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By William E. Ford, Edward Salisbury Dana

The monoclinic Wolframite Group and the tetragonal Scheelite Group are included here. Wolframite Group WoIframite (Fe,Mn)W04 a : b : c = 0.8300 : 1 : 0.8678 B = 89' 22' Hiibnerite MnW04 048362 : 1 : 0.8668 89' 73' WOLFRAMITE. Monoclinic. Axes a : b : c = 0.8300 : 1 : 0.8678; B = 89' 22'. mm"', 110 A 1TO = 79" 23'. ay', 100 A 101 = 62' 54' at, 100 A 102 = 61" 54'. $', 011 A 011 = 81" 54'. Twins: (1) tw. axis c with a (100) as comp.-face; (2) tw. pl. k (023), Fig. 449, p. 171. Crystals commonly tabular (1 a (100); also prismatic. Faces in prismatic zone vertically striated. Often bladed, lamellar, coarse divergent columnar, granular. Cleavage: b (010) very perfect; also parting (1 a (100), and 11 t (102). Fract,ure uneven. Brittle. H. = 5-5.5. G. = 7.2-7.5. Luster submetallic. Color dark

Jan 1, 1922

By Chung Yu Wang

MINING ENGINEERING presents the fourth in a series of articles on strategic minerals. Preceding it are "Cobalt" in January, "Sulphur" in May, and "Nickel" in August. Here, an authority in the field analyzes the resources, production, uses, defense impact and future outlook of Tungsten

Jan 10, 1951

By A. Ploszajski

This item examines the history and uses of tungsten, from discovery to superalloys via the lightbulb and electron beam instruments.

Apr 1, 2015

By W. P. Sykes

TUNGSTEN serves mankind in two major roles. The first of these is represented by the tungsten filament of the incandescent electric lamp, a common article of commerce. In the field of hard alloys it plays its second substantial part. A fortunate combination of physical properties in this metal ac- counts for its efficient service as a source of illumination. Tungsten melts at about 3400°C, has a relatively low vapor pressure and at the same time sufficient strength, both hot and cold, to serve satisfactorily as filaments, which may range in diameter from 0.060 to 0.0005 in. In the early days of the incandescent lamp, the pioneers realized the importance of using a substance of high melting point for the source of light. The metals osmium (mp approx. 2700°C) and tantalum (mp approx. 2850°C) were both employed to some extent. Tantalum actually attained some commercial importance in this field because it could be drawn into small wires of appreciable length. DUCTILE TUNGSTEN WIRE Before the year 1908, tungsten was considered a nonductile metal, since no one had succeeded in overcoming the brittleness so typical of the unworked metal at room temperature. The methods employed today in producing ductile tungsten wire were developed over a period of years. The process was largely determined by the exceedingly high temperature required to melt this metal. Even today the difficulties involved in producing an appreciable quantity of pure

Jan 1, 1953

By Donald I. Bleiwas

The U.S. Bureau of nines evaluated the potential availability of tungsten from 57 tungsten mines and deposits in 19 market economy countries (1). The 38 properties that were producing at the time this study was performed contain approximately 375,000 tons1 of W03 (tungsten trioxide). The total estimated recoverable resource from all properties studied, both producers and nonproducers, was 1.2 million tons W03 (demonstrated level). Approximately 143,000 tons of W03 is recoverable from producing properties with costs at or below the January 1983 market prices. The study indicates that by 1990 production from currently operating mines in market economy countries will decrease as their demonstrated resources become exhausted. Some of this potential decline may be offset by lower than anticipated levels of market demand, discoveries of additional resources at producing mines, development of other known deposits, and/or discoveries of new deposits. Development of new tungsten resources in market economy countries will likely result in costs higher than exist at currently producing properties. The People's Republic of China has been steadily increasing production and export of tungsten in various form and currently supplies about 25 pct of U.S. imports. China's tungsten mines are large, high-grade operations capable of producing at relatively low cost. These factors, coupled with China's apparent need for foreign exchange, could lead to further expansions of production and exports from China, with a consequent increased dependence by market economy countries on China for tungsten requirements and a threat to the survival of the market economy countries' tungsten industries.

Jan 1, 1984

By Zay, Jeffries

THE effect of thoria (ThO2) on grain growth in tungsten was discussed in some detail in a paper presented before this Institute by one, of the authors in 1918.1 In that paper it " was assumed that the, thoria was present in the tungsten entirely as a mechanical mixture. There was no indication in the experiments described that even a trace of the thoria was in solid solution in the tungsten. Langmuir,2 however, observed that thoriated-tungsten filaments under certain conditions showed electron emissions many thousand times greater than unthoriated tungsten at the same temperature. He concluded from his studies that a slight amount of the thoria had dissociated on heating the filament to a temperature near 220°. C. At this temperature and higher, part of the thorium diffuses to the surface of the filament where it evaporates at. a much faster rate relatively, than the tungsten, and also at a rate, nearly as fast as it is brought to the surface by diffusion: If the temperature is lowered to say 1800°,. C., diffusion of the thorium atoms to the surface is more rapid than evaporation, sown adsorbed film of thorium atoms is produced on the surface of the tungsten filament. The electron emission is governed by the outside layer of atoms so the emission from such a filament might be expected to approxi¬mate that of a thorium filament at the same temperature. PRESENCE OF METALLIC THORIUM IN THORIATED TUNGSTEN If the filament containing the adsorbed film of thorium. is heated to a sufficiently high temperature, the thorium atoms evaporate: rapidly and the electron emission becomes more nearly that of tungsten. On cooling again to 1800° C., or thereabouts, the emission 'builds up gradually to a maximum. The filament containing the adsorbed layer of thorium atoms is said to be "activated." By studying the rates of activation under different conditions of prior thermal treatment and at different temperatures, Langmuir was able to arrive at an estimate of the

Jan 1, 1927

Local conditions at Hatches Creek are described, together with the mineralogy, mining and treatment of tungsten ores, with particular reference to procedures adopted by Pimer Mines, N.L.The Hatches Creek tungsten field covers an area of about 20 square miles in: Central Australia; 285 miles' N.E. of Alice Springs. Access is by rail to Alice Springs, then by 200 miles of bitumen highway to Barlo Creek and 8,5, miles of bush track to the field. Passengers can also reach the mines by... A semi-desert climate prevails Rain; generally in the form of thunderstorms falls in the summer months: December to March. Average annual rainfall is approximately 15 inches but there is great variation from year to year, occasional droughts being followed by torrential downpours. Vegetation is sparse except in the wide creek beds. Surface water occurs in rock holes some of which, spaced miles apart, carry permanent water...

Jan 1, 1955

By P. W. Billwiller

Abstract The Britannia Mining and Smelting Company, Limited, have replaced diamond drills with percussion drills and tungsten: carbide bits for most of their blast hole drilling operations and have thereby reduced ore breaking costs. Two-inch Carset bits .are used, with one-inch hexagonal Atlas Chippewa alloy steel in 3-foot .and 6-foot lengths. Locally made couplings of Atlas SPS 245 alloy steel connect the rods. The machines used are 31½-inch automatic leyners with lugged or anvil block chucks. For drilling holes below the horizontal, the lugged machines with special adapter rods made from 114- inch solid round Atlas SPS 245 are required. These rods are lugged at one end and a water hole is drilled for six inches into the other end. Over this rod is placed a water swivel which permits the water or air to be sent directly into the steel. A decreased cost per foot, increased footage per shift, and the use of standard equipment and crews are some of the main advantages of tungsten carbide drilling over diamond drilling. Introduction Long-hole drilling with percussion drills and sectional steel was introduced in several American mines some twenty-five years ago. It did not prove very successful, however, because the rapid gauge loss in steel bits necessitated the use of very large starter bits. This in turn rapidly fatigued the straight carbon-steel then in use, made it difficult to maintain the couplings, and resulted in a slow drilling rate. The introduction of the tungsten carbide insert bit and alloy drill still has changed this picture and opened real possibilities for the application of percussion drills to blast-hole drilling. If this type of bit had been perfected ten years ago, much of the research work and experimenting done to apply diamond drills to ore breaking would have gone toward developing the application of the tungsten carbide bit to this problem.

Jan 1, 1950

By J. W. Reynolds

Introduction The Sullivan mine, at Kimberley, B.C., is the principal source of ore for the Consolidated Mining and Smelting Company of Canada, Limited. Current production amounts to about 2,500,000 tons of lead-zinc ore a year. With approximately 1,600,000 feet of percussion drilling and 700,000 feet of diamond drilling being carried on each year, any improvements in drilling practice are important. Testing of new equipment and drill bits is a major function of the Testing Department at the mine. Tungsten carbide bits have been the subject of many tests since 1947 and have been used in operations since 1948. This paper details with the methods of testing and gives comparative data on performance and costs for tungsten carbide bits as compared to steel bits. Operational use of tungsten carbide bits started in April, 1948, and the extent of application has increased considerably since that time. The scale of employment is illustrated in Table I, which also shows other statistics on the use of carbide bits. Up to the present time eighteen types of carbide bits or tipped steel, as made by six different manufacturers, have been tested. In general, one supplier's bits have been used in operations, but some large-scale operational tests have been carried out with other types. The types tried are shown in Table II. To date they have been, the subject of 33 tests, covering the destruction of 804 bits over an observed footage of 42,586 feet.

Jan 1, 1951

By A. Eugene Lillstrom

I N the development of iron mines and production of iron ore from the Marquette range, drilling blast-holes is an important phase of the mining cycle. The ground drilled in ore production can be classified into two main categories, soft hematite and hard hematite or magnetite. Within these categories the material exhibits a wide range of penetrability by percussion drills. Development work encounters various types of rock. Slate and altered basic intrusives constitute the softer types commonly encountered. Harder materials are represented mainly by greywacke, quartzite, iron formation, and diorite.

Jan 12, 1951

By Gunderson C. T

The use of carbide tipped integral drill steels and detachable bits is discussed in relation to the means of drilling or cutting employed. It is stressed that only by correct use can the full value of these tools be realised.Factors affecting carbide quality, the design of shanking steels and the requirements and techniques of brazing in inserts are considered.It is essential that the brazed jointing between carbide and steel be strong but ductile. The methods used for the manufacture of carbide tipped tools are briefly outlined.INTRODUCTIONIn recent years the application of tungsten carbide to various mining tools in the mining industry, has developed to the stage where it is now regarded as an essential item in the production of coal and metal ores. In fact it is claimed that certain mining operations would not be possible if it were not for the benefits obtainable from the characteristic properties of tungsten carbide. The advantages of this hardmetal have, to some extent, influenced manufacturers to revise design specifiations of some machines, while againsome machines have actually been designed with tungsten carbide as their basic medium for operation.In general the applications fall into the following three categories:(a) Drilling hard rock by percussive means.(b) Drilling soft rock and coal by rotary means.(c) Coal cuttingThis paper is concerned with tungsten carbide tools associated with these three activities in Australia, the effectiveness of their application and significant points in their design and manufacture.

Jan 1, 1958

By J. C. Heaslip

Introduction The greatest single advance in rock drilling practice since the advent of percussion drills was the introduction of tungsten carbide tipped rock drill?bits. The evolution of rock drills has been a long and highly diversified effort which has culminated in the highly refined ?drilling machines we know today, but because of the spectacular possibilities shown by ?detachable bits, and especially those with tungsten carbide inserts, there is little doubt that the cutting face of .the drilling unit has in recent days stolen the spotlight of rock drilling research and commanded the major attention of the rock drilling fraternity. "Solid" Steels Until about twenty years ago, all rock was drilled with a one-piece rod with a bit forged on one end. In the early years of the art of rock drilling, there was tried every conceivable pattern of :bit from the single-edge chisel to elaborate geometric 'designs. In the end, it was found that a 4-point bit with two sharpened cutting edges crossing each other at right angles would serve best for most rock drilling requirements. For some years thereafter, the main concern of drill manufacturers was .to obtain the best possible steel for drill rods. This was not accomplished as easily as might be thought. The cutting end had to be such that it could be hardened sufficiently to do its work without premature dulling and yet not so brittle as to shatter under the multiple impacts.

Jan 1, 1951

By I. S. Parrish

This article offers one of the infrequent looks at Chinese mining. It includes a brief review by Parrish of a tungsten symposium held there and his comments on and impressions of the mines he visited. In early Oct. 1981, a Symposium on the Geology of Tungsten was held in the Peoples Republic of China. There were approximately 100 participants. Half of them were Chinese. The remainder included representatives of the United Nations, geologists from other nations in Southeast Asia, and 10 invited specialists from other countries. The invited guests included K.F.G. Hosking of the Camborne School of Mines, United Kingdom; C.S. Hutchinson of the University of Malaysia; K. Mattson of LKAB Int. AB, Sweden; T. Kwak of Latrobe University, Australia; K. Sato and S. Ishihara of the Geological Survey of Japan; M. Clarke of the Department of Mineral Resources, Indonesia; P. Bateman of the US Geological Survey; and the author. R. Horsnail of Amax was also invited but was unable to attend because of delayed visa clearance. The meeting was noteworthy because the Chinese were presenting more than half the papers. In addition, following the formal session, everyone was taken to the famed Jiangxi tungsten district and toured four mines there. Organization and Background The idea for a symposium on tungsten geology was brought up in late 1979 during a visit to China by the Economic and Social Commission for Asia and the Pacific (ESCAP) and, in particular, by members of the Regional Mineral Resources Development Centre (RMRDC) of the United Nations. Discussions continued and in the spring of 1981 invitations were sent to selected geologists throughout the world. China's Ministry of Geology handled arrangements, scheduling, and logistics. Travel to China and all correspondence before the symposium were coordinated by the Bandung, Indonesia Bureau of RMRDC. All costs in China were met by the Peoples Republic of China. Airfares and "per diem" enroute for participants were paid by respective governments, sponsors, or individuals. On Oct. 10, visiting participants entered China from Hong Kong. The author and a few others traveled by train to Guangzhou (Canton). Most of the group flew in the next day. The entire group was then taken to Nanchang, traveling by sleeper train and arriving on Oct. 11. The symposium group stayed at the Kiangsi Hotel, where the meetings were held. Meetings Oct. 11 was a day of orientation and rest. The group was taken to an art museum and treated to a Chinese opera movie. The formal meetings began on Monday, Oct. 12. Simultaneous translations aided presentations, though more than half the Chinese speakers delivered their talks in English. The acoustics and sound system were excellent, and the Chinese provided 35-mm and overhead projectors. There was no screen, however, and the yellow, painted wall that was used detracted from projection clarity. In general, the Chinese papers were detailed, thoughtful, and professional. Some, naturally, were stronger than others. Taking them as a unit, one derives the following sequence to the Chinese approach to tungsten exploration: (1) Geologic investigations with mapping at a scale of 1:200,000 accompanied by only minor geochemical or geophysical work. (2) Geophysical investigation with regional gravity and magnetic surveys directed toward identifying deep, tectonic systems and seeking granites in thick, crustal environments. (3) Geochemical sampling in-

Jan 6, 1982

By L. Graydon Carpenter, Donald E. Garrett

Probably the largest single tungsten deposit in the U. S. is one that has yet to produce any tungsten; it is not even listed in tables showing U. S. reserves. This deposit is at Searles Lake, Calif., where the brine contains about 70 ppm WO3. Small though the concentration is, the amount of brine in the lake is so great that it is estimated at 170 million lb of WO3 (8.5 million units), equaling the total of all other known reserves in the U. S. This dry lake is located in the basin formed by the Argus and Slate ranges in the northeastern corner of the Mojave Desert (Fig. 1). It consists of a massive salt body some 35 sq miles in extent, varying in thickness from 0 to 120 ft and containing more than 3 billion tons of salt. A central section of about L. G. CARPENTER and D. E. GARRETT are with the Research Dept., American Potash & Chemical Corp., Trona, Calif. TP 47881. Manuscript, Nov. 4, 1958. AlME Trans., Vol. 214, 1959. 8 sq miles is exposed salt; the remaining area is overlain by mud. Except for the exposed sodium chloride (10 to 15 ft thick) the body consists of a very complex and heterogenous mixture of soluble crystals, containing at least eight major phases. It is only about 53 pct solid, the voids being occupied by a dense brine which is the raw material for two chemical companies operating in the valley.

Jan 3, 1959

By Tingting Li, Guodong Li, Dezhou Wei, Cong Han, Shuling Gao, Yanbai Shen

"The aim of this study is to solve the problem of tungsten leaching from scheelite concentrate using sodium hydroxide in the presence of phosphate by an autoclaving process, which is one of main development techniques for tungsten recovery. To understand the applicability and leaching performance of tungsten leaching from scheelite concentrate, the main work is to investigate the effects of leaching parameters such as initial concentrations of NaOH and Na3PO4, reaction temperature, stirring speed, liquid-to-solid ratio and reaction time on WO3 dissolution rate to obtain the optimal leaching conditions. The chemical composition and phase composition of the samples were evaluated by means of XRF and XRD. The content of WO3 in the leaching residue obtained via washing, filtering and drying was analyzed by thiocyanate spectrometric method. The optimal leaching conditions were found to be NaOH concentration of 6.76 mol·L-1, Na3PO4 concentration of 1.35 mol·L-1, reaction temperature of 180°C, stirring speed of 400 rpm, liquid-to-solid ratio of 2.0 and reaction time of 90 min. The results showed that tungsten leaching rate of 99.20% was reached under the optimal conditions. The technology exhibited superior leaching performance, which not only reduced the consumption of sodium hydroxide but also greatly decreased reaction time in comparison to a conventional autoclaving process. INTRODUCTION Tungsten is an important strategic metal, which is widely utilized in a variety of industries due to its high melting point, superior mechanical properties and heat-resistant performance [1-3]. The chief raw materials for the production of tungsten in nature are wolframite and scheelite [4, 5]. Among them, approximately two-thirds of the tungsten reserves contain scheelite deposits in the world [6, 7]. With the progressive exhaustion of high-quality wolframite resources, scheelite has become a predominant primary resource for the production of tungsten [8, 9]."

Jan 1, 2018

By J. P. BONARDI, William F. Boericke

BOULDER COUNTY, Colorado, ranked during the war years and until the end of 1918 as one of the foremost tungsten-producing districts of the world. In 1919 production fell off drastically, due to heavy importations of foreign ores from China, Burma and South America. So large were the imports that even after the enactment of a protective tariff in 1922 of 45c. per lb. on tungsten metal, equivalent to $7.14 per unit (201b.) of tungstic acid? (WO,), the stocks of metal in this country were extensive enough to supply the demands of industry, and prevent general resumption of mining by domestic producers. Even today there are only two producers in the Boulder district though at one time as many as twenty separate companies were in operation. About the same ratio holds for other tungsten-producing districts in the country, including California and Nevada. Total consumption of tungsten concentrate in terms of 60 per cent WO2 in the United States amounted to approximately 3790 tons in 1928, according to Frank L. Hess.' Of this amount, domestic mines contributed 1290 tons, and the rest, 2500 tons, was imported. Yet in 1917, with tungsten concentrate selling at $20 per unit, the Boulder district alone produced 2707 tons, indicating the effect of enhanced ore price upon production. It is believed by American tungsten miners that, given a sufficiently high tariff, all the demands of industry can be met by domestic production without placing a prohibitive burden on consumers. For instance, in steel manufacturing the percentage of tungsten entering into the manufacture is so small that, ?regardless of cost, it can constitute but a small fraction of the cost of steel to the buyer.

Jan 1, 1929

By Y. Guo, C. Cao

"China is rich in tungsten resource, but they are mainly associated minerals. The similar flotability of scheelite, fluorite, and calcite resulted in the difficult separation by flotation. This work summarized the current situation and the development of flotation reagents, technological process, and mineral processing equipments in China. Fatty acid served as the collector and water glass was the depressant to expand the flotability differences in traditional flotation technology. However the water glass inevitably influenced the flotation of tungsten minerals to a large extend, and the suppressed fluorite was difficult to recover by flotation. Abundant water glass lead to the bad settleability of the tailings and the tail water was difficult to circulate, resulted in serious environmental problems. Recent study proved that the selectivity of benzene armour hydroxyl oxime acid (BAHA) salts was adequate for the separation of tungsten minerals from fluorite, calcite and most silicate minerals without any depressant. By this way, sodium silicate was canceled completely in tungsten flotation, greatly improving the recovery of tungsten and the environmental problems caused by tail water treatment would be solved fundamentally. TUNGSTEN RESOURCES AND DISTRIBUTION IN CHINA China is rich in tungsten resources and the proved reserves accounted for 60% of the world's reserves [1]. However the wolframite has been dried up and the scheelite resources had become the main resource of the tungsten metal. Table 1 showed the most large and superlarge scheelite deposits in China. China has more than 40 large and superlarge scheelite deposits and the total metallic deserves is more than 3 million ton [2]. But most of the deposits were low-grade and the associated relationship was complicated. For example, scheelite was usually associated with wolframite, molybonite, bismuthinite, pyrite, fluorite, and calcite in Shizhuyuan and Yaogangxian mine."

Jan 1, 2016

THERE are three chief production zones of tungsten ore in China. In the Province of Kiangsi mines are located at Kanchow, East River, and West River. Their combined production is understood to amount to 300 to 350 tons of ore per month, and their original exportation is made through the port of Kiukiang, largely to Shanghai. The second zone is in Kwangtung Province, the mines there being at Tayulin. Produc-tion reaches about 200 tons per month and cargo is gen-erally exported through the port of Hong Kong. In the Province of Hunan approximately 25 tons of ore are produced monthly in the mines at Ton-on. Tungsten ore from Kiangsi and Kwangtung Prov-inces is generally about 70 per cent WO, (tungstic acid), while that from Hunan is of lower quality, run-ning about 65 per cent WO3. Kiangsi ore is received from the mines in 100-1b. and Hunan in 224-lb. gunny sacks. No repacking is done except as it is made neces-sary by the condition of the sacks. Kiangsi Province contains the Chinese districts pro-ducing the largest amount of salable wolframite or tungsten. Many districts west and south of Kiangsi have been found to have wolframite deposits.-Com-merce Reports.

Jan 1, 1928

By W. N. Marchant, P. T. Brooks, P. B. Altringer, R. O. Dannenberg

The US Department of the Interior, Bureau of Mines conducted laboratory tests to devise a process for recovering a marketable grade of tungsten from the brine of Searles Lake, Calif. The brine contains only 56 ppm W (70 ppm W03). Using ion exchange resins synthesized by USBM chemists, 98% oft he tungsten was extracted from the brine and 92% of the tungsten was recovered as a marketable iron-tungsten concentrate containing 44% tungsten as tungsten trioxide. Although major technical problems have largely been resolved, research is progressing to escalate testing in a process research unit to provide more reliable data for an economic appraisal.

Jan 8, 1979

By P. B. Altringer

The Bureau of Mines conducted laboratory tests to develop a process for recovering a marketable grade of tungsten from the brine of Searles Lake, Calif. The brine contains only 56 parts per million of tungsten (70 ppm WO3). Using ion exchange resins synthesized by Bureau chemists, 98 percent of the tungsten was extracted from the brine and 92 percent of the tungsten vas recovered as a marketable iron-tungsten concentrate containing 44 percent tungsten as tungsten trioxide. Although major technical problems have largely been resolved, research is progressing to escalate testing in a process investigation unit to provide more reliable data for an economic appraisal.

Jan 1, 1978