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Gold is actively precipitating at grades up to 80 g/tonne at and near the surface of the Waiotapu geothermal system, located in the Taupo Volcanic Zone of New Zealand. Many characteristics of this active system makes it analogous to the environment deduced for epithermal precious metal mineralisation in the circum Pacific region.The near surface area of the geothermal system is approximately 17 km2, caused to an extent by the upflow of deep, neutral pH fluids being deflected into a lateral flow of several km. This fluid has pervasively altered the rhyolite pyroclastic and ash deposits to an assemblage generally characterised by the term propylitic; major vein mineralisation is not observed. The temperatures at the 1100 m limit of drilling are 300¦C, and decrease to the surface along a boiling point curve.Condensation of steam and H S (subsequently oxidised) at the surface (derived 2from deep boiling) results in the formation of heated acid sulphate waters. These have caused a shallow (50 m) cap of advanced argillic alteration. Mixing of this oxidised condensate with the deep neutral pH fluid appears to be the principle cause of gold deposition from thiosulphide complexes. The major focus of gold mineralisation is in Champagne Pool, a hot spring which fills one of several 900 year old hydrothermal eruption craters.

Jan 1, 1984

By B. Vasanthakumar

In this study, the effect of adaptation of B.subtilis to sphalerite and galena with respect to the selective flotation of sphalerite from the sphalerite-galena synthetic mixture has been examined. The changes in the surface charge of the mineral and the bacterium, cell wall components and the profiles of secreted proteins are discussed. The flotation recovery of galena increases with the increase in the adaptation cycle of B.subtilis to sphalerite and galena, while the flotation recovery of sphalerite is independent of the adaptation cycle with either mineral. From the gel electrophoresis analysis, the protein profile for the unadapted and adapted cells is found to differ distinctly and this may be attributed to varying molecular weight fractions arising from different growth conditions. Electrokinetic measurements showed shifts in the iso-electric points of not only B.subtilis but also of the chosen minerals after adaptation. Additionally, the zeta potential of B.subtilis is found to become less negative after bacterial adaptation to the chosen sulfide minerals, while it showed an increase in the magnitude of surface negative charge after various enzymatic treatments. The change in the surface morphology and cell wall components such as phosphate, uronic acid and acetylated sugars of the bacterial species during adaptation to sphalerite and galena has been assessed. Selective flotation tests on a synthetic mixture of galena and sphalerite confirm that sphalerite can be preferentially floated from galena in the presence of the insoluble fraction of lysed B.subtilis cells initially adapted to sphalerite, with a high selectivity index. Keywords: bioflotation, b.subtilis, mineral adaptation, sphalerite, galena

Sep 1, 2012

By Jena P. K

Smaller deposits of high grade chalcopyrite or the concentrates of low grade and complex copper bearing ores, can be subjected to extraction processes other than smelting and converting. Low temperature chlorination and segregation processes are among those mentioned in the literature. In the present work, extraction of copper from a Brazilian chalcopyrite concentrate by slurry chlorination with chlorine gas at room temperature, dry chlorination by chlorine gas in the temperature range of 350 to 450¦C and segregation roasting of the calcined concentrate in the temperature range of 650 to 800¦C have been carried out. The effect of several experimental variables on the extraction of copper has been discussed in all these cases. Under optimum experimental conditions, 100 per cent Cu extraction was possible by either slurry or dry chlorination processes and around 86 per cent Cu by segregation roasting. For all the three cases, possible methods have been suggested to trial the studies on a pilot scale to assess their technoeconomic viability.

Jan 1, 1992

By Yongbin Yang, Meixia Cai, Yufeng Guo, Guanzhou Qiu, Tao Jiang, Jianjun Fan

"A series of sintering and metallurgical experiments were carried out to optimize the blast furnace burden structure in this study. The results indicated that the sinter disintegrated seriously with basicity around 1.4, and after this “turning point”, the sintering properties were improved gradually with the increase of basicity of sinter. Based on the results, an idea was put forward which focused on producing two different kinds of sinter with different basicity. Different with the original burden structure of 85% sinter with basicity 1.4-1.5 + 15% pellets, an alternative new BF burden structure was proposed by the following structure?44% sinter with basicity 1.05 + 44% sinter with basicity 1.87 + 12% pellets. This new alternative BF burden structure has been adopted by some steel plants.IntroductionIn recent years, conventional blast furnace (BF) process was put into operation to produce hot metal in “A” steel plant. “A” steel plant owns two sets of sinter strands at present. Because the sinter production capacity exceeds the actual requirements of BF, a burden structure with 85-90% self-made sinter + 10-15% purchased pellets is adopted to take advantage of the low–cost sinter. But the serious problems encountered with the BF operators are that the sinter disintegrated easily during transportation and storage process. Therefore, the rate of return fines is very high after sinter being screened."

Jan 1, 2012

By G. Hargrave, K. W. Moloney, M. R. Stokes

In recent years drivage advance rates in the UK have in- creased from 35m per week in the 1980's to 100/150m per week possible today. These extended rates of advance have resulted in an increase in the potential methane, dust and heat generation at the drivage face. In order to disperse this additional pollutant load requires an increase of fresh air at the face. Although advance rates have changed, current auxiliary ventilation practice has not. UK mining law requires that the fresh air must be delivered to within 5m of the face. This has lead to the wide spread use of overlap auxiliary systems, since a pure forcing system set at this distance would lead to excessive airborne dust. UK mining law does not at present consider on-board mounted exhaust scrubber fans to constitute an effective overlap fan within mechanised drivages. In an attempt to determine whether working conditions could be safely and economically improved within mechanised drivages, a series of preliminary full scale gallery trials were con- ducted. A summary of the principal findings of these trials are presented together with an outline of a series of representative CFD simulations, scale model experiments.

Jan 1, 1997

By Anand Anupam

Conventionally, beneficiation in Indian coal washeries is done using dense medium cyclones upto the size of 0.5 mm. Coal fines below 0.5 mm size are extensively cleaned by froth flotation. There are many problems associated with flotation of Indian coals, e.g. poor response of coal particles to flotation, misplacement of fine high-ash material to froth, loss of good quality coarser coals (within ?0.5 mm size range) to tailing streams, high cost of reagents, water contamination, etc. In addition, sophisticated control systems for efficient management of the fines washing circuits are needed. Thus, there is an escalation in the capital and processing costs. In view of these facts, studies were carried out to establish the cleaning potential of dense medium cyclones for beneficiation of fine coal down to a size of 0.1 mm, essentially aimed at reducing the load on fine coal circuits mainly comprising of flotation. ROM Coal (in the size range of -2 + 0.1 mm) obtained from JogtaOCM,Jharia coalfield possessing relatively low ash (about 21%) was used in this study. Purpose for using low ash coal was to further lower, its ash content down to 8% which is comparable, to the ash content of imported coal. After characterization studies, nine tests were carried out on the prepared feed sample for its beneficiation using a dense medium cyclone of non-conventional design (very low cone angle and longer barrel), by varying its apex and vortex finder diameters. The efficiency of separation has been evaluated using Tromp curves. It could be established that it is possible to produce a clean coal of 8% ash, with Ep value of 0.044, using Jogta OCM coal by treating it in a modified dense medium cyclone. These results are summarized and discussed in detail in the present paper. Keywords: dense medium, cyclone, fine coal, beneficiation, Jharia coal

Sep 1, 2012

By H. Kiyama

In order to further elucidate the mechanisms involved in autogenous grinding, the fracture of rock specimens in free-fall impact was studied using the theory of elasticity. Stress distributions in rock specimens under various conditions of impact were analyzed and the conditions for failure were examined in relation to the compressive and tensile strength of rock. The energy equation derived for autogenous grinding coincides basically with Lewis' generalized formula or Oka and Majima's formula, and it is sufficiently general to incorporate all of the three older theories, viz; those of Rittinger, Bond and Kick.

Jan 1, 1972

By J. L. Rodrigues Bravo

The aim of this paper is to show the results of the study that relate the variations of the bismuth content in the Caraíba Metais' electrolytic copper with the main electrolysis' process variables as electrolyte flow rate and temperature, anode's impurities content, electrolyte composition, current density, etc and their combinations and factors like cathode washing, blend of materials entering rod plant's furnace, analytical methods, shot-circuit inspection, etc. Also, the methodology considered arsenic, bismuth and antimony mass balance in the electrolysis and their electrolyte's molar ratio relations as well as bibliographic references of refineries that operate in similar conditions. The results showed the circumstances with the major probability of causing bismuth content increasing in the electrolytic copper and the main operating conditions that have to be fixed for having less bismuth variation and lower content in the electrolytic copper.

Jan 1, 2007

By B. M. P. Pingua, M. Nabiullah

Number of mine accidents occurred in Indian surface mines are due to poor quality of explosives and blasting accessories. Amlori open cast project is one of the major coal producing projects in India. Standard drilling and blasting parameters are used to achieve desired productivity of the mine. 150 and 260 mm diameter blast holes are used for blasting in coal and overburden benches. Most of shovel benches are 12 to 16 m in height and dragline benches vary from 25 to 30 m. High-energy bulk emulsions are used for blasting. The cup density and velocity of detonation of bulk emulsion explosives are 1100 to 1200 kg/m3 and 3.8 to 4.5 km/s respectively. An incident occurred on fire bench of Amlori open cast mines during mucking of blasted muck.

Jan 1, 2008

By Michal Rzyman, Nakamura Takashi, Shibata Etsuro, Grabda Mariusz, Oleszek-Kudlak Sylwia

"Thermodynamic considerations indicate that heavy metal oxides should easily react with HBr, the main gaseous product from the thermal decomposition of tetrabromobisphenol A (TBBPA), forming low boiling point metallic bromides suitable for volatile separation. Mechanisms and kinetics of the bromination reactions must be well recognized prior to developing of a new treatment for the simultaneous recycling of plastic waste containing brominated flame retardants (BFRs) and metal oxides (printed circuit boards, automotive shredder residue, plating sludge, metallurgical dusts). In this work, a differential scanning calorimeter and laboratory-scale furnace were used to investigate the possibility and conditions of the bromination of ZnO by product of thermal decomposition of TBBPA. The formed solid, condensed and gaseous products were analyzed by X-ray diffraction analysis, electron probe microanalysis, inductively coupled plasma analysis, ion chromatography and gas chromatography coupled with mass spectrometry. Introduction Tetrabromobisphenol A (TBBPA) is the largest volume brominated flame retardant (BFR) in production today and is used in more than 70% of the world’s electronic and electric (E&E) appliances [1]. The growth in the production of E&E products and the fact they become obsolete so quickly cause significant problems in the safe disposal and recycling of the electrical and electric waste (E-waste) and other BFR-containing waste [2]. Among various treatment processes, thermal methods are most useful since they allow the recycling and recovery of both the organic and inorganic fractions of the waste. However, incineration of the BFR-containing wastes results in the emission of hazardous organobromine compounds, while the main portion of bromine released from decomposed BFRs is present in flue gas as hydrogen bromide (HBr) [3]. HBr, which is known to damage incineration systems, seems to be a very effective bromination agent for many metallic oxides present in waste. The concept of this study is to take advantage this of its property."

Jan 1, 2008

By Rzyman Michal, Nakamura Takashi, Shibata Etsuro, Grabda Mariusz, Oleszek-Kudlak Sylwia

"Tetrabromobisphenol A (TBBPA) and many systems based on the synergistic effect of brominated organic compounds with Sb2O3 are extensively used as effective brominated flame retardants (BFRs) in many materials such as plastics and textiles. Thermal degradation of BFR containing plastics leads to the formation of hydrocarbons and gaseous compounds such as HBr and SbBr3. Our thermodynamic considerations indicate that these gases can act as bromination agents for metallic oxides such as ZnO, Cu2O, CuO, PbO and FeO. Moreover, these metallic oxides have the thermodynamic tendency to brominate easier than does Sb2O3. The aim of this study was to investigate experimentally the reactivity of ZnO with 1) HBr originating from the thermal decomposition of TBBPA and 2) SbBr3, which is formed during thermal degradation of brominated flame retardant plastics. The thermal treatments of the mixture of compounds of interest were investigated by thermogravimetry coupled with mass spectrometry.IntroductionTetrabromobisphenol A (TBBPA) and many systems based on the synergistic effect of brominated organic compounds with Sb2O3 are extensively used as effective brominated flame retardants (BFRs) in materials such as plastics and textiles. For instance, 4.5 million tons of flame retardant plastics containing BFRs are produced in Japan each year. Thus, in thermal treatments such as the incineration and melting of solid wastes, BFR containing plastics are intentionally or unintentionally included in the wastes. Thermal degradation of BFR-containing plastics leads to the formation of hydrocarbons and gaseous compounds such as HBr and SbBr3 [1-5]. Our thermodynamic considerations [6] indicate that heavy metal oxides such as ZnO, Cu2O, CuO, PbO and FeO should easily react with HBr prior to Sb2O3 and also with SbBr3, the main gaseous product in the thermal decomposition of TBBPA, forming low boiling point metallic bromides suitable for the volatile separation of heavy metals. The metal oxides are also expected to qualitatively and quantitatively affect debromination and decomposition of the flame retardant."

Jan 1, 2008

By B. M. P. Pingua & Md. Nabiullah

About 60 to 70 percent of bulk explosives are used in Indian coalmines to achieve coal production for power generation. Coal India Limited (CIL) is the major coal producing company in India. The average production of CIL is 400 to 450 million tonne coal per annum. The major subsidiaries of CIL are Northern Coalfields Ltd., Mahanadi Coalfields Ltd., Bharat Coking Coal Ltd., Eastern Coalfields Ltd, South Eastern Coalfields Ltd. and Western Coalfields Ltd. Most of the mines of CIL have watery holes. Therefore, high water resistance bulk explosives are preferred for better out puts.

Jan 1, 2008

By Azizan A

The paper presents the results of chlorination of beneficiated rutile and struverite (a tantalum-niobium bearing, rutile type mineral in alluvial tin deposits) by carbon tetrachloride in the range 623¦K to 773¦K. The chlorination of rutile could reach near completion at 773¦K in about an hour. The process was found to follow a modified pore-blocking law, with the basic reaction constant K varying inversely with the particle size, so that the basic process may be a reaction under interface control (chemical control) as modified by the pore blocking effect. The pore blocking factors for the various experimental conditions were evaluated and the predicted curves showed good agreement with the experimental data. In the case of Struverite, a similar kinetic behaviour was observed but the chlorination process was relatively slower than that in rutile. It was also observed that in struverite, niobium got chlorinated faster, followed by tantalum and titanium, indicating a good possibility of separation by chlorination using carbon tetrachloride.

Jan 1, 1996

By Zhigeng Xu

Pressure leach of a Yunnan marmatite concentrates with adding coal as the elemental sulfur disperser was investigated. The experimental results show that the coal with carbon content higher than 70% is incapable of dispersing elemental sulfur from minerals and cannot improve the leaching of zinc. The coal with low carbon content (lignite coal) can act as excellent sulfur-disperser in the pressure leaching at 423K. The mechanism of lignite coal as sulfur disperser was further discussed by ultraviolet, infra-red spectrum and mass spectrum.

Jan 1, 2008

By Ma Yuxin, Niu Fusheng, Yuan Zhitao, Bai Limei, Han Yuexin

"Using batch flotation experiment, contact angle measurement, particle size analysis, and scanning electron microscope (SEM), the influence and difference of pH value on the flotation rate of talc and chalcopyrite were investigate without collector at the pH range of 3~11. The results showed that, the flotation rate of talc decrease with the increasing of flotation time, while that of chalcopyrite hardly affect by flotation time, besides, the flotation rate of chalcopyrite is much less than that of talc, so the laws of flotation rate of the two minerals are independent of pH value. The flotation test data of two minerals are simulated with first order and multi-rate flotation kinetic model respectively. The simulation results showed that flotation of talc only meet the first order kinetic model, while chalcopyrite’s meet the both. In addition, According to test results of talc and chalcopyrite by the particle size distribution, SEM photographs and the contact angle measurement, the reason why talc did not conform to the first order kinetic model is not because of particle size distribution, but of particle shape. That is to say, because of sheet structure of talc, the contact angle of layers and sections are 74°and 52°respectively. At the same time, the contact angle of layers and sections are different between the particles. So flotation rates between talc particles are difference.INTRODUCTIONPossessing superior self-induced, collector-induced and sulfur-induced floatability, chalcopyrite exhibits good floatability at a wide range of pH values and potentials. Serpentine are regarded as the most difficult selected type in various chalcopyrite ore, and the predominant reason is that it contains talc. Talc, as a nonpolar layered silicate mineral, is one kind of common associated mineral in sulfide ores (Lu, 2010). Concentrate quality and flotation process of chalcopyrite are influenced as a result from the presence of talc. It is because that talc has inherent floatability which makes it readily mixed with the floated mineral and talc is easy to slime causing the slime coating of the valuable mineral (Beattie et al., 2006). Thus in order to improve the flotation effect of chalcopyrite, methods can be introduced from two respects. One method is that fast-floating talc mineral is floated preferentially, and the other is that sulfide mineral is floated prior to talc by depressing the flotation of talc mineral (Beattie et al., 2006), nevertheless, no matter with which the flotation effect of fine-sized chalcopyrite is not positive. Therefore, in order to realize the flotation separation of talc and chalcopyrite, the difference between the inherent floatability of fine-sized chalcopyrite and talc is researched and analyzed in terms of flotation dynamics in the absence of collector and frother."

Jan 1, 2016

The paper concerns an unconventional, yet promising, use of waste magnesite dust and fines. In India a significant amount of this dust is generated from some of the integrated iron and steel industries, refractory and cement plants, during calcination of raw magnesite. However. it is possible to utilize this dust, which is normally a waste, conveniently and economically for the production of magnesium. chemicals. A bench scale study was carried out to determine the rate of formation of sulfated com¬pounds of Mg.Ca,and Fe, inter alla, present in the dust system containing MeO constituents (in which Me=Mg.Ca,Fe,Si,Al etc.) Effects of various process parameters, which affect the reaction rate as also the purity of the product ,were also studied. Some work carried out to develop the process flow charts involving the salient steps to produce magnesium chemicals commercially is reported in the paper .

Jan 1, 1992

By T. R. Madhavan

The development of contact angles on highly polished ?uraninite surfaces, using sodium oleate and dodecyl ammonium acetate as collectors, has been studied at different collector and hydrogen ion concentrations. It was found that sodium oleate in acidic media (up to a neutral: PH) and dodecyl ammonium acetate in neutral and alkaline media give good contact angles. It appears that the combined forms of these collectors, viz., oleic acid and free amine, are more important in effecting contact. W ITH the emergence of uranium as a strategic metal in the last fifteen years, considerable effort has been directed toward the commercial recovery of uranium from its ores. This has resulted in the development of a uranium technology. It is only in recent years, However, that fundamental data regarding the floatability and surface properties of uraninite and ?pitchblende have been elucidated by different methods. Contact-angle measurement is one of the important tools for tl1e evaluation of the conditions of floatability

Jan 1, 1964

By E. M. Alcântara

This paper describes some aspects about the relationship between copper electrorefining addition reagents and the hydrogen in the cathode. The conditions of electrorefining were studied by factorial design methods. The advantages of this technique are reduction in the number of tests, well organized experiments; improvement in productivity and reliability of results. The dosage of the two main addition agents, glue and thiourea, were varied simultaneously and compared with the hydrogen content in the cathode. The influence of these factors, as well their interactions were analyzed by statistical methods denominated ANOVA (Analysis of Variance). The increase of thiourea quantities, within of levels studied, influenced significantly at 95% confidence in the hydrogen content in copper cathode.

Jan 1, 1999

By Liu Q, Siefken T. C, Misra V. N

Investigation of the differential flotation characteristics between arsenopyrite and pyrite in a ore concentrate have been carried out on a laboratory Leeds flotation cell. Experimental results indicate that some limited separation between arsenopyrite and pyrite is possible by differential flotation under the conditions of high pH and low pulp redox potential. The best performance in this testwork was achieved by using an oxidizing agent at pH 10.7. Of the oxidizing agents tested, NaOCI gave better oxidizing effect than KMnO4. It has also been observed that the pulp redox potential depends on the pulp pH value. At high pH values a hydroxide layer is formed on the arsenopyrite surface, which has the effect of a depressant on the arsenopyrite.

Jan 1, 1992

By Shugang Li

The layout and efficiency of the degasification system is heavily dependent on the distribution of and the methane migrating mechanism in the mining induced fractures in the overburden strata In this paper, physical modeling and numerical simulation are employed to study the mining-induced fracture zones and the stress distribution in these zones. The physical models show that both the fracture and compaction zones form a parabolic shape in the over- burden strata along the panel transverse direction. When this is generalized to the panel longitudinal direction, the shape of the mining induced fracture zone over the longwall gob can be represented by a 3-D elliptic paraboloid function. Through the observation of bed separation, fracture density and distribution pattern in the physical models, it is believed that the development of the parabolic fracture zone can be divided into three distinguishable phases. The expansion characteristics and sizes of the fracture zones can be estimated. The numerical stimulation studies can be used to estimate the extent of the stress release zones. The stress release zones can be also divided into a high compressive stress - fracture closure zone, stress relieved - fracture expansion zone, and intact zone. The methane desorption model is then used to analyze the methane migrating pattern in the fracture zone. The developed model has been verified by the results of a longwall gob degasification tests at a coal mine in Yangquan, China with a fair agreement. Such studies show that the model can provide a reasonable accurate tool for designing the gob-well degasification system for longwall mining operations.

Jan 1, 2005