latter, it was found that 85% zinc volatilization could be achieved in 4 hours at 1300 K. It is postulated that complete zinc volatilization could not be attained due to the formation and/or presence of gahnite and hardystonite, which might be stable in HCl/H2O atmospheres at 1100 K. The effect of adding small amounts of calcium chloride to react with gahnite and hardystonite to give zinc chloride and both calcium aluminates and silicates is being discussed. Test work on slurry feeding of this complex ore in a recently constructed 4-inch diameter fluid bed pilot unit has been planned for the near future.

Jan 1, 1995