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By V. Ramachandran

In view of the increasing environmental regulations that have been promulgated in the last 30 years, non-ferrous smelters and refineries have learnt to handle effectively the process waste streams that need to be bled from the system for impurities' control The cations of concern are copper, lead, zinc, cadmium, mercury, thallium, nickel, silver, sodium and potassium. Anionic species of arsenic and selenium also need to be addressed, Sulfates and chlorides-not a major concern at present-have come under scrutiny in the recent past. The current paper reviews several treatment options with reference to a) types of waste streams processed b )process chemistry c)discharge options and recovery of treated water and d) sludge disposal The long term goal of any smelter and/lor refinery should be to achieve zero liquid discharge from the plant. Methods to obtain zero discharge are discussed.

Jan 1, 2003

By V. Ramachandran

In view of the increasing environmental regulations that have been promulgated in the last 30 years, non-ferrous smelters and refineries have learnt to handle effectively the process waste streams that need to be bled from the system for impurities' control. The cations of concern are copper, lead, zinc, cadmium, mercury, thallium, nickel, silver, sodium and potassium. Anionic species of arsenic and selenium also need to be addressed, Sulfates and chlorides-not a major concern at present-have come under scrutiny in the recent past. The current paper reviews several treatment options with reference to a) types of waste streams processed b)process chemistry c )discharge options and recovery of treated water and d) sludge disposal. The long term goal of any smelter and/or refinery should be to achieve zero liquid discharge from the plant. Methods to obtain zero discharge are discussed.

Jan 1, 2003

By Jianxin Zhang

A process, in which arsenic in the residue is transformed directly into scorodite and copper dissolves into the solution simultaneously, was studied. The process was carried out in acidic ferrous sulfate solution under oxygen pressure. The optimum conditions of the process were determined as follows: the initial H2SO4 concentration of 10 g/L; liquid/solid ratio of 10; Fe/As molar ratio in the feedstock of 1; the addition of calcium lignosulphonate was 1% of sludge; oxygen pressure, temperature and reaction time were 1.5 MPa, 150 °C and 6 h, respectively. Under these conditions, arsenic transformed to crystalline scorodite in size of 5–10 μm, and the transformation efficiency reached 97.60%; meanwhile, the copper was leached with a high efficiency of 93.34%. The stability of the leaching residue was evaluated by TCLP testing, and the results indicated the concentration of arsenic in the leaching solution was extremely low as 0.04 mg/L and met the standard of safe stockpile.

By Peter A. Dawson, Rod L. Leonard, Karen S. Christensen

An investigation has been completed of the technical and economic feasibility of construction of a processing facility for gold extraction from arsenical tailings, grading nearly 12 g/t, stockpiled near Snow Lake, Manitoba, Canada. The tailings dump is comprised of arsenopyrite (45%), pyrrhotite (12%), and gangue constituents. The majority of the gold occurs as fully encapsulated particles or as a solid solution in the arsenopyrite grains. The chemical composition of the Snow Lake tailings (referred to as "ore" throughout the remainder of the text) is shown in Table 1.

Jan 1, 1990

By Maciej Wrobel, Joerg Hammerschmidt, Dana Nurgaliyeva, Alexandros Charitos, Jochen Guentner

"Smelting of copper concentrates in the flash smelter generates a flue dust stream that contains a substantial amount of copper and accumulates more than half of the arsenic input to the smelter. In view of its high copper content flue dust recirculation to the flash smelter is common practice. Globally traded copper concentrates are affected by ever increasing arsenic contents and cause an increasing circulating arsenic load in flash smelter operation. Control of the arsenic level in the smelter slag becomes a challenge. This interaction of arsenic loaded copper feedstock, need for flue dust recirculation and slag quality control call for possibilities to reduce the arsenic load of the recirculated flue dust stream.The technology of partial roasting is known from pre-treatment of copper concentrates before smelting, and gold concentrates before cyanide leaching, to remove the harmful element arsenic. The partial roasting technology can be adapted for use in the purification of the flue dust. A major challenge for flue dust treatment is its extremely fine particle size compared to usual concentrates. For this reason Outotec developed a new process, which allows handling of such fine flue dust. This process solution provides an efficient possibility to reduce the arsenic burden in copper smelter operations.The suggested process aims at reducing the arsenic load to the smelter by treating the flue dust prior to recirculation to the smelter. The presented results are based on test work in the Outotec R&D-centre in Frankfurt. It is possible to remove 80-85% of the contained arsenic and to collect it in an arsenic trioxide residue with a concentration above 90%. The final off gas contains SO2 from decomposition of sulphates that are contained in the flue dust. The off gas stream is relatively small. We assume that it is possible to combine the off gas stream with other smelter process gas streams and to treat it in an existing sulphuric acid plant. Coal is used as fuel and as reductant to reduce pentavalent arsenate to trivalent arsenite. Arsenite can be kept in gas form at temperatures above 450°C. This permits separation of a calcine stream with arsenic levels of 0.2 – 0.3%, which is recirculated to the furnace.Outotec has a wide range of roasting testing facilities from lab-scale to pilot-scale. Outotec has both capability to modify and adapt technology to specific ore or concentrate requirements, but also the necessary infrastructure in its research centers in Frankfurt and Pori to do appropriate validation tests in lab and pilot scale size plants."

Jan 1, 2016

By M. J. Soria-Aguilar, F. R. Carrillo-Pedroza, S. Preciado-Nuñez

"Dust originated from the Iron Blast Furnace (BF) and the Basic Oxygen Furnace (BOF) containing alkalis and zinc are not completely recycled because due affects the process efficiency. These types of dust represents an economical lost as a consequence of values contents of iron and carbon. Several processes in aqueous media have been developed to treat the steelmaking dust. This work presents a laboratory study for reduce zinc and alkali containing in BF and BOF dust, using different acid and alkaline solutions and oxidants as ozone. The results obtained show that the elimination of zinc and alkalis can vary from 5 % to 80 % depending on the treatment conditions (the solution, the oxidant and the temperature). The dust obtained from this treatment can to be recycling to the steelmaking processes to recovery iron and carbon values.IntroductionEach one of the steel making industry processes generate several sub-products and residues containing useful units of iron, carbon and other elements that are or could be recycled to the productive process. Some of those sub products are the dust from the gas cleaning system of the blast furnace and the dust from BOF reductive process; such dusts are sent to the sedimentary lagoons. The dust represent a lost of 2 % of the total iron and coal mineral’s content feed to the process.The typical iron, carbon and zinc content of the blast furnace dust is approximately 40, 24 and 0.3 % and the content of the BOF dust are 50, 15 and 0.9 % weight respectively, with physics - chemical characteristics that became them susceptible to be agglomerated and feed to the blast furnace. But the high content of zinc does not allow recycling it into the process. At the blast furnace the presence of zinc propitiate the formation of film in the furnace wall; these elements are vaporized in the low section of the cube of the furnace and they are dragged by the gases to the top and condensed again at the cube. Part of these condensed materials strongly adheres to the furnace cover harming it and reducing the empty space of that section, causing eventually a severe perturbation of the ascendant gas flux [1]."

Jan 1, 2008

By Chen Tian, Tingfeng Wu, Qinghai Pang, Junhong Zhang, Zhijun He

Microwave technology as new aided tool has been applied on waste water treatment and metallurgical fields. This paper explores the affected factors such as microwave power, microwave irradiation time, polyaluminium chloride (PAC) amount and addition of phosphoric acid on treatment of Blast Furnace gas washing water by utilization of coagulation associated with microwave. Through the orthogonal experiment, the optimum experimental parameters were obtained in the course of treatment of 300 ml Blast Furnace gas washing wastewater: 396 W microwave power, 2 min of microwave irradiation time, 0.12 ml Added PAC and 0.8 ml added phosphoric acid. It indicates the affected factors in descending order on removal of SS in BF gas’s washing water: Added PAC level, added phosphoric acid level, time of microwave irradiation, and microwave power while those parameters that can affect suspended solids(SS)’s hardness reduction in descending order are added phosphoric acid level, added PAC level, time of microwave irradiation, and microwave power. Also, it demonstrates those parameters that can affect washing water’s turbidity in descending order: Added PAC level, time of microwave irradiation, added phosphoric acid level, and microwave power. The results showed that PAC coagulation associated with microwave on treatment of Blast Furnace gas washing wastewater has several benefits: short treatment time, strong sedimentation velocity and other excellent characteristics, it can effectively remove suspended solids in wastewater, the SS hardness and turbidity can be reduced.

Mar 1, 2017

By Samantha Beeson, Collin Poole

"This paper examines the development of two new selective flocculation techniques for recovering KCI values from low grade carnallite potash ore.Direct recovery of KCI was achieved using one of two mid-range molecular weight polymers, one non-ionic and the other strongly cationic, in conjunction with the same selective anionic dispersant. From initial response studies on pure minerals and selective flocculation tests on synthetic mixtures, investigations were extended to recover KCI values from a natural carnallite potash ore. A single-stage process achieved products grading up to 61.3% KCI at recoveries up to 85.4% for the cationic flocculant suite and up to 64.8% KCI with recoveries as high as 90.3% for the non-ionic flocculant suite, with dispersant and flocculant dosages of 150-250gr1 and 10-75gr1, respectively. These results clearly demonstrate not only the feasibility of treating such problematic ores at low reagent dosages, but also the potential elimination of desliming prior to froth flotation.The experimental results presented are considered in terms of the reagent adsorption phenomena present in the system and various aspects of floe formation and cleaning.IntroductionAs high-grade sylvinite potash ores become scarce, lower grade sylvinite and carnallite potash ores are becoming more attractive. However, these ores often contain large amounts (up to 15% by weight) of water-insoluble slimes which must be removed prior to KC! flotation, owing to their high adsorptive capacity for the amine collectors used. The slimes are generally removed by scrubbing followed by hydroclassification and any residual material not eliminated is blinded with reagents such as guar gum or starch to inhibit interference in subsequent KC1 flotation.An alternative approach used commercially in Canada by Agrium Inc. involves water-insoluble slimes flotation prior to KC! flotation. In this process, the slimes are selectively flocculated and then separated by froth flotation. Losses of KC! to the slimes product and associated brine requirements are both reported to be less than those encountered in conventional desliming, but the technique is somewhat limited in its application at present."

Jan 1, 1997

By Donald R. Sadoway

The viability of treating certain forms of hazardous waste by direct electrolysis in molten oxides is under investigation. Secondary residue or waste mud produced in the course of chromate chemical production is the focus of attention in this study. The goal is to reduce the water soluble hexavalent chromium either to insoluble trivalent chromium or to chromium metal. Electrolysis tests have been conducted in a high temperature cell containing chromate sludge dissolved in an electrolyte composed of Al2O3, SiO2, CaO, and MgO. Oxygen production on a carbon-free anode has been confirmed.

Jan 1, 1992

By S. W. Robertson, M. T. Golela, S. Mxinwa

South Africa has one of the largest Cr-related industries in the world and generates large amounts of Cr-containing smelter dusts. It is normal practice to scrub Cr from the furnace off-gas in water, and to recover the Cr by adsorption, followed by recycling of the loaded adsorbent into the furnace. A study was conducted to find a low-cost adsorbent that is capable of removing sufficient Cr from the solutions generated by scrubbing. The test work focused on the evaluation of different clay minerals (attapulgite, bentonite, and kaolinite) as adsorbents for Cr. Cr(VI) could only be adsorbed after prereduction with e.g. ascorbic acid (ASA). An 80% removal of Cr(VI) could be achieved from a solution containing 20 mg/L Cr using bentonite clay after reduction with ASA. Attapulgite and kaolinite adsorbed less than 55% Cr after reduction with ASA. Both ASA and ferrous salts were found to be suitable reducing agents. The use of acid mine drainage (AMD) was also investigated as a low-cost alternative reducing agent, as AMD usually contains iron. The Cr(VI) reduction potential of the AMD was determined by redox titration against a solution containing 50 mg/L Cr(VI). Studies show that AMD can potentially be used as a reducing agent in a Cr removal process if it is available on site.

Feb 12, 2024

By G. Demi

Chromium ore exploitation has commenced in 1948 in Albania and there are produced about 24.3 million tons up to the end of 2006. Last years the prices and need were increased notably. Main export of chromium ores and concentrates was accomplished respectively 114 500 ton and 13 000 ton in People Republic of China during 2006 year. Location, status, reserves and grade of chromium deposits of Albania are presented in the paper. Chromium ore enrichment is related with their composition and Cr2O3 content, as well as with market requests. Actually, high grade chromium ores with Cr2O3 content over 38% ~ 40% are directly exported or treated in metallurgy, but last time have been exported and chromium ores with 28% ~ 30% Cr2O3 content for the reason that dressing plants can not be operated for investment lack. High grade chromium ores have been treated in heavy media separation plant before 1990. It is presented flow sheet, figures and necessity to put in operation HMS plant in the paper. Actually, low grade chromium ores with content 16% ~ 20% Cr2O3 are not enriched for the lack of investments, but before 1990 they have been concentrated in dressing plants producing chromium concentrates grade 48% ~ 50% Cr2O3. In the paper are shown technological schemes and industrial figures during more than 20 years operation and possibilities to reconstruct these mineral processing plants. Only chromium mineral processing plant of Bulqiza is in operation using as raw material its old existing tailings. The flow sheet and figures show that are possibilities to increase recovery and grade of concentrate in the plant. Separation and concentration of slimes in suitable equipment gives visible improvement of Cr2O3 recovery. Several tests have been carried out with flotation and magnetic separation methods for enrichment of low grade chromium ores. Flow sheet and figures of mineral processing ores content olivine as gangue mineral are interesting, because combination of gravimetric with magnetic methods is necessary in this case. In the paper are presented the tests and good results of low chromium ore pre concentration. Metallurgical treatment of chromium ores to produce Ferro chrome, as well as technological process, figures, consume of electrical power and materials in Elbasani and Burreli furnaces are shown and necessary investments to treat in metallurgy all produced chromium ores in Albania are considered.

Jan 1, 2014

By Robert S. Hedin, David M. Hyman

Acid mine drainage (AMD) is a common water pollution problem on active and abandoned coal mine sites in the eastern United States. AMD forms when surface mining brings unweathered pyrite-containing rocks to the surface or when deep mining allows oxygen to contact buried pyritic strata. In the absence of neutralizing compounds, the drainage that results can be extremely acidic and contaminated with dissolved iron, manganese, and sulfate. Drainages with pH < 3.0 and concentrations of sulfate greater than 1,000 mg/L, iron greater than 50 mg/L, and manganese greater than 10 mg/L are common. Where water flows through alkaline materials (such as limestone) before surfacing, the drainage is less acidic and occasionally circumneutral, but it can still contain high concentrations of sulfate and metals. Current water quality standards in the United States require that mine discharges have a pH between 6 and 9, total iron concentration less than 3.0 mg/L, and manganese less than 2.0 mg/L. At thousands of active and inactive mine sites, drainage does not meet these standards and is being treated before discharge by the mining company. At thousands of other sites, which were abandoned prior to the enactment of water pollution laws or were operated by companies that have gone bankrupt, untreated AMD is polluting receiving water systems. The standard mine drainage treatment system involves the addition of a1 kal ine chemicals to the water, which raises the pH and cause metals to precipitate in a settling pond. These systems are expensive, often costing tens or hundreds of thousands of dollars per year for chemicals, operation, maintenance, and disposal of the metal- laden sludge. Because the drainage on many sites will likely be contaminated for decades, there is financial incentive to find alternative water treatment systems. In the last five years, many mining companies and engineering firms have experimented with the construction of wetland treatment systems. Very few of the several hundred wetland systems that have been built are performing well enough to justify total abandonment of chemical treatment. Nonetheless, systems continue to be built because the mining companies have found that wetlands can reduce their AMD treatment costs. It is also their hope that further research and development will eventually result in systems that will completely rep1 ace chemical treatment and offer long term performance at minimal cost. The Bureau of Mines has been actively involved, from a research perspective, with this approach to AMD treatment since its inception. In this paper, the status of constructed wetland technology is discussed with respect to the construction and performance of systems, chemical and biological processes that affect AMD chemistry within constructed wetlands, and the future of this technology as perceived by the Bureau of Mines. ORIGINAL OBSERVATIONS The constructed wetland concept has its roots in observations of natural Sphaqnum peat wetlands that received acid mine drainage and, instead of being adversely affected, appeared to cause an amelioration of the polluted water (Huntsman et al. 1978; Wieder and Lang 1982). These observations instigated the idea that wet1 and systems might be used for the intentional treatment of mine drainage. Because the discharge of AMD into a natural wetland is prohibited in the U.S. by several laws, it has been necessary to construct wetlands which act solely as water treatment systems. Initially, most wetland research and construction efforts mimicked the original observations by utilizing Sphaqnum moss and peat. Despite promising laboratory results (Kleinmann et al. 1983; Tarleton et al. 1984; Burris et al. 1984; Gerber et al. 1985), virtually all field tests of Sphasnum-dominated constructed wetlands failed to provide sufficient water treatment for more than several months. Sphasnum proved quite sensitive to the stresses associated with transplanting, abrupt changes in water chemistry, excessive or insufficient water depth, and

Jan 1, 1989

By Ralph A. Sherman, J. M. Pilcher

BY surface treatment of coal is meant the application of a material, either solid or liquid, to the surface of pieces of coal. The purposes of surface treatment are varied. They may be to identify or "trade-mark" the coal, to modify the burning characteristics, the coking tendencies, or the behavior of the ash, to prevent the freezing of wet coal, or to control the dust. The control of dust is the usual purpose of surface treatment. TRADE-MARKING COAL The application of color to the surface of coal for the purpose of identification and registration of the trade-mark has been practiced to some extent. In 1928, the Glen Alden Coal Co. began to color its coal and adopted the trade-mark, "Blue Coal." The Old Ben Coal Co. later followed a similar practice with "Green Coal." A commoner means of identification of coal has been the stenciling of designs or pasting labels on large lumps or in the distribution of small cardboard tags through the smaller sizes. The details of the method used to color coal have not been revealed. Usually all of the coal is not treated, because of the expense. Only enough pieces are colored to show clearly when distributed through the coal. The patent literature gives information on some of the methods proposed. Esselen and Weiss 1 have patented the deposition of a coloring material in the valleys of the surface of the coal. Sperr2 covers the quenching of coke with water containing a pigment or dye that will deposit on the coke. He also suggests electroplating with copper or nickel. Glinsmann 3 subjects the freshly fractured coal surface to the action of an alkali or alkali earth ferricyanide and a ferric salt. Barsky and Hanson4 specify a method for the application of the same chemicals covered by Glinsmann.

Jan 1, 1943

By Ralph A. Sherman, J. M. Pilcher

BY surface treatment of coal is meant the application of a material, either solid or liquid, to the surface of pieces of coal. The purposes of surface treatment are varied. They may be to identify or "trade- mark" the coal, to modify the burning characteristics, the coking tendencies, or the behavior of the ash, to prevent the freezing of wet coal, or to control the dust. The control of dust is the usual purpose of surface treatment. TRADE-MARKING COAL The application of color to the surface of coal for the purpose of identification and registration of the trade-mark has been practiced to some extent. In 1928, the Glen Alden Coal Co. began to color its coal and adopted the trade-mark, "Blue Coal." The Old Ben Coal Co. later followed a similar practice with "Green Coal." A commoner means of identification of coal has been the stenciling of designs or pasting labels on large lumps or in the distribution of small cardboard tags through the smaller sizes. The details of the method used to color coal have not been revealed. Usually all of the coal is not treated, because of the expense. Only enough pieces are colored to show clearly when distributed through the coal. The patent literature gives information on some of the methods proposed. Esselen and Weiss have patented the deposition of a coloring material in the valleys of the surface of the coal. Sperr covers the quenching of coke with water containing a pigment or dye that will deposit on the coke. He also suggests electroplating with copper or nickel. Glinsmann subjects the freshly fractured coal surface to the action of an alkali or alkali earth ferricyanide and a ferric salt. Barsky and Hanson specify a method for the application of the same chemicals covered by Glinsmann. COATINGS FOR IMPROVEMENT OF APPEARANCE As a purchaser often judges coal by its appearance, modification of the surface has been attempted from time to time, particularly of the surface of outcrop or stored coal, which has become covered with a brown film of iron oxides, but information is lacking as to the extent or success of the

Jan 1, 1950

By Ralph A. Sherman, J. M. Pilcher

BY surface treatment of coal is meant the application of a material, either solid or liquid, to the surface of pieces of coal. The purposes of surface treatment are varied. They may be to identify or "trade-mark" the coal, to modify the burning characteristics, the coking tendencies, or the behavior of the ash, to prevent the freezing of wet coal, or to control the dust. The control of dust is the usual purpose of surface treatment. TRADE-MARKING COAL The application of color to the surface of coal for the purpose of identification and registration of the trade-mark has been practiced to some extent. In 1928, the Glen Alden Coal Co. began to color its coal and adopted the trade-mark, "Blue Coal." The Old Ben Coal Co. later followed a similar practice with "Green Coal." A commoner means of identification of coal has been the stenciling of designs or pasting labels on large lumps or in the distribution of small cardboard tags through the smaller sizes. The details of the method used to color coal have not been revealed. Usually all of the coal is not treated, because of the expense. Only enough pieces are colored to show clearly when distributed through the coal.

Jan 1, 1943

By G. M. Ritcey, A. W. Ashbrook

"This paper summarizes the optimum leach conditions for each Of several cobalt-containing arsenical feed materials, describes the solution treatment prior to purification of cobalt recovery, and discusses the plant operation on one feed as well as the treatment of effluents.IntroductionDuring the period 1962-1964, when the demand for uranium was low, Eldorado Mining and Refining Limited (Eldorado Nuclear Limited) made a decision to undertake a three-year diversification program. One area chosen in this program was that concerned with the processing of cobalt-nickel materials. Many such materials were evaluated over the three-year period, ranging from tailings, residues, ores, concentrates and speiss to metal scrap. Cobalt feed materials, on which much of the effort was concentrated, were those containing arsenic together with other metals such as silver, copper, nickel and iron. This paper describes the treatment of arsenic-bearing feed materials (ranging from 0.3 to 570/0 As) and the subsequent purification stages required before the separation and recovery of high-purity cobalt. Because of the current interest in treating cobalt ores, it seemed appropriate that the information on the treatment of various cobalt feeds should now be made available . Although a large amount of data were generated during the research and process development program, a complete scientific correlation and understanding could not be achieved. Nevertheless, the data may provide a guide to others involved in processing not only cobalt, but other arsenical ores."

Jan 1, 1981

By M. Ito

Cobalt-rich ferromanganese crust and nodule ores from seamount areas contain volcanic and sedimentary rocks as substrate or nuclei and these ores require mineral processing to remove the substrate/nuclei rock before smelting. This paper reviews the results of jig separation and air table treatment for the coarse fraction and flotation and hybrid jigging for the fine fraction. Using these techniques substrate/nuclei rock was removed from the cobalt-rich ferromanganese oxide components. The mineralogical properties and metallurgical treatment methods including hydrometallurgical treatment of low grade ore is also reviewed.

Sep 1, 2012

By Sune Eriksson, Stig Peterssonsune, Christer Fridfeldt

"Boliden Metal Corporation has developed a technique to treat complex copper concentrates containing large amounts of lead, zinc, arsenic, antimony and bismuth which cannot be treated in conventional smelters due to the impurities.Tests were carried out to treat such complex copper concentrates in the TBRC. They were performed in a pilot-plant TBRC with charges of 5 tons. These tests resulted in a new method to treat complex copper raw materials and produce a blister copper low in impurities. The background and data from the test work are presented as well as a flowsheet for a full-scale process.IntroductionThe Ronnskar Works is situated on the coast of the Gulf of Bothnia, 40 miles east of the Boliden Mine. Smelting began at Ronnskar in 1930 to process the complex ore extracted from the Boliden Mine. The Ronnskar Works has subsequently developed into a relatively integrated smelting plant.Copper and lead sulphide concentrates from Boliden&apos;s own mines as well as purchased copper raw materials are processed. The main products are refined copper and lead, but full utilization of the raw material also yields other metals and some metallurgical and chemical by-products. The products include gold, silver, zinc clinker, white arsenic, arsenic salts and arsenic metal , selenium and selenium compounds, nickel sulphates, sulphuric acid and liquid sulphur dioxide."

Jan 1, 1981

By Peter Godbehere, Christian Desroches, Viken Baboudjian

"Noranda Copper Smelting and Refining is a unit of Noranda Metallurgy Inc., comprising the Home smelter in Rouyn-Noranda, Quebec and the C.C.R. Refinery in Montreal East. The Home smelter provides custom smelting services for a wide variety of copper and precious metal bearing concentrates and recyclable materials, producing over 200 000 tonnes of anodes and 450 000 tonnes of sulphuric acid annually. The C.C.R. Refinery has an annual production of 360 000 tonnes of copper cathode, and is a major refiner of precious metals.Over the past twenty years, Noranda Copper has developed innovative processes and operating techniques to treat the ever increasing complexity of primary feed materials, while improving the quality of its final products, working conditions and reducing environmental emissions.This paper presents an overview of the operating practices of Noranda Copper with particular emphasis on the impact of impurities in the smelting and refining processes.IntroductionThe treatment of custom materials has been practiced by Noranda Copper since commencement of operations at the Home smelter in 1927 and the CCR refinery in 1931. Copper concentrates from a wide variety of regional, North American and overseas producers account for the bulk of the 800 000 tonnes treated annually, although recyclable and secondaries have increased in importance as feed sources in the past two decades. The geographical disadvantage of the Horne smelter compared with most custom smelters located on tidewater has provided an important incentive for Noranda Copper to develop the necessary technology and operating practices at its smelter and refinery to treat high value complex concentrates and other feeds containing significant concentrations of bismuth, antimony, arsenic, lead, tellurium, mercury, etc."

Jan 1, 1995

By P. R. Khangaonkar

The variety of intermediates, middlings, complex materials and wastes produced in the conventional processing of tin ores as experienced in the tin industry in South East Asia is reviewed. The problems associated with the treatment of these materials so as to produce useful products by hydrometallurgical or pyro-cum-bydrometallurgical approaches are discussed. Results of treatment of amang middlings consisting of cassiterite, struverite, ilmenite, zircon, monazite etc by chlorination with carbon tetra chloride are presented. The efforts to leach tin without letting iron coming in, by alkali leaching of certain wastes of tin processing are also briefly indicated. It is felt that pyro-cum-hydrometallurgical approach can help a viable treatment of these materials so as to obtain usable or value added products.

Jan 1, 1994