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By W. L. Austin

THE advance made in recent times in this branch of metallurgy is indicated y the attention the subject is receiving from important American copper-producing companies. Reference to the files of publications devoted to the mining industry discloses that some 20 American companies are actively investigating the amenability of their ore, or other material, to leaching methods, and that plants of varying capacities up, to 10,000 tons per day are under construction or are projected. Several leaching works are in commercial operation. It has been frequently pointed out that no method of leaching is universally applicable, for the reason that each ore differs in some particular from apparently similar ore found elsewhere, and also because local conditions are rarely the same even where the ore closely approximates in character that being worked at some other point. For this reason the older companies are approaching the matter in a conservative manner, experimentally determining for themselves the salient features in each instance. In considering a leaching proposition three factors at once fix the attention: (1) disengaging the metal from mineralized forms in Which it is found in nature; (2) recovering the metal in a commercial state after it has been dissolved; (3) the apparatus best adapted to carrying out the several operations.

Jan 8, 1914

By C. G. Anderson

Today, with a stringent economic and environmental climate prevailing in the copper business, there is increased interest in evaluating new processing alternatives for production. Hydrometallurgical pressure oxidation of copper concentrates is one of the more viable approaches and several technological candidates have emerged. Of these, an overlooked but, ironically the first industrially proven methodology, utilized nitrogen species catalyzation in the oxidizing pressure leach system to produce copper via SX/EW. Given its many inherent process advantages, this may prove to be a feasible process alternative for the future. In this paper, the history of the system and its application to copper concentrates and ores will be outlined. In particular, a novel methodology for effective recovery of precious metals from chalcopyrite concentrates will be discussed. Finally, the perceived economics of chalcopyrite concentrate treatment with this unique industrially proven process will be delineated.

Jan 1, 2001

By T. P. Meloy

The behavior of slime-sized particles in a flotation cell is neither well documented nor well understood. In general, slimes (or 'fines' as they will be alternatively called in this chapter) have been either ignored, eliminated, or treated empirically. Recently, however, some good experimental and theoretical work has been done that leads qualitatively to a clearer understanding of the problems involved. Fines are small particles that, owing to their smallness, behave differently from larger particles of the same material. The smaller the particle, the larger is its surface-to-mass ratio. The difference in the surface-to-mass ratio for a micron-sized particle and a centimeter-sized particle is 10,000 to 1. For our purposes we shall arbitrarily define any particle less than 10 µ 10-3 cm) as being a fine. This is generally considered the upper limit of colloidal-sized particles. Recently, the field of colloidal chemistry has successfully used the concept of the double layer to explain dispersion and flocculation of fine particles in a static system. Flotation, however, is a dynamic system due both to the turbulence of the liquid and to the coursing of the bubbles through the cell. Further more, a flotation system is a heterogeneous system in which there are a number of different types of particles which interact with one another. A further difficulty is that no two flotation systems are the same for minute quantities of a variety of common chemicals will alter the behavior of the system. These reasons make reproducible experimental results that can ex- plain fine-particle behavior difficult to obtain. In spite of these experimental difficulties, millions of tons of ore containing a large amount of fines are successfully floated every year. For example, at the Morning mill of American Smelting and Refining Co., a galena concentrate that was 42% -6 µ and a sphalerite concentrate that was 33% -9 µ were floated leaving a tailing that was 27% - 9 µ.l Ores that contain fines can generally be divided into two classes. In the first are those in which the valuable mineral tends to slime, such as galena and hematite. In the other class, one or more of the gangue minerals forms the slime; a typical example is barite. Though the problems due to the presence of fines are often the same in handling the two classes of ore, the method of handling them is different because of economic considerations. Nonmetallic mineral flotation is particularly affected by slimes, by either slime-coating effects or excessive reagent consumption. Though a given gangue mineral may not float under the conditions prevailing in the flotation cell, it may still be able to adsorb the collector. I£ it also slimes, a significant

Jan 1, 1962

By J. M. Adams

IT is my purpose to give some of the results obtained by an experience of nearly seven years in working ores by the method frequently called the Washoe Process, and in several mills of which I have had charge, but principally in the Owyhee Mill, at Silver City, Idaho, which had twenty '650-pound stamps, and sixteen pans. I shall discuss here merely the mechanical details for working ores generally, subdividing the subject as follows: 1. Preparation of the ore for the stamps; 2. The crushing in the battery; 3. The settling of sand or pulp in vats or tanks; 4. The treatment in the pans; 5. The results obtained in settlers, agitators, and concentrators ; 6. The straining of quicksilver, cleaning of amalgam, and retorting; 7. The saving of slimes and their subsequent treatment; 8. The loss of quicksilver. For descriptions of the various kinds of orebreakers, stamps, tanks, pans, settlers, etc., I must refer to the various works on these subjects, prominent among which are the reports of the United States Commissioner of Mining Statistics, and the volume on "Mining Industry," the third volume of the United States Geological Survey on the Line of the Fortieth Parallel through the gold and silver bearing regions of the great West, undertaken under the able guidance of Clarence King, assisted by Mr. James D. Hague and others. In this discussion it will be assumed that the general arrangement of the quartz mill is understood; and the question will be treated how to secure, from such a mill, the greatest economy in working, combined with the largest results. This place seems fittest for a single preliminary suggestion-namely, that there should be double "floors" throughout the mill, so that nothing can sift through and be lost.

Jan 1, 1874

By Matthew Scott

Introduction The refining of precipitate is the final stage of all the processes involved in gold mining and cyanide milling, by which the precious metal is at last obtained in a concentrated form, which can be accurately valued and marketed. Possibly one ought to say, conveniently shipped, for accuracy in valuation depends in many instances on a toughening treatment given the bars as received at the Mint so as to obtain a homogeneous metal that lends itself to representative sampling; which, of course, entails a surcharge on the regular Mint charges for the extra work necessarily undertaken. There are several methods of refining zinc-gold precipitate, each with its advocates; the method employed depending not always on the quality of the bullion produced but on the local exigencies of the case in point. These methods are more or less detailed in various textbooks and it is not the purpose of this paper to discuss them, but to confine ourselves to the specific case as stated in the title of the paper. At the outset, it behooves the writer to express his thanks to Mr. Brigham, the General Manager of the Hollinger Mines, for the kindly consideration and encouragement given in developing this process. This will be better understood when one considers the immense values involved, tending towards conservatism in practice, and making one chary of radical innovations. This process has been in satisfactory operation now for about two and-a half years, during which time over twenty-five million dollars value in fine gold has been produced, so that it may be reasonably held that the process is successful.

Jan 1, 1931

By M. Nishikawa

The Hachinohe Smelter employs the Imperial Smelting Furnace (ISF) for production of zinc and lead and handles a large number of concentrates and recycled materials. In recent years, recycled materials such as zinc-bearing materials, lead sludge and Waelz oxide have provided up to 30% of the feed materials at the plant. To allow for a satisfactory operation using such a wide range of recycled materials, the Hot Briquetting Plant was built in 1986 and started its operation in January 1987. In April 1988 the zinc production capacity of the ISP was increased from 81,000 to 101,000 tonnes per year. The additional production in the ISP has been attributed to the utilization of the hot briquetting process. This paper describes the various facts of the smelter, concentrating on hot briquetting operations and treatment of hot briquettes in the ISF.

Jan 1, 1991

By R. E. Johnson, W. Kat, B. R. Palmer, van Sandwijk A., G. Van Weert, S. Honingh

In-plant recycling of dust from iron making BF's creates undesirable circulating loads of volatile trace elements such as zinc and lead. Disposal of such dusts creates environmental problems, hence a separate treatment is indicated. Since the bulk of the zinc and lead compounds occurs in the fine dust fraction; hydrocycloning the slurry from the BF gas cleaning operation results in upgrading the material for treatment. A process has been proposed, whereby the zinc and lead are solubilized from the fine fraction with spent hydrochloric acid from steel pickling. The stoichiometry of this autoclave oxidation process is adjusted to simultaneously precipitate, by oxyhydrolysis, most of the iron for recycling to the BF's. Lead and zinc are successively recovered from the filtrate as low chloride precipitates. This paper describes additional testwork, leading to the design of a pilot plant which was planned to begin operation in 1992.

Jan 1, 1993

By Galen H. Clevenger

Although there are exceptions, oxidized silver ores containing the higher oxides of manganese are generally refractory to hydrometallurgical methods of treatment. When these ores are of high enough grade they can be smelted; indeed, some rather low-grade ores of this type have been smelted at a profit because of their fluxing value. In the past, when these ores could not be smelted, they either were not treated or were treated at low efficiency, generally by cyanidation. The need for thorough investigation of the problem was therefore evident for some time before the writers began their research. The problem of treating manganese-silver ores seems to have been recognized first about 35 years ago by C. W. Goodale in applying pan amalgamation at Tombstone, Ariz. He attributed the low extraction of silver to the fouling of the mercury by manganese rather than to the presence of a refractory compound of manganese and silver. Although definite knowledge as to the cause of the poor extraction of silver was lacking, a more or less effective preliminary treatment, that is, a chloridizing roast, was applied.

Jan 1, 1925

By N. A. Barcza

DC plasma-arc technology using a hollow graphite electrode (cathode) has been successfully implemented in the primary metallurgical industry in South Africa up to the 30 MW scale. Mintek has applied its expertise base, established over the past fifteen years, to testing the treatment of metallurgical wastes such as carbon- and stainless-steel plant dusts, lead- and zinc-containing slags, and residues from the base-metal industry. Favourable results have been achieved, and disposable products were produced. The evaluation of numerous wastes indicates that recovery of zinc as metal gives the best economic return from these sources. Direct recovery via a splash condenser or electrolytic zinc extraction from fume are the two preferred alternatives under review. In both instances dehalogenation is an important issue, but can be achieved by suitable treatment processes. The Enviroplas technology provides a flexible, commercially viable approach to the treatment of a wide variety of wastes. Mintek, together with its associate Pyromet CC, are installing a plasma- arc pilot-plant facility with both an ISP lead-splash condenser of about 5 t/d condensed zinc capacity and a combustion chamber to burn zinc vapour to zinc oxide. This will demonstrate the suitability of the Enviroplas technology for treating specific metallurgical wastes, so that customized industrial plants can be engineered based on large-scale testwork.

Jan 1, 1994

By Pejman Oghazi

During the last decade the output of mining companies has increased rapidly. The key driver is the increase in demand for raw materials in the developing world, and thus this demand has driven up ore prices. From the time when the Raw material group (year 2000) started to introduced their index, it was set to 100 points. Today, year 2011, the index is over 400, which means that ore prices have quadrupled since then. Mine companies have to go deeper in the mines to access the ore bodies to increase the mine capacity and to be able to respond to the market. By going deeper in the mine, there will be new challenges that have to be considered. One of these challenges is how to handle the mine water that is produced in the mine. The water has to be moved to the surface in order to keep the mine from flooding, and this causes more challenges. One solution is to pump the mine water up to the surface without treatment; however, this causes considerable pump wear and the water will still require treatment on the mine?s surface. Another solution is to treat this water in the mine before pumping it to the surface. Metso Minerals has a system solution to treat the mine water, by separating the solids from the mine water. This system reduces the erosion in the pumps and will save many maintenance hours in the long term. One other option is to use the treated water in a closed circuit and reuse it in the process. This system can be divided into three steps: Firstly, a spiral dewaterer to remove the coarse solid particles. For the next step, lamella thickener is used to remove most of the solids, and lastly tube press to handle the sludge from the underflow lamella thickeners. Keywords: mine water, mineral processing, dewatering, separating

Sep 1, 2012

By Swanson AR, Nicol SK

A study has been made into the influence of feed size distribution on the flotation response of coal. The results show that a full description of the flotation response of a coal must not only consider the inherent floatability of the coal, but also, the size distribution of the feed to flotation. The performances of a number of flotation circuits were compared using a coal which was "poorly floating" because of its size distribution. Split feed flotation, two stage reagent addition, and reflotation of classified tailings all gave better yields than that obtained by conventional single stage flotation. The optimum flotation circuit for the washing of the coal in question, was reflotation of classified tailings.

Jan 1, 1978

By Ian J. Corrans, Gary Johnson, John E. Angove

Activox® is a hydrometallurgical process used to oxidise sulphide concentrates. The process is based on two relatively simple, established unit operations; i.e. fine or ultra-fine milling (UFM) and pressure oxidation under mild conditions. An under-standing of, and ability to control the pulp chemistry during oxidation has resulted in the successful Activox® treatment ( on a batch scale) of a wide variety of sulphide flotation concentrates; • pyrite/arsenopyrite + gold • pyrite/chalcopyrite + gold • pyrite/chalcocite + gold • pyrite/enargite/tetrahedrite + gold Oxidation rates are rapid (1-2 hours retention time) and gold

Jan 1, 1995

By W. J. Guay

Carbonaceous gold ores containing gold dispersed in sulfides are refractory to cyanidation because: (1 ) the carbonaceous materials adsorb gold during cyanidation; (2) a portion of the gold s so finely dispersed in the sulfide mineral lattice as to preclude contact with cyanide solution; and (3) a portion of the gold is chemically combined with carbonaceous material. Techniques which have been used to treat these ores are: (1) roasting or chemical oxidation to decompose sulfide and carbonaceous materials; (2) flotation to reject carbon; (3) the use of kerosene or other reagents to passivate the adsorptive carbon compounds; (4) carbon or resin in pulp; (5) flotation of a bulk concentrate which is treated by one of the above methods; and (6) the use of chelating agents which have a stronger affinity for gold than the activated carbon in the ore.

Jan 1, 1981

By W. J. Guay

Carbonaceous gold ores containing gold dispersed in sulfides are refractory to cyanidation because: ( 1) the carbonaceous materials adsorb gold during cyanidation; (2) a portion of the gold is so finely dispersed in the sulfide mineral lattice as to preclude contact with cyanide solution; and (3) a portion of the gold is chemically combined with carbonaceous material. Techniques which have been used to treat these ores are: (1) roasting or chemical oxidation to decompose sulfides and carbonaceous materials; (2) flotation to reject carbon; (3) the use of kerosene or other reagents to passivate the adsorptive carbon compounds; (4) carbon or resin in pulp; (5) flotation of a bulk concentrate which is treated by one of the above methods; and (6) the use of chelating agents which have a stronger affinity for gold than the activated carbon in the ore.

Jan 1, 1981

By C. W. A. Muir

Laboratory and plant-scale testwork on the extraction of gold from highly refractory antimonial and arsenical concentrates using both direct low-alkalinity pressure cyanidation, and acidic pressure pre-leaching followed by ambient low-alkalinity cyanidation, is described. A novel method for treating effluent solutions containing extremely high concentrations of base metal cyanides, as well as arsenic and antimony compounds, was developed in order to make the process ecologically acceptable.

Jan 1, 1984

By C. H. Madsen

THE Hard Rock gold mine is in the Little Long Lac mining area, Thunder Bay district, northwestern Ontario. It is four miles by road from the town of Geraldton, which is on the Canadian National railway, 180 miles northeast of Port Arthur. The original discovery of gold-bearing quartz veins on the property was made in 1931. Shaft sinking began in the fall of 1934 and approximately 7,400 feet of lateral development on four levels was completed. In 1935, further discoveries were made half a mile west of the early workings, and the No. 2 shaft was sunk in this area in a porphyry zone. In January, 1938, a 20C-ton cyanide plant was completed and began drilling ore from the gold-bearing porphyry orebody. The daily feed was increased gradually to 300 tons in the next six months and a recovery of 97.5 per cent was effected. During the summer of the same year, a new and larger orebody was discovered to the north of the porphyry zone. It occurs in a band of iron formation and contains a high percentage of pyrite and arsenopyrite. Extensive tests were rr.ace on this sulphide ore in the Mines Branch ore dressing laboratory at Ottawa, in the laboratory of Canadian Industries, limited, at Toronto, and later at the mine, to find a suitable method of treatrr.ent. As a result of this research, a Potation plant was added to the original cyanide mill and on November 7th, 1938, differential flotation was used to separate the pyrite from the arsenopyrite fraction of the ore. The pyrite concentrate was re-ground and cyanide:l, and the arsenopyrire concentrate was stored for subsequent treatment. Differential flotation was discontinued in April, 1939, in favour of bulk formation of all the sulphides, and the whole cyanide residue was stored. On March 15th, 1939, a 10-ton pilot roaster was completed and rests were conducted on the arsenopyrite concentrate and the bulk concentrate. The results obtained led to the building of two roasters of the same type, large enough to roast all the concentrates. These roasters were put in operation on September 24th, 1939, and the calcines were cyanided in the original circuit.

Jan 1, 1941

By J. S. Roberts

"Campbell mines has been in operation since 1948. Part of the process consists of roasting of a flotation concentrate which contains arsenopyrite.At present operation level the milling rate averages about 850 t.p.d. and about 48 t.p.d. of concentrate is roasted. The gas emissions at present contain between 3 and 3.5 t.p.d. of arsenic trioxide, about2 - 2.5 t.p.d. of particulate matter and between 19 - 25 t.p.d. of sulphur dioxide. The particulate is extremely fine calcine dust and it assays about 4 oz. Of gold per ton.Until 1974 the gas was discharged untreated through a 125' stack.UntreatedThe decision was made in 1972 to erect a gas treatment plant, construction ran through 1973 and operation began in 1974. The cost of the installation was about 1.3 million dollars.On investigation the process technology, it was apparent that the plant operated by giant Yellowknife for the same purpose was the model we should study. I would like to acknowledge the fine cooperation we had from giant, the plant that emerged is very similar to theirs and incorporates some improvements suggested by them and based on their operating experience.The plant is designed to remove arsenic and solid dust and it has no provisions to remove sulphur dioxide.We depend upon the 125' stack to assure adequate dilution. Because of the nearby airport the stack cannot exceed 125'. A stack burner is provided that can ""y used to heat the stack gas and carry it higher into the atmosphere when there is an inversion condition.The removal of arsenic from hot gas is fairly simple. The sublimation point is about 425°f, a few degrees above this point the arsenic is a gas and a few degrees below it condenses into a solid form. The arsenic could have been removed by simply dropping the temperature below the condensation point and collecting all the solids in a baghouse. This would have removed the possibility of recovering the gold in the calcine dust and would have produced an impure and more bulky arsenic material to be placed in safe storage. The decision was made to collect the solid dust in a hot electrostatic precipitator operating above the sublimation point and subsequently lower the temperature below the condensation point and collect the arsenic in a baghouse."

Jan 1, 1976

By Blaisdell J. L, MacPherson G

The present communication records the results of a research investigation conducted in the Porcupine Gold Mines in Timmins, Onto. Soon after silicosis became a compansable disease in Ontario under the Workmen's Compensation Act in 1926, the attention of mine operators and physicians was drawn sharply to the prevalence and importance of this condition in the mining industry. A number of examining centres were established in Northern Ontario by the Workmen's Compensation Board, and the yearly X-ray examination of miners was made compulsory.Although working conditions were soon improved, the mining industry realized that they were confronted by a problem demanding basic research for its final solution. The late Sir Frederick Banting had, for a number of years, been interested in silicosis, and it was upon his suggestion that an experimental investigation was undertaken at the McIntyre-Porcupine Mines Ltd., Schumacher, Ont., in November, 1932. A preliminary report of this investigation was published in 1937 by Denny, Robson and Irwin and a further report by the same authors in 1939.Accepting the theory that silica exerts its injurious effect upon animal tissue through a slow transformation into silicic acid in the presence of body fluids; these authors assumed that if the solubility of the silicious material retained in the lung could be sufficiently reduced, the usual fibrotic response would be modified or would not occur. A search was therefore undertaken for some non-toxic compound that would fulfil this purpose. After investigating ma:qy substances, Denny and Robson discovered in 1936 that the presence of small amounts of aluminum powder almost completely inhibited the solubility of silicious material in vitro. An intensive study of the mechanism involved later showed that the reduction in solubility was due chiefly to a coating of the silica particle with a thin film of a gelatinous hydrated alumina which on drying formed the crystalline alpha aluminum monohydrate boehmite (AI203.H20). The presence of this absorbed layer on the surface of the quartz was indicated by -staining it with aurin (ammonium salt of aurin tricarboxylic acid) and proved by Germer and Storks by means of electron diffraction patterns.Inhalation experiments with animals were at once begun, using pure quartz dust with and without aluminum powder. (See original communications.) These observers showed that while typical silicosis was produced in about 5 months in the control animals receiving silica dust alone, the...

Jan 1, 1945

By Rudolf Gahl

SOME time ago the Detroit Copper Mining Co. had to decide the question whether it would pay to re-treat slime-tailings, and several machines were tested in order to ascertain the type of construction which would give the greatest saving. In previous tests on the ore of this company, several tables proved far inferior to the Frue vanner, and for this reason they did not receive any serious consideration. In the late tests, however, one table was found to surpass the vanner in the percentage of saving made. The Frue vanner used in these tests had been adjusted approximately to the slope which the slime-vanuers in the concentrator of the Detroit Copper Co. had at that time, about 2 in. between the inside of the wooden posts, or 0.272 in. per ft. It had not been determined, however, if this slope was the most economical one for treating the slime-feed in the mill, or for re-treating the tailings from the slime-vanners, and I was instructed to ascertain by test-runs, under different conditions, the best adjustments for the work to. be done. In order to determine if a change in the adjustments of the machines would improve the results, it seemed sufficient to continue running the tests between the vanner and the table before mentioned, keeping the feed and all other conditions the same, but. varying the adjustments of the vanner .from run to run. I employed a vanner-man of long experience to operate these machines, who expressed the opinion that a slope between 2 3/8 and 2.5 in. between the posts (0.323 and 0.340 in. per ft.) would give the best results. Some runs made this way gave a considerable improvement. While for a slope of 2 in. (0.272 in. per ft.) the saving had been only 40.5 per cent. of that of the table, it .was 49.2 per cent. for 2.5 in. (0.340 in. per ft.) slope. A decrease of

Sep 1, 1909

By Fisher WJ

The'treatment of the South Alligator valley uranium ores passed through three phases dictated by economic circumstances during the years 1956- 640 In the first phase high grade ores were treated by hand sorting and wet gravity separation for recovery of high grade concentrate to meet a United States Atomic Energy Commission (U.S.A.E.C.) contract for plus 50 per cent pitchblende concentrates. Secondly tailings from the gravity plant and some high grade ores were trucked to Rum Jungle and sold to the Australian Atomic Energy Comm- ission (A.A.E.C.). Thirdly solvent extraction plants were built at Moline (previously Northern Hercules) by United Uranium N.L. (UOU.N.L.) and at the South Alligator River by South Alligator Uranium N.L. (SOA.U.N.L.). These were the first solvent extraction plants designed in Australia, as earlier plants used the ion exchange process for recovery of uranium oxide. The plants were small, indeed the S.A.U.N.L. 15 ton per day plant was possibly the smallest commercial plant known, but they operated efficiently with good recoveries, and were placed on a care and maintenance'òbasis when contracts were filled. Sulphuric acid was supplied in bulk to both plants by the A.A.E.C. from the 30 ton a day acid plant at Rum Jungle. Gold was recovered as a by product of uranium ore from the Moline plant.

Jan 1, 1968