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By R. H. Waddington

Historical The limitations of reverberatory furnace operation have prompted many investigators to consider electric furnaces for melting electrolytically refined cathode copper. In the majority of cases where experimental work was performed, the furnace used was of the granular resistor, induction, or indirect-arc rocking type, and attempts to adapt the three-phase direct-arc furnace to copper melting appear to have been relatively few. In 1935, the International Nickel Company of Canada, Limited, carried to an advanced stage its experimental investigation of continuous melting of copper in the three-phase direct-arc furnace, and demonstrated that this process was technologically and economically practicable. Trial operations were conducted at the Huntington, W.Va. works of the Company, and were followed by the installation at Copper Cliff, Ontario, in 1936, of a full-scale unit for commercial operation. Two years later, a second unit was installed -which raised the electric melting capacity to a point permitting complete replacement of the coal-fired reverberatory furnace operation in the production of refined copper castings.

Jan 1, 1946

By K. D. Bulin

"An interesting brief history review of shovels as the primary excavating tool will permit the reader to see that immeasurable development and resources have preceded the shovel excavators which today are used extensively throughout the mining industry. With this as a background, the shovel manufacturer has the ability to utilize his resources best in those areas of shovel development in which the maximum benefits of increased reliability, performance and ease of maintenance will improve the operating rewards to the user of the equipment. The author explains the function of the shovel as a part of the material handling system. A detailed description of those areas of the shovel in which the most recent developments and major improvements have been implemented in the manufacture of the shovel excavator arc included."

Jan 1, 1973

By W. J. Cherones

This paper describes the history of the development and application of the electric mining shovel in open-pit mining, dea1ing particularly with far-reaching advancements in three primary areas: metallurgy, mechanical design and electrical systems. Hoist drives and crowd drives, including the Magnetorque and Electrotorque systems, and the integral propel drive are given close attention.

Jan 1, 1972

By D. D. Howat

In the field of high temperature smelting processes there have been two dramatic changes in the past twenty years. These are, first, the application of tonnage oxygen for direct injection for the refining of molten iron and other metals and to provide the means of enriching air used for the combustion of fuel. Second, the application of electric power for the generation of high temperatures in place of the combustion of fossil fuels. Of these two developments the application of tonnage oxygen for the refining of molten iron has virtually revolutionised the steel industry throughout the world. The magnitude of this development is exemplified by the fact that less than 5 per cent of the world's steel production in 1960 was made by this process or 16 million tons out of a total of 350 million tons of steel produced, while in 1970 over 40 per cent of the world steel production was made by this process, ie, 251 million tons out of 628 million tons total. In the same period the proportion of steel produced by the old-established open-hearth process has shrunk from 75 per cent to 38 per cent. In the whole history of the development of high temperature metallurgical smelting processes there has never been anything remotely approaching this. The other development, the application of electric power for the generation of high temperatures has not had the impact of the oxygen injection process but I believe that what we should call the electric smelting revolution in metallurgical processes has very far-reaching ramifications for steel production and other pyrometallurgical processes. This may seem a bold and brash statement but it must be remembered that the oxygen injection process constitutes a link in the chain critically dependent upon the production of vast tonnages of molten iron from very large modern blast furnaces. The Achilles heel of this chain of processes, upon which such a large percentage of the world's supply of steel depends, is the availability of metallurgical coke in turn dependent on natural resources of coking coal. Without any exception each industrial country in the world faces a shortage of resources of coking coal and in some cases a critical shortage. Certainly within the present century the major iron and steel producing countries of the world will face this critical shortage of coking coal and major modifications to steel making processes will become inevitable. W. F. Cartwright (Deputy Chairman of B.S.C) said recently that there are considerable doubts as to whether the world will be able to provide enough coking coal to meet world steel demands from the late 1970's onwards if the B.F.remains the main means for making iron from ore. This is one of the supreme ironies of the world metallurgical situation to-day when the technology of iron and steel production has reached an extremely high peak of technical efficiency. The newest modern iron blast furnace capable of producing 6 000 to 8 000 tons per day of molten iron represents probably the most efficient piece of high temperature metallurgical plant and operation known to man. The conversion of this molten iron into steel by the oxygen injection process has made available to the engineering industry steel of a quality and at a price which is quite remarkable. Yet this vast metallurgical pyramid rests on the completely insecure and uncertain foundation of inadequate world resources of coking coal. The shortage of reserves of coking coal in this country is acute and it is possible that these resources will be exhausted within the next twenty years. Yet unless some completely unexpected catastrophe occurs the demand for steel in this country will probably rise at a faster rate than in the Western world due to the expansion of the Bantu population and the increased standard of living. To offset the inevitable shortage of coking coal are our much greater resources of bituminous coal which although of low grade provide a suitable fuel for electric power generation. The geographical disposition of the coal fields in relation to the great industrial areas of the Transvaal makes it inevitable that the development of the pyrometallurgical industries must depend heavily on electric power. The position in this country with regard to electrical power generation and consumption is rather anomalous. Per capita consumption of electric power is high - in 1964 almost twice the world average of 870 KWH and twenty-five times the average of 34 KWH for the Continent of Africa. In 1964 fifty-four per cent of the total world electric power was used in industry - the ratio being approximately 1/9 mining to manufacturing uses. As shown in Table I in 1969 67.2 per cent of the total output of electric power from ESCOM was used for mining and other industrial uses but almost in the ratio 6/4 mining to industrial uses. These figures emphasise the enormous importance of the mining industry to the economy of this country and underline the major contribution made by the gold mining industry. What is of very significant importance is that although the mining industry remains by far the largest single consumer of electrical power the consumption of power for industrial uses is rising rapidly as shown in Table II.

By William L. Saunders

MANY members of the Institute, who participated in the visit made, during the Bethlehem meeting of February, 1906, to the shops of the Ingersoll-Rand Company, at Phillipsburg, N. J., inspected with interest the new Electric-Air drill, which the company had set up for the purpose of showing it in actual operation to American. mining engineers. At the request of the Secretary of the Institute, I promised at that time to prepare a paper for our Transactions, describing the construction and advantages of the machine. But such a paper would then necessarily have contained much that was only expected or claimed by the designers and manufacturers of the drill, and not yet incontrovertibly proved by varied and long-continued practice. However moderate such statements might have been, they would have given inevitably to the paper, to some extent at least, the air of a prospectus, rather than of a technical contribution. I therefore decided, with the Secretary's approval, to postpone the writing of the promised paper until it could set forth the results of adequate actual practice, as well as the latest details of construction, etc., based upon practical experience. That period has now arrived. The Electric-Air drill has been exhaustively tested in the field, under varied and arduous conditions and upon the hardest rocks. It is now fairly in the field; its merits and performances are matters of unimpeachable record, and its place among established competitors can be definitely determined. As a representative of the Ingersoll-Rand Co., as well as a member of the Institute, I may be permitted to add that my company, being largely interested in the manufacture of air-

Jan 9, 1907

By A. E. Martin, Gerhard Derge

IF the molecular constitution of molten slags were better known, the nature of chemical reactions in slags and between slags and metals could be better understood and as a consequence might be better controlled. Constitutional information can be obtained by studies on either the molten or the solidified slags. Valuable as the studies on solidified slags admittedly are for many purposes, especially as control methods in steelmaking, they are always of questionable value in giving information on the molecular constitution of liquid slags. However, the characteristics of molten slags such as viscosity, rates of diffusion, and electrical conductivity can be determined experimentally and interpreted along with other knowledge on slag-metal and slag-gas reactions so as to provide direct information on liquid slags. Metallurgists are accustomed to regard reactions in molten slags as involving only neutral molecules, whereas it is quite possible that ionic constituents are actually involved. For example, the dissociation of calcium silicate usually is represented as Ca2SiO4 = 2CaO + SiO2 although a reasonable alternative would be to write Ca2SiO4 = 2Ca+2 + Si04-4 Such ionic dissociation has been suggested frequently without adequate experimental proof. This paper deals especially with electrical conductivity measurements on slags of the blast-furnace type. These measurements were made to determine whether or not slags are ionized and, if so, to provide a qualitative estimate of the extent of ionization. Electrolysis experiments that indicate the identity of the ions present are also reported. Since the presence of ions has not been considered carefully in modern slag studies, the relevant literature will be reviewed. REVIEW of LITERATURE In 1906 Aiken1 obtained a patent for a continuous process of producing iron electrolytically by passing a direct current through a bath of FeO-SiO2 to which iron oxide was added periodically to maintain a uniform concentration. The patent also included the addition of CaO and MgO to the bath to lower its melting point. The silicate melts involved were thus in the same system as basic open-hearth slags but with higher FeO and lower CaO contents. Electrical conductivity measurements were made on some molten silicates by Doelter2 in 1907. Natural silicates, such as

Jan 1, 1943

By F. D. Mahone

MUCH crude oil, as produced from the well, carries varying amounts of water, which may be present as free water in' globules sufficiently large to settle out, in time, if the fluid is allowed to stand, or as an emulsion formed by myriads of minute water particles, each surrounded and entrapped by a film of oil through which it cannot break under the action of gravity alone. Such an emulsified mixture of oil and water is commonly termed "cut oil." When such an emulsion is subjected, under proper conditions, to the .influence of a high-potential alternating-current field, the minute water particles rupture the enveloping oil films and coalesce into larger water droplets this procedure continuing until all the water is freed into drops of such size that they readily settle out. This action has been photographed by the micro-moving-picture camera; under, the microscope, the breaking-up of the emulsion, as described, is seen to be accomplished in a few seconds. The low power requirements of the process, from records of commercial plants, substantiate the theory that the action is that of a multitude of electrical condensers in series, rather than that of a number of conducting paths. The minute water particles serve as the metallic elements, or plates, of the condensers and the separating oil acts as the dielectric. Such surface charges as the particles may have are removed, and the intervening oil is broken, probably electrically by the voltage and mechanically by the attractive force between adjacent oppositely electrified particles. The principle of breaking up an emulsion under the influence of an alternating electric field was discovered by F. G. Cottrell and Buckner Speed, through experiments conducted, at the University of California, which resulted in a plant being installed on the property of the Lucile Oil Co. in the Coalinga field, California, early in 1909. This plant was able to reduce 14-per cent. emulsion to less than 2-per cent. with commercial success.

Jan 7, 1924

By G. E. Archie

THE usefulness of the electrical resistivity log in determining reservoir characteristics is governed largely by: (I) the accuracy with which the true resistivity of the formation can be determined; (2) the scope of detailed data concerning the relation of resistivity measurements to formation characteristics; (3) the available information concerning the conductivity of connate or formation waters; (4) the extent of geologic knowledge regarding probable changes in facies within given horizons, both vertically and laterally, particularly in relation to the resultant effect on the electrical properties of the reservoir. Simple examples are given in the following pages to illustrate the use of resistivity logs in the solution of some problems dealing with oil and gas reservoirs. From the available information, it is apparent that much care must be exercised in applying to more complicated cases the methods suggested. It should be remembered that the equations given are not precise and represent only approximate relationships. It is believed, however, that under favorable conditions their application falls within useful limits of accuracy.

Jan 1, 1942

By G. F. Cross

INTRODUCTION THE electrical system associated with the mining development of the Hudson Bay Mining and Smelting Company, Limited, at Flin Flon, Manitoba, may be conveniently divided into three main parts, namely, the Island Falls power plant, the transmission line, and the distribution systems at the mine and metallurgical plants. For a description of the Island Falls power plant and the transmission line, the reader is referred to the paper, to be presented at this meeting, by R. W. Davis and M.F. Huffaker (1). The transmission line and sectionalizing combinations are shown diagrammatically in Figure 1. The present paper deals with the distribution systems at the Flin Flon mine and metallurgical plants. THE FLIN FLON DISTRIBUTION SYSTEM In the high-tension sub-station at Flin Flon, each incoming 110 kv. line is provided with manually operated, gang-type disconnecting switches. Each line is connected to Canadian General Electric type F.H.K. 39-60B-F.2 T.P.S.T. 110 kv. 400 amp. oil circuit breakers, each provided with M.K.4 centrifugal motor-operated closing mechanism. Gang-type disconnecting switches are installed on each side of incoming line breakers, and a complete ring bus system is formed through station tie breaker, which is' further provided with gang-type disconnecting switches on either side. The?bus tie breaker is of Canadian Westinghouse design, type G.22B, 110 kv., 400-amp., solenoid-operated. All three breakers are provided with bushing-type current transformers, and the two line breakers are further equipped with bushing-type potential devices. Oxide film lightning arresters (121 kv.) are installed on each incoming line and are located outside the station. Each line is further provided with interlocked gang-operated ground disconnecting switches. All disconnecting switches are mechanically connected to auxiliary switches, which provide pilot service to indicating lamps in the remote-control room, located in a separate building.

Jan 1, 1935

By J. A. Russell

AS THE LOCAL electric generating plants increased in size and capacity and costs of producing electricity came down, it became apparent that it was no longer good economy to operate individual boiler plants at the Company's various collieries to power steam hoists and compressors. Great economies could be made by burning the Coal at central power plants and using electric power at the collieries. During the period after the end of the war, a steady and continuing programme of replacing first the smaller steam-driven units, and later the steam-driven compressors, was undertaken, and finally the larger hoists, those at No. 12 Colliery in New Waterford and No. 20 Colliery in Glace Bay, were the last units operated by steam.

Jan 1, 1958

By R. E. Wade

THE Butte, Anaconda & Pacific electrification is of peculiar interest, in an incidental way, to the entire mining fraternity, and especially the engineering branch, not only in this great Northwest country but throughout the entire Western mining country, which is rich in minerals and water power. It is probably fair to say that the prime object of mining and smelting engineering is to reduce the cost of production, and in the case in hand the relative location of mines and smelter brings the cost of transportation of ore to the front. While some might assign this item to the railway people, it is inseparably a part and parcel of the general scheme of the production of metal from the ore. In considering the electrification of the B., A. &. P. railway the mining and smelting engineer, above all, wants to know what saving will be effected by the change in motive power. Unfortunately the new power has been in use during a very limited period and on the Smelter Hill section of the road only, and no reliable data, from actual service conditions, can be obtained until the entire electrified section has been in service for a reasonable length of time. Any remarks on this subject at the present time, therefore, must of necessity be general in nature and more or less descriptive. The railway, electrical and mining worlds and the country in general are indebted to the B., A. & P. railway for the pioneer work it is now doing, as it undoubtedly marks the beginning of the electrification, within the comparatively near future, of all transcontinental roads between the Missouri river and the Pacific coast. Together with this goes the development of an untold wealth in water power and all natural resources within the same territory. For the first time in the history of electric railway work, in this country, direct current at a potential of 2,400 volts is being used. With this potential there is a great saving in transmission of energy to the locomotives and there are only two substations, one at. either end and 26 miles apart, for supplying the power for the movement of trains of heavy tonnage over the main line and for switching movements at terminal and intermediate yards, and comparatively little feeder copper is required.

Jan 11, 1913

By Xuyang Liu, Xuewei Lv, Chenguang Bai, Meilong Hu

"The electro-deoxidation process for ilmenite concentrate in molten salt was studied by cyclic voltammetry and AC impedance spectroscopy. The results from cyclic voltammetry are consistent with those of AC impedance spectroscopy. The results showed that the electro-deoxidation process for ilmenite concentrate consists of two steps. In the first step, Fe is reduced from the ilmenite concentrate. The second reaction is the decomposition of TiCh. CaTiCh is an intermediate product. At low voltage, the electrochemical reaction is the main step. With the increasing potential, the diffusion of ion is the main rate controlling step for the electro-deoxidation of FeTiO3.IntroductionTitania and titanium-rich products are mainly prepared from ilmenite concentrates (FeTi03), which contain about 40%-60% T1O2 after ore dressing and other physical or chemical processes [1]. At present, the main methods to prepare titania are the sulfuric acid process and the chloride process, but the sulfuric acid process consumes a large amount of sulfuric acid and the materials requirements for the chloride process are strict [2], Since the Electro-Deoxidization in Molten Salt (FFC) method was put forward in 2000, many researchers have successfully extracted the metal and alloys by this method, such as Ti, Cr, Tb, Si, Al-Si, TiV, FeTi, etc. [3-7], FeTi alloy is a typical hydrogen storage material, and because of its favorable properties, the preparation of FeTi alloy has become a hot research topic [7-9]. However, the mechanism of electro-deoxidization has not been studied thoroughly [10-11]. Therefore, in this study, the electro-deoxidation process for titanium concentrate was investigated by electrochemical methods, and the study makes a contribution to improving the current efficiency of the electrolysis."

Jan 1, 2012

The dissolution behavior of gold and silver from Au/Ag alloys in aerated cyanide solutions has been investigated using rotating disc electrodes. The variables studied included concentration of cyanide, oxygen partial pressure and rotating speed of the disc. The dissolution potential and the rate of dissolution were obtained in view of the anodic and cathodic current-potential relationships. The results were discussed in terms of a mixed potential theory. The results showed that the dissolution rate of gold and silver from the alloys was partially controlled by chemical reaction, but largely by transport of either oxygen or cyanide, depending on their relative concentration under the experimental conditions employed in this study.

Jan 1, 1995

By Chi-Ming Chang

Alloy powders are commonly used in the purification of zinc sulfate solutions for use in standard electrowinning practice. The primary goal of this research was to study the use of zinc-lead alloys for similar reactions in the galvanic stripping of impurities from organic solutions. The effects of various parameters on the electrochemical behavior of commercially produced zinc-lead alloy powders were determined. A qualitative evaluation and summary of the influence of the more pertinent parameters on iron removal from di-(2-ethylhexyl) phosphoric acid (D2EHPA) by galvanic stripping is given. Water concentration, oxygen content and reaction temperature were the principal factors affecting the reaction rate and process efficiency. Activation energies were also calculated and indicated that the reaction changes from chemical to diffusion control .with increasing temperature in the range of 35" to 45°C. The results showed that zinc-lead alloy gave faster reaction rates with less sensitivity to process variables than SHG zinc as a reducing agent for galvanic stripping. The role of lead could be as cathodic sites for the reaction which enhances the zinc dissolution or anodic half reaction. The morphology of the zinc-lead alloy surfaces, before and after the reactions, supports this assumption.

Jan 1, 1998

By Geir M. Haarberg

Electrochemical techniques, mainly linear sweep voltammetry and potential step chronoamperometry, were used to study the behaviour of dissolved phosphorus species in cryolite-alumina melts, The presence of AIPO4 or Na3PO4 gave rise to voltammetric current waves due to electrode reactions involving phosphorus species at potentials where dissolved alumina is stable in cryolite melts, Diffusion kinetics for dissolved P(V) species were studied, Data from industrial cells were used to determine mass balances for phosphorus, For cells being fed with secondary alumina, more phosphorus tends to end up in the produced metal, Laboratory experiments to study the effect of phosphorus in the bath on the current efficiency for aluminium were also carried out.

Jan 1, 2004

By A. P. Paiva

With the aim of establishing a valuable alternative to the conventional methods, studies regarding the recovery of precious metals by solvent extraction have been increasing over the past few years. In this work, the selectivity of extraction presented by Cyanex 471X toward silver is investigated. Simulated chloride solutions considering contents of iron and copper usually present in actual leaching practice were used. The characterization of the aqueous solutions - in terms of the multiple equilibria established by the chlorocomplexes of the different metals and their relation to the total chloride concentration of the base-electrolyte - was successfully carried out by cyclic voltammetry. The results obtained support the important contribution of the electrochemical techniques for the understanding of the overall extraction phenomena.

Jan 1, 1994

By Garry W. Warren

The electrochemical oxidation of chalcopyrite in the absence of-a chemical oxidant was studied in ammonia/ammonium sulfate solutions by anodically polarizing electrodes prepared from massive chalcopyrite. The effects of pH, cupric and ammonia ion concentration were systematically evaluated. Kinetic parameters were obtained from the anodic charge-transfer regions of the anodic polarization curves. Increasing ammonia and hydroxyl ion concentrations increased the rate of oxidation. A mechanism is proposed which explains the first order dependence of (NH3) and (OR) associated with a single electron transfer process. An empirical relationship which accurately describes the dependence of the rest potential (i.e. zero current potential) on solution composition is also given.

Jan 1, 1978

By Pengkai Wang, Huimin Lu, Xiaoxiang Zhang

"In this paper, it was studied an electrochemical reduction process of carbon dioxide in ionic liquids such as 1-n-butyl-3-methylimidazolium hexafluorophosphate ([Bmim] PF6) as the electrolyte. The electrolysis experiments were carried out under current and potential controls. The cathode products contained carbon nanotubes, carbon nanofibers, nanographites, and amorphous carbon. To establish the actual current and potential ranges, the electroreduction of carbon dioxide dissolved in the ionic liquid was studied by cyclic voltammetry on glass-carbon (GC) electrode at room temperature. The electrochemical mechanism of carbon dioxide electroreduction was studied for explanation of all obtained results. Carbon dioxide in ionic liquids was electroreduced, similar to metals oxides being electroreduced in molten salts.IntroductionGlobal warming caused by the increase of carbon dioxide in the atmosphere has become one of the most concerning environment problems, so the solution to this greenhouse effect is very urgent. However, the carbon dioxide is also a cheap and abundant raw material that represents a potential source for the production of chemicals and fuels. Therefore, the development of the technologies that achieve simultaneous reduction and conversion of carbon dioxide to fuels is important. The electrochemical reduction of carbon dioxide is one of the effective approaches to transform CO2. Many investigations have been carried out on the electrochemical reduction of CO2 in both aqueous [1] and non-aqueous [2] electrolyte solutions with different electrodes. The solubility of CO2 in water is very low even under high pressure of CO2, and some investigators have brought focus into the electrochemical reduction of carbon dioxide in organic solvents, because they dissolved much more CO2 than water did. However, the hazardous or toxic properties of organic solvents hinder their use."

Jan 1, 2009

By Y. C. Guan

The cementation of gold on to copper and zinc in ammoniacal solutions has been studied using rotating disc electrodes. The cathodic reduction of aurous ammine was studied on a gold rotating disc electrode and the anodic dissolution of copper and zinc was studied in the absence of aurous ammine. The cementation rate was found to be a first order with respect to the concentration of aurous ammine and to be proportional to the square root of the disc rotating speed. Based on the results obtained, it was concluded that the cementation reaction was controlled by mass transfer of aurous ammine to the reaction surface under the experimental conditions.

Jan 1, 1995

By Y. C. Guan

In an attempt to replace the traditional cyanide process of extracting gold, a new technology using ammoniacal solutions has been developed. In this study, the electrochemical behavior of gold in ammoniacal solutions at temperatures above 100°C has been investigated. An electrochemical cell in an autoclave has been introduced to carry out this study. The system consists of a gold working electrode, a platinum counter electrode, and an external saturated calomel electrode (SCE) which is connected to the autoclave system through a Birch wood plug. Techniques used in this study included potentiodynamic polarization, galvanostatic polarization, cyclic voltammetry, and Tafel polarization. The electrochemical reaction mechanisms governing the dissolution process are presented.

Jan 1, 1996