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By Zhang Libo, Peng Jinhui, Zhang Zhengfu, Fu Mengbi, Han Yamei

In this paper, results of a novel synthesis method of carbon-coated LiNi113Mn113Co11302 cathode material for lithium-ion battery are reported. The carbon coating was produced from a precursor, glucose, by microwave-pyrolysis method. The structure, morphology and electrochemical performance of the bare and carbon-coated LiNi113Mn113Co11302 were characterized by X-ray diffraction, scanning electron microscopy and charge-discharge tests respectively. The L8(27) orthogonal experiments were carried out to optimize LiNi113Co113Mn1130z/C technological conditions. The conditions of the orthogonal experiments were that the glucose content were 1.5 % and 4 %, the holding time were 15min and 30min, the heating temperature were 400 °C and 500 °C and the solvent were H20 and CH3CH20H. The main experiment target include specific capacity at 0.1C and 0.2C, Capacity retention rate, medium voltage attenuation rate and The fifth discharge medium voltage. The data were analyzed by Minitab 14 statistics software. The results of analysis of variance indicated that the most influential factor was the glucose content despite of discharge rate. Secondly, the effect of the solvent was equivalent to the holding time.

Jan 1, 2013

Two main aspects need to be considered when analysing a potential petroleum development project. Firstly, an estimate of the recoverable reserves must be made, and in many instances, these reserves must serve as collateral to finance development if outside capital is required. Secondly, the likely production profile and cash flow has to be established, and this cash flow then must meet debt service require- ments and in addition generate the required profits. In making these crucial deter- minations, the impact on the project of a wide variety of risks has to be analysed. A computer model, which represents the project in its entirety, is a great aid in determining project viability. Such a model requires imput from geologists, engineers and economists, and interpretation of the model must also be a joint effort. Communications, and inter react ion amongst individuals and disciplines is essential if the best answers are to be obtained

Jan 1, 1983

IN preparing a sample of refined lead for analysis, it is necessary to exercise great care to avoid contaminatien, as the amounts of the various impurities present in market lead are very small. The lead is cut into convenient-sized pieces, which are flattened out with a hammer, so that, on putting tbe lead through the rolls, strips of about one inch in width and Ij32iu. in thickness are obtained. The hammer, anvil, and rolls should be carefully cleaned before use. The strips oflead are cut up into pieces of about one inch square. If the lead is roIled out very thin and cut up into small pieces there is considerable risk of the acid acting too violently and causing loss through frothing over. A blank assay on all the reagents used should becarried right through, along with the actual analysis of the lead. This is of the greatest importance, particularly with regard to the determination of such impurities as iron, sulphur, arsenic, and antimony.METHOD OF ANALYSISThe method of analysis is as follows: Take two lots of 600 gIm. each, place in a large beaker, add 2000 cc. distilled water and 750 cc. concentrated HNOs. Cover with a clock glass and warm on a hot asbestos plate until all action ceases. (If any white precipitate forms, filter off and examine for Sn and Sb.) Add 420 cc. H2S04 (1-1), and stir well while adding the acid: Allow PbS04 to settle, pour off the clear liquid into a 12-in. porcelain evaporating dish, and start evaporating down, the dish being placed directly on an 8-in. ring gas burner. Wash the precipitate three times by decantation using approximately 1200 cc. hot water for each washing, and stir well...

Jan 1, 1922

By Bengt H. Fellenius

THIS PAPER deals with the analysis of results from axial testing of vertical single piles, i.e. the most common field test per-formed. Despite the numerous tests which have been carried out and the many Papers which have reported on such tests and the analysis thereof, the understanding of pile test loading in current engineering practice leaves much to be de-sired. The reason for this is that the engineers have concerned themselves with mainly only one question: "Does the pile have a certain least capacity?", finding little of practical value in analysing the actual capacity and the pile-soil interaction. This Paper aims to show that engineering value can be gained from elaborating on a pile test ? during the actual testing in the Held, as well as in the analysis of the results. The first portion of the notes make use of an earlier Paper by the author (Fellenius. 1975). However, additional views and recent literature have been incorporated.

Jan 1, 1988

By L. R. Plitt

A new simple correlation has been developed to evaluate the performance of classifiers. The new correlation has been tested on existing data from 150 different hydro-cyclone classification tests. It is shown that this model provides a meaningful improved method of mathematically describing the classification process.

Jan 1, 1971

By Renato G. Bautista, Gary A. Beetner, Anthony L. Frey

The flow of material in a pump mixer-settler extractor was studied photographically and visually by injecting dye into the equipment and following its advance through the various sections of the equipment. Volumetric measure of the flow was obtained from analysis of the photographs. The organic portion of the settling chamber, the fluid surrounding the pump mixer, and the pump mixer itself were found to be operating in plug flow. The aqueous portion of the settling chamber was found to be partially mixed. Significant dynamic effect was noted due to density changes in the feed streams. The quantitative and qualitative observations made of the flow within a single stage should be of value in predicting the flow patterns in all similar equipment, including opaque and liquid metal solvent extraction systems.

Jan 1, 1973

By L. K. Smith, E. M. de Kock, J. van der Walt

A systematic approach to the analysis of alternative methods of ventilating and cooling large hot mines is presented. The important factors that have a bearing on ventilation and cooling requirements and practices, such as air flow through the mine, geographical distribution of eat loads, and micro-ventilation considerations, are dealt with. The analysis of these factors leads to definitive ventilation and cooling strategies, air and water process design, specifications of details, and designs of the associated plant and equipment.

Jan 1, 1983

The Red Lake greenstone belt is an irregular mass of lavas sedimentary rocks and intrusives which is approxiately 35 miles long 18 miles wide and 7 miles deep. Basaltic volcamcs are the oldest rocks w1thm the belt. They are believed to have been laid down on an ancient crust which is at least 3 billion (3 x 109) years old and was composed partly of sediments. The basaltic rocks are overlain by acid volcanics and sedimentary rocks which have been complexly folded and are preserved as a down-folded remnant of younger rocks within the older crust. The volcanics and sedimentary rocks of the greenstone belt have been cut by intrusives with a wide range of composition. The emplacement of the intrusives and the accompanying regional metamorph-ism which terminated the orogenic activity in this area are believed to have occurred approximately 2.4 billion years ago. The basalts and many of the basic and ultrabasic intrusives undoubtedly had their source in the sub-crust or mantle. At least some of the granitic intrusives are believed to have had

Jan 1, 1965

Evidence for Middle-Late Triassic large-scale, silicic volcanism characteristic of extensional continental terranes is widespread in the Tasman Orogenic Zone in Eastern Australia. Detailed study of an area of south-east Queensland has defined the eroded remnants of a large collapse caldera and an associated area of rhyolite dome building and regional downsag which may be a second caldera (Stephens, 1986). The silicic volcanics and minor basaltic to andesitic products have been assigned to the Aranbanga Volcanic Group (Cranfield, in prep.) and the associated granite complex has been named the Mungore Complex (Ellis, 1968). Published isotopic age dates on the Mungore Complex are 212-219 m.y. (K-Ar Biotite; Ellis, 1968) and 226 m.y. (pooled Rb-Sr on several similar plutons in the region; Webb and McDougall, 1967). Basalts within the area have been dated at 219 m.y. (GSQ Annual Rpt., 1986). The collapse caldera (Mungore Caldera) lies on the intersection of 4 major structural features: 1) the Mt. Perry Lineament, a meridional fault zone extending for over 600 kilometres in a NNW-SSE direction and which has faulted the eastern part of the caldera 5 kilometres sinistrally. The lineament has been active at least from mid-Permian to Late Triassic and has localised activity into the Tertiary. Granite plutons of the same age as'the Mungore Complex- are topographically prominent and largely concentrated east of the Mt. Perry Lineament and its extensions (Nash, 1986); 2) the extension of the Darling River Lineament, a continental-scale, ENE trending feature which correlates with regional structural discontinuities but which lacks expression as faults within the Tasman Orogenic Zone;

Jan 1, 1987

This paper reviews the development and operation of a small underground tin mine in NE Tasmania. Tin mineralisation was discovered in the Lottah area in the 1880s with early alluvial and eluvial workings leading to the development of large low grade open pit operations. Apart from short lived activities operations ceased in 1915. Intensive exploration in 1978 - 1981 outlined substantial tonnages of low grade tin mineralisation (0.2% Sn) of open pit material. An underground ore body was also located (800 000 tonnes 0.6 per cent Sn). Spectrum Resources Australia Pty Limited acquired a 98 per cent interest in the property in 1988. Mine and mill development began in early 1989 based on an underground mine utilising trackless mining using room and pillar with fill stoping. The milling circuit involves primary jaw crushing, Barmac secondary crushing to 1 mm, Mogensen and DSM screens with jigs and tables to make a wet concentrate. Final tin concentrates are produced by high tension and magnetic separation. Planned production rates are 500 t/day with a mine life of six to seven years.

Jan 1, 1990

This paper reviews the development and operation of a small underground tin mine in NE Tasmania. Tin mineralisation was discovered in the Lottah area in the 1880's with early alluvial and eluvial workings leading to the development of large low grade open pit operations. Apart from short lived activities operations ceased in 1915. Intensive exploration in 1978-81 outlined substantial tonnages of low grade tin mineralisation (0.2% Sn) of open pit material. An underground ore body was also located (800 000 tonnes 0.6% Sn). Spectrum Resources Australia Pty Limited acquired a 98 percent interest in the property in 1988. Mine and mill development began in early 1989 based on an underground mine utilising trackless mining using room and pillar with fill stoping. The milling circuit involves primary jaw crushing, Barmac secondary crushing to lmm, Mogensen and DSM screens with jigs and tables to make a wet concentrate. Final tin concentrates are produced by high tension and magnetic separation. Planned production rates are 500 t/day with a mine life of 6-7 years.

Jan 1, 1990

By Wolfgang Hermann

The ancit-process of the Eschweiler Bergwerks-Verein, an affiliate Company of ARBED S.A., Luxembourg, was developed in its principles by the Dutch State Mines, Limburg, in the mid-50's with the aim of producing a smokeless domestic fuel on the basis of low volatile hard coal. In 1967, the EBV erected a 10 t/h large- size pilot plant along these principles in the Aachen mining district and further developed the acquired know-how. In hardly 10 years more than 650 000 t of ancit briquettes with unit weights between 17 and 100 grams were produced and in the meantime stream rates of over 85 % of the yearly utilization hours have been reached. In more than 10 blast furnace trial runs involving substitution rates up to 100 p. c. ancit have proved the suitability of ancit as a metallurgical fuel both for a burden with a high and a poor iron content. Construction work for a minor process-step to enable processing of coal with a higher content of volatile matters is finished and first results are expected by summer this year. A pilot plant with a 30 t/h capacity working on a low-volatile coal basis is being planned. Engineering and construction are supervised by MecanARBED. Luxembourg, as responsible contractors.

Jan 1, 1977

By J. Nalaskowski

A study of the interfacial properties of the basal plane and the edge surfaces of talc is described in this paper. The isoelectric point measured at the two different crystallographic planes by the streaming potential method was found to be similar and exists at about pH 3.0. In the case of the edge surface the zeta potential increases at higher pH values which can be attributed to the hydration of magnesium ions at the edge surface. The atomic force microscopy (AFM) colloidal probe technique was used to measure interaction forces. For such experiments a 20 um talc particle was attached to the AFM cantilever and forces between the edge of the talc particle and two different crystallographic planes of talc were measured at various pH values. These measurements, while being qualitative due to the poorly characterized contact area, show differences between the properties of the base plane and edge of the talc and correspond to the results from streaming potential measurements. Finally, the differences in the hydration of the basal plane and the edge of talc are revealed from molecular dynamics (MD) simulations. The basal plane of the talc is much less hydrated than the edge, as can be seen from the water density distribution functions, which correlate quite well with the contact angle measurements at the basal plane surface and the edge surface of the talc sample.

Jan 1, 2006

By P. Marinos, G. Tsiambaos, H. Saroglou

Anisotropy is a characteristic of intact foliated metamorphic rocks (slates, gneisses, phyllites, schists). ?esting was used to establish the anisotropic behaviour of selected gneissic rocks. The effect of anisotropy on various mechanical properties (strength, deformation) and dynamic properties (wave velocity) was examined. The rock samples were also tested at successively higher confining pressures in order to evaluate the effect of anisotropic behaviour at high overburden pressures. L’ anisotropie characterise les roches foliées (schistes, gneiss, phyllades). Dans ce travail des essais en laboratoire ont été exécutés afin de déterminer le comportement anisotropique des roches gneissiques. L’ effet de l’anisotropie a été examiné par rapport aux propriétés méchaniques (résistance, deformation) et propriétés dynamiques (vélocité ultrasonique). En outre des essais des roches ont été exécutés a des compressions latérales successivement plus grandes afin de déterminer le comportement des roches sous grands charges. Anisotropie ist eine Eigenschaft der geschieferten Gesteine (TonSchiefer, Gneis, Phyllit, Marmor). Versuche wurden durchgeführt, um anisotrope Verhalten von gneis Gesteinen zu ermitteln. Der Einfluss von Anisotropie auf mechanische (Festigkeit, Dehnung) und dynamische Eigenschaften (Wellegeschwindigkeit) wurde bestimmt. Die Dreiaxialversuche wurden unter grossem allseitigen Drücken entnommen, um das anisotrope Verhalten auf grösse herrschende Spannung zu bestimmen.

Jan 1, 2003

By H. Saroglou

Anisotropy is a characteristic of intact foliated metamorphic rocks (slates, gneisses, phyllites, schists). Testing was used to establish the anisotropic behaviour of selected gneissic rocks. The effect of anisotropy on various mechanical properties (strength, deformation) and dynamic properties (wave velocity) was examined. The rock samples were also tested at successively higher confining pressures in order to evaluate the effect of anisotropic behaviour at high overburden pressures.

Jan 1, 2004

By E. O. Jones

DURING the heating of cold-worked nickel silver, the tendency of the material to crack is well known. The present research deals with this question, and may conveniently be divided into the following sections: Changes in these alloys during heating and cooling, determination of the temperature at which cracking occurs, effect of grain size, quenching cracks, methods of overcoming annealing cracking. The work is far from complete, in particular the influence of impurities on this tendency has not been investigated, but the results so far obtained lead to certain definite conclusions, which are of theoretical and practical importance. CHANGES IN ALLOYS DURING HEATING AND COOLING During the annealing of many metals at a temperature just below that at which recrystallization sets in, there is evidence of some change, the effect of which is to harden and embrittle the material. This effect has been most clearly demonstrated in the cases of aluminum, copper, brass, and nickel silver, and appears to be a common property of cold-worked metals and alloys, or, at any rate, the non-ferrous ones. The effect would obviously offer an explanation for certain types of annealing cracking, but the trouble is so much more common in the nickel silvers than in the other alloys that some special cause should be looked for. There is, however, fairly good reason for believing that similar cracking may occur in some of the brasses; D. Bunting suggests that the a brasses toward the saturation limit are subject to a transformation closely allied in nature to that known to occur in the nickel silvers at around 320° C. Although the existence of this critical temperature range was known, it did not necessarily follow that this transformation was responsible for the trouble under investigation, so the first portion of this paper deals with the attempts made to determine whether other critical changes might not occur in these alloys. There were already reasons for the belief that such would prove to be the case, as the mechanical properties of the nickel

Jan 7, 1925

By Earl Bardwell

THE determination of suitable and safe annealing temperatures is one of the most important problems arising in the operation of a copper rolling mill. Certain of the larger mills have worked this problem out for themselves and in these mills the operation has become more or less standardized. In some of the mills pyrometers are used to measure the temperature of the annealing furnaces and careful watch is kept to see that overheating does not take place. In a considerable number of the mills, however, dependence is placed entirely on the judgment of the operator. The almost total lack of literature bearing on this subject seems sufficient warrant for the publication of this paper. The discussion of this subject naturally divides itself into two parts: (1) The effect of annealing temperature on physical properties; and (2) changes in the microstructure of refined copper due to cold rolling and annealing. I. THE EFFECT OF ANNEALING TEMPERATURE ON PHYSICAL PROPERTIES For the purpose of investigating this phase of the subject six test bars were selected, varying in oxygen content between the limits of 0.036 and 0.070 per cent. The chemical composition of each of these test bars was as follows:

Jan 8, 1914

By AIME AIME

WEDNESDAY night, by long tradition, is al- ways set aside for the annual dinner, even when, as it was this year, it is Ash Wednesday. Whether the somewhat smaller attendance than last year is attributable to that cause, the unexpectedly long persistence of business depression, or whatever may have been the reason, it was a joyous occasion, and the grand ball-room of the Commodore Hotel was as completely filled With diners as * was consistent with com- fort. In the half hour before the dinner was actually served the guests assembled in an adjoining room and not only exchanged greetings but proceeded along the receiving line to greet the guests of honor. The number present was so large that hardly more than half of them had been able to do this before the summons to the dining room sounded and a hearty and immediate response was made to it. Toy balloons at each plate, inflated and directed at the heads of companions or nearby friends, but which were just as likely to carom from the nose of a hurrying waiter, successfully broke the ice as well as not a few plates. It would be interesting to know whether the pleasure the guests derive from these de- vices is in part based on the all-too evident annoyance of the waiters, and what the relative quantitative relationships are.

Jan 1, 1931

By W. B. Boggs

Part 1 Originally, the copper produced at the Noranda ?smelter was shipped in the form of blister bars to the Laurel Hill refinery of the Nichols Copper Co., New York. In 1930 a refinery was built at Montreal East for the purpose of refining Noranda copper and copper from the Hudson Bay Mining and Smelting Co., at Flin Flon. After investigation of the probable costs of making anodes at Noranda and at Montreal, it was decided to make them at Noranda rather than to continue to make blister bars there. Fuel is a major item of expense in making anodes: and since less fuel would be required in making anodes from molten copper than in making them from blister bars, a lower anode furnace cost could be expected at Noranda than at Montreal. Further, the expense connected with making blister bars at Noranda would be eliminated. The cost of treating anode and wire bar furnace slags is a serious item in a refinery, and it was found that the cheapest method would be to ship such slags back to Noranda. With the anode furnace at Noranda, much less anode furnace slag would be made at the refinery. Against these savings which would be effected by making anodes at Noranda must be set the high operating cost of an anode furnace at Montreal, using only tank-room scrap and the Flin Flon copper. This furnace would be handling a comparatively small tonnage and would have a high cost per ton. The usual equipment for making anodes from. liquid copper consists of either a stationary reverberatory furnace or a tilting Tacoma-type furnace together with an anode wheel of the Clark or Walker type. The reverberatory type of furnace has been developed from the furnace used in the old Welsh process of smelting and refining copper, while the tilting furnace is a development of the holding furnace, which is essentially a Peirce Smith converter without tuyeres and provided with burners.

Jan 1, 1932

By Leizhang Gao, Zhengfeng Qu, Pingsheng Lai, Chenguang Bai, Meilong Hu

Since Fray-Farthing-Chen (FFC) Cambridge process was proposed in 2000 for electrochemical extraction of titanium from titanium oxide, a great quantity of research has been carried out to investigate the mechanism of the electro-reduction of the process. Results show that the intermediate products of perovskite phases are inevitable during the electro-deoxidation process. In this paper, a new perspective focus on the anodic behavior was applied. The behavior of the graphite anode with different times has been investigated. Although the main anodic process in the electrolysis is the oxygen evolution by means of the CO2. The interphases of calcium species appeared on the cathode are closely related with chlorine ions in the molten CaCl2. In addition, the released CO2 from the anode is related with the formation of CaCO3 which floated on the surface of the molten salt.

Mar 1, 2018