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By J C. Furness, F S. Cannon

Metal casting operations are a significant source of hazardous air pollutants. In particular, high production iron foundries emit significant quantities of volatile organic compounds (VOCs) during pouring, cooling and shakeout of iron castings made in green sand molds. End-of-the-pipeline capture and destruction methods to reduce VOC emissions add crippling costs to foundries. Alternately, the incorporation of advanced oxidants (AO) into metal casting green sand systems has been shown to reduce emissions from high production iron foundries in the US, and at the same time reduce operating costs. Cost savings are driven by the benefits of AO in clay recovery systems. Emissions reductions are the direct result of cascading AO-based reactions taking place in green sand molds. This sustainable greening of the metal casting process is a prototype for the development of other AO and non-AO process-based solutions for sustainable high temperature processing of materials. Fundamentals of AO technologies will be discussed along with the performance characteristics of AO processing systems in the metal casting industry and the breadth of other processing and remediation applications for which AO technologies have the potential to be successfully employed.

Jan 1, 2002

Fine coal is substantially more costly to process than coarse coal because of technical difficulties associated with separating fine particles and removing process water from both clean coal and refuse. Therefore, companies are often forced to discard coal fines to waste impoundments. According to a recent report published by National Research Council, the U.S. coal industry is discarding 70-90 million tons of coal fines annually to 713 active impoundments, most of which are located in Central Appalachia. On October 11, 2000, a 72-acre impoundment near Inez, Kentucky, accidentally released 250 million gallons of coal slurry into nearby underground mines, creeks, rivers, and schoolyards, thereby creating serious environ-mental concerns. Fortunately, recent advances in separation technologies make it possible to recover fine coal more efficiently from existing coal preparation plants and from waste streams previously discarded to impoundments. The availability of these new technologies allows companies to increase profitability and minimize environmental risks, which are conducive for achieving sustainable mining.

Jan 1, 2003

By Wayne Loel

THE application of aerial photographs to all phases of geologic mapping is set forth, indicating the advantages to be gained in different types of country and under varying climatic conditions, Methods of field and office procedure are given from a geological point of view, as well as suggestions regarding the best methods of aerial mapping for different uses and under varying field conditions, including the study of submarine geology. Aerial photographs with accompanying geologic maps are shown to illus-trate the appearance from the air of different geologic features under varying climatic and topographic conditions.

Jan 1, 1938

By Walter Loel

THE application of aerial photographs to all phases of geologic mapping is set forth, indicating the advantages to be gained in different types of country and under varying climatic conditions. Methods of field and office procedure are given from a geological point of view, as well as suggestions regarding the best methods of aerial mapping for different uses and under varying field conditions, including the study of submarine geology. Aerial photographs with accompanying geologic maps are shown to illustrate the appearance from the air of different geologic features under varying climatic and topographic conditions.

Jan 1, 1938

By P. A. Mingione

"AEROPHINE@ 3418A is a unique sulfide mineral promoter produced by Cyanamid, based on phosphine (PH3) chemistry. It has proven effective as a collector for the sulfide minerals of copper and particularly lead (galena), as well as for secondary gold and silver values. AEROPHINE 3418A has widest application as a Cu and/or Pb collector for complex ores of Cu-Zn and Pb-Zn, which frequently have significant quantities of associated precious metal values. Advantages shown in the use of AEROPHINE 3418A are improved selectivities against Zn- and Fe-sulfides, increased precious metals recoveries, reduced total collector consumptions for Cu and/or Pb flotation, and increased flotation kinetics leading to higher recoveries of these values. Operating plant, pilot plant and laboratory test data from treating different ores are presented, demonstrating the advantages in use and preferred application of AEROPHINE 3418A.INTRODUCTIONCyanamid operates the only phosphine and phosphine derivatives plant in North America, located in Niagara Falls, Ontario. Specialty chemicals manufactured at this facility are used in many diverse applications, including solvent extraction reagents and textile flame retardants. A unique phosphine-based sulfide mineral promoter, AEROPHINE 3418A, is also produced. The origins of AEROPHINE 3418A promoter date back to the 1960's, when it was established that sulfide mineral collectors based on phosphine chemistry demonstrated efficacy. This new collector chemistry was found to provide flotation performance differing significantly from those of more traditional thiol collector chemistries such as xanthates, dithiophosphates, mercaptobenzothiazoles, thionocarbamates and those with xanthogen groups. Some of the advantages ultimately demonstrated by AEROPHINE 3418A promoter compared to these traditional collectors include:"

Jan 1, 1990

By Valeriano Antonio Corbellini, Marilda Macagnan, Rosana de Cassia de Souza Schneider, Tiago Bjerk, Mariela de Souza Vieira

The great potential of Brazil for the agricultural production makes our country a generator of agro industrial residues. In this context, the solid-state fermentation appears as a technology that shows alternative ways for those residues, adding values to these raw materials, through the production of substances of industrial interest, besides reducing the possible environmental problems. The main objective of this study was to apply the bovine fat residue associated to the garden grass for the fungal lipase production. Initially, 75 microbial cultures were isolated from garden grass samples after incubation of the mixture with bovine fat. From these cultures were selected the filamentous fungi, whose lipase production abilities were evaluated. The isolation and the selection were accomplished by using a differential culture medium containing Tween 80 as inducer substrate of lipase production. The colonies with lipolytic potential were detected by the presence of white precipitation haloes on the agar. With agro industrial residues the best lipase producer fungus was identified as Penicillium sp in 6 days of solid state fermentation. The crude enzyme obtained was tested in transesterification process for the biodiesel production.

Jan 1, 2008

By Marilda Macagnan, Rosana de Cassia de Souza Schneider, Valeriano Corbellini, Tiago Bjerk, Mariela de Souza Vieira

The great potential of Brazil for the agricultural production makes our country a generator of agro industrial residues. In this context, the solid-state fermentation appears as a technology that shows alternative ways for those residues, adding values to these raw materials, through the production of substances of industrial interest, besides reducing the possible environmental problems. The main objective of this study was to apply the bovine fat residue associated to the garden grass for the fungal lipase production. Initially, 75 microbial cultures were isolated from garden grass samples after incubation of the mixture with bovine fat. From these cultures were selected the filamentous fungi, whose lipase production abilities were evaluated. The isolation and the selection were accomplished by using a differential culture medium containing Tween 80 as inducer substrate of lipase production. The colonies with lipolytic potential were detected by the presence of white precipitation haloes on the agar. With agro industrial residues the best lipase producer fungus was identified as Penicillium sp in 6 days of solid state fermentation. The crude enzyme obtained was tested in transesterification process for the biodiesel production.

Jan 1, 2008

By R. W. Culley

"In many areas of Saskatchewan, known gravel deposits have been depleted or are diminishing rapidly; in other areas, particularly in the north, demands for all-weather highways and access roads are far exceeding the supply of gravel sources with which to surface them. These two problems have made conventional methods of air-photo and ground surveys insufficient for gravel location. In the first case, hauling costs on construction now warrant searching for buried deposits and for smaller, less obvious surficial deposits that may be closer to the project. In the second case, search and access conditions are so difficult and costly that the ratio of successes to failures must be kept very high. The Department of Highways has long been aware of the oncoming scarcity of quality gravel deposits and is continually investigating ways of forestalling it. One of these ways is the use of airborne geophysical methods that permit rapid coverage of large areas and that sense and discriminate between earth properties to a significant depth below ground surface. In 1967, the Department began an investigation of an airborne conductivity survey method called INPUT*, or ""Induced Pulse Transient'', leading to a trial in 1968 and data analysis in 1969. The results of this trial initiated• modifications to the technique to improve its sensitivity for mapping shallow deposits. Part way through this modification in 1970, a decision was made to change to an airborne resistivity survey method called EPHASE*. Trials with this technique were conducted and analysed in 1971. This paper is an explanation of the E-PHASE system and a summary of the results from one of three areas mapped in 1971."

Jan 1, 1973

By I Doye

Acid mine drainage is a serious environmental problem caused by the oxidation of sulfide minerals responsible for highly acidic, sulfate and metals-rich drainage. Several methods of mine waste management have been developed that reduce liabilities on environment. Layered co-mingling of waste rock with compacted tailings, covers with capillary barriers effect, and co-disposal of waste rock and tailings are these new methods which are used to reduce the formation of acid mine drainage. These methods shield waste rock dumps from oxygen. These techniques could prevent oxidation reaction. In this study, alkaline industrial wastes are used with acid generating tailings to inhibit acid mine drainage. The alkaline wastes selected are cement kiln dust (CKD) and red mud bauxite (RMB). These alkaline materials are used to keep neutral conditions in the fine material layer and to inhibit the metabolic activity of Thiobacillus ferroxidans which catalyses the oxidation of sulfide minerals. A series of timed static leaching tests were performed by reacting samples of mine tailings with two, five and ten per cent alkaline material in order to characterise geochemical balance between liquid and solid phases. Column tests have been set up with oxidised tailings, waste rock, CKD, and RMB. Column tests have been carried out to simulate layered co-mingling, covers, liners, and co-disposal of waste rock and tailings. Column leach tests were conducted in order to investigate the long-term neutralisation potential of alkaline materials and the drainage water quality. Bacteria counting were performed on each sample after testing. The results obtained show that the addition of alkaline materials permit the retention of near neutral conditions in the fine material layer, thus increasing water quality and preventing bacteria development. In fact, the pH results show that the use of five per cent, ten per cent CKD or ten per cent of a mixture of CKD and RMB permit the retention of neutral pH conditions in the reactive layer. At these percent rates, the concentrations of Al, Fe, Cu, Zn, and SO4 in solution are significantly reduced compared to those obtained with the tailings only. In presence of waste rock, the relative position of the fine material layer is important. When the fine material layer overlaying reactive waste rock is composted of reactive tailings with ten per cent CKD and ten per cent (CKD:RMB), a delay was observed before achievement of near neutral pH. The neutral pH conditions remain stable over time. The mixture of CKD and RMB provides a better short-term neutralisation than the use of CKD alone. The use of alkaline materials is beneficial in order to reduce the concentrations of Fe and other metals such as Cu and Zn as well as the number of viable bacteria. The use of ten per cent RMB alone does not involve the neutralisation of reactive tailings. In the cases where the fine-grained layer are below or mixed with the waste rocks, the near neutral pH values are directly reached with ten per cent CKD. However, the pH values decrease rapidly and the number of viable bacteria increases.

Jan 1, 2003

By G. E. S. Lima, I. K. R. Andrade, N. G. Viana, R. O. G. Martins, L. M. Sathler, L. G. Pedroti, C. M. M. E. Torres, W. E. H. Fernandes, C. M. Silva, M. A. Caetano

In Brazil, kraft pulp mills are rapidly expanding and industrial waste generation is increasing. Technical feasibility of using solid wastes from kraft pulp mills as raw material in other industries may be an interesting approach to manage environmental and economic aspects of the industry. This paper proposes the incorporation, in different proportions (0, 2.5, 5 and 7.5%), of alkaline solid wastes from pulp mills, namely dregs and grits, to clinker in the Portland cement industry. The research was carried out in two steps: (i) characterization of dregs, grits and clinker; (ii) laboratory testing (determination of soundness by the Le Chatelier method, determination of setting times, determination of water content of the paste with normal consistency, determination of compressive strength and static modulus of elasticity). The results showed that the addition of dregs and grits to the clinker up to 2.5% were feasible according to the Portland cement Brazilian standards.

Mar 1, 2017

By Charles G. Kemsley

IN view of the truly remarkable development of special steels for special purposes, the mining industry has for years looked forward to a time when steel makers would come forward with a product which would be an improvement over the straight carbon steel which has always held the field for drilling rock. In order to avoid making changes in conventional shop practice, the industry has perhaps been too insistent upon obtaining a water hardening steel which could be handled in the blacksmith shop by long established methods. As early as 1932 or 1933, an oil-hardening tool-steel of the one per cent carbon, plus chrome, plus molybdenum type was applied to hollow drill steel. It was known as a hard as well as a tough steel, and one that, theoretically, should give a good account of itself as a rock drill, if properly heat-treated; and so it has proved in actual trials. There were numerous deterrents which retarded adoption of this steel. For several years there has been a constant improvement in the drilling qualities of the straight carbon steel, and, considering the higher unit price ? of the alloy, there has been considerable doubt in the minds of some mining? men as to what advantage there might be in the use of alloy over straight carbon for hollow drill steel. The alloy being an oil-hardening steel, its adoption meant having two kinds of steel in the mine, for a time, and that spelled trouble, unless some positive means of identification was adopted. The hardening and forging ranges of alloy steel being narrow also made necessary much closer control over these operations if poor results were to be avoided. These thoughts undoubtedly prevented its use becoming wide-spread, for, as a matter of actual record, less than fifteen per cent of all the hollow drill steel used in Canada today is alloy.

Jan 1, 1942

By Charles G. Kemsley

MR. C. R. WHITTEMORE: It is interesting to note that the mining industry is making increased use of alloy steels for drilling. They will undoubtedly lead to greater footage at lesser cost. Mr. Kemsley states that, for use in hard ground, the shanks are brought to a hardness of 435 to 440 Brinell by heating them to approximately l,800°F. It seems to me that this temperature is excessively high-it is considerably above the critical point of the steel. The only effect of such a high temperature is to lessen considerably the impact resistance of the steel. The possibilities of an oil quench, followed by a tempering draw which does not lessen the hardness of the steel too much but increases its toughness, might well repay further study; also the temperature control, a factor which depends on the composition of the steel. However, service results are undoubtedly the best criterion of practice. MR. KEMSLEY: I would like to point out that the steel is not quenched at 1,800°F. After heating to this temperature, it is laid aside to cool gradually; this high temperature is necessary to produce the required hardness by simple normalizing-cooling in still air. We all know that ideal conditions for hardening steel demand salt baths and furnaces with automatic temperature control, but for most companies the cost of such equipment having sufficient output capacity is prohibitive. The end we are trying to attain is to make good drills at a cost that will be within the means of any mine.

Jan 1, 1942

By A. V. Tarasov

In order to improve technical, economic and environmental performance of hydrometallurgical processing of intermediate products containing copper and nickel, the Gintsvetmet Institute and the IMET Institute of the Russian Academy of Sciences have conducted studies into the efficiency of the use of alternating current of industrial frequency on processes applied for hydrochemical leaching of various copper- and nickel-containing materials. It has been found that: 1.Imposition of alternating current over the process of leaching of softly reduced nickel oxide with recycled copper sulfate solutions resulted in an increase by 20 to 30% of the rate of the copper cementation process and reduced by 20% its activation energy. At the same time, the recoveries of nickel, cobalt and iron to the leach solution increased up to 82.2%, 78.5% and 57.1%, respectively, and that of copper to the cement precipitate up to 74%. Optimal process conditions have been identified with respect to the current density, electrode material, copper concentration in solutions and the process temperature. 2.In the process of hydroelectrochemical sulfuric acid leaching of nickel and copper sulfides, the grain size, the phase form of sulfides, the solution composition (H2SO4, Cl?, Cu2+, Fe3+)and the current amperage had an effect on the nickel recovery to the solution, which reached 90%, while the degree of copper transfer to solution did not exceed 20%. The process of hydroelectrochemical sulfuric acid leaching of nickel and copper sulfides with an addition of Cl? made it possible to selectively recover nickel into the leach solution along with concentrating copper in the leach residue. 3.When subjecting samples of commercial-grade magnetic fractions of converter matte to sulfuric acid leaching, the imposition of electric current, the concentrations of sulfuric acid and chloride ion in the solution and the duration of the reaction process had an effect on the process. The nickel recovery was 85% and that of cobalt and iron was 95% and the recoveries reached 97.5%, 98.3% and 99.8% as a result of repeated treatment of the primary residue under similar process conditions. Up to 75% of copper, 75% of sulfur and 99.0-99.5% of palladium was concentrated in the solid reach residues. The experimental data obtained indicates that the use of AC for hydroelectrochemical sulfuric acid leaching for separation of copper- and nickel-containing intermediate products has favorable prospects.

Jan 1, 2003

By E Philippa, J Vitanza, C Hawtin, B Miller

B Miller , E Philippa , C Hawtin and J Vitanza

Mar 22, 2022

By C. Perea, O. Restrepo, C. Ihle, H. Estay

In this study, research on the use of monosodium glutamate for copper leaching, with emphasis on the thermodynamics and oxidant characteristics, is presented. Copper dissolution was conducted following a hydrometallurgical route, using monosodium glutamate in alkaline solutions. The effect of oxidizing agents such as hydrogen peroxide (H2O2) and potassium permanganate (KMnO4), and the efficiency of copper leaching with glutamate compared with glycine have been studied. Results, obtained at room temperature, showed 92% recovery of copper using 0.03 M hydrogen peroxide, 0.5 M monosodium glutamate at a pH of 9.44.

Mar 2, 2022

By M. Deniz Turan, HASAN NIZAMOGLU, MÜCEVHER TURAN, RAMAZAN ORHAN

Tailings, or flotation waste, formed during copper production may be considered in the class of valuable wastes because of the amount of copper they contain. With the decreasing grade values of copper ores, the utilization of wastes like tailings that carry certain amounts of copper as secondary sources has become a necessity in both the economic and environmental senses. This study was carried out with the aim of using ammonium derivatives for the recovery of copper from tailings waste produced during copper production and utilizing their complex formation characteristics. In the conditions of six hours of leaching at 30 °C in the presence of 22.5 percent ammonium hydroxide and 100 g/L ammonium persulfate, 91.47 percent of the copper was transferred into the solution, while iron was not transferred, indicating that copper can be selectively recovered from tailings.

By Hasan Nizamoğlu, M. Deniz Turan, MÜCEVHER TURAN, RAMAZAN ORHAN

Tailings (flotation waste) that is formed during copper production may be considered in the class of valuable wastes due to the amount of copper it contains. Owing to the decreasing grade values in copper ores, utilization of wastes such as tailings that carry certain amounts of copper as secondary sources has become a necessity in both the economic and environmental sense. This study investigated the usage conditions of five different ammonia salts as leaching reactants for the purpose of selective extraction of copper from tailings. For this purpose, the effects of parameters such as leaching temperature and leaching time were examined at different concentrations of ammonium hydroxide, ammonium carbonate, ammonium nitrate, ammonium chloride, and ammonium persulfate. The copper extraction efficiency in the case of using the aforementioned salts by themselves were listed as (NH4)2CO3 (73%) > (NH4)2S2O8 (69%) > NH4OH (64%) > NH4Cl (42%) > NH4NO3 (40%). The highest copper extraction efficiency was obtained in the leaching process that was conducted with the solutions obtained by mixing ammonia salts in the best conditions. Accordingly, as a result of 6 h of leaching at 30 °C in the presence of 22.5% NH4OH and 100 g/L (NH4)2S2O8, 91.47%of the copper was transferred into the

Jun 3, 2020

By H. R. Hammond

The situation of The Consolidated Mining and Smelting Company of Canada Limited, or Cominco, may be somewhat unique in that the Company is not only a manufacturer of ammonium nitrate, but as a mining company is a major user of its own product. This situation has resulted in highly successful application of ammonium nitrate-oil explosives. Several noteworthy techniques have been developed and others have been improved. Use of this material in the mining industry has led ammonium nitrate producers to adopt the term nitro-carbo-nitrate or INN for ammonium nitrate-oil blends. A small blending plant at Cominco's largest mining property, the Sullivan Mine, at Kimberley, B.C., is producing more than 80% of all the explosive used at the Sullivan, and is supplying two other Cominco mines. Application has required intensive research to determine the best forms of ammonium nitrate for use in small holes drilled for development and long-hole stoping. It has led not only to experiments to determine the best blending oil, but also to development of loading techniques to the point where NCN is being moved through loading tubes over 700 feet. It has required research into mining practices such as hole arrangement and blasting of development cuts. It has resulted in the development of a special product for secondary breaking. All this has been accompanied by the recognition of the importance of insuring safe practices at every stage.

Jan 1, 1963

By L. C. Atkinson, E. A. Azrag, T. M. Hanna

The results of using a simple analytical solution and a relatively complex numerical model to estimate ground water inflow to an open pit mine are compared. The analytical solution assumes lateral, radial flow to a fully penetrating pit in an idealized confined aquifer, whereas the numerical model simulates fully three-dimensional flow to a partially penetrating pit from a water table aquifer. The latter is a more realistic simulation of the problem, but the former method is significantly easier to use. Comparison of the results obtained with the two methods for some typical hydrogeologic conditions encountered in mining yields ratios between them in the range of 0.2 to 0.6. These values can be used as a coefficient in the Pit Flow analytical solution to produce reasonable estimates of in-flow even when there are significant differences from the idealized conditions implicit in its application.

Jan 1, 1995

By T. M. Hanna

The results of using a simple analytical solution and a relatively complex numerical model to estimate ground-water inflow to an open pit mine are compared. The analytical solution assumes lateral, radial flow to a fully penetrating pit in an idealized confined aquifer, whereas the numerical model simulates fully three-dimensional flow to a partially penetrating pit from a water table aquifer. The latter is obviously a more realistic simulation of the problem, but the former method is significantly easier to use, Comparison of the results obtained with the two methods for some typical hydrogeologic conditions encountered in mining yields ratios between them in the range of 0.15 to 0.60. These values can be used as a coefficient in the Pit Flow analytical solution to produce reasonable estimates of in-flow even when there are significant differences from the idealized conditions implicit in its application.

Jan 1, 1992