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By T. S. Qiu

In view of the bad effect that Na-bentonite direct adsorb Pb2+-containing wastewater, this article has carried out two kinds modification treatment on Na-bentonite: the direct microwave radiation modification and microwave radiation organic modification by adding quaternary ammonium salt?cetyltrimethylammonium bromide,and analysis the main influencing factors of the modification effect. In static conditions, preparing Pb2+-containing wastewater as the research object, it has respectively studied the effects of Na-bentonite, microwave soil of direct microwave modification and microwave soil of organic modification on the process of adsorption Pb2+, and discusses the effects of pH value, temperature, adsorbent dosage, stirring time on the adsorption Pb2+ in wastewater by modified bentonite, at the same time it does a verification test to the practical Pb2+-containing wastewater. Comparison the effects of adsorption Pb2+ in wastewater, the results show that organic modified microwave bentonite is obviously better than direct microwave modified bentonite and Na-bentonite, and can make 6 mg/L Pb2+-containing wastewater meet the national discharge standards. Through scanning electron microscope, the result of test is that organic modified microwave bentonite is the cause of improving adsorption Pb2+ in wastewater. Preparing modified bentonite by microwave heating will not only shorten the response time, reduce energy consumption and work-load, but also modified effect is good.

Jan 1, 2014

By J. -H. Wu, S. Nishiyama, Y. Ohnishi

The behaviors and stress distributions of the inclined jointed rock masses with different dip angles obtained from DDA are compared to the results of laboratory tests. By calculating the block stress distributions, it is confirmed that DDA can reproduce the arching around the trap door when lowering the trap door. The shapes of arching change with the angles of inclined layers. In addition, the earth pressures acting on the trap door shows non-symmetrical distributions when the layers are not horizontal. The stress concentration occurs in one side of the rock masses close to the trap door. Furthermore, the surface settlements are also related to the inclined angle, and the loosening zone in rock masses can be different from Terzghi’s theory [1]. Since, simulations have good agreements with the laboratory test , it demonstrates the applicability of DDA to explain the mechanical behaviors of tunnel, such as arching phenomenon, non-symmetrical earth pressure distributions acting on the trap door, and the surface settlement profile in the jointed rock masses. Dans cet article est décrite l’étude numérique du perçage d’un tunnel dans un massif de couches rocheuses jointes inclinées. La simulation à l’aide de l’Analyse de Déformation Discontinue (DDA), en faisant varier l’angle d’inclinaison des couches de roche, nous apporte des résultats en termes de distributions de contraintes et de comportement des couches, résultats qui sont ensuite comparés avec des résultats de tests en laboratoire. Les résultats confirment le fait que la DDA est capable de reproduire le phénomène d’arcage autour de la trappe lorsque la trappe s’abaisse. Les formes d’arcage varient selon l’angle d’inclinaison des couches de roche. Par ailleurs, lorsque les couches ne sont pas horizontales, la distribution de pression agissant sur la trappe est assymmétrique. La concentration de contraintes se produit du coté proche de la trappe. De plus, les tassements de surface dépendent eux aussi de l’angle d’inclinaison. En conséquence, les résultats de simulation sont en accord avec les tests en laboratoire, ce qui prouve que la DDA permet d’expliquer des comportements mécaniques du tunnel tels que l’arcage, les distributions assymmétiques de pression du sol sur la trappe, ainsi que le profil du tassement de surface dans la masse de roches jointes. Dieser Beitrag beschreibt eine numerische Studie über Tunnel im geklüftetem Fels. Das Verhalten und die Druckverteilungen in den unterschiedlich geneigten und geklüfteten Felsenmassen wird mit Hilfe des Discontinuous Deformation Analysis Programms (DDA) simuliert, und mit Laborversuchen verglichen. Die Resultate bestätigen, dass DDA der Gewölbewirkung im „Trapdoor“ Experiment gut reproduzieren kann. Die Form des Gewölbes, ändert sich mit unterschiedlichen Neigungswinkeln der Schichten. Bei geneigten Schichten entstehen unsymmetrische Druckverteilungen. Auch die Oberflächenabsenkung ist von dem Neigungswinkel abhängig. Die gute Übereinstimmung der Simulationen mit den Laborversuchen zeigt, dass die DDA-Methode gut geeignet ist, um das mechanische Verhalten von Tunneln, wie z.B. den Effekt der Gewölbewirkung, die unsymmetrischen Druckverteilungen bei geneigten Schichten, oder die Oberflächenabsenkung in geklüfteten Felsenmassen, zu erklären.

Jan 1, 2003

About 15 per cent of total electricity (400 MkW) was generated by nuclear power plants in the world (2009) and about 36 000 tons of uranium has been mined in uranium mines annually. Radioactive waste material is produced from uranium mines and nuclear power plants. The wastes must be disposed or stored safely for long-term. If they leak and/or move from disposal or storage sites due to air/groundwater flow, then a serious environmental pollution can occur. Hence, multi-layer system has been proposed and employed in order to seal off these radioactive waste materials from biosphere. Basically, bentonite is now used for establishing absorbing and sealing layers in this system. However, the amount of high quality betonite is very limited and in some cases it is hard to be obtained.On the other hand, a great deal of refuse from coal burning plants is produced every year and the amount of it is expected to be higher each year, especially in developing countries. More than half of flyash is utilised and the remaining is disposed at the disposal sites. However, the life of the disposal site is limited and it is diff cult to find a new disposal site. It is requested that the percentage of the utilisation of the flyash be increased in every field.From the above two points of view, a flyash-based barrier layer/cover system is considered in this research and this paper discusses the applicability of flyash as a content of barrier layer/cover material based on the results of a series of laboratory tests.

Dec 6, 2010

By Zhihe Dou, Zimu Zhang, Guozhi Lv, Yan Liu, Xiaoli Jiang

"Cyclic heat stewed slag washing water carries high content of alkali and calcium and may cause serious tube scaling and impose an adverse impact on normal production. This study proposes a solution to utilize washing water by absorbing and mineralizing CO2, potentially restraining scaling and being able to create calcium carbonate powders. Effects of water flux on water quality, utilization ratio of CO2 and yield of calcium carbonate powder have been investigated; meanwhile, features of calcium carbonate powder are also represented. On the other hand, effects of factors such as as injection flux, pressure of CO2 on utilization ratio of CO2, morphology and purity of calcium carbonate are also investigated. The results show unambiguously that after soften injection of CO2, calcium ions were removed effectively via precipitation, alleviating the scaling problem. High purity yet fine carbonate powder could be achieved.IntroductionNowadays, 0.34 tons of blast furnace slags will be produced when producing 1 ton of pig iron; ensuing that, 0.12 tons of steel slag will be generated with 1 ton steel production while 1.57 billion tons of steel output all over the world in the year of 2012. It is therefore a critical issue to realize zero discharge of steel slags to achieve sustainable development and cyclic economy of iron and steel industry. In recent years, research institute of MCC and China JINGYE engineering company developed a heat stewed steel slag self-decomposition technology GENERATION III to solve the problem of instability of steel slags and realize the zero discharge. However, the problem of circulation line scaling which may cause the clogging, even exploding, need to be solved. The principles of the technology are: directly spraying water to the high temperature steel slag when it is poured into the hot closed pot, realizing the selfdecomposition via utilizing the waste heat of steel slag. The washing water is recycled to achieve a cyclic utilization. The process is shown in Figure 1."

Jan 1, 2014

By M. K. Pathak, A. K. Mukhopadhyay, D. C. Panigrahi

Changes in machinery operating and design parameters often result in unexpected vibrations or changes in the vibration patterns. Vibration in a system is an undesirable element that can cause machinery distress. Potential damage can be prevented by identifying the vibration level that is due to the changed operational parameters. This is necessary for the safe and reliable operation of plant equipment. This paper presents a documented study on vibration events that resulted from alterations in operating and design parameters in a mine ventilation fan and analyzes the causes by defining the sequence of events that led to its performance deficiency. This paper is based on experimental effort to study the vibration behavior of a ventilation fan under varying operating conditions.

Jan 1, 1999

By Y. Kumagai, F. A. Souza

"Electroless plating process has been used in many fields such as automobile and electronic industries. Solutions used in these processes must be disposed or treated. Commonly, in these solutions metal ions, organic materials and others chemicals are in very high concentration. It is very difficult to keep the environmental regulations for disposal of these materials, and the cost of the plating process becomes higher.The objective of this study was to investigate the recovery of components of those baths in order to decrease the cost of the plating process as well as to meet the environmental regulation.In this study the recovery metal ions, sulfate ions, phosphite ions and organic compounds were investigated. Organic compounds used in electroless plating solutions are the organic acids. In this work the solvent extraction of the most used organic acids included citric, lactic, succinic, tartaric and malic was studied. The solvent phase considered in these studies was ethyl acetate.About 95% of the metal ion was recovered by chemical plating onto mica powder. The hypophosphite remained is oxidized to phosphite and with the sulfate ion, both are recovered as calcium salts by selective precipitation in pH 7 and 2 respectively. Organic acids were recovered by solvent extraction using ethyl acetate as solvent phase and the best results were for lactic acid and succinic acid.Along with this study, was developed the analytical parameters to perform wastewater analysis by using Ion Chromatography, High Performance Liquid Chromatography (HPLC), Fourrier Transform Infrared Spectroscopy (FTIR). Ion chromatography was used to perform analysis of sulfate and phosphite ions in liquid matrix, HPLC was used to perform analysis of organic acids in liquid matrix and FTIR was used for characterization of the solids obtained in the recovery processes."

Jan 1, 1997

By Jianbo Lan, Desheng Huang, Xiaoying Qiu, Zhaohua Ke, Liusheng Ge, Xinjin Xiao, An Guo, Qiaofa Lan

Magnesium salt rare earth enrichment (MREE) is a crucial intermediate raw material in the deep processing of rare earth elements and material preparation, serving as a front-end raw material for the synthesis of rare earth oxides. With the current disposal process for MREE, neutralization slag with high rare earth residue is generated during further extraction of rare earth from the MREE and accumulates in huge piles. Therefore, the combined disposal process of MREE and neutralization slag was put forward. MREE was solubilized using 4 mol/L sulfuric acid to achieve an endpoint pH of 0.75, dissolving the rare earth and obtaining an acid solution. The MREE and neutralization slag were added in a mass ratio of 1:2 to the acid solution sequentially. The pH of the endpoint was controlled to 4.8~5.0 for neutralization and decontamination. This resulted in the production of rare earth sulfate liquid of similar quality to the original MREE disposal process, meeting subsequent extraction requirements. The neutralization slag underwent a water washing process, with two washes (first with 0.2 mol/L acidity water at a solid-liquid ratio of 1:2 and second with deionized water at a ratio of 1:4), resulting in water-washing slag with a rare earth content of 0.24% and a rare earth yield of 97.08%. Notably, zero wastewater discharge was realized. This innovative process effectively addressed the challenges of high rare earth residue in neutralization slag and stockpile accumulation, offering valuable theoretical and practical insights for MREE disposal.

May 31, 2024

By Binbin He, Baiwei Lei, Rehamutula·Rouzi, Zheng Wang, Chao Li

Methane explosions are highly destructive and constitute a primary hazard affecting mine safety. Seals are commonly employed to obstruct the propagation of methane explosions within tunnels, with the aim of reducing the damage caused by methane explosions. In order to study the influence of the seals’ position on the parameters of methane explosion damage, this study takes the Lake Lynn Experimental Mine No. 501 in the United States as a background case. It investigates the methane/air explosion damage parameters at different positions of seals in a fully sized roadway using the GASFLOWMPI code. The coupling mechanism between methane explosion gas expansion and reflected waves is analyzed. Finally, the variation patterns of explosion damage parameters are analyzed based on explosion damage criteria. The results show that as the distance increases between the seal and the explosion source, the maximum overpressure and impulse at the seal decrease exponentially, and the decrease is more significant when the seal is closer to the explosion source. The maximum velocity and maximum dynamic pressure increase first and then decrease, reaching their maximum values at approximately 115 m. They are approximately 163.355 m/s and 30.485 kPa, respectively. According to the analysis of explosion damage criteria, it is found that overpressure damage is the main form of methane explosion damage. But the damage of impulse and dynamic pressure is not be ignored. The relative position between the seal and the gas expansion area significantly impacts the parameters of methane explosion damage due to the coupling effect of gas expansion and the overpressure reflected wave from the seal. When the seal is set in the gas expansion zone, the further the seal is from the explosion source, the greater the dynamic pressure damage and the more minor the overpressure and impulse damage. The closer to the explosion source, the more significant overpressure and impulse damage changes. When the seal is set outside the gas expansion zone, the further the seal is from the explosion source, the more minor the overpressure and impulse damage to the seal, and the dynamic pressure damage increases first and then decreases.

Apr 24, 2024

The Mining Enforcement and Safety Administration has called attention to the increasing frequency of accidents occurring during mine maintenance and repair tasks in a recent publication. Data from the agency's Health and Safety Analysis Center have been compiled and presented in a report titled "Analysis of Injuries Associated with Maintenance and Repair in Metal and Nonmetal Mines,"* a booklet aimed at answering four questions: (1) Which pieces of operating equipment are most frequently involved in maintenance accidents; (2) Which maintenance functions are the most hazardous; (3) Which tools are most often associated with injuries; and (4) What is the comparative hazard of welding or flame cutting vs. mechanical or electrical maintenance functions.

Jan 3, 1978

By Eileen Ashworth

Introduction A study was completed that investigated the enrollment in mining engineering programs in 24 universities and colleges. All programs considered in the study award four-year bachelor of science degrees in mining engineering. They also provide all the engineers for the mining industry and a large portion of the geotechnical engineers working on environmental problems, storage of hazardous waste, civic, and Federal government underground projects. The numbers used as the base for the study are those reported by each program to SME-AIME and published yearly (SME, 1986). Data for the study came from the period 1975-1985. Also, since some programs include students in related disciplines and special categories, such as cooperative students, a few inaccuracies were unavoidable. A 23-page document has been prepared that reports on the overall picture of current enrollment, the trends, and discusses the results, perceived effects, and what can, or should, be done. There has been an obvious, and dramatic decrease in total undergraduate enrollment since the late 1970s. In 1978, 3117 students were enrolled. In the 1985 fall semester, enrollment was 1022, less than one-third. There were 485 seniors, 265 juniors, 147 sophomores, and 125 freshmen. The downward trend in total enrollment is likely to continue for at least another two years. Class size The catastrophic drop in enrollment is shared by all programs across the country. It does not discriminate between types of programs, coal or hard rock mining, or location. In general, 1985's enrollment is about 30% of whatever the maximum enrollment was in any program, though this varies from the teens to 50%. The latter percentage occurs only for some programs with special circumstances, particularly new programs not well established in the late 1970s. The beginning of the decline in enrollment has occurred at slightly different times as affected by the demise of each program's local industry. The numbers in each class produced from a specific freshmen year (Fig. 1) are worthy of comment. The dramatic drop in enrollment for all classes after 1982 is clearly demonstrated. The timing coincides with the general downturn in the mining industry, when many employed engineers were laid off and new graduates could not find jobs. Also, significantly fewer students are being attracted to mining programs as freshmen. The number of seniors shown seems inappropriate. Where did so many seniors come from and why are so few graduates produced? There is an increasing trend for students to take four-and-a-half or five years to graduate. Therefore, they are counted twice, once when they are first classed as seniors and again the following year. Some students purposely delay graduation to obtain more summer work experience and take additional courses. They believe that this gives them a better

Jan 8, 1986

By R. Venugopal, Saxena. V. K., U. Sankrityayan

"There is a dire need of a technology which can break the mineral interfaces to enhance liberation with minimum energy consumption in mineral beneficiation processes. Understanding of mineral crystal system and interfaces is essential to develop such methodology. So, this study is carried out to find out the role of mineral crystallography in milling and liberation. Data related of mineral crystallography, Vickers Hardness Number, Bond Work Index and beneficiation processes were collected from literature and detailed statistical analysis has been carried out to establish a correlation among these parameters. It was found that atomic weight and cell parameters shown statistically significant relationship with Vickers Hardness Number of minerals, which controls the milling characteristics of ores. Liberation characteristics of five different kinds of ores were analyzed considering the types of interfaces between valuable and gangue minerals. It was found that phase interfaces play vita role in liberation and coarser liberation can be achieved in the minerals of incoherent crystal systems like manganese and zinc ores. Study of this subject can help us to understand the effect of stress wave propagation in solids and its effect on crystal interfaces. It can also help us to design a technology of future to break the mineral interfaces.INTRODUCTIONCommunition is energy intensive mineral processing operation and consumes up to 2% of the total electric power generated in the world. Energy consumption due to comminution is increasing every year as there is growing needs to exploit lower grade ore bodies and process rejects (Blazy et al., 1994; DOE, 2005). Low grade ores require crushing and grinding to liberate the valuable minerals which are further separated from gangues by various beneficiation methods like gravity separation, floatation, leaching etc. Currently, comminution methods are selected based on the reduction ratio and energy consumption but effect of grinding methods on subsequent processing methods specially on liberation also need to be studied to optimize the entire beneficiation process. Most of the attempts made in past to minimize the energy consumption in milling to enhance the mineral liberation were focused on compression mechanism, chemical additives, thermal treatment, microwave treatment and electric disintegration (Kilpelm and Austin, 1982; Norgate and Weller et al, 1994; Bearman et al., 1997; Kumar et al., 2010; Wang el al., 2011; Singh et al., 2012). But the role of mineral crystallography on milling and liberation behavior of minerals not fully explored yet."

Jan 1, 2013

By Sejong Kim, Younghoon Moon, Youngseon Lee, Eunyoo Yoon, Yonghyun Song

"Mg alloy has a high specific strength, however, their thickness reduction was limited on most parts because of their poor stiffness. Since the modulus of rigidity is an intrinsic property, improvement of modulus of rigidity to the enhancement of stiffness is impossible. Therefore, the modification of shape and structure is available method to enhance the stiffness of real part fabricated by Mg alloy sheet. There are many thin walled parts which are located in outer section of electromagnetic system.Poor stiffness is often shown on wide surface area part with steel sheet, which has also high modulus of rigidity. In these cases, various groove patterns are used to increase the stiffness of part. However, some different methods have to be used when general groove pattern can’t be used. So, we would like to propose some new method to high stiffness on thin walled precision forging of Al or Mg alloys.An effect of proposed method on stiffness enhancement can be confirmed by fabrication of prototypes as well as structure and forming analysis based on FEM."

Jan 1, 2015

By Tiago de Souza, Caroline Gonçalves, Carlos Eduardo de Castro, Everton Dias

The Miraí plant from Votorantim Metais, has two screening stages to the bauxite classification after scrubbagem. The final product has hold the larger size of 0,84 millimeters (20 mesh). There are two sieves Haver & Boecker (model R-TE 3658 x 10972), which have four modules with cut size sieves of 10 mesh (1.70 millimeters) and ¼ inch (6.35 millimeters) on the primary screen, and 20 mesh (0.84 mm) on the secondary screen, all made of polyurethane. The actual configuration was established according to the empirical tests realized that aimed the increase material load on the secondary screening. However, having in mind the screening process improvement and use the fractions smaller than 0,84 mm, which have significant levels of Alumina and low reactive silica, was proposed a new test of change the sieves opening for 6 mesh in the primary screen and 28 mesh for the secondary sieve. The objective of this work was measure the ore alterations on the particle size distribution on the screening steps, increasing the plant weight and ratio recovery before and after the test.

Jan 1, 2014

By Woo, Hur, Kim, Ki Nam, Seung Min, Kyoung Sik

Tandem cold mill (TCM) is a process to obtain flatness as well as thickness desired by the customer by rolling hot-rolled coils continuously. The final stand of the TCM plays the most important role of flatness control, which usually uses the real-time measurement at the exit. However, as the material property increases, it is not easy to handle flatness with only the final stand. In order to overcome such a limitation, we propose a feedback control method to strengthen flatness control for non-final stands. The proposed method was tested in an actual production line, and the effect is proved for 45K or less steel grade.

Oct 1, 2019

By Anu Martikainen

Utilization of belt air in underground coal mines has been discussed extensively during the last decade. The Final Report of the Technical Study Panel on the Utilization of Belt Air and the Composition and Fire Retardant Properties of Belt Materials in Underground Coal Mining formed by the Miner Act of 2006 recommends research on leakage, use of booster fans, and escapeway safety. This paper discusses the role of ventilation modeling in evaluating primary escapeway pressurization in a three-entry development system to improve emergency escape in a coal mine using belt air. The intake entry of the NIOSH Bruceton Experimental Mine was pressurized using a 1.1 m (42 in) diameter, 37 kW (50 hp) fan. The work details air movement in the simulated three-entry system and the resulting leakage patterns. Three mine ventilation software packages were compared to analyze their performance in predicting the airflows and leakage conditions with different fan settings. NIOSH researchers found that the measurement results correlated well with the results of modeling.

Jan 1, 2010

By R. H. Grau, C. D. Taylor, A. L. Martikainen

Utilization of belt air in underground coal mines has been discussed extensively during the last decade. The Final Report of the Technical Study Panel on the Utilization of Belt Air and the Composition and Fire Retardant Properties of Belt Materials in Underground Coal Mining formed by the Mine Improvement and New Emergency Response (MINER) Act of 2006 recommends research on leakage, use of booster fans, and escapeway safety. This paper discusses the role of ventilation modeling in evaluating primary escapeway pressurization in a three-entry development system to improve emergency escape in a coal mine using belt air. The intake entry of the National Institute for Occupational Safety and Health (NIOSH) Bruceton Experimental Mine was pressurized using a 1.1-m (42-in.) diameter, 37 kW (50 hp) fan. The work details air movement in the simulated three-entry system and the resulting leakage patterns. Three mine ventilation software packages were compared to analyze their performance in predicting the airflows and leakage conditions with different fan settings. NIOSH researchers found that the measurement results correlated well with the results of modeling.

Jan 1, 2010

By I. Protkova

Versa Power Systems solid oxide fuel cell (SOFC) stacks operate at intermediate temperatures 700 ? 800 °C allowing the use of metallic interconnects. Thermal expansion good matching with other stack components and cost restriction led to selecting ferritic stainless steels as interconnect material. Analytical tools and techniques were developed to understand the ferritic stainless steel behavior at high temperature while exposed to dual environment. Analytical tools such as X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) have provided valuable information towards describing interconnect degradation in a variety of testing conditions. Several examples are presented to demonstrate interconnect oxidation and its relation with SOFC testing results.

Jan 1, 2005

By Shengli Wu, Mingyin Kou, Laixin Wang, Xinliang Liu, Zhennan Qi, Yujue Wang

Softening and melting experiments were conducted on four kinds of imported lump ores named A-D, under different temperature intervals within the self-developed visualization high temperature furnace. By calculating the reduction and shrinking degree under different intervals, softening and melting indexes were determined. These ores all expanded firstly followed by shrinkage with the temperature increasing. The difference of lump ore’s own characteristic led to different softening and melting behavior. The results showed that the looser the structure was, the better the reducibility will be. The compact structure and good reducibility led to high expansion rate. The beginning softening temperature declined and the ending softening temperature increased because of high porosity, which resulted in wide softening temperature interval. The charging ratio of lump ore A should be improved. Lump ore B should be distributed in the center of the blast furnace. Lump ores C and D should be used less.

Jan 1, 2016

By Timo Kankaanpää

Keywords: Solvent extraction, dispersion, phase separation, CFD The liquid-liquid dispersion phases are separated by gravity in a solvent extraction settler. This separation step is made more effective by picket fences. The picket fence geometry and its physical placement have a significant effect on the separation process, because the purpose of a fence is to smoothen and control organic-aqueous dispersion flow in the first part of the settler and achieve a deep and dense dispersion layer in the front end of the settler resulting in a clean phase separation. In this study, physical phenomena in the solvent extraction process and phase separation in a solvent extraction settler with and without picket fences have been examined using a commercial CFX software package. It can be concluded that the used CFD-approach proved to be a complementary tool for optimizing and designing the solvent extraction settler.

Jan 1, 2005

By J Safarian, D Hariswijaya

Treating bauxite residue as an alternative source of metals for iron and aluminium industry is an approach to promote circular economy in metal industries. Reduction of metal oxides with H2-based process is an important step on decarbonisation of metal industry. In this study bauxite residue pellets were prepared and were reduced with different H2-H2O gas compositions at different temperatures which yielded with various degrees of reduction. The bauxite residue pellets were made from a mixture of bauxite residue and Ca(OH)2 powders and sintered at 1150°C. Hydrogen reduction was carried out on the oxide pellets using a resistance furnace at elevated temperatures in controlled reduction atmosphere of H2-H2O gas mixtures which resulted in reduction of iron oxides in the pellets. Unreduced and reduced pellets were subsequently heated to 1400°C to study their smelting behaviour using differential thermal analysis (DTA) and thermogravimetric analysis (TGA) technique to investigate the evolution of phases related to slag formation via smelting. Equilibrium module of Factsage™ ver 8.1 was utilised to analyse results of thermal analysis. It was observed that Tricalcium phosphate-β (CaP2O8), Bredigite (Ca7Si4MgO16), Rankinite (Ca3Si2O7), and calcium alumino ferrite (Ca[Al,Fe]6O10) were formed during thermal analysis as intermediate phases. The initial slag formation for sintered and reduced pellets occurred at 900°C which mainly contains calcium and small amount of strontium component. The slag formation rate increases significantly starting from 1100°C when iron oxides started to form initial molten slag phase which then followed by other oxides dissolution in the system. Gas formation was observed at 1180°C and it was found that the gas to be released from unreduced pellets is O2 meanwhile the gas to be released from reduced pellets is SO2 gas. Gas formation rate for both pellets start to increase at 1280°C when the remaining chemically bonded gas start to be released from the system.

Jun 19, 2024