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By F. M. Stephens

This paper is to be presented at the annual meeting of the American institute of Mining and Metallurgical Engineers, San Francisco, February 1959. Permission is hereby given to publish with appropriate acknowledgements, excerpts or summaries not to exceed one-fourth of the entire text of the paper. Permission to print in more extended form subsequent to publication by the Institute must be obtained from the secretary of the Institute. If and when this paper is published by the Institute, it may embody certain changes made by agreement between the Technical Publications Committee and the authors, so that the form in which it appears here is not necessarily that in which it may be published later.

Jan 1, 1959

By A. Goldberg, T. E. Tietz, J. E. Dorn

INTRODUCTION THE concept that the flow stress for plastic deformation of metals in the work hardening range is a function of the instantaneous values of the strain, strain rate and test temperature was promulgated by Ludwick1 many years ago. This thought has been more or less a guiding principle throughout the immediate period of development and growth of mechanical metallurgy. It has been tacitly assumed or knowingly applied to many investigations on the plastic behavior of metals. Spurred by the theoretical interest and practical importance of the plastic behavior of metals, many investigators have attempted to determine empirical, semi-empirical, and theoretical equations2-18 relating the flow stress with the strain, strain rate, and temperature. Although the applications of such equations have been extensive, the experimental verification of the existence of a mechanical equation of state is weak. Furthermore, some of the available evidence on plastic flow appears to suggest that no simple functional relation between stress, strain-rate, strain and temperature can exist. The mechanical equation of state demands that [a = a(e, E, T)[I]] Where o = true stress = load/instantaneous area e = true strain = In Instantaneous gauge lengths initial gauge length e = true strain rate T = temperature] This formulation implies that [da] is an exact differential. Therefore the flow stress (o) is a function of the instantaneous values of the strain (e) the strain rate (e) and the temperature (T), independent of the previous mechanical or thermal history. Having reached a certain strain, strain rate, and temperature, by any path whatsoever, a definite and fixed value of the flow stress should be obtained. One check on the validity of the mechanical equation of state is easily obtained. Consider the following three tests on the stress-strain curve at constant temperature: [A. Strain at rate [ei] B. Strain at rate i2 C. Strain at rate [Ei] to [ei] and continue test at i2] A graphical representation of possible results of such tests are shown in Fig I. If, for strains greater than [el], test (C) data coincide exactly with the data from test (B), as shown in Fig Ia, a limited verification of the mechanical equation of state is obtained for the range of strain rates from [ii] to [e2]. But if the data from test (C) differ from those of (B) beyond strain [el] where the strain rate is changed from [e,] to [€2i] the mechanical equation of state is not

Jan 1, 1948

By Fashina Olugbenga Emmanuel, Ghazali Akeem, Adegbola Adekunle Amos, Omotoyinbo Joseph Ajibade, Olaniran Oladayo

"Modern engineering materials are required to be light weight and corrosion resistant, coupled with high strength and hardness. In this work, Al formed the parent metal and alloyed with 2.03% of Copper by sand casting process. The cast product 2024 was warm worked at various temperatures ranging from 300 to 5600c at 5%, 10%, 15% and 20% deformation respectively and aged accordingly. The results showed that the mechanical properties vis-à-vis hardness, tensile improved with increasing % deformation at a higher temperature. This was due to the progressive close-up of the voids emanated from casting by increasing deformation which is evident from the micrographs. MATLAB was also adopted to generate a model capable of determining the trend of flow of stress at operating temperatures. This was of immense value due to an increasing impact at higher percentage deformation with temperatures. Hence, Al -alloys will find applications in land vehicles, ships, trains, and aircraft, at elevated temperature.INTRODUCTIONThe problem of safe vehicle design with maximum impact energy absorption is a significant subject in structural crash worthiness design [1]. All engineering designs are expected to ensure the safety of users' life. This informed several studies meant to probe the causes of component failures in equipment, vehicles, and aerospace design and decide on appropriate solutions through materials selection techniques. A common example is in the design of crankcases and heads, piston, and cylinder blocks. As with engine blocks, cylinder heads can be made of Cast Iron or Aluminium Alloy. A head made of Aluminium alloy is lighter in weight than if it were made of Cast iron [2]."

Jan 1, 2013

By A. R. L. Thoresson, S. J. Lennon, F. P. A. Robinson

This paper reports and discusses experimental work carried out on heavy nickel-electroplated turbine-disc steel. Mechanical and fatigue tests were used to determine whether the coating was suitable for turbine-disc applications. It was concluded that dehydrogenation treatment is necessary in order to produce compatibility of the coating and substrate

Jan 1, 1988

By J. A. Venter

Mineralogical studies indicate the Pt-Pd-Bi-Te class to react poorly on the flotation stimuli and indications are that these minerals are slow floaters. However, recent studies performed on a number of minerals from this class indicated strong interactions with potassium ethyl xanthate resulting in the formation of dixanthogen (only one of several xanthate species). The poor flotation response is not a result of poor interaction of xanthate with the surface. It is proposed that the oxidation products of sulfides in the process water interact with the PGM surface. To test this, the effect of thiosulfate (an important oxidation product of sulfides) was investigated by employing electrochemical measurements and FTIR spectroscopy. The electrochemical investigations indicate no strong effect of thiosulfate on the interaction of xanthate with the minerals surface as well as the reduction of oxygenthiosulfate is likely not responsible for the poor flotation response of these minerals in industrial plants.

Jan 1, 2014

By A. J. Hendron, G. Mesri, R. M. Semple

Squeezing ground conditions in hard-rock tunneling are associated with fault zones containing brecciated rock and gouge. Gouge is a stiff clay-like soil that exhibits a propensity to creep. The ground loads applied to tunnel supports in squeezing ground are known to be significantly time dependent. Accordingly, an experimental and analytical study is presented that deals with soil creep and its application to the prediction of tunnel support requirements in squeezing ground conditions. Relatively undisturbed samples of fault gouge obtained from Straight Creek tunnel in Colorado and Pacheco tunnel in California are classified as very stiff to hard clays of low plasticity. Constant-load undrained triaxial compression tests are performed on these materials. A simple, three-parameter creep equation is developed that adequately describes the observed deformation of fault gouge with respect to applied stress and time. The equation is shown to fit existing creep data of various soil types. The creep equation is used to modify an existing continuum-mechanics solution to the time-dependent behavior of unlined and lined cylindrical openings in a creepsensitive medium under a hydrostatic state of stress. Assuming properties for the medium that are representative of the fault gouge materials tested, parameter studies are performed for unsupported and supported tunnels in squeezing ground. The analyses permit estimates to be made of the steel set supports required for tunnels at different depths in various squeezing ground conditions.

Jan 1, 1974

By J. Bigu

A theoretical radiation mine model, suitable for underground uranium nines, has been investigated. In this model, the rate of ventilation and/or the radon (thoron) gas emanation from mine walls are time-dependent. Several cases of practical interest have been investigated including sinusoidal, linear, exponential, stepwise, or a combination of two or more of the above. Analytical solutions were obtained for the time-dependent radon (thoron) gas emanation rate. However, because of the extreme analytical complexity of the solutions corresponding to the time-dependent ventilation rate case, numerical solutions were found using a special Runge-Kutta procedure and the Hamming's modified predictor-corrector method for the solution of linear initial-value problems. The mine model makes provisions for losses of radioactivity, other than by ventilation and radioactive decay, by, say, plate-out on mine walls, and by other mechanisms. Radioactivity data, i.e., radon, thoron, and their progeny. obtained with the above mine model for a number of ventilation and emanation conditions, are presented. Experimental data obtained in an inactive stope of an underground uranium mine for a time-dependent air flow case are shown. Air flow conditions (ventilation rate) were determined by tracer gas techniques using SF6.

Jan 1, 1987

By K Kinnunen

A strong correlation between the reduction degradation index (RDI) of production sinter and the titanium content of the sinter mix was identified at the Ruukki sintering plant between 2000 and 2004. The titanium distribution in different mineral phases was studied using samples from pot sintering tests. Titanium additions were made using two different materials: rutile and crushed titanium-bearing haematite pellets. While both titanium additions clearly increased the RDI, titanium seemed to favour secondary haematite. The study focused on the effect of titanium in haematite, because haematite is reduced to magnetite in the RDI test. During the haematite-magnetite reduction, reduction degradation was observed. To increase accuracy, the phenomenon was investigated first by sintering and then reducing synthetic minerals under controlled laboratory conditions at the University of Oulu. The effect of titanium oxide in solid solution in magnetite on the magnetite to haematite transformation rate was studied first in order to simulate the final stage of the sintering process. In other experiments, haematite samples doped with 0.5, 2.0 and 5.0 wt per cent titanium oxide were studied using thermogravimetry under a controlled gas atmosphere (CO/CO2/H2/N2). Sintered samples were reduced using the same gas composition as in the RDI test. Polished sections for optical microscopy and SEM-EDS analysis were prepared from both reduced and oxidised samples and unreduced sintered samples. The titanium oxide content of haematite had a clear effect on reduction degradation of the samples. Furthermore, increasing titanium oxide content in solid solution in magnetite radically accelerated the oxidation rate. Similar observations regarding the effects of titanium have been reported earlier, but this was the first time the effect of very small additions of titanium were shown to deteriorate blast furnace burden quality and a reason suggested behind the process.

Jan 1, 2007

By Agus Sasmito, SRIVATSAN JAYARAMAN SRIDHARAN, Akash Adhikari, Purushotham Tukkaraja

The amount of toxic fumes produced during blasting operation depends on the types of explosives used, product formulation, degree of confinement, conditions of use, and reactivity of the explosives with the host rock. Ammonium nitrate and fuel oil (ANFO) is still the explosive of choice due to its lower price and ease of use/loading. If not properly monitored and controlled, toxic fumes produced from blasting operations can have serious health hazards [1]. This paper presents a novel technique developed to track trapped fumes during a development blasting.

Aug 1, 2022

By Sunil Vytla, Agus Sasmito, Akash Adhikari, Srivatsan Jayaraman Sridharan, Purushotham Tukkaraja

Previous studies on blast fumes (carbon monoxide and nitrogen dioxide) clearance and workplace reentry time have overlooked the effects of toxic gases trapped in the muck pile. The currently available models for calculating the mine reentry times assume that all post-blast fumes are emitted upon detonation. However, recent studies reported that as much as 60 to 70% [1–5] of the fumes or gases produced during an underground development blasting could remain trapped in the adjacent rock mass or in the muck pile. Trapped fumes are slowly released [1–5], and when disturbed, high concentrations are released, representing a possible risk during the loading and transportation of the muck pile. In this study, mathematical models were developed using computational fluid dynamics to understand the behavior of the trapped fumes and their effect on mine reentry time. The three scenarios considered for this study include (i) gas emission source with no muck pile volume, (ii) gas emission source with non-porous muck pile volume, and (iii) gas emission source with porous muck pile volume. The estimated reentry times in all three scenarios were compared to see how porous media affects dilution time. It was observed that scenario 3, with fumes trapped in the muck pile, took a significantly longer clearance time (more than double) as compared to scenarios 1 and 2.

May 17, 2022

By D. R. Spears, C. E. Jordan

The U.S. Bureau of Mines examined the influence of turbulence on the fine bubble flotation of fine-sized (minus 40 micron) galena in order to improve flotation efficiency. Fine bubble flotation was carried out in a spinning-disk flotation cell and was compared to results obtained from flotation in a conventional cell at equivalent agitation levels. An automated electrochemical technique was used to monitor the turbulent velocity distributions of the fluid within the cell as a function of time and position. The velocity profiles were used to increase the precision of the fine particle, turbulent flotation model. While improved flotation response was obtained with intense agitation, the effect of bubble size was small. These results matched the model's predicted response for fine particle flotation.

Jan 1, 1989

By R. M. G. Machunter

The presence of ultra-fine particles affects the separation performance of wet gravity separation equipment. Several studies have been undertaken to establish the maximum level of these particulates that can be tolerated by spiral separators and it has been found that unless the ultra-fine material is effectively processed, relatively low proportions in the ROM material combined with high feed rates can result in degradation in plant performance and/or excessive water consumption. The maximum level of particulate material in the process water has been determined by examination of separation performance of spiral separators under varying slime loading. This work has been conducted utilizing various feed sources and a robust ‘rule-of-thumb’ has been derived.

Jan 1, 2005

By Liang Dianyin

In this paper, the molybdenite flotation tailing of cleaner-scavenger bank which has a mass of very fine particles has been taken as raw ore to be processed by flotation with/without ultrasonic. The effect of ultrasonic frequency, intensity, processing time and uploading location on molybdenite flotation efficiency is investigated by four-factor three-level orthogonal experiment, and the effect significances of these ultrasonic variables to molybdenite flotation efficiency have also been evaluated. Single-factor analysis of variance is conducted to investigate whether the effect of ultrasonic on molybdenum ore flotation efficiency is significant or not. The samples extracted from different ore species in different time have been mixed to analyze the particle size. The results show that the particle size of +38µm in concentrate obviously increases while the particle size of -25µmobviouslydecreaseswith ultrasonic, which means that ultrasonic is good for flotation due to sludge removing effect. Keywords: ultrasonic, flotation efficiency, sulfide ore, tailing, grade, sludge removing

Sep 1, 2012

By M. Rudolph, A. van Hall, G. Öktem, S. G. Özkan, A. Hassanzadeh

Despite the four-decade study on ultrasound’s (US) impact on mineral’s floatabilities, there is still not clarity regarding its role in mineral surface wettability. For this purpose, the present investigation endeavours ……the hydrophobicity and floatability characteristics of a chalcopyrite-pyrite-quartz (Cp- Py-Qtz) system in the presence and absence of an ultrasonic pre-treatment. The ultrasonic process was carried out by a sonopuls at a constant frequency of 20 kHz with an adjustable power level from 30 to 200 W. Initially, the impact of sonication time (15, 30, 45, 60 and 90 s as well as 10, 20 and 30 min) and power magnitude (30, 60, 90, 120 and 180 W) were evaluated while the dissolved oxygen, temperature, conductivity and pH were also monitored. Collector-less micro-flotation tests were carried out on the non-pre-treated and the US pre-treated samples at 60 W and 15 s. The samples’ hydrophobicities were determined by the drop shape analysis approach. The dissolved-oxygen level was varied using a mini bench pressurised water reactor to study the effect of O2(aq) concentration on the chalcopyrite and pyrite wettability characteristics. The results showed that the minerals’ hydrophilicities were relatively more sensitive to the sonication’s time than its power that resulted in reducing all three minerals’ hydrophobicities. In addition, it was found that the dissolved-oxygen content and creation of sub-micron sized bubbles led to an improvement on chalcopyrite and pyrite hydrophobicities. Finally, we proved that the Cp’s floatability increased and Qtz’s recovery reduced while being subjected to the ultrasonic irradiation (15 s at 60 W); however, Py’s recovery remained constant. This conclusion confirmed the possibility of a selective separation in ultrasound-assisted copper ore flotation. We recommend that further advanced investigations be conducted, using an X-ray photoelectron spectroscopy (XPS) and atomic force microscopy (AFM) to thoroughly understand the surface modifications induced by the ultrasonication

Jan 1, 2020

By D. E. Ng?andu

The experience of Mufulira concentrator, of the Zambia Consolidated Copper Mines Limited, with underground mine drainage water, which is used in milling operations is discussed. It is shown that the underground mine water has a deleterious effect on flotation performance. The adverse effect of the underground water was successfully negated by adding lime into the primary ball mills and increasing the pH of the slurry, from a ?natural? pH of 8 to the flotation pH of 10.5. Traditionally, the pH modifier, quicklime, had been added downstream of the milling. Changing the lime addition point further reduced lime consumption by 50%,?a key issue as lime accounted for over 60% of the Mufulira flotation reagent costs. The nature of the effect of the underground water at Mufulira, particularly the sensitivity of the flotation to the pH at which the milling was conducted, characterized galvanic interaction. A large-scale plant situation is presented in which the desired electro-chemical response in the flotation was achieved, by a deliberate manipulation of the milling environment. The experience provides practical testimony of a more fundamental role for the milling process, other than the mere physical preparation, i.e. size reduction and liberation, of mineral particles prior to flotation.

Jan 1, 2001

The Effect of Using Different Comminution Procedures on the Flotation of Platinum Group Minerals The use of High Pressure Grinding Rollers (HPGR) has been widely reported to have major benefits in the treatment of minerals such as iron ore and diamonds. To date there have been few investigations into its use in the treatment of ores containing Platinum Group Minerals (PGMs). HPGRs are known to reduce energy consumption and wear costs and improve the throughput in the circuit. In the present investigation the effect of the comparative use of HPGR and conventional crushing in combination with either dry or wet rod milling on the flotation of PGMs was studied using batch flotation. Previous studies of a base metal sulfide ores had shown that either HPGR or conventional crushing followed by dry milling produced the highest grades and recoveries. However in the present study it was observed that a similar treatment produced the worst results and the highest grades and recoveries were obtained for the case of conventional crushing in combination with wet milling. The HPGR showed no advantages in terms of flotation performance and dry milling produced particularly poor flotation results. The results were investigated further using various surface characterisation techniques in order to determine the reason for the decrease in grades and recoveries of platinum when using dry milling and HPGR as opposed to the case for base metal sulfides. The feed and product samples were analysed using ToF-SIMS, XPS and MLA. The paper will propose reasons to explain the different flotation behaviour of the two ore types following the various comminution processes focusing on the surface characteristics of the ores, the particle size distribution and the pulp chemistry.

Sep 13, 2010

By B. McFadzean

Thiol collector mixtures are commonly used in the flotation of base metal sulfides and platinum-bearing ores. There are synergistic benefits claimed for these collector mixtures, with mixtures lowering total dosage requirements, improving coarse particle recovery and the rate of flotation. Some of the secondary collectors are known to have frothing effects. Therefore, a previous study aimed to decouple froth and pulp effects and considered only the bubble-particle attachments in the pulp. This was achieved through microflotation experiments, where various ratios of the ethyl and isobutyl chain lengths of xanthates, dithiocarbamates and dithiophosphates were used as collectors. Results from these experiments showed a marked increase in galena recovery using mixtures of xanthate with either dithiophosphate or dithiocarbamate. In the current study, the froth phase was introduced in the form of batch flotation studies to determine whether benefits noted during microflotation experiments would be carried through to a more realistic froth flotation scenario. The findings show that there was no significant difference in the flotation recovery between the best single collectors and mixtures of these collectors. In addition, single collectors that behaved poorly in microflotation experiments showed good flotation performance in the batch flotation experiments. The differences between the microflotation results and the batch flotation results are attributed to differences in particle froth stabilizing properties and/or differences in energy input between the microflotation and batch flotation cells. In addition, galena and pyrite showed marked differences in frothing effects and in their preferences for collector type. Keywords: froth flotation, collector mixtures, sulphide minerals

Sep 1, 2012

By R. G. Diale, H. R. Chauke, T. M. Ledwaba, P. E. Ngoepe

FeCo alloys play an important role in soft magnetic materials with a wide range of technological applications due to their high saturation magnetization and Curie temperature. However, these alloys have low ductility at room temperature. The ductility can be improved by the ternary addition of elements such as V. A density functional theory supercell approach was used to generate B2 Fe50Co50-xVx (0 ≤ x ≤ 50) structures and the properties were evaluated at different atomic percentage compositions to determine the ductility at room temperature. The structures were fully optimized to obtain better equilibrium ground-state properties such as lattice parameters and thermodynamic properties for both binary and ternary systems. The stability of Fe50Co50- xVx was evaluated from the heats of formation, elastic properties, and phonon dispersion curves. Furthermore, magnetic strength was evaluated from magnetic moments. It was found that all structures are thermodynamically stable due to the negative heats of formation. The calculated Pugh’s ratio and Poisson’s ratio confirm that alloying with V effectively improved the ductility. It was also found that Fe50Co50-xVx showed a positive shear modulus for the entire concentration range investigated, in agreement with phonon dispersion curves. The ternary addition of V to the FeCo system resulted in reduced magnetic strength due to a decrease in magnetic moments. These findings reveal that B2 FeCo-V alloys can be used as components and actuators for the automotive industry.

Jun 10, 2024

By A. P. Van Wyk, G. Pirnaar

The effect of vanadium on the susceptibilities of chromium and chromium-nickel steels to reversible temper embritlement was evaluated. The steels investigated were approximately equivalent to steels of as 970 Grade 708A42 and as 970 Grade 817M40, the major difference being that molybdenum had been replaced by vanadium in various concentrations. It was found that the vanadium had a detrimental effect and, in al the concentrations tested, enhanced the susceptibility to reversible temper embritlement of both the chromium and the chromium-nickel steel. The detrimental role played by vanadium in reversible temper embritlement is explained by a consideration of the effect of vanadium carbide, as well as of free vanadium, in solid solution in ferrite.

Jan 1, 1987

By B Wentzinger, Y Keulemans

This paper presents the results of a field study designed to assess the impact of vane rotation speed on the estimated undrained strength for two Australian bauxite tailings storage facilities. The vane test results are assessed against cone penetration and dissipation tests results to identify if partial drainage may be an issue. An innovative tool capable of measuring pore pressures during vane shear testing, the Piezovane™, is introduced as an improvement over the standard field vane to assess drainage conditions in real-time.

Jul 1, 2021