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By Hajime Miki, Mutia Dewi Yuniati, Tsuyoshi Hirajima, Keiko Sasaki

Acid mine drainage is mainly due to pyrite/arsenopyrite oxidation processes, and suppressing such processes is important issue. As a promising process it is reported that silicate ion can complex with catechol (1,2-dihydroxybenzene) and this complex is oxidized to a solid silica layer on the surface of those sulphide minerals. Detailed behavior was investigated from the result of electrochemical experiments. Results of polarization potential showed that oxidation peak can be seen only in the presence of both silicate ion and catechol addition at this peak potential and this peak can be identified as silicate-catechol complex oxidation to silica. Potentiostatic experiments indicated the dissolution kinetics of pyrite. Untreated pyrite dissolution rates were higher than pyrite treated with catechol and silica solution. To enhance the silica layer reaction on pyrite, the pyrite potential was held at 550 mV vs. SHE in catechol silica solution. This pyrite dissolution kinetics was almost the same as untreated pyrite. Potential hold followed by drying for 30 min process resulted in much lower pyrite dissolution rates. Drying is important for development of the silica layer. Analysis of this potentiostatic curve provided a way to estimate the thickness of the produced silica layer and kinetic information of treated/untreated pyrite. Untreated pyrite showed thinner initial layer thickness on the surface of pyrite (oxidized passive layer, not silica) and higher oxidative kinetics of pyrite compared with silica-coated pyrite.

Jan 1, 2014

By Kafui Nyavor

Acid mine drainage (AMD) is presently the biggest single environmental problem facing the mining industry. New and expanding metal mines in most parts of the world have to demonstrate their ability to contain this problem to obtain operating permits. Conventional methods of controlling acid mine drainage have primarily been limited to collecting the drainage and neutralizing with alkaline materials which do not provide a permanent solution to the AMD problem. Since acid mine drainage results from the oxidation of sulfides in the presence of oxygen, water and iron-oxidizing bacteria, controlling any of these three factors contributing to pyrite oxidation provides a potential at-source remedy for reducing or preventing acid mine drainage formation. Physical properties such as hydrophobicity also play an important role in the attachment of bacteria, adsorption of oxygen, water, and other ions that subsequently lead to the oxidation of pyrite. In this communication, the suppression of pyrite oxidation by treatment with fatty acid amines (FAA) was investigated. The FAA treated pyrite samples were tested at various conditions of temperature and pressure. At an elevated oxygen pressure of 500 psi and a temperature of 600 C, less than 0.2% oxidation was obtained for the FAA treated pyrite samples, while over 1.2% oxidation was obtained for the untreated samples in 10 hours of oxidation time. Accelerated column oxidation tests at ambient condition showed that FAA mated samples reduced pyrite oxidation by at least 75% in 81 days.

Jan 1, 1994

By Ettore Contestabile, Cameron Thomas

Implosive-type electrical/mechanical connectors such as XECONEX have been used extensively for joining electrical transmission lines. This implosive action of explosives has also been applied to other forms of high energy metal working with excellent results. However, as with many other products, the inherent blast energy of these units has caused some environmental concerns especially when used in proximity to inhabited areas.

Jan 1, 1995

By Ettore Contestabile, Cameron Thomas

Implosive-type electrical/mechanical connectors such as XECONEX have been used extensively for joining electrical transmission lines. This implosive action of explosives has also been applied to other forms of high energy metal working with excellent results. However, as with many other products, the inherent blast energy of these units has caused some environmental concerns especially when used in proximity to inhabited areas.

Jan 1, 1995

By J. J. De Witte, J. G. Cazort

The Paranam plant in Surinam (formerly Dutch Guiana) was built during 1939-40 to supply crushed and dried bauxite for the growing U.S. aluminum industry, supplementing production from the Suriname Aluminum Co.'s Moengo works, which began operation in 1922. A subsidiary of Aluminum Company of America, Suralco's total annual production from these two plants averages 2.55 million dry metric tons of various grades of bauxite. Starting in 1941 with bauxite from mines on the west side of the Suriname River, annual production at the Paranam plant has varied from a low of approximately 450,000 tons to more than 1 million tons in 1949. High production rates during World War II and the late 1940's rapidly depleted these reserves, and in 1950 plans were made to mine the known deposits on the east bank of the river, about five miles downstream from the original Paranam plant.

Jan 11, 1960

By D. M. Sloan

While surety capacity for the mining industry continues to shrink, States are demanding greater financial certainty for closure/post closure obligations. To combat these demands, larger mining companies are pursuing a Mining Surety Reinsurance Program that requires a significant up front capital contribution. This paper outlines an alter-native program for middle market mining organizations. The program utilizes a “Blended Finite Risk” environmental insurance solution with surety acting as the “front” in states where insurance is not an acceptable form of collateral. Marsh proposes creating separate programs for each State requiring surety. The reason for separate programs stems from each states’ different surety rules. Insurance companies typically require at least $5 million in future value remediation liabilities for finite risk programs. Since most middle market mining companies have obligations that fall below this threshold, the Blended Finite Risk Program contemplates combining several companies closure/post closure liabilities to accomplish the minimum amount required by the insurance company. Why use a Blended Finite Risk Program? One of the primary benefits is the financial assurance that funds will be available for planned remediation. For example, the financial assurance may be required by a government agency. The certainty may help facilitate a merger or acquisition. Additionally, the funds may be part of a CER-CLA PRP settlement. In all cases, the insurer providing coverage would be a secure independent 3rd party. A Blended Finite Risk Program also provides a long-term solution – up to 30 years and in some select cases longer. The benefit to a state or the BLM is the removal of financial uncertainty. An insurance company writing the policy would have an AA or AAA balance sheet. The hardening of surety markets coupled with the tightening of financial assurance requirements in many states have necessitated the posting of 100% collateral. This program substantially reduces these collateral requirements.

Jan 1, 2004

By J. E. Gill, A. R. Byers

The Surf and Pugsley gold-copper mines; owned and operated by Surf Inlet Consolidated Gold Mines; Limited; are about 6 miles inland from; the head of Surf inlet; on Princess Royal island; Skeena mining division; British Columbia. Surf inlet is a fiord 360 miles in an air line northwest of; Vancouver.

Jan 1, 1954

By Alexander Smith

Surf Point and Edye Pass mines are on the northwestern part of Porcher island; 25 miles southwest of Prince Rupert. During the 1930's they produced about $750; 000 in gold from ore averaging better than one-half ounce a ton. The deposits are quartz veins; containing auriferous pyrite; concentrates average about 8 oz. gold a ton. The veins occur in a quartz diorite; stock. Their distribution shows an apparent control by primary flow structures; for the principal deposits lie on the axis of an arch of flow layers. The technique used in mapping the structures in the intrusive is that known as the Cloos method and described by Balk.

Jan 1, 1954

By M. B. McClenaghan

"Abstract - The Matheson area of northeastern Ontario is of great interest for mineral explo­ ration because of its geological similarities with the adjacent Timmins, Kirkland Lake and Larder Lake gold camps. Exploration in the area, however, is hampered by the presence of an extensive and thick cover of glacial sediments. For this reason, till geochemistry has be­ come an important exploration method. The Ontario Geological Survey&apos;s Black River -Matheson (BRiM) reconnaissance till sampling project, carried out between 1984 and 1988, was designed to aid exploration in the Matheson area by documenting the Quaternary stratigraphy and providing a database of till geochemistry. Till samples were collected by backhoe trenching of surface pits in areas of thin drift ( < 5 m) and by sonic overburden drilling in areas of thicker drift. This paper summarizes the results from the shallow till sampling component of the BRiM project.Two hundred and eighty-two surface samples were collected from Matheson Till, the youngest till sheet in the area, which was deposited during the Late Wisconsinan. For each sample, the non-magnetic heavy mineral (>3.3 S.G.) and fine (-250 mesh) till fractions were analyzed geochemically. In addition, visible gold grains were recovered by panning the heavy mineral fraction. Five areas that display multi-element anomalies in both till fractions warrant further investigation: (1) western Egan Township, overlying the Bradley Lake Syenite; (2) around and south of the Munro and Croesus mines, in Munro and Guibord townships; (3) central Garrison Township overlying the Garrison Stock; (4) south of Ore Car Lake in northern Thackeray Township; and (5) southeastern Harker Township. In these areas, Matheson Till has a local provenance and the bedrock sources for these anomalies are nearby in the up-ice (north­ northwest) direction. Due to the fine-grained nature of gold in bedrock deposits in the BRiM area, the small size of most gold grains recovered from till samples (<50 1-1m) and the variable distribution of gold in the heavy mineral concentrate and fine fractions, the fine fraction in addition to the more commonly used heavy mineral concentrate should be used for gold exploration.Surface till samples have been affected by weathering to a depth of s3 m. Weathered till is characterized by a very low carbonate content in the matrix fraction, the absence of sulfide grains in the heavy mineral concentrate and higher concentrations of copper, nickel and zinc in the fine fraction than in the heavy mineral concentrate. As a result of the weathered/ oxidized nature of the surface till samples, the fine fraction is a better sampling medium for base metal exploration."

Jan 1, 1992

By J. T. Burwell

As is well known, the alloys of iron containing 18 ± per cent chromium, 8 ± per cent nickel and less than 1.2 per cent carbon exhibit the same allotropic modifications as iron. The face-centered cubic or gamma phase is stable at high temperatures and the body-centered cubic or alpha ferrite is presumably stable at room temperature. The transformation from the gamma phase to the alpha phase in alloys of the above composi-tion (18-8 or stainless steel) is sluggish; even moderately rapid cooling permits the retention of the gamma phase. Cold-work, however, causes the transformation from gamma to alpha to occur at room temperatures. It is difficult, nevertheless, to induce complete transformation regardless of the method of cold-working. Since metallographic polishing is very effective in transforming the surface austenite to ferrite, as indicated by the magnetic studies of Buehl and Wulff, 1 it was decided to investigate the phenomenon by electron diffraction methods.

Jan 1, 1939

By W. R. Tyson

IT HAS BEEN KNOWN for many years that alloy steels can become brittle when tempered in the range of 350-600°C, or cooled slowly after heating to higher temperatures. The metallurgical literature reveals that blacksmiths were aware as early as 1883 that water quenching was necessary after heat treatment above 600°C to avoid brittleness. It has also been known for years that the problem is associated with trace impurities; a paper in the Journal of the Iron and Steel Institute of 1894 refers to the brittle, faceted fractures that occur in steels containing arsenic, phosphorus or sulphur. However, definitive investigation of the mechanism of embrittlement has been possible only within the last decade with the introduction of new experimental techniques to investigate surfaces, especially Auger electron spectroscopy. It is now possible to study in detail the chemistry of surfaces with a resolution of an atomic layer or two, and enormous progress has been made recently in studying the segregation of impurities to grain boundaries by exposing the boundaries by fracture inside the microscope. A clear picture of the processes occurring and their interpretation is now emerging, as was particularly clear at the recent 1977 ASM Materials Science Seminar on Interfacial Segregation held in Chicago in October. Recent research in this area has pointed the way for commercial exploitation of this new knowledge and experimental technology. It is the purpose of this article to trace progress in understanding temper embrittlement and to indicate other areas where control of interfacial segregation and its effects can be important in metallurgical applications.

Jan 1, 1978

By Bishop I, Toon S

To determine whether 130 felt earth tremors around Edwinstowe, Nottinghamshire U.M, which also experienced severe surface fissuring, were caused by coal extraction, a surface seismometer array was established around Thoresby Colliery. Over the next year, 785 microseismic events were detected. The spatio- temporal seismicity patterns are clearly associated with the commencement, continuing extraction and closure of faces. Of particular note are events which locate at the surface and appear to be related to the active fissuring. Events occur within days of commencement of production and cease when production finishes, with good correlation between face advance and hypocentral position. Naturally occurring microseismic events have also been detected up to 1 km ahead of active longwall faces in the Midlands using triaxial geophone packages grouted into the seam together with a surface seismometer in the top of the borehole. The quality of these data were very high and guided waves can clearly be seen with the dispersive characteristics associated with seam waves. In one experiment more than 2000 events were detected in only two days of monitoring even in a relatively noisy surface environment. This paper demonstrates how very accurate locations (5 10 metres) can be generated using three-component digital data from only one borehole. The surface seismometer and the borehole P-wave onset can give extra precision for the height of the event relative to the seam. The event distributions give a dynamic, three-dimensional image of the developing patterns of fracturing above, below and ahead of the longwall face with important implications for roof control, subsidence prediction and gas Migration.

Jan 1, 1992

By Styles P.

To determine whether 130 felt earth tremors around Edwinstowe, Nottinghamshire U.K, which also experienced severe surface fissuring, were caused by coal extraction, a surface seismometer array was established around Thoresby Colliery. Over the next year, 785 microseismic events were detected. The spatio-temporal seismicity patterns are clearly associated with the commencement, continuing extraction and closure of faces. Of particular note are events which locate at the surface and appear to be related to the active fissuring. Events occur within days of commencement of production and cease when production finishes, with good correlation between face advance and hypocentral position. Naturally occurring microseismic events have also been detected up to 1 km ahead of active longwall faces in the Midlands using triaxial geophone packages grouted into the seam together with a surface seismometer in the top of the borehole. The quality of these data were very high and guided waves can clearly be seen with the dispersive characteristics associated with seam waves. In one experiment more than 2000 events were detected in only two days of monitoring even in a relatively noisy surface environment. This paper demonstrates how very accurate locations ( 5 10 metres) can be generated using three-component digital data from only one borehole. The surface seismometer and the borehole P-wave onset can give extra precision for the height of the event relative to the seam. The event distributions give a dynamic, three-dimensional image of the developing patterns of fracturing above, below and ahead of the longwall face with important implications for roof control, subsidence prediction and gas migration.

Jan 1, 1992

By Raghoottma S. Pandurangi, Mohindar S. Seehra, Pedro Bolsait, Bronwyn L. Razzaboni

"Surface IR (infrared) modes of crystalline and fumed (amorphous) silica particles, calcined at temperatures up to 1095°C, have been studied by Fourier transform infrared spectroscopy. The ability of these same particles to lyse cells has been measured by a hemolysis protocol. The untreated crystalline and amorphous materials differ by a factor of 40 in specific surface area, and the intensity per unit mass of the sharp surface silanol band near 3745 cm-1 in the amorphous material is an order of magnitude larger than in the crystalline material. A similar difference is observed in the lysing potential of the two materials. The intensity of the silanol band increases after calcination for both materials, reaching peak values near 500°C, followed by a dramatic drop at higher calcination temperatures, and reaching negligible values for materials calcined near 1100°C. The lysing potential data follow essentially the same pattern for both crystalline and fumed silica. These results are consistent with the hypothesis that the surface silanol groups are involved in cell lysis. Further experiments are suggested to evaluate the relationship between the surface structure of ailica particles and their potential cytotoxicity. IntroductionThe characterization of the surface structure of various allotropic forms of silica is of interest because the cytotoxicity of silica particles of respirable size has been commonly related to the chemical interaction of functional groups on the surface of such particles with the lipoproteins contained in cell membranes (1-3). It has been found that the cytotoxic potential of silica particles varies greatly with their crystalline structure (4,5), particle size (6-8), surface composition (9), and molecular surface configuration (1,10). Studies of the infrared (IR) modes of various forms of silica have been reported by a number of researchers (3 ,11-19). Several books and reviews (20-24) have dealt with the identification of functional groups on silica surfaces and the effect of heat treatment on the surface structure. The nature of the surface is said to be critical in determining the biological activity of silica dusts (3).Fourier transform infrared (FTIR) spectroscopy is a highly sensitive ·technique for identifying IR surface modes of tine particulates, and it was deemed of interest to examine the surface structure and its relation to lysing potential of two widely different types of respirable silica dust. The lysing potential of respirable dust particles has been considered a first-level test for potential cytotoxicity."

Jan 1, 1990

By Armine F. Banfield

Selection of a plant site is becoming increasingly more difficult and important, mainly due to advances in technology, antipollution laws and changing economic, social and community conditions. Discussion falls naturally under three headings: economic considerations, terrain considerations and environmental considerations. Aside from acquisition of surface rights, problems having to do with terrain, or topography, usually can be dealt with by management alone. Economic considerations largely involve decision-making by management plus negotiations with government regulatory agencies acting under set rules. Environmental considerations, such as air and water pollution, townsites, housing, schools, noise abatement, appearance, surface rehabilitation and the like usually are under the control of federal, state or municipal bodies with a large degree of decision-making. Successful solution of environmental problems often requires lengthy negotiations, during which public relations by the mining company play an important part. Existing union regulations or customs may confine decision- making and the establishment of wage rates, working conditions and regulations. These usually require considerable planning and negotiation. Initial production often is delayed by formal negotiations involving environmental considerations. Surface facilities usually can be divided into two broad categories: those for concentrating ores--such as gold, silver, base metals, low-grade iron ore and potash-which should be close to the mine to reduce ore-transportation costs to a minimum, and those where the ore is shipped elsewhere for treatment, such as direct-shipping iron ores, complex high-value ores requiring specialized treatment and ores from which special products are derived for local markets. The long-term aspects of plant-site selection too often are given no or insufficient consideration because of immediate financial limitations. As a result, additional capital expenditures may be required later for relocation of townsites, roads, railroads and plants to provide additional room for extension of open-pit operations, tailings disposal, storage, or danger to foundations through underground subsidence or open-pit mining. In the past, hillside sites for concentrating plants were preferred to take advantage of gravity-feed methods The modern trend, however, is to place as much equipment as possible on approximately the same level. Some costs relating to plant sites are included in this section. They are ranges as of the year 1970, and are offered only as general guides. Such costs will vary widely with geographical location and, of course, are subject to escalation due to increases in wage rates and cost of materials. Items in the bibliography contain more detailed and comprehensive data on specific subjects. Most contain bibliographies of their own.

Jan 1, 1973

By N Pirouznia, F Rashidi Nejad, S Naraghi

Sungun Copper Mine, which is the second largest copper mining operation in Iran has a large tailings storage facility with a seepage control dam located downstream of the main dam. Surface and groundwater in surrounding area of the tailings storage facility has been monitored for ten years. This paper will discuss the results of the surface and groundwater monitoring and seepage control at the Sungun Copper Mine. The results of the study show that if the tailings storage facility influence the water quality of the rivers, this effect is not significant, so that the prevailing parameters of the measured parameters were within the permissible standard of drinking water in Iran.CITATION:Rashidi Nejad, F, Naraghi, S and Pirouznia, N, 2018. Surface and groundwater monitoring and seepage control at the Sungun Copper Mine, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 439–453 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By Duane L. Whiting

Jan 1, 1985

By Jie Li, Longxiang Li, Wenbing Guo, Gaobo Zhao, Yuhang Hu

Surface subsidence caused by underground longwall mining is a very complicated process in time and space, influencing building and structures on the surface of the mining area, including houses, pipelines, and highway. The field monitoring data of surface subsidence are essential for protecting them. This study investigated the dynamic and residual subsidence characteristics of both the surface and the highway over a 730-day monitoring period on a longwall panel. Three monitoring lines (Lines 1–3) were established to monitor the subsidence process, and three stages were identified: initial stage of surface subsidence, active period of surface subsidence, and residual subsidence deformation stage. The maximum subsidence value on the highway (1,786 mm) was smaller than that on the surface (2,094 mm), and the maximum subsidence velocity on the highway (41.7–50.8 mm/day) was also lower than that on the surface (66.7 mm/day). During the residual subsidence deformation stage, both the surface and highway subsidence velocities decreased to below 0.6 mm/day. Furthermore, differences in subsidence characteristics between the surface and the highway were analyzed, with the subsidence value on the highway always being less than that on the surface, while the subsidence velocity during the residual deformation stage was not always lower. This could be attributed to the influence of dynamic loads from vehicles, which could induce additional residual subsidence on the highway. Further investigation into this phenomenon will be conducted in future research.

Jul 1, 2023

By W. J. Schitt

Section 15 covers a loose collection of topics that involve water in some way. The chapters in this section include Dredge and Placer Mining (Chapter 15.1), Solution Mining: Surface Techniques (Chapter 15.2), and Solution Mining: In Situ Techniques (Chapter 15.3). The dredge and placer systems involve water in several forms. The segment on hydraulicking or hydrosluicing discusses the use of monitors to direct high-pressure water jets to move material. As such, this represents an alternative to mechanical breakage, loading, and hauling. This chapter also covers placer mining (except dry placering) where the water provides the medium that promotes the separation of minerals based on their density and other settling characteristics. Thus placer mining is generally limited to concentration of gold, tin ore, diamonds, and other heavy minerals that are already liberated and are contained in a less dense matrix. The third topic, straight forward dredging, as in sand and gravel operations, involves water only in an incidental way. Here water simply covers the minerals of interest. Thus the dredging system need only lift a payload from the submerged location to the surface for further processing or handling

Jan 1, 2008

By Q. Zhang, X. C. Wang, S. Mao

Phosphate ore is an important strategic mineral resource in which apatite is the main valuable mineral. Flotation is the most commonly used method to separate apatite from middle-low grade phosphate rock. Selective flotation separation is based on the difference of physical and chemical properties of minerals occurring at the three interfaces of mineral/bubble/water. Surface and interface chemistry of mineral have been playing an important role in interpreting and governing its flotation phenomenon. In-situ, visualized and high-precision analytical techniques, such as Time-of-Flight Secondary Ion Mass Spectrometry, Atomic Force Microscopy and Molecular Simulation, have been applied to explore and uncover microscopic nature of apatite flotation. Consequently, a great progress at molecular or atomic level on surface and interface chemistry of apatite flotation has achieved in the past decades. In this paper, the research progress of surface and interface chemistry of apatite flotation such as surface wettability, surface-charging characteristics, surface dissolution behavior, adsorption mechanisms of fatty acid collector and depressor on apatite surface were systematically reviewed. This review will be helpful for the development of more selective reagents and efficient technologies for apatite flotation. Keywords: Apatite, Flotation, Surface and interface chemistry, Surface analysis technology

Jan 1, 2020