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By Paul M. Tyler

THE farmer pays the phosphate miner! Phosphorus is used in fireworks; goes to battle in military smoke screens, incendiary shells, and tracer bullets; and, in vermin destroying pastes, does its part in the war against insects. A lemon phosphate can be had for a nickel at most soda fountains, and tens of thousands of tons of phosphate rock are mined annually for use in the food industries, chiefly for making monocaleium phosphate baking powder. Sodium phosphate cleaning, washing, and scouring compounds consume substantial quantities: the iron and steel industries buy a few thousand tons yearly to make ferrophosphorus and to balance foundry-iron furnace charges; and even nonferrous metallurgists use a little for phosphor bronze and other alloys. Phosphoric acid, its salts, and diverse other derivatives of this versatile element have countless applications, and industrial outlets are increasing rapidly, especially in the United States. Nevertheless, in this country nearly 90 per cent and in the whole world fully 95 per cent of the phosphate rock consumed is absorbed ultimately in agriculture.

Jan 1, 1938

By Li YQ, Yoon RH

The photoresponse of natural mineral pyrite and galena electrodes has been studied in aqueous solutions on freshly fractured surfaces (some fractured in situ) using moderate overvoltages. When fractured in situ, the electrode potential of both minerals instantly drops several tenths of a volt. Pyrite exhibits a spontaneous anodic photocurrent at fracture, which indicates upward band bending (depletion layer) on the n-type electrodes. The negative surface charge responsible for the depletion layer is believed to arise from a surface state that is intrinsic to pyrite surfaces, possibly modified by hydroxide ion adsorption. The flat band potential, Vty, of pyrite is at approximately -1.0 V (SCE) at pH 9.2 but to reach V(b, pyrite has to be cathodically decomposed. In contrast, galena assumes the flat band potential at fracture. Subsequent polarisation of galena at potentials positive of Vth produces an anodic photocurrent (upward band bending) and polarisation negative of Vro a cathodic photocurrent. Most of the galena electrodes studied were degenerate n-type and at potentials negative of Vtb, no cathodic photocurrents are observed, indicating the bands cannot be bent downward, consistent with the Fermi level at the surface merging with the conduction band edge near Vn,. Several were close to intrinsic, with the photocurrent changing sign near Vn,.

Jan 1, 1993

By John W. Antalovich

Normally I would like to begin a talk on photogrammetry by defining the word. However modern technology has changed the science so radically that it bears little resemblance to its original definition. Photogrammetry as defined is a science of taking accurate measurements from photography. Today's photogrammetrist, in addition to working with photography, finds himself working with magnetometers, infrared scanners, radiometers, holo¬graphy, lasers, side-looking radar, digital interfaces, computers and countless other modern space age concepts. The modern photogrammetrist is a pilot, photographer, lab technician, mathematician, geologist, programmer, engineer, physicist, and cartographer. His modern instrumentation and many spheres of activity all have a role in the environmental sciences. For example, the magne¬tometer which measures the earth's magnetic fields is used to locate the earth's ore deposits. The infrared scanner captures the heat emitted from the earth to detect ground waters and thermal pollutions. To elaborate on each of his many endeavors would take volumes rather than this short paper. I have elected therefore to discuss what I feel is his most important role in the environmental sciences - that of cartographer.

Jan 1, 1970

By Vincent Doyon

For several years, the GDD SSW EM Probe is being used in nickel?s mines in Canada and Brazil to define ore limits, reduce dilution and predict nickel grades. It is used with success to test most if not all percussion blast holes at all Falconbridge Mines in Sudbury and Raglan and all Inco?s Thompson mines. However, after testing the SSW Probe in other metal mines, we realized that EM conductivity does not define ore limits by testing blast holes for copper, zinc or gold. For non-conductive ores, no instrumentation is yet available on the market to reduce dilution, by outlining quickly and inexpensively the real shape of an orebody. To that effect, Instrumentation GDD Inc has developed a new revolutionary photonic probe that will make the reduction of dilution possible by probing blast holes. Once surveyed with the probe, a computer draws graphs of the ore grade as a function of depth for each blast hole. A contribution by Canada Economic Development made possible the development of this new technology. Canmet and Soredem also cautioned this technology developed by Instrumentation GDD Inc. This new photonic probe will allow: 1) to better understand the shape of the orebody 2) to raise the grade of the ore fed to the mill 3) a more complete extraction of the ore 4) to raise the competitiveness of mines

Oct 1, 2004

By D. Botha, J. F. Cronjé

"SynopsisAlthough women all over the world have been involved in mining activities for centuries, mining has always been considered a very masculine industry due to its heavily male-dominated workforce as well as the physicality of mining work. The mining industry has not been an obvious career choice and preferred place of employment for women; women were mainly employed in administrative and advisory positions. Until 1994, women were legislatively prohibited from being employed in underground operations in South Africa, but the Mines Health and Safety Act, No. 29 of 1996, removed these restrictions. In addition, new mining legislation (the Mineral and Petroleum Resources Development Act, No. 28 of 2002) and the accompanying Mining Charter make specific provisions for the inclusion of women in core mining activities and require 10% of core positions to be filled by women.This article voices perceptions of the physical ability of women employed in core mining positions. Findings are drawn from empirical work undertaken at platinum, phosphate, and copper mines. Quantitative and qualitative research paradigms are used. It is evident that women find it extremely difficult to perform mine work that requires physical strength and stamina. Practical recommendations, informed by the literature review and empirical findings, are made with the objective of contributing to the sustainable deployment of women in the mining industry.IntroductionFor many years, mining has been considered the foundation of the South African economy. Although the mining industry in South Africa is currently under considerable pressure and experiences various challenges, including escalating operational costs, electricity tariff increases, safety-related issues and associated production stoppages, poor productivity, labour unrest, and reduced demand both globally and domestically, it remains a key contributor to the national economy and development of the country (IDC, 2013, p. 9).Until 1994, women were legislatively prohibited from meaningful participation in the mining industry and were denied access to skills and jobs, self-employment, and entrepreneurship. The newly elected democratic government in 1994 initiated substantial socio-political and economic transformation in South Africa. Nearly every sector in the country was transformed and re-shaped, primarily through sector-specific legislation, but also through negotiations between government, industry, and labour unions to create and refine the so-called sector charters, which included the Mining Charter. The vision of the new regime, the African National Congress (ANC), was to ‘transfer power to the people and transform society into a non-racial, non-sexist, united, democratic one, and change the manner in which wealth is shared, in order to benefit all the people’ (ANC, 2007)."

Jan 1, 2015

By F. R. Erick Mulder

"AbstractTwo bottom-hole samples have been taken from two new completions in the Turner Valley field, Royalite Lowery No. 8 on the west flank and Royalite No. 73, which was deepened into a lower fault block, on the northeast flank. From the bottom-hole oil of Royalite Lowary No. 8 a synthetic sample was prepared to simulate the original fluid in the reservoir, saturated at the gas-oil contact conditions. The sample from Royalite Lewery No. 8 has been shown to be the original fluid present at this well and represents the oil phase near the oil-water contact in• the reservoir. Complete chemical analysis, P.V.T., and viscosity data have been obtained on these reservoir fluids, which represent the range of saturation from the gas-oil to the oil-water contact in the Turner Valley oil structures. Sampling techniques and the application of the analytical data to reservoir conditions and field operations are discussed. Super-compressibility curves for an average separator tail gas have also been prepared. These data have not been available before. They will be of fundamental value in futu.re reservoir engineering studies of this field and will also serve as a guide in determining operating practices."

Jan 1, 1950

By Mariola Saternus

The quality of the liquid metal has the biggest influence on the quality of the final products. In the metallurgical industry, and especially in aluminium production the refining process is the important technological stage. Today the most popular are refining reactors with impellers like URO ? 200, which can generate small gas bubbles. A rotary impeller also makes the metal bath to be stirred well. There are two basic hydrodynamic parameters: the flow rate of refining gas and the mixing of refining gas (impeller rotation) that influence metal stirring and generating small gas bubbles. The paper presents the influence of the flow rate of refining gas on the hydrogen removal process from aluminium (final hydrogen concentration), taking into consideration the refining process of AlSi7Mg alloy and using URO - 200. The mathematical model of this process is also presented. The equation needed for calculation of the final hydrogen concentration as a function of the equivalent bubble diameter is shown. Basing on this equation the calculations of bubble diameter and optimal refining time are done. This paper presents the physical model (the water one) of aluminium refining process and the gas dispersion taking into account the fact that the gas flow rate is changing from 2,5 to 17,5 l/min and the impeller speed is changing from 0 to 400 rpm. Schemes of gas dispersion in liquid metal in comparison with the model data are shown and the optimal values of the gas flow rate and the impeller speed are chosen.

Jan 1, 2006

The Physical Basis of Non-Random Breakage in an Iron-Oxide Ore Hosted Copper Gold Ore

Sep 13, 2010

By Paul Laforest, Michael Moats, Daniel Majuste

The interaction of anode and electrolyte chemistry in copper electrorefining is complex. This is especially true with regard to the behavior of Group 15 elements (As, Sb, and Bi). To better understand this system, laboratory electrorefining experiments were conducted using commercial anodes with As/(Sb + Bi) molar ratios of 0.54 and 3.8 and an electrolyte collected from a commercial refinery. The effect of adding thiourea during plating was also examined. Twenty-one hour copper deposits were produced in the laboratory to simulate starter sheet production. The mechanical properties of the electrodeposited copper as measured by an industrially relevant empirical bend test and a one-point bend test developed by UFMG are reported. The crystal structures of the samples were also examined.

Mar 1, 2017

By Grieveson P, Terry B. S

Carbothermic reduction of sulphide minerals for achieving a selective separation of metallic species from complex minerals has been discussed by considering the prevailing oxygen potential during the course of reaction. Construction of univariant plots for the reduction of sulphides with carbon monoxide gas or carbon and in the presence of either lime or anhydrous calcium sulphate is the key feature of this work. The theoretical calculations for univariants in the Cu-Fe-S-O system indicated a preferential separation of metallic copper and iron by imposing a chemical potential. This is evident from a logarithmic plot of sulphur dioxide partial pressure against reciprocal temperature. The results are compared with empirical data for the reduction equilibrium. The reduction behaviour of the constituent sulphides are also discussed together with the experimental results and theoretically predicted phase stability diagrams.

Jan 1, 1992

By Ruddle R. W.

An outline account is given of the smelting of copper and the chemistry of the process. A table provides compositions of the more important minerals from which copper is won by smelting. Roasting is discussed as is smelting using reverberatory furnaces, blast furnaces and flash smelting. A brief discussion of converting covers the upright (Great Falls) converter and the horizontal (Peirce-Smith) converter.

Jan 1, 1953

By E. Peters

As in other fields of Extractive Metallurgy, Hydrometallurgy is preoccupied with separation processes and with oxidation-reduction processes. The physical chemistry of each type of process can be described in terms of thermodynamic equilibria and in terms of reaction kinetics. Reaction kinetics are much more important at the low temperatures limiting hydrometallurgical processes than in com- parable pyrometallurgical operations and the number of cases in which the kinetics can be described by simple liquid-phase mass-transfer models are sharply limited. It is convenient to subdivide the applicable rate phenomena into processes in which (a) interface reactions control the rate,(b) mass transfer processes control the rate, (c) solid state process affect the rate, (d) thermodynamically predicted phase changes or molecular reactions fail to take place, (d) metastable substances or supersaturated phases persist, and (elchomogeneous reactions in solution affect the chemistry and the kinetics. Examples are drawn from the unit steps of leaching, cementation, hydrogen reduction, and electrowinning.

Jan 1, 1973

THE metal iron has physical and chemical properties which are somewhat different from those of steels, but a knowledge of the pure metal is a useful starting point in studying the behavior of steels. Solid iron exists in two different crystalline forms, called alpha (a) and gamma (?) iron, the former being the ordinary form at room temperature. When heated above the "A2 point," 1400°F. (760°C.), the metal becomes non-magnetic, and at the "As point," 1670°F. (910°C.), it undergoes a change in crystalline form to become gamma iron. In the range 1400 to 1670°F., it is sometimes called beta (0) iron to distinguish it from the magnetic alpha, but the two are identical in crystal structure. When gamma iron is further heated to 2550°F. (1400°C.), it changes into delta (d) iron, which is identical with beta or non-magnetic alpha iron. Pure iron melts (in a hydrogen atmosphere) at 2795°F. (1535°C.); the melting point is generally lowered by alloys or impurities. PROPERTIES OF IRON AT HIGH TEMPERATURES Many of the properties of iron undergo abrupt changes at the transition temperatures. (1) For example, in heating through the As point a sudden shrinkage in volume occurs. Similarly, melting is attended by sharp physical changes such as an increase in volume. Table 27 contains a summary of the measured physical properties of pure iron at several temperatures. Usually the properties change smoothly within the range of stability of a given form, but this is not always the case. For example, the specific heat reaches a sharp maximum at the A2 point although no transformation occurs. Solvent Powers of Liquid Iron. Liquid iron is capable of dissolving most of the other metals and many nonmetallic elements as well. Of the metals which are liquid at the melting point of iron only lead, silver, and bismuth refuse to dissolve to an appreciable extent. The non-metals presumably dissolve by virtue of the formation of an iron compound; for example, sulphur is thought to dissolve as the compound FeS. However, there is no satisfactory method of proving that this

Jan 1, 1944

By C. P. Broadbent

The process metallurgy of many nickel laterite smelting operations is controlled largely by the physical chemistry of the slag system. Consequently, accurate phase diagram information and physicochemical property data are essential to interpret and predict the behaviour and optimisation of the overall process. The system (SiO2 - MgO - FeO) first described by Bowen et al. between 1914 and 1935 and the system (SiO2 - MgO - FeO - Fe2O3) determined by Muan and Osborne in 1956 are of particular relevance to the study of nickel laterite smelting slags as these systems form a reasonable approximation of many industrial slags. This paper will review the literature for these (and other relevant) phase systems. In addition data available from the ternary and (quasi)ternary phase diagrams will be compared with data obtained from industrial slags. The physico-chemical properties under consideration will include; melting and crystallisation behaviour (solidus and liquidus temperatures), viscosity - temperature relationships, heat flux considerations, electrical conductivity, surface and interfacial tension.

Jan 1, 1993

By Animesh Jha

"Fine ceramic powders (<500 nm) exhibit exceptional physical and mechanical properties in engineered structural ceramics. The production of fine powders, in particular the non-oxide ceramics, via a cheaper route than the organic solvent route has been rather elusive. This paper examines the physical chemistry of sub-oxide vapour-phase reduction reaction for the nucleation of non-oxide ceramic phase. Well known vapour species eg SiO and BO in the production of technical ceramic powders (SiC, BN) are particularly discussed for understanding the nucleation process of SiC and BN ceramic phases respectively. The regimes of partial pressures and temperatures are particularly 'identified. The calculated nucleation rate as a function of the temperature is compared with the experimental results on powder morphology. The production of amorphous and nanocrystalline h-BN powders is discussed in the context of substrate structure and thermodynamic parameters.IntroductionThe physical and mechanical properties of ceramic components are strongly dependent on the powder particle size and morphology used for their fabrication. For example the strength (Os) of the structural ceramic components increases with decreasing average grain-size (d) in accordance with the Hall-Petch relationship: Os = 0""0 + k/(d)1/2. Here k is an empirical constant which can be established from the graphical relationship. However as the particle size approaches submicrometer-size range, the dependence of strength on the particle size becomes more complex [1]. The design of ceramic components based on nanometer-size particles have recently become an important field which can offer ceramic materials with properties comparable to their metal counterparts. Several materials based on these concepts have been developed and reported by Niihara [2]. For example, the Al2O 3-SiC nanocomposite, having average B-SiC grain size 0.3-2um with intragranular SiC particulates of 5-10 nm has unusually high strengths (1100 MN/m2) at low and elevated temperatures combined with enhanced fracture toughness (> 4 MN-ml.5) which is an unusual combination in structural ceramics. Besides mechanical properties, as the particle size of ceramic powders approaches the nanometer-size range, the charge transport properties also improve by many times. The effect of particle size on the electrical conductivity of Si3N4-TiN composites has been well documented [3.4]. The size of ceramic particulates without doubt plays a pivotal role in determining the properties of ceramic components."

Jan 1, 1996

SLAG composition, slag constitution, reactions in slag, and reactions between slag and metal-in other words, the physical chemistry of slags-are matters of great importance to the open-hearth operator, whether or not he makes use of any detailed knowledge of them. Although this is a relatively young branch of the science of steel- making, much progress has been made; however, much remains to be learned, and many of the statements that can be made at present are probably--or even certainly-subject to future change. Nevertheless, the physical chemistry of slags is sufficiently developed to provide a reasonably secure basis for real understanding of steelmaking reactions. FUNDAMENTALS OF SLAG CONTROL By way of introduction, some time is spent in this chapter on effecting an easy transition from some of the more "practical" manifestations of slag to discussions couched in the more formal language of physical chemistry. This necessitates a certain amount of repetition, but it is felt that the purpose of the chapter is best served in this way. Reactions in the metal phase have products that find their way into the slag and are important components thereof; they are discussed in detail in the preceding chapter. Some substances distribute themselves Between slag and metal in definite fashion, and others are found only in the slag. Their reactions are a large reason for this chapter. Limitations of Slag Control. The open-hearth process is essentially oxidizing and cannot be otherwise operated. (Oxygen gradients in the furnace, the mechanism of oxygen inflow, and similar subjects are discussed in Chapter XIX.) As shown in the calculations of material and heat balances for the charge (see Chapter XV), from 25 to 50 lb. of oxygen will flow from air or combustion gases into the charge or molten bath during the heat for each ton of liquid steel

Jan 1, 1944

By Benjamin Vidales

Copper in concentrations above 0.5 weight percent in iron and steel causes hot shortness. This tendency is intensified in the presence of dissolved tin above 0.05 weight percent in the alloy. The understanding of the mechanism of removal of copper from molten iron and steel is of industrial importance. In this investigation, we present the experimental results of the removal of copper from molten iron using sulphide flux in the temperature range 1000°-1500°C. The solution thermodynamic properties of binary sulphide melts have been estimated by using the relevant phase diagrams and the behaviour of copper sulphide in these melts is discussed. The kinetics and thermodynamics of the removal reaction are also explained and, the experimental results are also reported showing the equilibrium distribution of copper and sulphur in molten iron.

Jan 1, 1995

By N. M. Levine

This work defines and systematizes the physical factors of the problem of leaching and demonstrates for the first time the utility of macropore volume, micropore volume, specific surface, pore size distribution and permeability as parameters of leaching based on a study of the recovery of uranium from the Top Black member of Chattanooga Shale.

Jan 1, 1962

By George I. Adams

PHYSICAL AND CLIMATIC DIVISIONS. PERU is divided into three regions-the coast, the sierra, or high mountainous region, and the a montana," or forest region of the Amazon basin. The Coast.-The coast is an arid region. No rain falls excepting in the extreme northern part, which borders the Gulf of Guayaquil. There is, however, a slight precipitation in the form of mist (garua), which occurs on the coast hills during the so-called winter months. The aridity of the coast is due principally to the antarctic or Humboldt ocean-current, which, being cold and having a temperature lower than that of the land, absorbs rather than produces vapors. The coast mists occur during the season when the land is relatively cold. Near the Gulf of Guayaquil the antarctic current diverges from the coast, so that in the Tumbes valley and adjacent country the conditions in the summer months are such as produce rains. In the remaining valleys of the coast, agriculture is made possible only by means of irrigation, and is accordingly very limited in extent, although rich and varied. In the northern and south-central portions of the coast, plains extend inland from the sea, while in the southern part there is a coastal plain separated from the Pacific by a range of coast hills. Between the northern and south-central plains, as well as between the south-central and southern, the foothills of the sierra descend to the seacoast. The Sierra.-The sierra embraces the high land dominated by the lofty cordilleras of the Andes. In the southern part of Peru there are two cordilleras, the western and the eastern, which enter from Chile and Bolivia respectively, and inclose between them the Titicaca Lake basin. To the north of Lake Titicaca these cordilleras unite in the knot of Vilcanota, south of Cuzco. From this knot three cordilleras, known as the western, the central, and the eastern, extend to the northward, reuniting in the

Jan 7, 1908

By G. J. McDougall

After defining activated carbon, the author describes its structure and outlines the physical characteristics distinguishing one type of activated carbon from another. The adsorptive properties of these carbons, the raw materials used, and the manufacturing processes-chemical activation, and physical or thermal activation-are outlined. The high-temperature thermal route (which is the most important for the products employed in gold recovery) using coconut shells or coal as the raw material is then discussed In some detail.

Jan 1, 1991