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By Violetta Pavlova

Knowledge of geometrical properties of blocks in a hard jointed rock among other things is of considerable importance for prediction of rock mass behavior and for its exploitation. This paper presents a new approach to obtain the information about percentage of blocks with desirable geometrical properties in a jointed rock mass extending through a large region of interest. A model of a rock mass separated by finite number of systems of parallel plane discontinuities which form discrete blocks is discussed. A computational procedure has been derived to analyze the volume and shape distribution of blocks in the rock mass.

Jan 1, 1992

By Mani Manimaran, Inna Dymov, Mariam Melashvili, Chris Fleming, Joe O’Day

This paper presents experimental evidence that supports the use of bromine/bromide as a potential alternative to conventional cyanidation for gold leaching. The study evaluated a brominebased lixiviant, Stabilized Bromine, with considerably lower vapour pressure than liquid bromine. Using a rotating device, the rate of gold dissolution was determined at various concentrations of this reagent. The reactivity of pure pyrite, arsenopyrite and chalcopyrite minerals was also evaluated in stabilized bromine reagent. Furthermore, bromine leaching of gold in a number of gold bearing ores was undertaken. Results showed that significantly higher gold recovery can be achieved with bromine than with cyanide when leaching gold encapsulated in sulphides, but bromine consumption was high owing to simultaneous oxidation of the sulphides. The greatest promise for the bromine leach process was with oxidized gold ores. The recovery of gold from oxide ores with bromine was comparable to that achievable with cyanide and bromine consumption was reasonable when leaching was conducted at a near neutral pH of ~6. In the case of oxidized gold ores containing copper mineralization, it is possible that bromine consumption may be lower than cyanide consumption, since there is evidence to suggest that bromine is less reactive than cyanide with copper minerals.

Jan 1, 2014

By Inga Tuzovskaya1i

Three types of gold species were observed for gold-zeolites, prepared by reduction of ionexchanged Au species in a series of zeolites: (i) Au3+cations, (ii) neutral Au0 n or charged Aus+ n clusters suggested to be inside the zeolite channels, (iii) Au nanoparticles with diameter varied from 2 through 20 nm located on the external surface of zeolite microcrystals. Contribution of the gold species formed in zeolite after the ion exchange was found to depend on zeolite type, acidity of zeolite, temperature of reduction and time of storage of the exchanged and reduced Au-containing zeolites. Au3+ ionic species and clusters Aun were formed after the ion-exchange procedure (in contrast with the familiar production of Agn in same zeolites). Gold nanoparticles were observed only as the result of reduction of the Au-exchanged forms at elevated temperatures due to reduction of Au3+ species and aggregation of clusters.

Oct 1, 2003

By Philippe V. Scheers

Polycrystalline gold, glassy carbon and gold-activated glassy carbon electrodes were compared for the production of hydrogen peroxide by the cathodic reduction of dissolved oxygen. Gold was deposited on glassy carbon by sputtering with a sputter coater and by electrodeposition from a diluted KAuCl4 solution using short potential steps. The sputtered gold particles were not adherent enough, but there were no adhesion problems with the electrodeposited gold particles. The gold coverage of the glassy carbon surface could be varied by applying a different number of potential steps. The overpotential for the electroreduction of oxygen to hydrogen peroxide decreases with increasing gold coverage of the glassy carbon surface, and for gold coverages exceeding about 16 %, the overpotential is close to that observed on polycrystalline gold.

Oct 1, 2003

By Larissa Agrizzi Ronqueti

The effect of coiling temperature on selective oxidation behaviour of binary and ternary iron-based model alloys containing different contents of Si or Mn were investigated by SEM and SIMS. The experiments were carried out with a temperature ranging from 450 °C to 700 °C, under N2-5%H2 gas flow with a Dew Point of -3.3°C, for different durations. SEM images of binary iron-based model alloys revealed a decrease of grain boundary oxidation depth with increasing Silicon or Manganese content. At 530°C and 600°C SIMS results showed no Silicon diffusion toward surface, contrary to the results analyzed for Fe-x%Mn. Tests results and Wagner’s theory application (specific cases Fe-0.2%Si and Fe-0.5%Si) showed that grain boundary oxygen diffusion coefficient “DoGB” is almost 60 to 70 times faster than oxygen bulk diffusion coefficient. These results helped to broaden knowledge of single-element effects on grain boundary oxidation, in addition, will contribute of the future works in new steels with complex alloy compositions.

Aug 17, 2017

By Robert W. Buechley, Charles R. Key, Jonathan M. Samet, Marion V. Morgan, Arnolfo A. Valdivia

INTRODUCTION The Uranium Epidemiology Study at the University of New Mexico was initiated in 1977 with the objective of assessing health effects of uranium mining in the Grants, New Mexico, area. The planned approach was a cohort study of mortality that would capitalize on the availability of health records at the Grants Clinic. During the first year, emphasis was placed on determining the feasibility of the proposed study: Were adequate records available? What was the quality of available information? Could a cohort be established? The first year's work confirmed the study's feasibility (Buechley, 1979). Subsequent efforts have focused on the health and exposure data base and comprehensive follow-up. A retrospective cohort study of early miners is in progress; a prospective cohort study of miners who began working under the current Federal standard is planned. This report will summarize the current status of the Uranium Epidemiology Study. A chronology of the study's activities follows (Table 1). TABLE 1. Uranium Epidemiology Study Timetable 12/77 Official start of study. 12/77-8/78 Abstracted Grants Clinic records of 21,780 persons examined for mining companies from 7/57 through 12/76. Checked company personnel records to establish who had worked underground 1 year or more through 12/76. 7/78- Obtained physical exam and mining history information on qualified miners from Grants Clinic and companies. 9/78- Obtained working level month information from companies and other sources. 12/78- Checked qualified miners list with New Mexico death tapes and New Mexico Tumor Registry files. 9/80- Submitted qualified miners list to Social Security Administration for search of its records. 12/80- Obtained copies or abstracts of early State Health Department and Mine Inspector's reports. 3/81-4/81 Conducted Pilot Respiratory Disease Survey. 3/81- Verified underground status of qualified miners via company personnel records. 3/81- Verified smoking and mining histories of qualified miners via Grants Clinic records. 3/81- Began establishing cohort with first underground experience after 1970. 4/81- Checked qualified miners list with Post Office, Voter Registration Office, Motor Vehicle Division, telephone directories, city directories, and other sources. BACKGROUND Uranium Mining in New Mexico The Grants, New Mexico, uranium belt measures some 110 by 25 miles in Cibola, McKinley, and Sandoval counties (Kelley, 1963). The three chief mining districts are, from east to west, Laguna, Grants, and Gallup. Average annual production was about 5,500 tons, or 45% of United States uranium, from 1966 through 1978. Despite a drop in this figure in 1979, to 40%, New Mexico still leads the nation in uranium reserves and production (Hatchell, 1981). In 1918 carnotite, a yellow uranium vanadate, was identified in the Shiprock area (Chenoweth and Learned, 1980; N.M. Energy and Minerals Department, 1981). It received little attention at the time because of its apparently limited volume. In 1950 an important uranium outcropping was discovered by chance in limestone at Haystack Butte, northwest of Grants. In 1951 deposits were discovered in sandstone at Poison Canyon, north of Grants, and at Jackpile, northeast of Laguna. In 1955 finding of radioactive cuttings at an abandoned oil test site near Ambrosia Lake led to drilling and discovery of the first underground deposits (Melancon, 1963). Ore bodies were also found near Church Rock in the 1950's (Rautman, 1977). A uranium rush followed. At various times during 1952-1962, 60 mines and 5 mills were in operation (Gay, 1963). In the early 1960's the price of uranium fell, and many miners left the area. Subsequent market fluctuations have produced shutdowns and consolidations, development and expansion. Many early uranium miners came to New Mexico with

Jan 1, 1981

By A. W. Khair

This paper presents an analysis of ground movements recorded from longwall operations in the Northern Appalachian region in West Virginia. The site chosen for the investigation was selected due to varying heights of overburden and topography and was instrumented for both surface and subsurface measurements. The instrumentation areas consisted of two panels covering various sections with unique geologic and topographic features. Instrumentation included surveying monuments and shallow boreholes using an inclinometer for measuring horizontal strata displacements. Vertical strata deformation was monitored utilizing a unique design of the mechanical grouting method. Full length borehole profile extension was measured using Sondex displacement rings in the inclinometer installation. Subsurface displacements, i. e. caving zone, fractured zone, and highly deformed non-fractured zone were identified. The nature of surface disturbances with respect to varying geologic settings were compared, and an attempt was made to simulate final strata caving and bed separation using finite element analysis.

Jan 1, 1987

By Suresh Chikati, Gangadharan Santhanam

Twin tunnels were constructed to a length of 863m using TBM in one of the underground metro projects. The tunnels pass through complex geological conditions (soil, rock and mixed conditions). This paper presents the consideration of volume loss and the corresponding ground settlement associated with the excavation of twin TBM tunnels by analytical and numerical methods. Empirical methods were used to calculate the ground settlement induced by the excavation of twin tunnels. The ground settlement values were directly derived from the two parameters: the volume loss and trough width parameter. These parameters are calculated based on the geological conditions at the tunnel face and tunnel overburden. The finite element software, Plaxis 2D was used to model the soil parameters with appropriate geological conditions. Twin tunnel excavation is simulated in Plaxis 2D and the effect of tunnelling on the ground was simulated by percentage volume loss. The suitable line contraction value was applied to the tunnel linings to simulate the volume loss. The surface ground settlement was directly obtained from Plaxis 2D. Instrumentation arrays were proposed along the twin tunnel alignment, to provide the ground settlement monitoring data within the influence zone of tunnelling activities. The derived ground settlement values from analytical and numerical methods were compared with the actual field instrumentation and monitoring data. From the field instrumentation data, the actual volume loss values were calculated. The compatibility of ground settlement and volume loss calculated using analytical and numerical methods and those measured using field instrumentation data is discussed in this paper.

Sep 1, 2022

By Jiwei Duan

The energy transferred from a hammer to the pile top is considered as the effective energy in this paper. The effective energy is related to the pile dimensions, soil and pile-soil interface properties. This relation may be expressed as an equation based on the dimensionless theory. The relationship between pile capacity and effective energy was studied by performing a series of wave equation analyses using a commercial software called GRLWEAP (Wave Equation Analysis Program) by GRL Engineers, Inc. The results show that the pile capacity increases with the blow count when the effective energy is constant, however, it has a little change as the blow count is over 100 blows per foot. The pile capacity decreases as the ratio of pile penetration depth to pile diameter increases if the effective energy is constant. The pile capacity will increase as the pile diameter and wall thickness increases if the effective energy is constant. The pile stickout (pile length above the ground surface) does not have a significant effect on the effective energy and may be neglected. Curves for pile capacity versus effective energy are presented to be used for preliminary hammer selection according to effective energy and hammer efficiency. Finally, a case from PDA testing was studied. Measurements of the effective energy and pile capacity by CAPWAP were presented and compared with the results by GRLWEAP.

Jan 1, 2006

By Xinhua Wang, Xuefeng Liu, Die Yang, Lifeng Zhang, Wen Yang

"CSP thin slab continuous casters are well used in recent years. The control of heat transfer in the mold is very important because it is correlated with several slab defects. The mean heat flux of CSP mold was studied based on the plant production data of LCAK steel and weathering steel. The effect of various operation conditions on the heat flux was analyzed and discussed. The results showed that the heat flux was 2.1-2.6 MW/m2 on the wide face and 1.2-2.2 MW/m2 on the narrow face for the casting of LCAK steels. During the casting of weathering steel, the heat flus was mostly 2.05-2.5 MW/m2 on the wide face and was 1.1-1.8 MW/m2 on the narrow face. The heat flux depended largely on the casting speed. The heat flux on the wide face increased obviously with increasing casting speed when the casting speed was relatively low; however, at high speed, the heat flux increased slowly or kept constant. At low casting speed, the heat flux depended little on the superheat of the molten steel. The mean heat flux depended little on the level fluctuation at continuous casting mold.IntroductionCSP thin slab continuous casters are used more frequently in recent years for its low cost of construction and manufacturing. The structure of CSP mold is very different from that of conventional thick slab casting mold, inducing the difference of heat flux between them. There have been some studies about the heat flux of thick and medium slab casters [l, 2]. Heat transfer in the mold is very important for the solidification of molten steel because it is correlated with several slab defects such as slab break-out, longitudinal crack, and surface depression. Moreover, higher casting speed is desired to improve the productivity. The control of solidified shell is extremely important. The heat flux is largely influenced by several casting parameters such as the cooling intensity of the mold, the casting speed[3], the mold flux powder [3, 4] and the carbon content of steel as well [5]. The investigation on the heat flux and affecting parameters can help to understand the solidification of molten steel in the mold."

Jan 1, 2013

By Fumihiko Sumiya, Shinya Tanaka, Yukio Kato, Kenji Tanaka, Tetsuya Sawada

When explosives are heated under an acidic environment due to metal sulfide and sulfuric acidity, their decomposition temperature falls remarkably and decomposition reaction occurs quickly, and then explosives have the risk of the deflagration to the detonation transition. Heat resistant commercial explosives which can be used under conditions of high temperature of 200ºC and an acidic environment were studied. We developed the explosive composition consisted of ammonium perchlorate (AP) as oxidizer, saturated hydrocarbon oil as fuel and binder, and calcium carbonate as decomposition inhibitor. The characteristics of this explosive composition show a heat resistance over 24 hours at 200ºC, and a detonation velocity over 2,500 m s-1. This explosive composition has a cap-sensitivity at temperature higher than 100ºC. Cost effective heat resistant commercial explosives were created by the optimization of the grain size of AP as a main component, the addition of saturated hydrocarbon oil and calcium carbonate, and the control of bulk density by the addition of micro-balloons.

Jan 1, 2003

By Y. Mercadier, M. Ait-Ali, M. Dostie

"This paper presents the results of an analytical study to assist in the design of blast furnace tuyeres, including a prediction of the heat transfer process.IntroductionA blast furnace tuyere must be made of a material which must con serve its geometric and structural integrity in the environment of the fire-ball of the furnace. It must be cooled by a fluid forced through its internal cavities in such way as to keep its maximum temperature below the allowable limit. The prediction of the convective heat transfer coefficient inside the tuyere is of great importance in the design of new tuyeres with increased service life. We have developed a computer program which can predict the convective heat transfer coefficient for two-phase flow. This paper shows how the program work s and how it can be used for the numerical simulation of tuyeres.To simulate the h eat transfer conditions in water-cooled tuyeres, one has to predict:a) The heat flux (radiation and convection) generated by the combustion gases. This was evaluated using the single-zone gas-furnace model. This model yields results which are of the right order of magnitude. A more fundamental study of radiation heat transfer based on combustion and gas concentration s will be reported in a future publication.b) The local convective heat transfer coefficient at all points with in the tuyere.Prediction of the Convective Heat Transfer CoefficientTo calculate the convective heat transfer coefficient for refrigerant stream, semi-empirical correlations developed by the nuclear industry were adopted. These correlations permit us to analyze the entire range of the convective boiling range, as shown in Table 1. Our first attempt, with a single-phase flow correlation, has shown the need to take nucleate boiling into account."

Jan 1, 1982

By Mariana H. Staia

Thermodynamic calculations based on the free energy minimization method were performed for the system Ti-Fe-Mn-0-C1-C in order to evaluate the chemistry associated with the chlorination of an ilmenitic concentrate using CCl4. In the calculations various weight ratios of FeTi03/ CC14, a , were considered, which varied between 0.32 to 0.98 at temperatures ranging from 673 K to 1273 K , at atmospheric pressure. The results obtained indicated that the operating conditions for a process in a packed bed reactor, which implies the chlorination of both Fe and Ti, are 0.39 < a < .49 at T 1173 K.

Jan 1, 1993

By Denise Corrêa de Oliveira

Common dry batteries use zinc as the negative electrode. Producers commonly use additives such as mercury to prevent corrosion and to increase the mechanical resistance of the zinc anode. Alkaline batteries also contain it, as an anti-corrosive agent. When mixed with the common municipal solid waste, heavy metals as zinc and mercury pollute soil and ground water supplies, moving to the food-chain and affecting human health. Due to these possible damages, this kind of waste must be properly disposed, or recycled. Thus, even in low amounts (ppm) in batteries, mercury has to be eliminated or, at least, its content should be reduced. This work presents the use of pyromettalurgical processes, to reduce mercury content and recover zinc. The tests involved batteries treatment at temperatures from 300° to 1000°C. Mercury is eliminated up to 650°C, and zinc is evaporated at higher temperature treatment. C

Jan 1, 2001

By J. A. M. Cano

An extensive research work was developed by Samarco Mineracao S/A to study the quality characteristics of blast furnace pellets produced with high content of MgO. Comparative blast furnace simulation tests were conducted both in Samarco and foreign laboratories. The objective was to evaluate the behavior of high MgO and normal Samarco pellets in the blast furnace operation. Additives such as dolomitic hydrated lime, dunite and magnesite were used for increasing pellet MgO content. The test results showed that pellets produced with high MgO content are similar in quality to normal Samarco Pellets.

Jan 1, 1991

By T. Hayashi

A sophisticated process of extracting ultrafine sulfide mineral particles of under 1µm size suspended in clay slurry has been developed through studies of electrochemical properties of particle surface. Experimental procedure and data of the process applied to some clay ores containing sphalerite and pyrite, and molybdenite and other sulfide minerals are reported. Discussions concentrated on the function of process reagents, particularly on various modifying reagents, and on the effect of dispersed or flocculated state of ultrafine particles in slurry which affect significantly the performance of the process.

Jan 1, 1982

By Z. G. He, S. H. Chen, P. Egger

A new model for hollow rock bolts which comprises rock material, hollow bolt material, bolt/rock interface, is developed on the base of the composite element method (CEM). The main advantage of the new model is that it can be incorporated into the conventional finite element analysis. So the mesh generation of bolted rock structures becomes more convenient and feasible, which is very important in the optimisation of reinforcement design: the mesh can be kept unchanged when the number and orientation of bolts are adjusted. The comparison of the calculation results with a conventional FE approach shows the robustness of the proposed method. Un nouveau modèle numérique de boulons creux comprenant la roche, le matériau du boulon creux et l’interface roche / boulon est développé sur la base de la méthode des éléments composites (CEM). L’avantage principal du nouveau modèle est la possibilité de l’incorporer dans une analyse aux éléments finis conventionnelle. Ainsi la génération du maillage d’une structure rocheuse ancrée devient plus simple ce qui est très important pour une optimisation du projet : en cas d’ajustement du nombre et de l’orientation des boulons, le maillage reste inchangé. La comparaison de résultats de calcul avec ceux obtenus par un code aux éléments finis conventionnel montre la robustesse de la méthode proposée. Auf der Grundlage der Verbund-Element-Methode (CEM) wird ein neues Modell für hohle Reibungsanker entwickelt, das den Fels, das Ankermaterial und die Kontaktfläche Fels / Anker umfasst. Der Hauptvorteil des neuen Modells ist die Möglichkeit, es in eine konventionelle FE-Analyse einzubetten. So wird die Netz-Generierung für verankerte Fels-Bauwerke einfacher, was für die Optimierung des Verankerungs-Projekts von Wichtigkeit ist: wenn Zahl und Orientierung der Anker variiert werden, bleibt das Netz unverändert. Der Vergleich von Rechenergebnissen mit solchen aus einer konventionellen FE-Rechnung zeigen die Robustheit der vorgestellten Methode.

Jan 1, 2003

By D. A. Meyn, R. L. Holtz, C. S. Pande, M. A. Imam, D. J. Singh

"Various theoretical and experimental techniques used to search and develop new metal hydride systems suitable for hydrogen storage are described. The main theoretical technique under study makes the use of electronic structure of the candidate materials. Microstructural characterization techniques like transmission electron microscopy are being used to study the hydride formation. Novel processing techniques for material preparation such as those needed to produce thin films or amorphous phases are also being utilized. The techniques are illustrated with results from Pd, FeTi and Mg2Ni systems.IntroductionOf the four methods of hydrogen storage, compressed gas, cryogenic liquid, metal hydrides, and gas-solid adsorption, the metal hydride storage method is more attractive from the point of view of high volumetric density and safety. Compressed gas storage has disadvantages of extreme pressure, weight, and volume requirements, whereas storage of hydrogen as cryogenic liquid is unattractive due to the requirements of extremely low temperatures and high consumption of primary energy. Moreover, the number hydrogen atoms present in a volume of 10- 22 Cm3 (nH) in liquid hydrogen state (- 20K) is 4.2 whereas number of hydrogen atoms that can be accommodated in a free volume of 10-22 cm3 of various hydrides are as follows: LiH--5.9, TiH2--9.2, ZrH2--9.2, VH2--l0.2. High hydrogen concentration is usually associated with a large H/Metal atomic ratio but is also a function of structure."

Jan 1, 1994

By M. Kanuchová, J. Briancin, M. Achimovicová

"Faculty of Mining, Ecology, Process Control and Geotechnology, Technical University, Košice, Slovakia An industrial eccentric vibratory mill was used for direct and short-time mechanochemical reduction of ilmenite concentrate (FeTiO3) and anatase (TiO2) with magnesium metal powder in order to reduce Fe and Ti resp. and hereby to convert them to the more soluble phases suitable for further hydrometallurgical processing. X-ray diffraction analysis of FeTiO3 after 60 min of milling with Mg confirmed the presence of Fe0 and Mg2TiO4 phases and for TiO2 after 180 min of milling the new TiO and MgO phases have appeared. X-ray photoelectron spectroscopy has detected Fe0 (metal) and Mg2+ species which are corresponding to the product of FeTiO3 mechanochemical reduction. The product of TiO2 mechanochemical reduction has revealed XPS spectral lines corresponding to Ti2+, Ti4+ and Mg2+ species on its surface. Morphology of mechanochemically reduced samples was studied by scanning electron microscopy analysis. Subsequent leaching of mechanochemically reduced FeTiO3 and TiO2 was performed in dilute HCl and H2SO4 at 80oC and compared with mechanically activated samples. The recovery of Ti has reached 100% for FeTiO3 and 79% for TiO2 after 60 min of leaching. Based on this study the flowsheet for possible processing of natural refractory titanium ores patented by author was adapted and documented. INTRODUCTION Ilmenite (FeTiO3), along with rutile (TiO2) represents the most important titanium resource necessary for titanium industry, for production of titanium metal, alloys and pigment grade TiO2 which are becoming more important and versatile for various industries such as an aircraft and aerospace, navy, chemical, automotive, medical and offshore wind industries, for machine and plant engineering and architecture as well, mainly due to high corrosion resistance. Pigment grade TiO2 is utilizing in pigment, plastic, glass, paper and rubber industries (Zhang, 2011). There are obvious research efforts for development of the potential alternatives to the expensive thermo-chemical commercial processes of titanium raw materials processing. Zhang (2011) has summarized conventional thermo- a electrochemical processes which involved a combination of pyrometallurgical, hydrometallurgical and electrometallurgical technologies and highlighted the improved hydrometallurgical routes promising for commercial application in the future. Such improvement could also be mechanical activation of FeTiO3, TiO2 by high-energy milling which causes their structural disordering, the changes of physical and chemical properties, consequently and has a positive effect on the dissolution kinetics (Achimovicová et al., 2014a, 2017, Baláž, 2008). The various types of mills such as a planetary ball mill, a vertical ball mill, a drum mill, an attritor were used for mechanical activation of FeTiO3 as a pretreatment process for subsequent leaching (Achimovicová et al., 2014)."

Jan 1, 2018

By R. C. Miranda

Artificial vision systems are increasingly used to assist humans to perform different tasks in different areas. These systems are able to recognize patterns in complex images, which can provide multiple data. Currently, vision systems are used in both; monitoring traffic - which uses radars for vehicular plate recognition- as in metallurgical and food industries for strict quality inspections. Their use in mining occurs in measuring the speed of froth over the lip of a cell, in determining the shape and size of pellets, in obtaining from the tendency of mineral content and as a replacement for laboratory analysis of particle size. With this advanced tool, it is possible to achieve significant improvements in quality, productivity, and especially in reducing costs in pelletizing plant of iron ore. The objective of this paper is to contemplate the current situation of image analysis in the pelleting plants and glimpse at the potential applications that are being developed. This paper also presents the conception and implementation of an automatic control system of the pellets size distribution applied on a pelletizing plant of iron ore. The article demonstrates the strategy used for measuring the size distribution of the iron ore pellets, based on image analysis and the strategy implemented on advanced process control, which shows substantial gain on plant performance.

Sep 1, 2012