Search Documents

By Strathmore R. B. Cooke

That calcium will activate quartz for flotation with anionic collectors such as soaps has been known for a number of years,1 2 3 and the method has been applied to the concentration of various iron ore 4 5 6 as well as to other materials. Clemmer gives the permissible pH range for the activation of quartz by calcium as between 9.5 and 12.5 with an optimum value of 11.0, and Hertzog7 has determined the calcium abstraction of iron ores and of Ottawa sand, but otherwise little quantitative data are available. The purpose of the present investigation was to determine those conditions under which dilute solutions of calcium chloride will activate quartz for anionic flotation and to determine the amount of calcium ion adsorbed by quartz. Those variables, the influence of which was primary, such as calcium, sodium, and hydrogen ion concentrations, were studied. Other factors which influenced the results are discussed in the description of the experiments. Three different experimental methods were used to determine the activation of the quartz. The first method was to treat a sample of ground, deslimed quartz with solutions of calcium chloride and sodium hydroxide, and to determine the calcium adsorbed by chemical analysis of the solution. Ad- vantages are that a direct value for the

Jan 1, 1949

By R. Upadhyaya

Aluminium alloy matrix cast composites have been synthesised by incorporating fine graphite powders (0.5 - 20 µm size) and chopped carbon fibres (6.5 pm P). 3-6 mm length) by liquid metallurgy technique. Incorporation of these second phase materials exceeding 6-8 wt% invariably resulted in agglomeration of the dispersoids and sometimes leading to even total rejection. It was found that small additions of mischmetal (1-3 wt%) during dispersion resulted in better incorporation without much agglomeration of the dispersoid as evident from the macro and micro structures of the composites. Further, the additions of mischmetal increased the volume of the effective incorporation of the dispersoid even to the extent 50- 60%. The mischmetal addition results in a significant increase in the power factor of the stirrer motor indicating an apparent increase in the viscosity of the system. The higher viscosity of the melt increase the shear transmission conditions within the melt during stirring thereby breaking the agglomerates of the dispersoids. The increased viscosity of the melt seems to be due to the formation rare earth - aluminium inter metallics precipitation, as observed in the metallographic studies, thereby making the process a "pseudorheocasting? technique. A provisional patent has been filed based on this work.

Jan 1, 1989

By Xian-Dong Zhou, Guo-Sheng Sun, Jianzhong Luo, Hong-An Guan

"Oxygen utilization rate of the pretreatment process which adopts biological contact oxidation method for slightly polluted supply water is relatively low, less than 10%, usually lower than 3%. So the aeration amount is not determined by calculated value of oxygen demand when doing process design, but by the ratio of gas and water. The aeration way of the biological pretreatment process for slightly polluted supply water was introduced in this paper. In the foundation of the principles of mass transfer kinetic theory and experimental data, the change law of DO (dissolved oxygen) and ammonia in the aeration tank was analyzed to explore aeration method which will help to improve the overall effectiveness of handling capacity.IntroductionThere are many kinds of filler used in the biological contact oxidation process, such as flexible solid filler, composite filamentous filler, powdery clay filler, particle ceramic filler and so on. Regardless of the different forms of filler, there are a couple of common points in the function of the aeration[1,2]: (1) The aeration process in biochemical tank not only provides adequate oxygen for the biological reaction, but also plays as a role of stirring water; (2) Biochemical reactions mainly happen in the upper reaches of tank, but seldom at down-streams.This paper, from the perspective of changing aeration way, discussed the feasibility of improving the effectiveness of biochemical reactions without increasing aeration amount, which would have some leading significances for the operation and management of similar projects."

Jan 1, 2008

By S Prakash, P S. R Reddy, S K. Biswal, V N

The beneficiation potentials of two Indian iron ore slime samples by flotation technique using both cationic and anionic collectors are investigated. The direct and reverse flotation of slimes using oleic acid and dodecylamine as the collector have been studied using both conventional cell and flotation column to upgrade the iron content. The characterisation studies of iron ore slimes indicated that the samples are extremely fine in nature and contain substantial amounts of martite, magnetite, goethite, limonite, kaolinite and quartz beside hematite as the dominant iron mineral phase. The samples on average contain around 52 - 58 per cent Fe, four to seven per cent SiO2 and five to six per cent Al2O3. Taking into account the physico-chemical properties of the slimes, it is attributed that both the samples need to be deslimed by hydrocyclone before flotation. The results of both cell and column studies on sample I showed that a feed containing 57.5 per cent Fe could be upgraded to 65.5 per cent Fe at 50 per cent overall recovery with simultaneous decrease in SiO2 and Al2O3 content to 2.3 per cent and 1.8 per cent respectively by using oleic acid as the collector. In the case of sample II, it has been established that reverse flotation of silica is the better technique to improve both the grade and recovery of iron. Batch flotation studies in cell indicated that a product with 63.1 per cent Fe could be obtained at 40.0 per cent yield with 63.6 per cent iron recovery by the combination of reagents such as gum acacia, sodium hexa meta phosphate and dodecylamine. The performance of column flotation techniques is far superior to that of the cell with respect to both grade and recovery. The concentrates are found to be quite suitable for commercial exploitation as pellet feed.

Jan 1, 2005

By A. W. Breed

The bioleaching of arsenopyrite, the oxidation of arsenate and the precipitation of ferric arsenate are competing reactions, hence their rates depend on the relative concentrations of the respective species, and the activity of the bacterial culture. Bacterial arsenic resistance may be attributed to the Pst+Pit-mutation and an energy dependent efflux pump. Pst+Pit-mutations result in a reduced uptake of arsenate. This enables the bacteria to survive in solutions in which the arsenate concentration is significantly higher than the arsenite concentration. However, the excretion of arsenate requires energy. Therefore, in the absence of an energy source or during periods of reduced bacterial activity, the inhibitory effect of arsenate may manifest at concentrations to which the culture has been adapted. The chemical ferric leaching rate of pyrite and arsenopyrite decrease with a decrease in the solution redox and may be described using a modified Butler-Volmer equation. The bacterial ferrous-iron oxidation kinetics of L. ferrooxidans also depend on the redox potential, and can be described using a Michaelis-Mententype model modified to account for both temperature and pH. A model developed using the independently determined ferric leaching, and ferrous-iron oxidizing kinetics, has been shown to compare well with the experimental data for the continuous bioleaching of pyrite. Keywords: Leptospirillum ferrooxidans, arsenopyrite, bioleaching, sulphide minerals ferrous-iron oxidation kinetics, ferric leaching kinetics, redox potential

Jan 1, 2000

By Yann Sivry, S. Subramanian, Divyasree C. Prabhakaran, Jean Riotte

The potential of a bacterial strain isolated from water samples collected from a chromite mine in Odisha, India has been assessed for the bioremediation of hexavalent chromium, a toxic environmental pollutant. The isolate was identified as Sphingopyxis sp., a Gram negative bacterium, adopting molecular biological protocols and biochemical characterization techniques. Detailed investigations on the bioremoval of Cr(VI) were carried out using Sphingopyxis sp. cells and the various parameters affecting the biosorption process were evaluated. About 55 % biosorption of Cr(VI) was obtained using Sphingopyxis sp. bacterial cells and the residual chromium in solution was found to be bio-reduced to the trivalent form, namely Cr(III). Thus, complete bioremediation of Cr(VI) could be achieved using the mine isolate, with contributions from both biosorption and bioreduction mechanisms. The Cr(VI) biosorption isotherm obtained for the isolate was found to follow a typical Langmuirian behavior and the free energy value of biosorption was determined to be ~-25 kJ/mol, indicative of involvement of chemical binding forces in the bioremediation process. The chromium biosorption kinetics by the isolate followed a pseudo second order reaction. The FTIR spectral studies revealed that carboxyl, hydroxyl, amino and phosphate groups were involved in the biosorption process. X-ray photoelectron spectroscopic studies on the bacterial cells interacted with Cr(VI) confirmed the presence of both Cr(VI) and Cr(III) on the cell surface. The electrokinetic studies revealed that the surface potential of the bacterial cells were less electronegative subsequent to interaction with Cr(VI), compared to the cells alone, which further testified to the binding of positively charged Cr(III) ions, formed by bioreduction of Cr(VI), to the bacterial cell surface. A marginal shift in the iso-electric point obtained for the bacterial cells interacted with Cr(VI), corroborated the involvement of chemical binding forces in the bioremediation process.

Jan 1, 2016

By M. V. Sowmya

Batch biosorption experiments were carried out for the bio-remediation of Cr (VI) ions from aqueous solutions using Serratia marcescens, a Gram negative, heterotroph and Gram positive bacterial isolates from a chromite mine. The influence of various experimental parameters such as contact time, pH, concentration of Cr (VI) ions and amount of biomass was evaluated with respect to the uptake of Cr (VI). The bio-sorption of Cr (VI) was found to be quite rapid and the percentage biosortion was found to increase with increase in the equilibrium chromium concentration. The free energy of biosorption of Cr (VI) was estimated to be in the range of -23 to -25 kJ/mol for the chosen bacteria. The uptake of chromium by the bacteria was confirmed by EDX and FTIR spectroscopy. As a follow up of this study, bacterial strains resistant to hexavalent chromium were isolated from a chromite mine in Karnataka, India and identified as Arthrobacter sp., Micrococcus sp. and Exiguobacterium sp. using 16s rRNA sequencing. The efficacy of the bacterial isolates for Cr (VI) uptake was assessed and over 90% bioremoval could be achieved for Serratia marcescens and Micrococcus sp. isolate. Possible mechanisms of chromium uptake by the microorganism are discussed. Keywords: bioremediation, hexavalent chromium, biosorption, bioreduction

Sep 1, 2012

By W. M. Pierce

THE present work has been done in an endeavor to correlate and complete the data on the constitution of alloys of zinc with other common, metals, dealing exclusively, however, with the zinc-rich alloys in which the zinc content is between 90 and 100 per cent. This investigation has included the systems lead-zinc, cadmium-zinc, iron-zinc, copper-zinc, aluminum-zinc, nickel-zinc, manganese-zinc, cobalt-zinc, tin-zinc, and magnesium-zinc. The important ternary system zinc-lead-cadmium and the zinc corners of other ternary systems have been investigated in connection with this work but will not be dealt with here. Zinc does not form a single homogenous zinc-rich solid solution over any considerable range of concentration with any of the metals mentioned. A limited range of solid solubility is said,; by previous investigators, to occur in several cases and certain effects on the properties of zinc are attributed (with varying degrees of consistency among different writers) to the presence of certain other metals dissolved in zinc. The increasing use of rolled zinc and the possibilities offered by zinc as a casting alloy in certain fields have it made essential to determine precisely these equilibrium relationships. In carrying out this .investigation reliance was placed chiefly on two methods, conductivity measurements and microscopic analysis. The first method proved valuable in determining the existence and extent of solid solubility. The second method stands alone as a means of determining structural characteristics and supplements the first method in the measurement of solid solubility. The scleroscopic hardness of all conductivity specimens was measured partly for its value from the point of view of mechanical properties and partly; as a check on the conductivity curves in indicating the limits of solid solubility. No hardness curves are included in this paper, for in no case were they important in arriving at the constitution of any system.

Jan 2, 1922

By D. S. Kingery

Experiments initiated by the Bureau of Mines on August 26. 1969, and recent work of others, have demonstrated the effectiveness of ventilation for controlling concentrations of respirable coal mine dust. Substantial reductions in dust concentrations have been attained by increasing the volume and rate of air movement across the face and by controlling the airflow pattern. Ventilation experiments conducted by the Bureau using high-pressure fans as auxiliary ventilation units showed that lace-generated dust could he effectively controlled in five mines employing continuous mining machines. Additional data was obtained on industry installations in two mines using similar ventilation systems. By maintaining an airflow approaching 100 fpm across the entry, the experimental system reduced the concentration of respirable dust by factors as great as 6.4. In all mines where the system was used the face-generated dust concentrations were reduced to below 3 mg/m3. Total respirable dust in two cases was above the 3 mg/m value because of the dust content of the intake air. In some mines. depending upon the type of coal being mined and other dust control factors in use, it was possible to Obtain concentrations of less than 2 mg/m Although the technology for the application of the dust control system investigated is readily available, it is evident that additional engineering studies should he made in each mine where the system is to be applied.

Jan 1, 1969

By Bian Xue, Wu Wenyuan

In order to recycle the iron and rare earth from the Baotou tailings, a roasting method was developed involving the addition of C, Ca(OH)2, and NaOH, designed to both decompose the rare earth minerals and convert haematite into magnetite and allow its recovery. The effect of various parameters such as roasting temperature, roasting time, C addition, Ca(OH)2 addition, and NaOH addition on the reduction ratio of haematite (iron sesquioxide) and decomposition ratio of rare earth were investigated. The results showed that the reduction ratio of haematite and the decomposition ratio of rare earth could be as high as 85% and 95% respectively when the roasting temperature was 650°C, roasting time was 60 min, Ca(OH)2 addition was 4%, NaOH addition was 3%, and C addition was 1.5%.

Jan 1, 2014

By E S. Souza, H Delboni Jr, M F. Calixto

This paper aims at presenting the results of laboratory, pilot plant and simulation studies for the design of the grinding circuit for the beneficiation of compact itabirites from the Conceitpo mine. Two alternatives were investigated, both utilising the current crushing circuit up to tertiary crushing. Under alternative #1, quaternary crushing was considered to produce the feed of the ball mill; under alternative #2, high pressure grinding rolls were selected to prepare the ball mill circuit feed. Pilot scale studies pointed towards the use of high pressure grinding rolls (HPGR). The circuit design was based on a throughput of 720 t/h, representing a nominal solids flow rate of 600 t/h, considering a design factor of 1.2, and P80 of 95 ¦m.

Jan 1, 2007

By L. Xu, R. Bhaskar

While a NIOSH accepted procedure exists for determination of quartz in the respirable dust samples from coal mines, no specific procedure has been defined for quartz determination in bulk samples. In this study, the effect of particle size on the estimation of quartz using the infrared technique was evaluated. Several laboratory tests were performed to determine the dependence of the infrared absorbance peak height on the different sizes of quartz particles. The significant dependence observed between quartz particle size and the measured peak height indicates the potential for erroneous interpretation of the quartz in bulk samples depending on how the samples are prepared. A procedure to reduce the effect of size in the determination of the quartz content is suggested.

Jan 1, 1994

By Marcela Gotelip Barbosa

Pellets are the main iron input to the blast furnace at ArcelorMittal Lazaro Cardenas iron and steel making facility in Mexico. Pellets are made at this facility using the concentrates generated and shipped from their captive mines viz., Las Truchas, Pena Colorada, Volcan Sonora. The concentrating plants, after grinding the ore to the liberation size, use magnetic separation and flotation to reject the silica, sulphur and phosphorous impurities. At Volcan Sonora Mines, the ore is contaminated with phosphorous minerals, and hence, after magnetic separation, the phosphate minerals are floated using anionic carboxylate collector (sodium oleate). Apart from floating the phosphate minerals, the sodium oleate also has some tendency to smear on the iron bearing mineral surfaces leaving a hydrophobic surface, which is expected to reduce the green pellet strength due to absorption of ultrafine sized air bubbles on these surfaces, and further generate higher levels of dust during the induration process. In order to alleviate this industrial problem, comparative studies were carried out on the concentrates from magnetic separation using reagents from synthetic sarcosinate and carboxylate family collectors. Results have indicated that the sarcosinate family members not only were found as replacement to carboxylate collectors, but also reduce the phosphorous content below the values achieved with oleate, thus have considerable benefits in the downstream steel making process. Based on the results, plant runs are being taken up at Volcan Sonora. In this article, the laboratory results obtained on iron grades and recoveries, and phosphorous rejection using both the reagents are presented.

Aug 1, 2018

By Ariti J

The mineralogy and extractive metallurgy of platinum and palladium in ores and residues is examined and the relative reactivity of Pt, Pd, PtS and PdS in cyanide and chloride media at 20¦C is discussed. Electrochemical measurements establish that Pd is readily leached in chloride media but more slowly in cyanide media due to a passivating PdO film. The passivating oxide film on Pt prevents leaching in either system at ambient temperatures. The results of leaching Au, Pd and Pt from an iron oxide residue obtained from the Sherritt Gordon Process using CN/air and Cl-/H202 are compared. It appears that passivation is overcome either by roasting at ?600¦ or by leaching at >_100¦C.

Jan 1, 1991

By R. N. Chakravorty

Early detection of spontaneous combustion is of utmost importance in underground coal mining to prevent major disruptions of production and to ensure a safer working environment. This paper presents the work done in developing a suitable system for the early detection of heating in a hydraulic coal mine. Laboratory studies on the products of oxidation for Balmer 10 seam coal showed that a significant amount of carbon monoxide is produced during the early stages of heating and that detection methods based on the analysis of other gases, such as hydrogen, ethane or ethylene, are not a better alternative for this coal. The four-point carbon monoxide monitoring system recently installed at the hydraulic mine is discussed in this paper. It is believed that by studying the trend of carbon monoxide concentration in the mine air, it will be possible to detect heating at an early stage. Field tests carried out so far have indicated that infra-red technology will prove to be a powerful tool in the hydraulic mine, particularly for locating hidden oxidation or fire in cracks, fissures, underground workings and coal outcrop areas before it spreads extensively. The project is jointly sponsored by EMR, CANMET, Mining Research Laboratories and Kaiser Resources Ltd.

Jan 1, 1978

By G E. Smith, G N. Lye

Wall control blasting practices are necessary to reduce the impact of blasting on mine faces but can also have a significant negative impact on mine productivity and operating costs. The conventional practice in deep open pit mines is to use so-called trim blasts adjacent to pit walls. To provide burden relief these trim blasts have fewer rows than full production blasts and are fired to a cleared free-face; hence they are termed æunchokedÆ. This practice leads to scheduling constraints on the pit operations and can cause ore dilution due to excessive muckpile movement. The use of such trim blasts stems from the perception that increased wall damage results from æchokedÆ blasts. These concerns are based on the unproven assumptions that blast vibration levels and explosive gas penetration increase with increased blast burden and face confinement. This paper describes work undertaken as part of a major investigation into wall control blasting at the KCGM Fimiston Mine, Kalgoorlie, Western Australia. It details a study to assess damage effects due to blast burden. Borehole air pressure measurements and borehole video camera inspections were done behind a series of single blastholes drilled with varying burden distances, as well as behind a dedicated trim blast and a full production blast. It was found that the measured damage effects, including visible rock cracking, dilation, and the limited extent of gas penetration behind the blastholes, did not vary significantly with burden or blast type for the cases tested. This result was in complete agreement with detailed vibration measurements conducted by Blair and Armstrong (2001) during the study, which found that vibration was independent of blast burden. As a result of these investigations, changes to the blasting practices at the mine were implemented. Dedicated trim blasts and free-face blasting have been replaced by modified production blasts and the practice of æchokingÆ blasts has been introduced. This has resulted in a significant improvement in productivity and cost savings without compromising pit wall integrity.

Jan 1, 2001

By T. C. Rao, D. D. Patil

The fishhook effect, wherein the recovery of fine particles in the underflow increases with decreasing particle size, has been observed in hydrocyclone classification. A systematic study was carried out to determine the factors affecting the recovery of very fine particles to the underflow. Attempts were made to identify factors, i.e., design and operating variables, that affect the size at which this phenomenon occurs. Experimental results show that the sizes at which the fishhook effect occurs is mainly a function of feed size distribution and solids concentration and is less dependent on the design variables.

Jan 1, 2002

By D. Hongjun

In this paper, the flotation rule and behaviors of kyanite-group polymerphous minerals were studied in modified Hallimond tube in detail. Furthermore, the energy change of collector/mineral systems before and after adsorption and the net charge densities of the atoms on the minerals surfaces were calculated by use of quantum chemistry. The flotabilities in minerals were successfully explained.

Jan 1, 1995

By Maurício L. Torem, Isabella A. Scorzelli

Taboca Mining is one of the largest producers of tin in the world. In its pilot plant, significant amounts of a middling of 90% xenotime (YPO4) and 10% zircon (ZrSi04) are produced. Until now, these minerals of this ore body could not be separated successfully. This paper presents some aspects of the fundamentals of xenotime and zircon flotation with anionic (fatty acids) and cationic (amine acetate) collector, as well as the influence of the superficial leaching of the minerals with cold HCI and HNO3 on the floatability. The mineralogical studies showed that both minerals are optically liberated in -212+106 µm size fraction. Surprisingly, SEM analysis indicated that both xenotime and zircon contain very small inclusions (1-5 µm) of thorite (ThSiO4). On the other hand, zircon is fairly metamictizated giving rise to malacon. Zeta potential tests showed that the isoelectric points of xenotime and zircon correspond to a pH value of 4.5 and 4.7, respectively.The pretreatment with HCI and HNO3 displaced the isoeletric point (IEP) of the minerals to the left. The microflotation tests indicated that the floatability of both untreated and treated minerals are quite similar in the presence of the collectors studied in this work. Adsorption mechanisms are also suggested.

Jan 1, 1995

By Hosking JW, Muir DM, Ruane M, Smith I. Hinchliffe WD

Maintaining carbon activity is critical to the satisfactory recovery of gold in the Carbon-in-Pulp (C.I.P.) process. Reduced activity can lead to gold losses in tails and lower tonnage throughput.Carbons from a number of W.A. C.I.P. circuits have been examined for the extent of fouling by inorganics such as calcium, magnesium, copper, nickel and silicon. Many of these carbons have exceedingly low activity leadingto low gold loading and excessive contact times. The relative importance of these fouling agents and cyanide levels on carbon activity is discussed. Mathematical modelling shows that relatively small improvements in kineticactivity lead to much lower tank volume require-ments and carbon residence times.

Jan 1, 1984