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By Karl Houseley, Dr. Robert J. Chapman

"A gravity concentration process has been applied to ores from the Clogau Mine, north Wales, the Tyndrum deposit, central Scotland and an alluvial ore from Leadhills area of Scotland. In the case of the Welsh ore and the alluvial deposit the gold grains in the concentrate and tailings streams have been characterised in terms of their three dimensions.In the case of Welsh ore, the thickness of a gold grain has been shown to be the single most important factor in determining behaviour in a gravity concentration operation. Six indices were used to quantify the overall geometry of the gold grains and those which incorporate a thickness term have proven to be effective in predicting the destination of gold particles within the concentration circuit. It is proposed that the most simple of these, the Heywoods flakiness ratio, has potential for the control of milling operations as an alternative to the established practice of characterising the size of the mill discharge.The effect of grain geometry on the recovery of fine gold has been studied using Tyndrum ore. The recovery of gold by gravity concentration increased from 20% to 70% when the criteria used to design the milling operation was the prevention of over grinding of gold grains.The destination of alluvial grains in the concentration circuit did not show such dependence on shape, and this has been attributed to the effective classification of all the gold grains in the sample by fluvial action producing a population of similar geometric characteristics."

Jan 1, 1996

By Jessica Egan, Daniel Hodouin, Claude Bazin

"The recovery of gold by leaching is influenced by the size of the gold carrier particles and the chemical environment. Using the relationships between the leaching rate, infinite recovery and particle size for a given set of chemical conditions, it is possible to simulate gold recovery for various feed size distributions. However the use of these particle size relationships is only valid if the leaching of gold from a given size class is independent of the production history of this size class. For instance, to use these relationships it is necessary to verify that gold recovery from the leaching of the 200-270 mesh size class remains the same if the size fraction is taken from a coarse or finely ground ore sample. Several laboratory tests were carried out to answer that question. Results of the tests show that within the large error margin associated to gold content measurements, the history of the production of a size class does not affect the gold leaching from that size class. Emphasis of the discussion is put on the difficulty associated with the processing of data containing significant measurement errors as it is the case for gold assays of leaching tests.INTRODUCTIONMore than 75% of the gold produced in the world is extracted by cyanide leaching of gold ores. The ore is ground to expose the gold carriers and the ground material is reacted in an oxygenated cyanide solution that dissolves gold, leaving solids gangue minerals that are disposed to tailings ponds or returned in underground mines as paste fill. The gold contained in the solution is recovered by either the carbon in pulp process or by cementation onto zinc powder, before being melted and casted into a brick (Marsden and House, 2006)."

Jan 1, 2009

By P. T. L. Koh

The effect of particle shape on the flotation process has been investigated in laboratory experiments with monosized spherical ballotini and roughly ground ballotini. The particles were treated by partial methylation with trimethylchlorosilane to achieve varying degrees of hydrophobicity. In flotation, the process of film thinning and liquid drainage is critical in the formation of a stable bubble-particle attachment and this is affected by the particle shape and surface hydrophobicity. The rate of attachment affects the overall flotation rate. Flotation tests with different particle sizes at various degrees of partial methylation have been performed in a modified Denver cell. Predictions from a computational fluid dynamic model of the cell which incorporates fundamental aspects of bubble-particle attachment are compared against flotation test results. Contact angles of the particles have also been measured using the capillary rise technique to indicate surface hydrophobicity.

Jan 1, 2014

By J. J. Carlson

Studies were carried out to determine whether filtration rate changes observed in an iron ore concentrator were due to variations in particle shape. It was confirmed that ores mined from different locations differed in filtration rates by as much as 60%. However, when image analysis was used to quantify the shapes of the individual particles in the filtration feed, it was found that the particle shapes showed almost no variation, and the shapes did not correlate with the filtration rate. It was also determined that the filtration rate variations were not caused by changes in particle size distribution. These results suggest that the differences in filtration rate are due to factors other than size and shape, such as surface chemistry.

Jan 1, 2008

The relationships between backfill-transportation parameters (solids concentration, velocity, and pipe diameter) and the wear rate of backfill-transportation pipelines is well understood. However, the degree of wear experienced by a pipeline depends not only on the transportation parameters, but also on the characteristics of the solids making up the backfill, i.e. the particle-size distribution, hardness, shape, and sharpness of the particles. Therefore, unless data corresponding to the specific wear rate of the solids are available, the determination of the wear rate for pipes transporting an uncharacterized backfill is largely guesswork. This paper describes an evaluation of particle characteristics with special reference to particle sharpness so that pipe wear rates can be correlated with solids of different size distributions and sharpnesses.

Jan 1, 1993

By Saghar Farajzadeh, Fatemeh Kazemi, Ataallah Bahrami

Spirals, the most common equipment for the separation of heavy minerals such as chromite, are greatly affected by size distribution and the liberation degree (hence the specific gravity and size) of the feed particles. In this study, the efficiency of spirals in separation of low-grade chromite particles has been investigated by studying the distribution of grade, size distribution and liberation degree of feed, concentrate, and tailings of spiral. For this purpose, mass balance constraints were applied to the spiral-containing chromite processing circuit. Afterwards, the grade variations and size distributions have been investigated. According to the results, when the feed to the spiral has a larger size distribution, the enrichment ratio of the feed is 1.32 and, with the smaller feed size, this value has increased to 1.99. When the spiral feed has a larger size distribution and higher specific gravity, the recovery of chromite increases with increasing particle size up to 250 microns, and then with increasing particle size, recovery decreases with a relatively steep slope. Evaluation of spiral efficiency with respect to particle liberation degree has also shown that despite the high degree of liberation of spiral feed in size fractions smaller than 75 microns (88.9%), the liberation degree of spiral concentrate and tail in this faction is equal to and less than that of feed, which can indicate poor spiral performance in these size fractions.

Oct 27, 2020

By J Ledgerwood

Namakwa Sands is a mineral processing company based on the West Coast of South Africa and is solely owned by Exxaro Resources Limited. Mineral ore is mined and processed, concentrated and both chemical and mechanically upgraded before being sent for electrostatic and magnetic separation units. The final high value mineral products report as Zircon, Rutile and Ilmenite.The recovery of non-magnetic material is largely dependent upon a number of factors, including but not limited to dew point, ambient temperature, feed rate, mineral size distribution, specific gravity and mineral content in head feed. One important limiting factor to recovery in typical dry mill operations is the particle size distribution of the feed. Variance in the particle size has catastrophic consequences for recovery. This is the reason for this study. Until recently large variances in non-magnetic production were viewed to be a function of machine operation. This view was later rejected with the feed size distribution determined as the major driver of low recoveries, for Namakwa Sands orebody 50 per cent variance in particle size distribution can be noticed within one day. This is because of the successive mining blending techniques employed.The predicament is that the two modes were so closely placed together that recovery of a single mode is almost impossible without the consequence of greatly reducing recovery. The second mode was found at 125 µm while the first was at 90 µm. Interestingly, for the mentioned feed type a cumulative size distribution of a unimodal feed type is almost exactly the same as for a bimodal size distribution. Thus a plot of cumulative size distribution will show no difference due to the modes being so close together. This is the reason why this phenomenon was not noticed before.The study also found that, using an high tension roll (HTR) or rare earth roll, a fine stream with a single mode at 90 µm versus a coarse stream with a single mode at 150 µm would yield completely different results interms of yields. Larger conductive particles are thrown from the roll while small particles loose charge faster (entrainment). Results in terms of the bimodal size distribution show that even though 25 per cent of the feed type is greater than 150 µm the yields followed a similar pattern to that of the coarse particles rather than that of the majority (75 per cent) fine particles. This confirms what was published by M Ziemski and P N Holtham in 2005 on charge decay rates; they mentioned that particle bed effects played a major role in recovery.

Oct 5, 2011

By V. K. Gupta

A detailed laboratory study was carried out to investigate the effect of the particle size distribution on the grinding rate parameters, Si, for the dry ball milling of quartz and limestone. Contrary to the present belief, the Si values were found to vary strongly with the particle size distribution. In particular it was observed that: (i) the Si values increased with the fineness of the particulate charge - the increase being more pronounced in the case of the coarser sizes, (ii) the next finer size class had the maximum effect on the breakage of the particles of a given size class, while the coarser size classes had only a slight effect, (iii) the effect of two or more size classes was non-additive, and significant higher order inter-size interactions were indicated. The importance of these results in the context of the analysis, design and scale-up of the comminution systems is discussed.

Jan 1, 1987

By Braulio Fernández, Gonzalo Montes-Atenas

The mechanisms taking place during the leaching of chalcopyrite when it is in contact with other sulphide minerals, particularly pyrite, is still a matter not fully solved. The GalvanoxTM process has been suggested as a technical solution to extract copper from chalcopyrite at commercial level inhibiting passivation phenomena widely reported in the field of hydrometallurgy. Although there are some rules of thumb to implement the process in fully flooded stirred conditions such as the optimum pyrite/chalcopyrite mass ratio should range between 2 and 4, among others; not many research studies have been focused on studying the effect of the surface contact area between chalcopyrite and pyrite to reach best copper extraction conditions. The aim of this research work is to determine the effect of the mass and surface area ratio between the minerals and the surface area of each of the mineral species effectively exposed to the leaching solution. Different particle size distributions of pure pyrite and chalcopyrite were contacted in a small column and subjected to leach tests using sulphuric acid in concentrations close those used in industrial leaching processes. The mass and surface area ratios which optimize the extraction of copper were obtained. It was found the best leaching conditions were attained when reducing the particle size distribution of pyrite regardless the particle size distribution of chalcopyrite. Further analysis concerning the impact of this conclusions on large scale operations is presented and discussed.

Jan 1, 2014

By B. McFadzean, I. Achaye, T. Chidzanira, J. Wiese

"Froth stability has an overriding effect on metallurgical recovery and grade for many ore types. Froth recoveries of less than 10% are common for low stability froths such as those in sparsely mineralized ores or in cells at the back end of flotation circuits. It is well known that, aside from chemical factors such as frothers and electrolytes, the mineral particles themselves have the dominant influence on froth stability. The particle properties of size and hydrophobicity are expected to have the greatest effects on froth stability. The aim of this study was to understand the effects of particle size on froth stability and to quantify these relationships.The study compared a synthetic ore of pyrite and quartz, with carefully controlled size ranges and hydrophobicity, with conventionally milled platinum-bearing UG2 ore and the bulk reverse flotation of hematite ore. A novel bench-scale continuous column flotation cell and continuous mechanical hybrid cell with large relative froth volumes, as well as a three-phase froth stability column were used to characterize the froths.It was found that froth stability could be related to the concentrate particle surface area by a Langmuir-type relationship. This is indicative that the mechanism by which particles stabilize the thin films in froths is similar to the mechanism by which surfactants lower surface tension. Different froth stabilities were found for different ores and this was thought to be the result of different particle sizes and distributions, which resulted in different packing densities in the thin films and Plateau borders. Interestingly, there was a clear relationship between the feed particle size and the froth stability even though froth stability was dependent on the concentrate particle surface area. It seems that the feed particle size is a good predictor of the surface area of particles in the concentrate. Concentrate particle size did not show a clear relationship with froth stability since it was already shown that it is both the size and the amount of the particles in the froth that contribute to the stability.INTRODUCTIONThe stability of the froth in froth flotation is important to the recovery and grade of the valuable mineral. Too stable a froth and the grade is reduced; not stable enough and the recovery may be compromised. Platinum-bearing ores with fragile, poorly mineralised froths are known to have froth recoveries that are routinely less than 10% (Crosbie et al, 2009). There are a number of chemical, physical and operating parameters that can affect froth stability, including reagent dosages, air flow rate, pulp density and particle properties. Arguably, the largest contribution to froth stability is from the particles that stabilise (or destabilise) the thin films in froths. Particle size, hydrophobicity and shape all affect froth stability to some extent."

Jan 1, 2016

By Kelsall D. F, Trahar W. J

The size by size batch flotation behaviour of copper activated sphalerite from synthetic mixtures with quartz was determined. In terms of recovery of sphalerite, the size fractions could be grouped into coarse, intermediate, and fine ranges. The behaviour of the coarse and fine ranges was significantly poorer than that of the intermediate range in both the extent and rate of flotation.Each size fraction had a fast and a slow floating component.The main effect of changing the copper sulphate addition was to alter the proportion of any size fraction which was fast floating. No correlation could be found, between the amount of copper on the spha:lerite andeither the flotation rate of the mineral or the amount of copper added to the system. It was found that fine particles did not appear to consume greatly disproportionate amounts of copper sulphate during conditioning. A modified conditioning procedure was found to lead to a higher rate of flotation and recovery of coarse sphalerite and to make poss1ble substantial savings of copper sulphate.

Jan 1, 1975

By C. B. Espag de Klerk, J. de Goede, M. Le Roux, Q. P. Campbell

"Excessive amounts of moisture in product coal can influence the efficiency of downstream utilization processes due to a decreased calorific value and handling problems. Stockpiles can be used to decrease the moisture content of coal by means of gravity drainage and evaporation. This paper is focused on the evaporation of moisture from a coal stockpile surface with the aim of investigating the effect of particle size on the rate of evaporation as well as the depth to which evaporation extends.It was observed that moisture initially evaporates at a higher rate from a stockpile consisting of fine particles (-6.7 mm) than from coarser particles (-13.2 mm +6.7 mm). This high rate of evaporation is restricted to the outer shell of the fine coal stockpile. However, for coarse coal, the porous nature increases the depth at which evaporation occurs. Evaporation of moisture was observed up to the fourth day of each experimental run, after which steady state was obtained. It was shown the water can evaporate from the surface into the body of the stockpile, depending on the coal particle size and void spacing. An experimental reclaim depth of 0.4 m was achieved after 4 days. IntroductionCoal stockpiles serve as surge capacity for downstream utilization processes and can also be used for moisture reduction by means of gravity drainage and evaporation. Excessive amounts of moisture in coal can cause handling problems and, most importantly, will decrease the calorific value, leading to inefficient combustion.Research has shown that evaporation by means of wind and solar action is considerably more effective than gravity drainage(Williams, D.J. 2006), but the effect is limited to a restricted depth from the exterior of the stockpile (Boyapati, E. and Oates, A. 1994; CSEM-UAE, 2010). The effectiveness of wind and solar action can be improved by orienting the stockpile perpendicular to the predominant wind direction, maximizing the surface area of the pile, and reclaiming the coal from the pile gradually in shallow cuts over a large area (Williams, D.J. 2006)."

Jan 1, 2016

By N. Mangesana

The effect of high solids concentration and coarse particle sizes (d50 ranges 90?300 µm) on the viscosity of a suspension of water and silica sand was investigated. The experiments were designed to include conditions that have been tested by other authors and those encountered in the operation of tumbling mills. The rheological data was measured using a tube rheometer with operating pseudo shear rates of up to 1500 s-1. The rheograms obtained depicted dilatant behaviour. The Otswald-de Waele, Bingham, Herschel-Buckley and Casson models were fitted to the experimental data. The Herschel-Buckely model, which approximates the yield point and gives an indication of the shear thinning or shear thickening behaviour of the suspension, was found to provide the best description of the flow curves for all slurries. The Herschel-Buckely model was then used to determine the apparent viscosity of all the tests. The apparent viscosity and yield stress increased with solids concentration and particle size at the different pseudo shear rates. The increase in slurry viscosity with solids concentration was attributed to increased frequency of particle-particle interactions. The increase in slurry viscosity with particle size was attributed to increased inertial effects. At low shear rates the sand slurry exhibited shear thinning behaviour for all solids concentrations. At higher shear rates above 1000 s-1the high solids concentration suspensions exhibited a transition from shear thinning to a shear thickening behaviour.

Jan 1, 2008

It is widely accepted that particles stabilize flotation froths and that stable froths result in improved flotation performance. Predicting the effect of particle addition on froth stability is, however, challenging. Furthermore, there is currently no technique that allows the prediction of the effect of different flotation reagents on froth stability, without carrying out froth stability experiments.

It is widely accepted that particles stabilise flotation froths and that stable froths result in improved flotation performance. Predicting the effect of particle addition on froth stability is, however, challenging. Dynamic surface tension measurement using maximum bubble pressure presents an attractive technique to investigate the effect of surfactant and particles at the air-water interface. The range of bubble lifetimes that can be studied (typically 0.1 to 60 s) is analogous to variations in air rate in flotation cells, and the corresponding changes in surface tension give an indication to the diffusion and adsorption rates of particles at the interface. In this paper, we use dynamic surface tension measurements to investigate the effect of particles on bubble surfaces at the microscale and link this to bulk froth stability measurements carried out using a froth column. Using the maximum bubble pressure method, the results show that the addition of particles results in lower surface tension, both at the dynamic (i.e. short) bubble lifetimes and towards equilibrium (i.e. 60 s bubble lifetime). This corresponds with the bulk froth stability measurements, where the three-phase system yielded more stable froths than the surfactant only system. Furthermore, increased particle loading at the air-water interface, whether through higher surfactant concentrations or lower air rates (longer bubble lifetimes), gave lower surface tension and higher froth stability. This demonstrates the link between bubble loading and froth stability. It is proposed that the maximum bubble pressure technique can be used to predict froth stability for two- and three-phase systems, enabling the effect of particle loading to be accounted for and quantified. Moreover, the technique has the potential to allow rapid determination of particle and surfactant diffusion at the air-water interface and prediction of the corresponding effect on bulk froth behaviour.

By Primak. George J.

"In the development of a new product as well as during its introduction on the market, it is very important to give due consideration to problems involving patents, licenses and trade marks. At the very beginning of the research and development program, it is obviously essential to ascertain, through a suitable patent search, that the product in question will not infringe any patents which are still in force. Then, a possibility of achieving one's own patent or proprietary position on the product or the process of its manufacture should be carefully explored. Licensing arrangements that one may reach with respect to patents and know-how covering such new product may, in the final analysis, determine its over-all success or failure. If one can count on licensing revenues or some favourable cross-licensing arrangements with respect to a newly developed product, this may go a long way to achieving profitability and success. The selection of a good trade mark is probably one of the most important acts that one has to perform once the product is developed, as customers will identify the new product by such a trade mark. In many instances, successful marketing and widespread acceptance of a product are largely due to its appealing name or trade mark, accompanied by proper promotion and advertising. Once the trade mark has been adopted, it should be registered in the Trade Marks Office to provide the protection afforded by federal statute. If the product is to be manufactured, sold or licensed in some other countries, similar considerations should be made with regard to each such country."

Jan 1, 1973

By E. M. Hill, D. E. Walsh, J. T. Hollow, H. K. Lin

Fairbanks Gold Mining, Inc. (FGMI) began blending and processing True North ore at their Fort Knox mill on April 12, 2001.Gold extraction subsequently dropped from 88% to 71% during the last week of April 2001. 25% of the gold values remaining in the leach tailings were gravity recoverable free gold. Significant quantities of stibnite and arsenopyrite were also identified in the tailings. In laboratory bottle roll tests, the gold extraction from a composite of leach circuit feed collected during the same period was 72.6%, when leached at an average NaCN concentration of 0.16 g/kg. The extraction increased to 82.4% and 91.7% with 0.5 g/kg NaCN, and 0.5g/kg NaCN plus 0.075 g/kg Pb(NO3)2, respectively. A passivating layer surrounding liberated gold particles and resulting from sulfide mineral dissolution, likely contributes to reduced gold recovery, which can be substantially increased by the addition of lead nitrate. Lead species remain in the solid residues after leaching and were not mobilized using Meteoric Water Mobility Procedure.

Jan 1, 2003

By N. Wagner, P. den Hoed, J. D. Steenkamp, S. Soqinase

In pyrometallurgical processes, metal oxides are reduced from molten slag through carbothermic reduction. It is of interest to evaluate the reactivity of the carbonaceous materials towards substances such as slag. Characterization techniques such as coal petrography can provide insight into the influence of feed coal properties and how they potentially dictate reductant performance. This study aimed to compare the petrographically determined organic composition of coal to reductant reactivity. Two South African medium-rank C bituminous coals and one anthracite sample were investigated together with high-carbon ferromanganese industrial slag. The reductant reactivity tests were conducted at 1500°C in a muffle furnace to assess the potential of carbonaceous reductant in reacting with the main slag components. SEM-EDS was applied to understand the extent of MnO (and to a lesser extent, SiO2) reduction from the slag. Coal 2, consisting of a greater proportion of vitrinite (59.5 vol% on a mineral matter-free basis and 54.7 vol% including mineral matter) was the most reactive reductant. The anthracite sample, with the highest inert maceral proportions (71.8 vol% including mineral matter and 76.8 vol% on a mineral matter-free basis), was the least reactive reductant.

Feb 6, 2023

By A. Bruynesteyn

Results are presented from a series of tests designed to determine the beneficial effects of the microorganism Thiobacillus ferrooxidans upon the leaching of uranium from a pyritic uranium ore. Minus 1-inch (-25mm) 0.0711 percent uranium containing, pyritic ore from the Rio Algom Mine at Elliott Lake, Canada was leached with lixiviants of various Eh and pH as well as being subjected to a biologically-assisted ferric iron leach. In all cases, the biological leach gave superior extraction. At pH 1.6, the biological leach gave 100.6 percent extraction and the ferric iron leach 69.8 percent. This improvement in extraction is associated with a relatively rapid biological breakdown of the pyritic material, thus liberating uranium mineralization associated with these pyritic materials and regenerating the ferric sulphate lixiviant in situ.

Jan 1, 1981

By H R. Watling, W van Bronswijk

Of the various copper sulfides in the EarthÆs crust, chalcopyrite is by far the most common. This mineral is also the most difficult to leach, with hydrometallurgical extraction processes characterised by prohibitively slow kinetics. While a number of processes, including leaching at atmospheric pressure and temperature, pressure leaching at higher temperature, and bioleaching of concentrates in stirred tanks and whole ores in heaps have been demonstrated to some extent, there is currently no full-scale unit process for the hydrometallurgical extraction of copper from chalcopyrite ores. Titan Resources NL operated a test bacterial heap leach at Radio Hill, Western Australia in 2001, to extract nickel and copper from a mixed sulfide ore that contained significant amounts of chalcopyrite, pentlandite and pyrrhotite. A proprietary mixed bacterial culture was used to inoculate the heap, and the nickel and copper were precipitated from the resultant solution as mixed hydroxides. Although 65 per cent of the copper from the Radio Hill heap was eventually recovered, the rate of extraction followed an unexpected trend, as the initial rates of copper recovery were much slower than column tests had suggested. It was postulated that this was due to dissolved copper precipitating as covellite or chalcocite in the most poorly aerated zones within the heap, ie furthest from the aeration pipes at the base. It was further hypothesised that the lack of oxidants (oxygen, ferric iron) and the likely inactivity of bacteria in these areas limited the re-dissolution of such secondary copper precipitates. In this study the above hypothesis was tested in column experiments using the same mixed sulfide ore and a synthetic leach solution. One set of columns was aerated and another set was operated without aeration. Results showed that precipitation of copper occurred regardless of whether the column was aerated or not. The results suggested that pH of the leach solution played a significant part in the precipitation of the copper. Further column tests revealed this to be the case. These results are described here in detail.

Jan 1, 2004