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By Zhikai Wang, Wensheng Lyu, Peng Yang

"To better understand the mechanical behavior of the compression deformation of backfill under high stresses corresponding to large depths, consolidation compression tests were performed for cemented tailings backfill with a cement-sand ration of 1:10 and 30% water under confined conditions. After applying different loading stress functions from 0.5 MPa to 32 MPa, the final axial deformation of the test specimen of backfill was obtained, and the micromorphology of backfill was studied before and after consolidation by scanning electron microscopy. Additionally, fitting analysis was performed for backfill confined compression deformation data and device model constitutive equations by the minimum square law. The constitutive model was revised according to the analysis results. The research results indicate that, as the load increases, the void ratio e obeys the functional relationship e=alnt + b (where a and b are fitting constants and t is compression time). Under the high-stress conditions of confinement, the constitutive model of backfill consolidation and creep can be used to describe the creep behavior of the backfill. Under high-stress conditions, after the consolidation of the confined backfill, the space between the tailing particles diminishes, the particles becomes more compact, and particle slippage occurs. INTRODUCTION With the depletion of shallow mineral resources, the mining industry has gradually shifted to deep mining (Zhang, Li, An, and Huang, 2010). Furthermore, with the continuous introduction of sustainable development policies regarding development and utilization of mineral resources, the mining industry must protect the limited available land and make full use of mineral resources as much as possible (Sijing, 1994; Zhihua, 2009). Backfill mining technology offers an unparalleled advantage in fully recovering mineral resources, controlling pressures, and improving environmental protection. As a result, this method has been widely used in various countries in the world (Burd, 2002; Benzaazoua, et al., 2008). Of the underground mines in the world, 45% of the large and medium-sized non-ferrous-metal mines and 37% of the gold mines use backfilling (Fuhrman, et al., 2014; Khaldoun, Ouadif, Baba, and Bahi, 2016). In addition, 45% of underground non-ferrous-metal mines and 37% of the gold mines use the filling method (Mchaina, Januszewski, and Hallam, 2001). According to incomplete statistics, more than 80 metal mines operate at a depth of more than 1 km; the depths of several typical deep mines are shown in Figure 1 (Burd, 2002; Fall, et al., 2009)."

Jan 1, 2017

By Cleusa Cristina Bueno Martha de Souza

Hydrometallurgical techniques for processing metals are becoming an efficient method for recovering metals. Although batteries' manufacturers have got rid of mercury content, some efforts have been made for recovering other metals enclosed in the battery formula. This paper discusses the bench scale experiments in the purification process of leached solutions from alkaline spent batteries. After leaching process using sulfuric acid as leachant, the solutions containing Fe, Cd, Pb, MIl, Zn and K were neutralized to precipitate iron hydroxide. In a second step, the purification experiments were carried out with excess of zinc dust to try to remove Cd while Mn and Zn still remain in the solution to be recovered in an electrolysis stage. The purification experiments procedures were conducted at different temperatures and times to find out properly conditions from the viewpoint of metals removal After filtration the solutions were submitted to chemical analysis to certify the metals content extracted.

Jan 1, 2001

By Joao Felipe Costa, Jair C. Koppe, Andre Zingano, Cleber Gomes

"Run-of-mine Brazilian coal has high ash content and low calorific power. Therefore, the coal must be washed to achieve the power plant specifications for burning coal. A large amount of waste results from the coal preparation, and it must be disposed of in waste piles or waste dams, depending on the material size. These waste disposals are the cause of serious environmental problems, not only in the short and medium terms, but mainly in the long term, due to the risk of provoking acid drainage or spontaneous combustion. Waste disposal requirements also demand large areas. Other problems include the pillar and roof stability in abandoned and mined out areas, building of edifices on the old and active mines, and mining under urban areas. To solve these problems simultaneously, backfilling the entries in mined out areas began with two objectives: to understand the mechanical behavior of the filling material and to model the backfilling of room-and-pillar coal mine entries through numerical simulation. Laboratory tests were performed for different filling material (with and without cement) to determine its mechanical properties and failure criteria. Based on this study, it was possible to conclude that the backfill method is a good strategy to improve the ground stability in room-and-pillar coal mines for the long term, especially for weak coal seams, and to reduce the quantity of material on waste piles on the surface.INTRODUCTIONRun-of-mine (ROM) Brazilian coal has high ash content and low calorific power. Therefore, the coal must be washed to achieve the power plant specifications for burning coal. Two types of waste are associated with power plants that bum coal for energy generation: 1) the waste from the coal preparation plant and 2) the ash from the power plant after coal burning.The Brazilian coal ash content in the ROM coal is between 45 and 55%. The clean coal is 20 to 30% ash for 4,500 kcal/kg (18,000 BTU). The coal preparation plant recovery is only about 35%. Santa Catarina State (SC) produces about 7 million tons/year of ROM coal, which results in a total of 4.5 million tons of waste. This is a large amount of waste that must be disposed of in waste piles or waste dams, depending on the material size. The waste and ash content is represented by silicate materials, such as clay and sand, and by sulfide materials, like pyrite and organic sulfur (between 1and5%)."

Jan 1, 2010

By ?. Kostadinov

Theoretical study of the behavior of grinding medium presented by TBP (tetraballpebs) was conducted by computer modeling of the position of grinding medium at different speeds and different drum fill factor. For the modeling were used known equations of motion derived for the ball load. Algorithm was created by SolidWorks software, allowing determination of center of gravity of the load in the mill and energy for grinding. These results were compared with similar results obtained by ball grinding medium. The capabilities of both grinding media are demonstrated by graphics under the following conditions: 1.Equal dimensions of the experimental model of the mill; 2.Equal mass of the grinding loads; 3.Comparison of grinding bodies with the same number, mass and density. Keywords: simulation, behavior, grinding medium, balls, tetraballpebs

Sep 1, 2012

By Lucas L. Costa, Luiz F. Lopes, Ludy C. Motta, Felipe P. D. Lopes, Sergio N. Monteiro, Lara S. Vasconcellos

"Environmentally correct materials like the lignocellulosic natural fibers, which are renewable and biodegradable, are being extensively investigated as possible substitutes for synthetic fiber in polymeric composites. Several natural fibers have never been thoroughly investigated as possible composite reinforcement. The fiber obtained from the leaves of the buriti (Mauritia flexuosa) palm tree is one example. Therefore, the objective of this work was to study the properties of buriti waste fibers, in amounts of up to 30%, reinforcing polyester composites.IntroductionIn the past century, the technological development gave priority to new synthetic materials with energy intensive methods of production. Today, there is a concern that conventional energy source such as petroleum, natural gas and coal are the main responsible for global warming. Therefore, the use of natural materials is gaining attention not only for the saving in process energy but also the renewable and biodegradable characteristics that make them environmentally correct. The lignocellulosic natural fibers extracted from cultivated vegetables like jute, sisal, hemp, coconut, flax, ramie and many others are typical examples. This type of fiber is being extensively investigated as a possible substitute for synthetic ones, especially the glass fiber, as composite reinforcement [1].A relevant example of lignocellulosic fiber substitution is nowadays occurring in vehicles. The automobile industry is applying composites reinforced with natural fibers to replace parts such as panels and seat cushions made of fiberglass or polymeric foams [4], as illustrated in Fig. 1. The practical reasons for this preference are that natural fiber composites present less damage to tools and molding equipments as well as relatively better finishing and less abrasive surface than corresponding parts made, for instance, of glass fibers. On top of these advantages, low cost is probably the main motivation for the industrial interest for natural fiber composites, especially in the case of residual fibers [5] or post-used fabrics such as jute sackcloth [6]. Natural fibers, however, are hydrophilic and will not form strong bonding with a hydrophobic polymer, normally used as composite matrix [1-3]. Another disadvantage is the heterogeneous characteristics of a natural fiber, which is typical of biomaterials. This results in a relatively great dispersion of dimensions and properties values such as the mechanical strength [1-3]."

Jan 1, 2008

By K. El-Barawi, Hussein M. Kamal

Chlorination was performed of iron-rich chromite ore from Barramyia, United Arab Republic (UAR), together with its concentrate. The effects of change of grain size, chlorine gas flow rate, time and temperature were studied. The extent and mechanism of chlorination were followed through chemical and structural analyses of the feeds and complete chemical analysis of the chlorination products. By conducting the chlorination process for short periods at 600°C or lower temperatures, products having high Cr-Fe ratios suitable for ferrochrome production can be obtained.

Dec 1, 1971

By Daniel E. Walsh, P. D. Rao

"A four-inch compound water cyclone (CWC) was tested to evaluate its gold recovery characteristics when processing -4.8 mm run-or-pit, placer material. Neutron activated placer gold particles (840 to 37 microns) were used as radiotracers (/98Au) in a closed circuit ewe test loop to determine concentrator recovery; a procedure believed unique to this study. The effect on gold recovery of gold size and shape, feed pulp density, feed pressure, vortex finder clearance (VFC), ewe cone type, top-size of the feed solids, presence or absence of heavy minerals in the feed, and the quantity of-37 micron slimes in the feed was investigated in over 300 tests.CWC concentration ratio and the top-size of the underflow solids were both affected by cone type, VFC, and feed pressure. Gold recovery was significantly affected by gold size, gold shape, and concentration ratio. These effects are complex, because significant size-concentration ratio and size-shape interactions exist. Radiotracer techniques showed gold particles had a residence time within the ewe of approximately one second. This study suggests ewe gold recovery is a concentration. This work suggests ewe gold recovery is a function of particle size and shape, and the flow rate through the cyclone. CWC cone ""bed density"" is considered important only as a thin, protective layer, which shields coarser gold particles from the entraining currents and facilitates their movement through the CWC.IntroductionCompound water cyclones (CWC), or automedium cyclones, are enhanced gravity concentrators for the beneficiation for slurries of sand, coal, and ground ore (Fig. 1). They are called compound water cyclones because of the compound slopes of their basal cones (Fig. 2) and are operated to suppress classification phenomena in favour of gravity concentration effects. The compound water cyclone is not a new wet concentrator. It was developed in the late 1950s by Dr. Jan Visman through research sponsored by Canada's Department of Energy, Mines, and Resources. Since that time, it has become a common unit in coal washeries for cleaning fine coal. CWCs and other versions of concentrating cyclones have also shown promise for heavy minerals and precious metals recovery."

Jan 1, 1988

By Wei-Tong Du, Zheng-Lei Guo, Yu Wang, Shu-Chao Wang

The influence of bottom blowing a CO2–O2 mixture on the bath temperature of a vanadium extraction converter was studied by using the characteristics of CO2 with weak oxidizing. It was studied in two aspects: oxygen content and temperature. The experiments showed, when the ratio of the mixture of CO2–O2 was 2:8 at 1300 °C, the bottom blowing of the converter inhibited the heating up of the hot metal, thus keeping the temperature below the carbon vanadium transition temperature. At 1360 °C, the sensible heat absorption by CO2 was 1.44 times that absorbed by O2 per mole. Meanwhile, at 1300 °C, 20% CO2 released the chemical heat of 13.58 kJ. So with the increase of the CO2 ratio, the bath temperature was reduced. The research showed that the bottom blowing of a CO2–O2 mixture had an advantageous effect by decreasing the temperature of the vanadium extraction converter.

Mar 1, 2018

By Cody Burcher-Jones

The recovery of rare earth elements (REEs) through heap leach/in situ techniques from so-called ion adsorption clays (IACs) is attractive due to their inherent simplicity. However, the underlying mechanisms of these processes are poorly understood. In this study, the deportment of REEs in a typical IAC material has been investigated and was found to concentrate in the phyllo-layers of the clays, especially hallyosite, and was readily desorbed by various ion-exchange reagents indicating various potential routes to liberate them. Here we are reporting the use of seawater (0.5 M NaCl), spiked with various amounts of (NH4)2SO4, and found better extraction using a reagent mixture than NaCl on its own. Further, the leaching of REEs from a bed of clay material was investigated over time to understand the rate of transport through the stagnant material. Results indicate that REE release is likely to be controlled by diffusion through the clay material, while desorption in agitated systems is rapid. A degree of fractionation between different REEs can be observed during diffusion. Nonetheless, the successful operation of in situ leach operations for this type of material would depend primarily on how easily solution cocktails can be made to flow through the bed material.

By Italo Onederra, Miguel Araos

"In order to characterize non-ideal explosives, the explosives industry rely on unconfined velocity ofdetonation tests and where possible underwater pond tests. The information obtained from such tests isquite helpful, however it cannot tell us much about the dynamics of the detonation reaction process. The detonation process has been studied for ideal explosives and the reaction zone length have been measured. However, for non-ideal explosives, that type of information is not available. Therefore, the primary aim of this work was to capture the detonation process of a non-ideal explosive using high speed video camera to determine the zone length."

Jan 1, 2017

By B. Manana

In heap leaching, the oxidative dissolution of value minerals encapsulated deep within large particles cannot be fully understood on the basis of the bulk solution conditions relative to variable solution conditions near the mineral surface. In the present study, the diffusion of the oxidising species through inner particle pores is simulated in a model apparatus that separates an inert platinum electrode under controlled reduction potential from the bulk solution through narrow pores of varying length. The Cu-NH3 system was selected as a model system and Cu(II)/Cu (I) as the redox couple of interest. Platinum probes inserted in the pores allowed the measurement of varying redox potentials along the pore length. Results showed that in a 10 mm pore, there exists a narrow (0.5 mm) zone near the reduction surface that is depleted of the oxidant and in which its supply is strongly diffusion limited, even if it is in abundance in the bulk solution. The consistent presence of this narrow diffusion region across all experimental results indicated that the transportation of the reduced species away from the reaction surface had the most significant influence on the potential variations within the pore. This was further supported by the minimal effect of varying concentrations of both Cu(II) and dissolved oxygen on the solution potential within this region.

By S. E. Clay, P. R. Taylor

A physical model for the diffusion and flow of gases through porous solids, which accounts for the random nature of individual gas molecules moving through a solid of definite structure, has been formulated. The model was solved using' the Monte-Carlo technique. It was then used to evaluate specific constants related to the dusty gas model and to describe the gas-porous solid diffusion phenomena. Experimental results were used to validate the stochastic model.

Jan 1, 1988

By Jochen Petersen, Thandazile Moyo

"The oxidative leaching of chalcopyrite in ammoniacal solutions has been evaluated using electro-analytical techniques. The anodic dissolution process has been established to be a seven-electron transfer process under nitrogen in ammonia–ammonium sulphate solutions and ammonia–ammonium carbonate solutions. The number of electrons transferred in the carbonate and sulphate salts suggests that the sulphur is oxidised to a thiosulphate intermediate and the copper and iron released as Cu+ and Fe2+. The Cu+ and Fe2+ is subsequently oxidised in solution in non-Faradaic reactions. The deportment of Fe2+ and S2O32- is affected by choice of the ammonium salt used in the leaching process. In the perchlorate salt, only five electrons are transferred, however observations made on the mineral surface after leaching do not support the formation of elemental sulphur. Scanning electron microscopy and energy-dispersive spectroscopy analysis of the mineral surface suggest presence of an iron–sulphur surface layer completely free of copper under the ammonia–ammonium sulphate conditions, an iron-rich surface layer under ammonia–ammonium perchlorate solutions and absence of surface layer build up under ammonia–ammonium carbonate solutions. INTRODUCTION Hydrometallurgical processes for copper extraction provide a viable route to recover the metal from mixed and low-grade ores, as well as overcome the environmental challenges faced by the traditional pyrometallurgical processes. Chalcopyrite is not only the most abundant of the copper sulphides, but also the most stable, making it recalcitrant to hydrometallurgical processes. Hence, hydrometallurgical processing of chalcopyrite continues to be an attractive area of research due to the vaguely understood surface chemistry of the mineral in different aqueous media. Different approaches to hydrometallurgical treatment of chalcopyrite can be carried out. These include thermal treatment prior to leaching, direct leaching and direct electrochemical leaching (Venkatachalam, 1991). Direct leaching of chalcopyrite can be carried out in various solution systems, as reviewed by Roman and Benner (1973) and Venkatachalam (1991). Ammoniacal solutions are attractive and effective lixiviants that form stable amine complexes with some base-metal cations while rejecting iron. Leaching of chalcopyrite in ammoniacal solutions in the presence of an oxidant is possible due to the stabilisation of copper(I) and copper (II) by ammonia at elevated pH levels. In oxygenated ammonia solutions, it has been suggested that chalcopyrite dissolves according to Equation 1 (Beckstead & Miller, 1977a):"

Jan 1, 2015

By T. Moyo

"The oxidative leaching of chalcopyrite in ammoniacal solutions has been evaluated using electro-analytical techniques and controlled bulk leaching studies. The anodic dissolution process has been established to be a sevenelectron transfer process under nitrogen in ammonia–ammonium sulphate solutions and ammonia–ammonium carbonate solutions, which suggests that the sulphur is oxidized to thiosulphate and the copper and iron released as Cu+ and Fe2+ in these systems. The deportment of Fe2+ and S2O3 2- is affected by choice of the ammonium salt used in the leaching process. In the perchlorate salt, only five electrons are transferred, supporting formation of different sulphur species as proposed for the sulphate and carbonate salts. Scanning electron microscopy and energydispersive spectroscopic analysis of the mineral surface after leaching indicate presence of an iron–sulphur surface layer completely free of copper in the sulphate system, an iron-rich surface layer in the perchlorate solutions, and absence of surface layer build-up in carbonate solutions. XRD analysis of a bulk leach residue from leaching in ammoniaammonium sulphate solutions showed the surface layer to be mostly amorphous (90%). The crystalline content (10%) is composed of 95% polymorphs of anhydrous iron oxide hydroxide FeO(OH). Choice of ammonium salt and the hydrodynamic environment of leaching have been shown to influence the presence or absence of the surface product, as well as its nature. IntroductionHydrometallurgical processes for copper extraction provide a viable route to recover the metal from mixed and low-grade ores, as well as overcome the environmental challenges faced by the traditional pyrometallurgical processes. Chalcopyrite is not only the most abundant of the copper sulphides, but also the most stable, making it recalcitrant to hydrometallurgical processes. Hence, hydrometallurgical processing of chalcopyrite continues to be an attractive area of research due to the vaguely understood surface chemistry of the mineral in different aqueous media. Different routes for hydrometallurgical treatment of chalcopyrite can be followed. These include thermal treatment prior to leaching, direct leaching and direct electrochemical leaching (Venkatachalam, 1991). Direct leaching of chalcopyrite can be carried out in various solution systems, as reviewed by Roman and Benner (1973) and Venkatachalam (1991). Ammoniacal solutions are attractive and effective lixiviants that form stable amine complexes with some base metal cations while rejecting iron. Leaching of chalcopyrite in ammoniacal solutions in the presence of an oxidant is possible due to the stabilization of copper (I) and copper(II) by ammonia at elevated pH levels. In oxygenated ammonia solutions, it has been suggested that chalcopyrite dissolves according to Equation [1] (Beckstead and Miller., 1977a):"

Jan 1, 2016

By B. Stuckert, P. Sheehan, J. Balfour, B. (Manas) Das, D. Fawcett

"With the growth of large scale surface mining operations, waste disposal and stability of waste dumps pose a challenging problem to engineers. Vibrations due to blasting operations proximal to these dumps further complicates dump design. Many dumps which are statically stable may become unstable due to the effects of blasting vibrations.A joint project between CANMET and Smoky River Coal Ltd. has been initiated to study the dynamic stability of waste dumps. The study involves development of an analytical algorithm combined with field monitoring to assess dump performance.Another objective of the study is to provide baseline data for a vibration attentuation relationships for sedimentary rock (coal) environments: most studies to date are for base metal mines. The effect of dump thickness on vibration response is also addressed.The key objective of the study is to present a methodology for assessing the dynamic stability of waste dumps. Implicit in this methodology are a number of assumptions concerning vibration attenuation in sedimentary rock environments, and response of the dump material to induced vibration. Where possible, these assumptions have been compared with monitoring data as a check on their validity."

Jan 1, 1989

By M R. Dehghan, H Mansouri, A Hakami, M A. Ebrahimi Farsangi, F Faramarzi

Today, it is accepted that rock fragmentation by blasting affects loading and hauling operations, and also directly influences on downstream processes such as crushing and grinding. In this research, the influence of rock fragmentation by blasting on the performance of three mills at Gol-e-Gohar iron ore mine No 1 was studied. Firstly, the fragmentation of conventional blast patterns in iron ore (5 × 6 m) was studied using image analysis and the performances of three mills were monitored. Then, a new blast pattern (4 × 5 m) was designed and nine blasts were carried out using this pattern. Increasing the powder factor form 1650 gr/m3 to 2480 gr/m3 by changing the blast pattern design showed that mill throughputs increase five per cent to 30 per cent for the new pattern.CITATION:Hakami, A, Mansouri, H, Ebrahimi Farsangi, M A, Dehghan, M R and Faramarzi, F, 2015. Study of the effect of blast pattern design on autogenous and semi-autogenous mill throughput at Gol-e-Gohar iron ore mine, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 315–320 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By I. S. Escobar

Copper, particularly the oxygen-free grade Cu-OFP, is a candidate material for containers for the long-term isolation and disposal of high-level radioactive waste (HLW) in underground repositories. After having been buried for a few hundred years, all oxygen will have been consumed in the repository, and corrosion of the copper will be caused entirely by contact with dissolved sulfides. Chloride is another potential corrodant, but in deep repositories where groundwater is neutral or slightly alkaline, the effect of chlorides can be ignored on thermodynamic grounds. Thus, the corrosion of copper in the presence of sulfide ion and under reducing conditions has been studied using cyclic voltammetry and Tafel slope measurements. It is possible to determine the effect of sulphide ion on copper corrosion resistance which is minimized at low temperature and also at low sulphide concentration. The presence of anions such as HCO3 under environmental conditions produces a beneficial effect because these ions are inhibitors.

Jan 1, 1999

By Isauro Rivera Landero, Martín Reyes Pérez, Eduardo Cerecedo Sáenz, Javier Flores Badillo, Mauricio Guerrero Rodríguez, Juan Hernández Ávila, Eleazar Salinas Rodríguez, María Isabel Reyes Valderrama

During column flotation of mining tailings of the Dos Carlos dam, it was observed that the effect of surface liquid flow (JL) is a variable that determines the rate of rise of packing bubbles and therefore, causes the generation of gas retained within the columnar system. Also overall more stable laminar flows were observed, in a range of superficial flow of liquid in the bottoms stream (JLT) from 0.446 to 0.68 cm/s, showing the stability in the range of superficial gas flow (Jg) from 0.1 to 0.5 cm/s. Observing a uniform bubble size for the three JLT evaluated, with a diameter between 0.05475 and 0.2525 cm, at all the range evaluated of Jg. Furthermore, an uniform performance was obtained, and with the same rate of rise of packing bubbles, showing a greater packing bubbles at JLT = 0.446 cm/s, due to the lesser bubble size observed, in comparison with the values of JLT of 0.68 and 1.017 cm/s.

Mar 1, 2017

By Jianzhong Li, Yunkai Wang

Lead substrate anodes are widely used in the electroplating and electrolytic field. However, with the change of internal stress, the oxide films are gradually generated on the surface of lead anode. Their structure and stress properties were studied during the oxidation by means of Raman spectra, XRD, SEM. The result showed that the diffraction peaks of lead were mainly found at the initial oxidation stage. With increasing oxidation time, Pb diffraction peaks were weakened and the diffraction peaks of PbO/PbO2 strengthened remarkably. When the oxidation time was above 10 min, monoclinic PbCrO4 was also generated in the oxide film with CrO4 2 ions solution as electrolyte. Raman spectra revealed that Raman peaks of PbO/PbO2 were gained. In addition, Raman peaks of PbCrO4 at 830–840 cm−1 were found using the CrO4 2 ions as electrolyte. Based on the relationship of the internal stress of oxide film and Raman peaks shift, PbO/PbO2 induced obvious stress generation in CrO4 2 ion electrolyte. The nucleation style of oxidation film was 3D progressive nucleation at first. After the peak current, it turned to be 3D instantaneous nucleation. In the oxidation process, the internal stress of PbO/PbO2.

Mar 1, 2017

By R. Venugopal, V. K. Saxena, A. K. Mukherjee

"Coal, iron and manganese ore samples were exposed to different ultrasonic intensities of 250, 300 and 350 W/L for five minutes and to an ultrosonic intensity of 270 W/L for different time durations of 3, 5 and 7 minutes. The ultrasonically treated samples showed reductions in D80 particle diameters of 6 percent for the coal samples, 5.95 percent for the iron ore samples and 35.63 percent for the manganese ore samples during grinding. The ultrasonic treatment was also observed to assist in reducing ash content in the coal product by 8 percent and to reduce manganese losses in rejects by about 5 percent. Ultrasonic treatment was concluded to be capable of assisting in the comminution of friable ores more prominently than the hard and porous materials.IntroductionComminution is an important unit operation in the mineral-processing, cement-making, powergeneration and pharmaceutical industries. But most of the milling technologies are considered to be energy inefficient, with less energy consumed in real size reduction and most of the energy consumed in the machine. This is more critical for the mineralprocessing industry because of the growing need to exploit lower-grade ore bodies and process rejects (Blazy et al., 1994; U.S. Department of Energy, 2005). Low-grade ores require crushing and grinding to liberate the valuable minerals, which are further separated from gangues by various beneficiation methods such as gravity separation, flotation and leaching. Various studies have been carried out to minimize energy consumption during milling by developing pretreatment methods that can initiate new fractures or improve the fracture density in materials before comminution. These studies were mainly focused on chemical additives; thermal, ultrasonic and microwave treatments; and electric disintegration (Klimpel and Austin, 1982; Norgate and Weller, 1994; Bearman, Briggs and Kojovic, 1997; Gaete-Garreton, Vargas-Hermandez and Velasquez-Lambert, 2000; Kumar et al., 2010; Wang, Shi and Manlapig., 2011, Singh et al., 2012).The fragmentation effect of ultrasonic fields in solids has been investigated since the 1950s, and Gärtner was probably the first researcher who attempted it (Gaete-Garreton, Vargas- Hermandez and Velasquez-Lambert, 2000). Sound waves can propagate in solids in the form of longitudinal waves, shear waves and surface waves, and in thin materials as plate waves.In surfaces, fractures and interfaces, various types of elliptical or complex vibrations of the particles make other waves possible. During ultrasonic-vibration treatment, cavitation bubbles nucleate, grow and collapse, generating microjets, whose impacts on the particles initiate microcracks. The ultrasonic waves can enhance the nucleation, growth and coalescence of flaws, caused by tensile or shear stress. The mechanisms operating in the materials and inducing these stresses have been identified as spall and compression-induced tensile microcracks, nucleating at preexisting flaws. These mechanisms are driven by the shock wave and cavitation effects in the surrounding fluid (Chen, Huang and Shih, 2003)"

Jan 1, 2016