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By C. E. MacQuigg

MAN?S desire to harden metal is older than recorded history and obviously would date from the moment when he found his implements were not equal to the demands of service. This need for hardness in metal may be divided roughly into two main classifications: (1 :I need for hardness through- out-for purposes of greater strength or elasticity of the whole implement or member, and (2) need for surface hardness alone. A strong steel needed to transmit stresses or resist de- formation is an example of the first class. In metals only surface- hardened, the chief need is for resistance to wear. Obviously the whole gamut of all uses can be imagined- from the extreme of a simple cantilever supporting a load in space to that of a solidly supported face plate serving to resist wear. It is the in- creasing of wear resistance which I propose to discuss.

Jan 1, 1939

By E. J. Sullivan

This study seeks to define the mechanism of oxyanion sorption onto surfactant-modified zeolites. Zeolites which have been treated with hexadecyltrimethylammonium bromide (HDTMA) surfactant to produce a hydrophobic surface are capable of sorbing both organic compounds as well as oxyanions such as chromate, selenate, and sulfate. Simple ion exchange and charge-balancing mechanisms do not fully explain this unusual phenomenon. The sorption of HDTMA surfactant appears to be partly ion exchange and partly sorption to non-ion-exchangeable sites. Sorption of chromate is a simple exchange mechanism with bromide, which co-adsorbs with HDTMA to form a surface precipitate. Information from this study will be used to design on-site and in situ treatment systems for contaminated water, such as filter beds and permeable barriers.

Jan 1, 1995

By E Corpuz, J Weissman, S Winter, R Evans

The surface-to-inseam (SIS) directional drilling technique has been utilised at Oaky Creek Coal for more than a decade to predrain both the Oaky No 1 and Oaky North mining areas. The cumulative drilling program constitutes a total of 140 lateral and 200 vertical holes, and 405 km of lateral drilling.The use of SIS gas drainage has been successful with the following site-specific benefits being recognised:ability to drain German Creek seam gas contents to residual gas levels of new mining areas within an 18-month period from commencement of well productionstructural geological verification of the mine design well in advance of development mining occurring in an areaability to conduct successful predrainage of the overlying Aquila seam to reduce subsequent goaf emissions.Appropriate and up-to-date geological knowledge during the design and drilling process is a significant influence to achieving success. Vertical production wells need to be located in a position that is most effective to remove water from hole. The lateral hole should not include intersections with significant geological structure.SIS drilling provides continuous seam roof/floor data to help define seam geometry and locate geological hazards with high accuracy. In faulted ground and with variable seam gradients, SIS data can resolve geological ambiguities from seismic sections and enhance seam correlation that would otherwise be available only from discrete and closely-spaced infill vertical exploration drilling.Here, we review some examples of SIS configurations and practice to highlight key learnings in drilling long inseam holes (up to 1900 m per arm) ahead of development and mining. Aspects on prerequisites, evolution of network design, tolerances and drainage outcomes in a variety of geological situations are discussed as technical basis towards a viable and effective SIS drilling program.CITATION:Corpuz, E, Evans, R, Weissman, J and Winter, S, 2015. Surface-to-inseam (SIS) drilling at Oaky Creek coal mine – SIS design aspects and drilling environment, in Proceedings The Australian Mine Ventilation Conference, pp 93–104 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 31, 2015

By S. H. Ash

THE MAGNITUDE of the anthracite industry's drainage problem in the Lackawanna River drainage area is realized when it is known that in 1948 the 27 pumping plants in this region pumped over 48 billion gallons of water to the surface from the mines in the Lackawanna Basin of the Northern field. This is almost 92,000 gallons per minute pumped against an average hydrostatic head of over 300 feet for that year. By comparison, Lake Wallenpaupack, the largest artificial body of water lying wholly in Pennsylvania, contains 71 billion gallons of water in its 24-square-mile area: the volume of water pumped from the mines in the Lackawanna Basin during 1948 was approximately 68 percent of that impounded in Lake Wallenpaupack. The Lackawanna. River and its tributaries drain a troughlike area of 345 square miles. The synclinal axis of this trough lies within the coal measures. All surface drainage into the valley must traverse some part of the coal measures. On the basis of 45.03 inches of rainfall recorded by the Scranton station of the United States Weather Bureau for 1948, the runoff from the Lackawanna River drainage area during that period was 135 billion gallons, approximately three times the volume of water pumped by all mine pumping plants in the Lackawanna. Basin of the Northern field during 1948. In other, words because of the pervious condition of the strata overlying the mine workings, approximately one-third of the total runoff in the Lackawanna River drainage area becomes mine water. This report, reveals that less than 7 percent of the 72 miles of pervious stream beds examined between Archbald and Pittston have been unproved.

Jan 1, 1952

By S. H. Ash

THE MAGNITUDE of the drainage problem of the anthracite industry in Pennsylvania's Western Middle field is realized when it is known that in 1951 nine pumping plants in this field pumped nearly 36 billion gallons of water to the surface. This is almost 68,000 gallons per minute pumped against an average hydrostatic head of 350 feet for that year alone. In 1948 over 20,000 gallons per minute was pumped by relay pumps against an average hydrostatic head of 265 feet. In addition to the water pumped to the surface, it is estimated that 15,000 gallons per minute overflows to the surface from underground pools in idle mines. The volume (second-feet) of water pumped and overflow water is almost 1;z times the, average mean flow of the Schuylkill River at Pottsville for the 8-year period 1944--51 (7, 13).4 Mahanov and Shamokin Creeks drain an area of 99 square miles in the Western Middle field, and all surface drainage in this area must traverse some part, of the coal measures before entering these streams. On the basis of 46.03 inches of rainfall (the weighted average of 6 recording stations for 1948), the runoff from the drainage area during that period was 51 billion gallons, approximately 1 times the volume of water pumped by all mine-pumping plants in the Western Middle field. In other words, because of the pervious strata overlying the mine workings, approximately two-thirds of the total runoff in the drainage, area becomes mine water tributary to the pumping plants.

Jan 1, 1953

By S. H. Ash

THE MAGNITUDE of the anthracite industry's drainage problem in the Northern field of Pennsylvania is realized when it is known that, for the 8-year period 1944-51, all pumping plants in this region pumped an average volume of 112.5 billion gallons of water from the mines to the surface each year. This is over 214,000 gallons per minute pumped against an average hydrostatic head of 400 feet each year for that period (12).4 By comparison, Lake Wallenpaupack, the largest artificial body of water lying wholly in Pennsylvania, contains 71 billion gallons of water in its 24-square-mile area; the average volume of water pumped from the mines in the Northern field each year during the 8-year period was 58 percent more than the volume impounded in Lake Wallenpaupack. The natural configuration of the drainage area overlying the Northern field subdivides the total area into two major drainage areas-the Lackawanna River drainage area and the Susquehanna River drainage area overlying the Wyoming Basin. Although the 169-square-mile drainage area overlying the Wyoming Basin is slightly less than half that of the Lackawanna River drainage area (10), the total volume of water pumped to the surface from mines in the Wyoming Basin is 21 percent more than the total volume pumped to the surface from mines in the Lackawanna Basin. From this, it is apparent that the Susquehanna River and the pervious deposits in the buried valley over which it flows in its course across the coal measures of Wyoming Valley is the greatest single source of mine water affecting mines in this area. Because of its relatively flat terrain, the wide flood plain of Wyoming Valley does not facilitate rapid runoff; consequently, much of the surface water seeps directly into the buried-valley deposits and eventually into the mine workings.

Jan 1, 1953

By Brett P. Spigarelli

"To meet the growing need for CO2 capture and storage technology, Michigan Technological University is studying CO2 capture using alkali-based solvents. The objective of the present study was to find a way to increase the absorption rate of CO2 into an alkali solution without reducing the absorption capacity of the solution. One approach to increasing absorption rate is to use a surfactant to chemically alter the gas bubble size. The surfactant chosen for the study was a neutral-charge polypropylene glycol methyl ether (PPGME) with a molecular weight of 200. Experiments were conducted to study the absorption rate of CO2 at varying surfactant concentrations. Results showed that as the concentration of PPGME increased in solution, the absorption rate also increased. The CO2 absorption rate increased from 3.45 x 10-3 mol/min CO2 at 0g/L PPGME to 3.92 x 10-3 mol/min CO2 at 0.48 g/L PPGME. This amounted to a 14% increase in the CO2 absorption rate with no decrease in the absorption capacity of the solution. IntroductionChemical absorption using an amine solvent is currently the most mature carbon capture and storage technology available. Amines are advantageous in that they have a fast CO2 absorption rate, which leads to a high CO2 removal efficiency. However, amine absorption has some considerable drawbacks, such as high energy requirements, high equipment corrosion rates, amine degradation in the presence of oxygen, high waste generation and a large increase in plant footprint if new equipment is constructed (Herzog and Golomb, 2004; D’Alessandro et al., 2010). Due to these drawbacks, Michigan Technological University (MTU) is studying CO2 absorption using alkali-based solvents, which address the above disadvantages of amine solvents."

Jan 1, 2015

By B. R. Mohal, S. Chander

"The adsorption and wetting behavior of freshly ground and aged coals has been determined in the presence of a nonionic surfactant. The amount of surfactant adsorption changes with the concentration and ""age"" of the coal. The freshly ground coal has smaller amounts of adsorption at lower surfactant concentrations than the ""aged"" coal whereas at large surfactant concentrations, the order is reversed . In the latter case, more surfactant is adsorbed on fresh coal than on the ""aged"" coal . . It is proposed that at low concentrations, the surfactant adsorbs through both hydrophobic and hydrophilic interactions with the molecule lying parallel to the· surface, whereas at higher concentrations surface micelles form at the hydrophobic sites. The wetting behavior correlates well with the adsorption behavior.INTRODUCTIONNonionic surfactants have many applications in the coal and mineral processing industry. They can be used as dispersing agents to modulate flotation, flocculation and filtration of particulates (1). They can also be used to increase the wettability of hydrophobic solids such as coal and can hence be used as dust suppressants (2,3). Although the adsorption of representative nonionic surfactants such as Triton N-101 (an ethoxylated nonylphenol with 9.5 moles of ~thylene oxide and HLB equal to 13.4) have been studied extensively on substrates such as calcium carbonate (4), silica (5) carbon black (6) and graphite (7), very few studies are available for coals. Coals differ from other substrates with respect to two important characteristics: 1) coal are porous and 2) coals consist of a patchwork of hydrophobic and hydrophilic sites (8). Since the adsorption characteristics of a surfactant are influenced significantly by the nature of the substrate the characteristics of the coals must be taken into consideration."

Jan 1, 1989

By G. A. Bala

As part of ongoing research to define mechanisms of microbial enhanced oil recovery (MEOR), this work describes the activity of Bacillus l1chen1formis JF-2 (ATCC 39307) Mosurfactant against crude oils with varying compositions. Surfactant based MEOR improves oil recovery by lowering the oil/brine interfactal tension (IFT) therefore permitting oil to be displaced or solub1lized into the aqueous phase.? MEOR is an Enhanced Oil Recovery (EOR) process which allows for the introduction of chemical and miscible fluids, in the form of microbial metabolic end-products, through the injection of microorganisms into the reservoir or stimulation of indigenous reservoir microbial populations. These microorganisms represent a replenishable in situ source of acid, gas, biopolymer, solvent, or surfactant products which can be. supported and manipulated by the addition of simple and inexpensive nutrients to enhance the recovery of oil. Microbially mediated surfactant production represents one mechanism of MEOR. Bacillus licheniformis JF-2. has been used in a mode 1 MEOR system based on Berea sandstone cores (permeabilly .85 to 400 md) to examine surfactant based MEOR of medium to heavy crude oils (API gravity 38.1° to 17.5°). Enhanced oil recovery was achieved with all oils tested using either cell free culture supernatants or microbial suspensions as injectants with no detrimental effect to the oil. Spatial distribution of cells following mf?crobtal flooding was analyzed with scanning electron microscopy. Data indkate complete distribution of cells with a predominance of organisms located distal to the point of injection. There appears to be no sign:if1cant recovery trend with respect to oil composition.. The biosurfactant produced by Bacillus lichen1form1s JF-2 lowers the interfacial tension of all oils tested equally well.

Jan 1, 1991

By J. Zachwieja

As part of a general review on study of surfactant blinding agents to improve gold recovery during cyanide leaching of carbonaceous gold ores, processes of CIL and RIL leaching using surfactants were investigated. When refractory ores were treated by surfactants, CIL and RIL leaching processes yielded significant improvement on gold recovery. This paper will discuss and compare the laboratory results from two different leaching processes on preg-robbing ores, as well as, illustrate the difference of potential fouling of the blinding agents on activated carbon and resins.

Jan 1, 2015

By Laura Prati

Gold-on-carbon catalysts resulted very active and selective in liquid phase oxidation [1, 2, 3] and during past studies we established that activity is ruled by two factors: particle dimension and gold exposure on the carbon surface [4]. These two parameters are also connected to the nature of activated carbon where the chemical nature of the surface oxygenated groups probably plays an important role [5]. Our studies, focused on the design of an active gold-on-carbon catalyst for liquid phase application, were aimed, operating a fine tuning of all the parameters involved in determining activity, to optimize gold-on-carbon preparation, keeping in mind that gold particle activity increases with decreasing particle size and increasing gold exposure. Gold sol immobilisation represents a versatile methodology in preparing gold catalysts [6]: throughout this work we used as sol stabilizing agent, the N-dodecil-N,N-dimethyl-3-amino-1-propan sulphonate (SB), that provides both sterical and electrostatic stabilisation, a condition we already demonstrated necessary to preserve particle dimension when carbon is used as the support [6]. We generated different gold sols by varying the relative amount of reagents (HAuCl4, SB, NaBH4), the type of alkali and the temperature of the gold precursor reduction. Moreover, as we had recently evidenced that there is also a carbon effect [5], we employed only one active carbon to immobilize the sols.

Oct 1, 2003

By Readett D. J

Soluble salts can be removed from Bowmans lignite by water and acid leaching. The success of the removal of water soluble or acid exchangeable impurities is directly associated with the efficiency of dewatering these slurries. The filtration characteristics of a slurry at its natural pH (4.0) were poor, with a filter cake moisture of 65%. Acid treatment of the slurry at pH2 caused the filter cake moisture content to drop to 61 %. Various oils, oily surfactants and a flocculant were tested to determine the conditions for minimum filter cake moisture. A series of pilot scale filtration tests were conducted on flocculant dosed slurries with and without washing on a horizontal test unit. Moisture contents of 54% were obtained in laboratory testing using high additions of oily surfactant. For the pilot scale test work, moisture levels close to 60% were obtained with low flocculant additions, similar to results obtained in laboratory studies. Removal of soluble salts could be correlated directly to the final moisture content of the filter cake. This process of leaching followed by filtration resulted in the removal of approximately 75% (more than 80% with washing on the cloth) of the sodium chloride originally present in the lignite.

Jan 1, 1989

By Q Zhou, G Barrett, Y Choi, J Jiang

As part of a general review of processing double refractory ores through Barrick GoldÆs autoclaves /carbon-in-leach (CIL) facility at Goldstrike, a study was made to evaluate the use of surfactants for reducing the loss of gold during cyanide leaching of preg-robbing gold ores. Consistent improvement of gold recovery was observed with surfactants at various testing conditions. This paper will discuss the results obtained from laboratory and pilot-scale testing, as well as, review potential mechanisms for the observed improvement in gold recovery.CITATION:Zhou, Q, Barrett, G, Jiang, J and Choi, Y, 2013. Surfactants for gold recovery improvement with preg-robbing gold ores, in Proceedings World Gold 2013 , pp 367-372 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By M. E. Lewellyn

A lower moisture content for a clean coal product means increased Btu content, or increased yields at the same Btu content, and lower operating costs. The conventional surfactant-based dewatering aids effeciently lower the moisture content but often the presence of residual surfactant in the filtrate and recycle water causes problems downstream. ACCOAL-DRI 1000, a surfactant-based dewatering aid, was developed to solve this problem by minimizing the downstream effects while efficiently lowering the moisture content. The theory of the use of surfactants in filtration will be discussed as well as the development and field evaluation of this new product.

Jan 1, 1988

By E. D. Goddard

There are similarities, and differences, in the surfactants used in cosmetics and detergents. In both applications anionic surfactants constitute the major category. Their main function is to clean, i.e. remove grease and particulate matter from fibrous or hard surface substrates. Cationic surfactants are used for conditioning substrates. Nonionic surfactants can function as a substrate cleanser but are seldom used as such in cosmetics; however, selected non-ionics are often employed as a primary emulsifier. Several specialized nonionic surfactants are used as a secondary surfactant in formulations to promote foaming and emulsification. Specific examples and modes of action of surfactants will be presented.

Jan 1, 1988

By D V. Boger

The use of chemical additives to initiate such processes as particulate separation through flotation or dewatering through flocculation, is common in the mining industry. The dosing of additives is none the less poorly controlled from a process control viewpoint and it is perhaps fortuitous that over-dosing or misuse of chemicals is rarely catastrophic to the production cycle. In many cases, such events would go undetected if it were not for economic considerations. Recently, the advent of orebodies with finer mineral disseminations and the push for greater efficiencies in both production and tailing disposal have resulted in the need for greater control of the dosing and utilisation of chemical additives. The need to grind at higher pulp densities and to finer sizes and to dewater to higher solid contents are but two examples that require a more stringent understanding of the true role of additives in controlling the rheology of suspensions and the influence of additives on the surface chemistry of particles. The inter-relationship between the surface chemistry of particles and the role of additives in controlling suspension rheology is now well understood for systems in which the average particle shape in the mixture is spherical or close to spherical. Luckily, this is the case for a large number of systems in the mining industry and the true role of typical additives in these systems will be explored. Difficulties arise for suspensions containing clays or other platey or needle shaped minerals and in many cases, quite small quantities of platey minerals dominate the rheology of suspensions. The role of additives in controlling the rheology of asymmetric particle systems is more complex but the effect of the additive in changing particle alignment in solution is the key to understanding suspension behaviour. The manipulation of the rheology of asymmetric particle systems will also be explored.

Jan 1, 1998

A C-CORE study on behalf of the government of Newfoundland identified the inner continental shelf off northeast Newfoundland as having a relatively higher potential for hosting placer gold than other parts of the inner shelf. Under the auspices of the Canada-Newfoundland Cooperation Agreement on Mineral Development, the Geological Survey of Canada conducted a three-year project to map the distribution of surficial sediments and the abundance of placer minerals (particularly gold) from White Bay to Cape Freels. Much of the study area is a fjord coast, with steep rocky slopes and scattered gravel beaches. The extreme east, from Hamilton Sound to Cape Freels, has a wide, shallow inner shelf, sandy beaches, and extensive coastal dunes. Relative sea level was high in the late glacial period. It has fallen continuously in the west, but in the east it dropped to -19 m, before rising to within several metres of the present level by 3 ka. In terms of surficial sediments and processes, five zones are identified: (1) Deep offshore deep basins that contain thick postglacial mud overlying glacialmarine gravelly sandy mud. This zone is below a depth of 370 m in White Bay, 300 m in the Notre Dame Basin. 2) Basin transition zone in which the sea bed has been eroded by currents, so that glacialmarine sediments are exposed in places. Winnowing has formed an uppermost layer of muddy gravel. There is a slight potential for enhanced levels of fine particulate gold, but the gold would not be exploitable. (3) Iceberg impacted zone Above 200 m the keels of icebergs impact the sea bed, causing furrowing and pitting. Furrows predominate in deeper areas, and pits are concentrated at the inner boundary of this zone. Iceberg turbates have developed in shallow waters (60-100 m). Combined with winnowing, iceberg turbation could enhance the potential for concentration of fine particulate gold, but not into economic quantities. 4) Wave dominated zone Above approximately 60 m the sea-bed sediments are highly mobile due to waves, currents, and iceberg impact. Sand is either rippled or organised into sand waves. Gravel is either poorly sorted, and organised into

Jan 1, 1995

By Scott G. Britton

Until now, only the range of typical construction projects which are repeated over and over during the life of a coal mine have been discussed. This chapter looks at underground construction projects which occur only once or twice during the life of any given mine and are major construction projects in both time and cost. These projects usually require the services of an outside engineering and construction firm with hands- on experience in design installation. Because of this involvement with engineering and construction firms (EIC), the role of the construction engineer will change from one of actively de- signing and directing tasks to one of planning, inspection, and quality control. To reflect this role change in the discussions, the focus of this chapter will be changed to a broad overview of project participation. Of course, the projects under consideration in this chapter could easily fill more than one book on their design and installation. In addition, major construction projects are extremely site specific, requiring months of data collection about site geology, physical conditions, and potential excavation and construction requirements. Therefore, no attempt shall be made to discuss any detailed construction aspects as was done in earlier chapters. The purpose of this chapter is to present the fundamental concerns of a staff engineer or supervisor. This engineer does not make the decisions on choosing the EIC firm, but assists and interacts with their project team to accomplish the goals set forth by higher management. The construction topics to be reviewed fall into three main categories. The first category is highlighted by the installation of a main surge bin; the second is typified by the construction of an underground shop; and the third category encompasses special projects such as rotary dumps, crusher stations, and foremen's offices. These categories highlight the differences between degrees of mine responsibilities for project completion. The first topic is usually a turnkey project by an E/C firm for a given mine. The second topic represents the leading role of the mine in the project with a contractor as a support service or equipment supplier only. The third topic, special projects, is an example of a joint venture-between a contractor (leading partner) and mine management. These roles can change with any given project, but the changes in management responsibilities for the construction engineer can be nicely illustrated for the purposes of this text. The first step toward constructing major mine projects is to analyze the mine which influence their design. From the mine management standpoint, these parameters should reflect the role the mine will play in the project construction. In other words, what is the nature of the proposed mine environment and what are the material, labor, and time requirements needed to assist or direct the chosen engineering and construction firm? Answering these questions requires some basic project planning and cost estimation work. Here, only a general treatment is necessary, since detailed discussions of these topics will follow in Chapters 8 and 10. For those persons interested in the role of the EIC contractor, I suggest beginning by reviewing the article by Beall, "The Role of an Engineering and Construction Contractor," presented in the October 1980 issue of Mining Engineering magazine.

Jan 1, 1983

By Quentin L. Rhoton

"The use of explosives in a surgical manner was approved to facilitate, due to time constraints, anextremely significant paleontological find in the Plunket Point area of the Dominion Range, Antarctica. The organic material revealed by surgical blasting techniques may have altered basic scientific dogma on Antarctic glaciation theory."

Jan 1, 1999

By A. Martikainen, H. Dougherty

"At the Kemi Mine, a recent expansion into the Surmaoja orebody required an increase in ventilation capacity. A new ventilation shaft was built with two main fans. The installation is near the entrance gate and only 1.7 kilometres from the nearest permanent dwelling. The main fans were first taken into use as exhaust fans in October 2014. Shortly after the fan installation, comments concerning fan noise were received from the neighbours. The first noise measurements were taken at the main fan installation site by Outokumpu personnel in March 2015. Due to higher than expected recorded values, during late June, 2015, a two-week environmental noise study was planned by the engineers and executed by a consultant specialized in noise measurement. The measurement results were analysed and compared to the requirements of the environmental permit and Outokumpu’s factory standards. While the measured values at the nearest dwelling were within the environmental permit limits, high noise values were recorded at the fan station. A second two-week study will be performed after construction of the main-fan heating station has been completed. Actions taken will depend on the outcome. INTRODUCTION The Kemi Mine is a part of the Outokumpu chain of integrated ferrochrome and stainless steel manufacturing in the Kemi-Tornio region in Finland. The mine itself is a large underground operation with a production capacity of 2.7 million tons of ore per annum. It is also the European Union’s only chrome mine, and at present (2015) the mine extracts 2.4 million tons of chrome ore per year. Safety, cost-effectiveness, and environmental friendliness are hallmarks of the Kemi Mine. Environmental impact produced by the operation of the mine is limited due to the insolubility of the oxide chromium ore, the gravity-based and chemical-free enriching process as well as the closed circulation system of the process water which serves both the whole mine and the enrichment process (Outokumpu, 2015). Importance of the environmental impact of the Kemi Mine is amplified by its closeness to the cities of Kemi and Keminmaa with the nearest habitants living less than 2 km away from the mine site. To show the cooperation with residents the Kemi mine organizes special “neighbour days” for the habitants of the areas closest to the mine. Also, information letters are sent to the neighbours, when changes that may affect the neighbours are being planned and executed."

Jan 1, 2016