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By M. Baeyertr

Since 1915 many papers and books have covered industrial applications of X-rays from various angles. Two of the more recent are a paper by Fink and Archer, which describes in detail the technique of radiography, and a paper by Clark2, which embraces the whole field of X-ray metallogmphy. This paper, therefore, is confined to work of the X-ray Laboratory of the Western Electric Co., which naturally divides into two categories: radiography and diffraction patterns of various types. Radiography Radiography is the field in which the application of X-rays has had most general appeal among the industries which produce or use metals and alloys. Equipment permitting the examination of heavy sections of metals less permeable than aluminum or other light alloys requires apparatus capable of generating hard X-rays over a considerable period of time. The equipment used in the work presented in this paper is practically identical with that described by Fink and Archer in their paper on radiography in industry and is easily capable of penetrating 1/8 in. of lead. Radiography is used in two major groups of problems: (1) in the development of cquipment and tools and (2) in studies of materials. So far there has been no instance in which the use of radiography for routine inspection is justified. This is partly due to the fact that the manufacture of telephone apparatus involves the production of many identical parts by standardized procedures and equipment that has had development and trial before being put on a regular production basis. It is during this stage of development of equipment and tools that radiography has been used to particular advantage.

Jan 1, 1931

By Charles S. Barrett, Robert F. Mehl

A study of the structures arising from the decomposition of the ß solid solutions in the Cu-Zn and the Cu-A1 systems is of peculiar interest in the study of the mechanism of precipitation from solid solutions. It is possible in these alloys, by varying the composition within the ß field, to precipitate from the same basic lattice phases having different lattice structures. It has been rather generally assumed heretofore that the type of structure originating from the decomposition of a solid solution— the Widmanstätten structure—-is determined by the lattice structure of the parent solid solution alone. In the first paper of this series1 evidence was advanced which threw doubt upon this hypothesis; but definite proof of the correctness or incorrectness of the hypothesis should be forthcoming from a study of these alloys, for if the structures originating, for example, from the precipitation of the a phase from ß and of the ? phase from the ß in the Cu-Zn system should be shown to be crystallographically different, the hypothesis would necessarily be held as definitely disproved. Furthermore, the newer proposal enunciated in the first paper of this series—that the origin of the Widmanstätten structure lies in a cooperation between the lattice of the parent solid solution and that of the precipitate-—which at present seems the only a1ternative hypothesis, would in such an event be given added weight. The work here reported shows that the Widmanstätten structures originating in the precipitation of the a phase from the ß and in the precipit'at.ion of the y phase from the y in the Cu-Zn system are indeed crystallographically different; and incidentally presents some new descriptive information on the Widmanstätten structure from a more general point, of view.

Jan 1, 1931

By O. T. Marzke, Robert F. Mehl

A study of the structures arising from the decomposition of the ß solid solutions in the Cu-Zn and the Cu-A1 systems is of peculiar interest in the study of the mechanism of precipitation from solid solutions. It is possible in these alloys, by varying the composition within the ß field, to precipitate from the same basic lattice phases having different lattice structures. It has been rather generally assumed heretofore that the type of structure originating from the decomposition of a solid solution— the Widmanstätten structure—-is determined by the lattice structure of the parent solid solution alone. In the first paper of this series1 evidence was advanced which threw doubt upon this hypothesis; but definite proof of the correctness or incorrectness of the hypothesis should be forthcoming from a study of these alloys, for if the structures originating, for example, from the precipitation of the a phase from ß and of the ? phase from the ß in the Cu-Zn system should be shown to be crystallographically different, the hypothesis would necessarily be held as definitely disproved. Furthermore, the newer proposal enunciated in the first paper of this series—that the origin of the Widmanstätten structure lies in a cooperation between the lattice of the parent solid solution and that of the precipitate-—which at present seems the only a1ternative hypothesis, would in such an event be given added weight. The work here reported shows that the Widmanstätten structures originating in the precipitation of the a phase from the ß and in the precipit'at.ion of the y phase from the y in the Cu-Zn system are indeed crystallographically different; and incidentally presents some new descriptive information on the Widmanstätten structure from a more general point, of view.

Jan 1, 1931

By Cyril Stanley Smith

The following table, which is composed of data given in the author's first paper on the thermal conductivity of copper alloys1, contains tile results which have been obtained by previous workers on the thermal conductivity of the copper-tin, the copper-phosphorus and the copper-tin-phosphorus alloys (the phosphor bronzes). a Dr. Ing. Diss., Aachen, 1909. Quoted by Schenk: Ann. der Phys. (1910) 32, 261. b Beibl. Ann. der Phys. (1906) 29, 178. c Jnl. Inst. Metals (1928) 39, 375. d Jnl. Inst. Metals (192.5) 34, 43. e Ges. Abhand. Kennt. Kohle (1919) 4, 400. Experimental Methods Since the method of obtaining measurements of the thermal conductivity was identical with that described in the author's previous paper

Jan 1, 1931

By Yap Chu-Phay

Although chronologically the Sb-Bi system was the first one studied by the writer, the theoretical basis of the equations used in this paper is fully discussed in the writer's paper on the iron-carbon system,' because he believed that many would be more interested in the iron-carbon alloys. He suggests, therefore, that the reader consult that paper to familiarize himself with the theoretical aspect of the thermodynamic treatment outlined herein. This paper is divided into two parts: Part 'I deals with the Sb-Bi system and Part II deals with the lead-rich side of the Sb-Pb system. Although the former system has not much practical interest now, it has great theoretical interest in that it is the one system that for a long time was thought to have (and under specific conditions still has) an anomalous solidus, which no amount of physical investigation could adequately account for. The latter system, of course, is particularly interesting in the lead-rich end. It will be shown that the thermodynamic method is capable of predicting reliably the equilibrium position of the solidus, and thus acts as a check on the experimentally derived solidus. PART I.—THE ANTIMONY-BISMUTII SYSTEM In connection with his studies in thermoelectric phenomena,-the writer was naturally interested in the system Sb-Bi. In consulting the International Critical Tables2 he found the constitutional diagram shown in Fig. 1 (not including Ôtani's solidus), essentially after Cook,³ who investigated the system carefully by thermal analysis. Note the isothermal crystallization of alloys varying in composition from about 48 per cent, (by weight) to pure Bi. This is anomalous, because, according to the phase rule, in a binary system when only two phases coexist, there is univariant equilibrium; that is, the composition changes with the tempera-

Jan 1, 1931

By Oluwasegun Samuel Odebiyi, Shaona Wang, Feng Gao, Biao Liu, Hao Du

Recovering vanadium from vanadium titanium-magnetite (VTM) ore using ( NH4)2C2O4 is a clean hydrometallurgical process, but the drawback is the low recovery and slow kinetics due to the formation of inhibitor. A novel energy-efficient mathematical model was derived for green leaching of VTM in which the mechanical activation (MA) removed the inhibitor “δ” (formation of impermeable product layer of CaC2O4) covering the reacting core of the CaV2O6 leaching process in ( NH4)2C2O4 solution. Before the MA processing, the formation of the CaC2O4 layer affects the kinetics (slow) and NH4VO3 leachability (low recovery). The dissolution rate enhancement and economic importance (in terms of leaching kinetic/recovery) of mechanical activation (MA) pretreatment in hydrometallurgical processing cannot be overemphasized. It is shown from the experimental and developed mathematical model results that the rotating speed of the ball mill (ωb) has a significant effect on the NH4VO3 recovery. At 360 rpm, the experimental result gave an 82% optimum recovery rate and a reaction rate constant of 0.01889s−1 with close correlation with the present models at 82.8% and 81% for liquid-to-solid layer diffusion and chemical reaction controls, respectively, with a reaction rate constant of 0.018883s−1. The close correlation between the experimental recovery rate results and the diffusion recovery rate model result justifies that the leaching process is diffusion control shrinking core kinetic with experimentally measured activation energy (Ea) value of 19.502 kJ/mol . This present model proved that MA enhances the dissolution rate regardless of the formation of a passivation layer on the material and best describes the kinetics of the MA hydrometallurgical processes compared to the shrinking core model.

Nov 3, 2023

By D. Van Dooren

The final goal of the research project is to develop a 3D FEM model that is able to predict the kinetics and micro-structural evolution during the bainitic transformation. The input parameters consist of thermodynamic and atomic mobility data obtained from the ThermoCalc and mCTRA databases combined with structural mechanics data extracted from the stress-strain curves of the fcc and bee phases. In this paper the general principles of the model are outlined and some interesting preliminary results are shown and commented. The full implementation of the model has presently not been achieved yet. In the model the bainitic transformation is considered as a sequence of martensitic (re)nucleation and growth of a ferritic subunit followed by the carbon rejection into the surrounding austenite. The (re)nucleation of the subunits will be described through a non-classical martensitic nucleation criterion. Once a nucleus has been activated at a specific location in the material, a full-sized subunit is instantaneously formed through a displacive mechanism. The stress state in the system that arises due to the transformation strain can be calculated by a 3D FEM programming code. Immediately after the formation of the subunit, another 3D FEM programming code calculates the carbon diffusion from the supersaturated ferrite into the surrounding austenite. The resulting stress state and carbon profiles will be used to determine where and when a new subunit will nucleate based on a renucleation criterion. Keywords: Bainitic Transformation, Modeling, Eshelby, Carbon Diffusion

Jan 1, 2003

By Feng Gao

A general unsteady- state model, based on a cracked substrate, has been developed to account for reaction and diffusion within porous substrate during oxidation of Carbon Fiber Reinforced Carbon matrix (CIC) composites. The effects of several parameters, such as diffusion and reaction rate ratio, oxygen concentration, and composite density, on oxidation process are explored. Also, theoretical results for a set of parameter values of the CIC composites are compared with experimental data. It shows that the model predicted values agreed well with the experimental data in weight loss. Based on this model, quantitative predictions of oxidation of a composite with cracked substrate can be made.

Jan 1, 1993

By L. A. Adorjan

The tensile strength of agglomerate models due to capillary forces has been determined by computation of the exact surface profiles. Graphs showing tensile strength as a function of moisture content and contact angle me given for spheres in cubic arrangement. Another model of cones attached to cube faces, in cubic packing, provides a better representation of angular particle agglomerates. An algebraic formula approximating tensile strength as dependent on surface tension, particle size, moisture content, contact and cone angles was developed. The phenomenon of "capillary evaporation" due to high negative capillary pressures is explained and its influence on tensile strength of agglomerates is evaluated.

Jan 1, 1977

By Lj. D. Andric

Development of modern devices for mechanical and mechanochemical materials activation has been dated since the beginning of last century. Rapid development of high-energy mills that are different in type, size, design and performances, has been occurred during the last four decades. Because of complete understanding of mechanical processing, entire knowledge of theoretical principles of high-energy mills is necessary. These principles are main causales of process that are happened in materials during the mechanical activation. This paper is occupied by theoretical principles of operation of high-energy mills. Conventional high energy mills with balls, high-energy planetary mills and high-energy vibrational mills are particularly considered in the paper.

Jan 1, 2014

By A. S. Richardson

THE rating of a mine ventilation fan, or the characteristic curves illustrating the duty it may be expected to perform under various mine conditions are, in general, determined by the fan manufacturers. The information is of importance to the operator, or engineer, of a mine in many ways. For instance, when an increased flow of air is desired and the fan speed is to be increased, it becomes necessary to know what increase in volume may be expected and what the power requirements will be. In other cases, it may be decided to make changes in the mine to reduce the resistance to the flow of air, or to make changes in the general system of ventilation. Under any changed mine conditions there will be a difference in the duty performed by the fan. When mechanical ventilation is adopted, the factors governing the selection of equipment for the new system include not only the requirements of existing conditions, but also those that may be expected with the development of the property. Efficiency of service is required over a variable range of operating conditions. Characteristic curves, giving the duty performed by their fans under variable resistance conditions, are published by most fan manufacturers. General statements as to the effect of variation in speed of the centrifugal-type fan, under fixed mine conditions, appear in textbooks and trade catalogs. However, to the author both sources of information appear to be unreliable, at least under certain circumstances. The catalog of a leading fan manufacturer says: 1. The volume of air delivered by a fan varies directly as the speed. 2. The pressure, or water gage, produced by a fan varies as the square of the fan speed. 3. The horsepower of a fan varies as the cube of the fan speed. While these statements are accurate when the fan is operating under conditions similar to those that exist when a blower is used to force air through a pipe, they are not correct under mine conditions that are by no means unusual. Such conditions may be found in deep mines operated through shafts, in which a wide range of temperatures may be

Jan 8, 1925

By Ronald J. Roman, Craig Olsen

Alterations were performed on a previously developed heap leaching model representing sulfuric acid solution leaching of a malachite sandstone ore. The alterations were made in order to approach a more realistic solution to the leaching equations used in the model and to provide a means of obtaining a constant acid con- centration in the model' s simulated heap effluent solutions. This constant acid concentration is desired if the effluent solutions are to be treated in a solvent extraction-electrowinning plant. An economic study was made showing a use of the leaching model for an imaginary heap leach operation. The example illustrates a method of selecting heap leaching parameters if data are available on mining costs, dump costs, capital cost, etc. This was achieved using an incremental investment technique.

Jan 1, 1974

By Subrata Ray

A large no of power stations are being set up in Chandrapur area having coal deposits. Several industries are also coning up in this area. The subsurface is geologically formed under Gondwana system and consists of shale strata at depths ranging from 8 to 12 m. The stress deformation characteristics of shale exhibits wide variation because of it's geological origin. In view of this, a study was conducted on bored cast in-situ piles installed for a Switch yard project to evaluate load settlement characteristics of three test piles to understand the probable engineering behaviour of the material at the tip and the sides. An approach is developed to simulate the load settlement behaviour as observed in the field, theoretically. This is based on the concept of load transfer. The fit is obtained by varying the parameters, thus may be considered as iterative in nature. The theoretical curves closely matched the observed curves. The results of this study are presented in this paper.

Jan 1, 1996

By G. Y. Liu

The structure-activity relationships for four thionocarbamate collectors are discussed in this pa-per. These collector classes are alkyl alkyl thionocarbamates, allyl alkyl thionocarbamates, acyl al-kyl thionocarbamates and alkoxylcarbonyl alkyl thionocarbamates. The main emphasis will be to highlight the differences between collectors and their affinities for copper and iron sulfide minerals on the basis of data on electronic-structure properties obtained by vacuum and solution density functional calculations, flotation experiments and analysis measurements. The mechanism of interaction of these collectors with sulfide minerals is also discussed with perturbation theory. The theoretical study results indicate that acyl alkyl thionocarbamates and alkoxylcarbonyl alkyl thionocarbamates have best performance in these agents as flotation collectors with improved collecting power for copper sulfide minerals and excellent selectivity against iron sulfide minerals, which are consistent with the experimental data reported in the literature.

Jan 1, 2014

By Salah A. Taqieddin

The blast casting technique of removing overburden is an innovative technique which was successfully used in the mining of certain surface coal and quarries. This method was found to be efficient in minimizing the labor and equipment cost while accelerating mining operation with safety. This method was successfully applied to horizontal as well as to dipping coal seams. Also it was practically applied to single as well as to multiple ore bodies

Jan 1, 1992

By Oladayo O. Komolafe and Majid Ghayoomi

p-y curves have been used over the years to determine the lateral resistance of piles. This method is popular among practicing engineers due to its simplicity and its ability to determine the slope, displacement, shear force, and bending moment for various depths along the pile. The ultimate lateral load resistance is a key component of p-y curve formulation. The p-y curve formulation by Reese et al. (1974) does not consider the effects of soil’s degree of saturation on theoretical ultimate lateral resistance of the failure wedge. This limits an accurate assessment of the lateral soil resistance near the ground surface and the consequent p-y curves. This paper extends the existing approach for determining the failure wedge in unsaturated cohesionless soils with suction dependency, especially for the depths that are above the water table within the wedge. The modification to the failure wedge analysis was made by considering the variation of the degree of saturation which affects effective stress and lateral earth pressure. Through a set of parametric analyses, the impact of incorporating principles of unsaturated soil mechanics in the estimation of theoretical ultimate lateral resistance is examined, and its implications on lateral pile response are discussed.

Sep 8, 2021

Many industries base their decisions on the assaying of tiny analytical sub-samples. The problem is that most of the time several sampling and sub-sampling stages are required before the laboratory provides its ultimate assays using advanced chemical and physical methods of analysis. As long as each sampling and sub-sampling stage is the object of due diligence using the theory of sampling it is likely that the integrity of the sought after information has not been altered and the generated database is still capable to fulfil its informative mission. Unfortunately, more often than not, unawareness of the basic properties of heterogeneous materials combined with the unawareness of stringent requirements listed in the theory of sampling, lead to the conclusion that massive discrepancies may be observed between the expensive outcome of along chain of sampling and analytical custody, and reality. There are no areas that are more vulnerable to such misfortune than sampling and assaying for trace amounts of constituents of interest in the environment, in high purity materials, in precious metals exploration, food chain, chemicals, and pharmaceutical products. Without the preventive suggestions of the theory of sampling serious difficulties may arise when making Gaussian approximations or even lognormal manipulations in the subsequent interpretations. A complementary understanding of Poisson processes injected in the theory of sampling may greatly help the practitioner understand structural sampling problems and prevent unfortunate mistakes from being repeated over and over until a crisis is reached. This paper presents an overview of the theoretical, practical and economic difficulties often vastly underestimated in the search for quantifying trace amounts of valuable or unwelcome components.

Jan 1, 2010

By C. L. M. Gough, L. A. Vermeulen, D. D. Howat

Formulae expressing the dependence of the mass of a grinding ball on the amount of material milled by a ball mill are derived. It is shown that, with the aid of these formulae, it is relativel rsimple for the results of a marked-ball test to be analysed and for the relative performance and cost-effectiveness 0 the various types of ball under test to be evaluated. Predictions based on theory and the results obtained in a marked-ball test in a ball mill are compared detail and shown to be in close agreement. The difficulties associated with marked-ball tests are considered, and an explanation for the decrease in the calculated consumption of the balls, which follows naturally from the theory, is presented. The marked-ball anomaly explained, and it is demonstrated that the ball consumption in a ball mill can be predicted with fair accuracy from the results of a marked-ball test.

Jan 1, 1983

By Karl Sundberg

DURING the past few years Swedish geo-electrical prospecting methods have been described in several papers; namely, by us in a paper en-titled "Electrical Prospecting in Sweden," published by the Geological Survey of Sweden, 1925, and in a paper, "Electrical and Electro-Magnetic Prospecting," read by Hans Lundberg at the 1926 annual meeting of the A.I.M.E. In a written discussion on the latter paper, Theodore Zuschlag has made some observations, pub-lished in the Trans. Vol. LXXIV, which has just ap-peared. In this discussion the theories of the Swedish geo-electrical methods are criticized. The statements of Mr. Zuschlag are the reason for, our submitting the following information.1 In developing an art, such as electrical prospecting, the first thing to do, of course, is to make clear the fun-damental principles of electrical prospecting and then apply them to practice. This application cannot, in this case, be made by theoretical calculations only, because Nature is far too complicated to permit of exact theo-retical calculations on the phenomena involved in prac-tical electrical prospecting. Therefore, it is necessary to start with simplified cases, then turn to more and more complicated ones, and, finally, to test the applica-tion of results found, first in the laboratory and then in the field under known conditions.. Only in this way can results of practical value be obtained. This pro-cedure comprises three important parts: theory, the work in the laboratory, and the work in the field. In the papers mentioned above, we have briefly out-lined the work done in developing the Swedish geo-electrical methods, mainly giving some practical results, because these are most important and most likely to interest mining people. Possibly, because the discus-sion of theoretical considerations in our papers has been brief and sketchy, Mr. Zuschlag feels justified in in-ferring that the theories used as the foundation in Swedish electrical prospecting methods are not free from fundamental objections. His fundamental ob-jections are:

Jan 3, 1927

By Xianguo C, Baoqi S, Shaozhong Z, Huiling Z, Zhengbing C

Acidless and fluoless flotation is a new method for separating feldspar from quartz at the natural pH value of tap water in the absence of any acid and fluoride and other inorganic reagents. The paper introduces the production application of this method in plants and research results on the mechanism involved in the flotation method.

Jan 1, 1993