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By T. Carageorgos

The removal of arsenic from process streams as ferric arsenate compounds is being practised by mining industries. Therefore, the solubility and stability of these solids is of considerable importance to the mining plants that have to keep the environment free from pollutants. There is some information on the solubility of the ferric arsenate compounds, mainly on scorodite, obtained from synthetic solution. However, there is not so much work on ferric arsenate compounds formed at high temperatures (175 - 230°C) during the leaching process. In the present work, the solubility of the ferric arsenate compounds formed during acidic pressure oxidation of arsenopyrite is presented. The results of the solubility tests showed that the ferric arsenate compounds formed at high temperatures (200 - 230°C) and high pressures (1034 - 1551 kPa 0,) released arsenic into solution in amounts less than 1.2 ppm and iron in amounts no higher than 1.0 ppm. So, they seem to be potential compounds for arsenic and iron disposal.

Jan 1, 1998

By Ralph P. Hackl

Biooxidation processes for treating arsenical and other types of refractory gold ores are touted by many as being simple, inexpensive and environmentally friendly. One of the advantages claimed by proponents of biooxidation is that arsenic is disposed of as insoluble ferric arsenate which is suitable for long term disposal in tailings ponds. However, there is considerable controversy as to the stability of ferric arsenate with respect to re-dissolution of arsenic. In particular, there is concern that the amorphous ferric arsenate produced at low temperature is not stable, especially at the alkaline pH's required for cyanidation. There is a general lack of published information on the stability of arsenical bioleach tailings. Past work on ferric arsenate stability has usually involved purely chemical systems and the use of synthetically prepared precipitates. Upon completing the Salmita bioleach pilot plant campaign (Hackl and Wright, 1989) the author had the opportunity to test the stability of the arsenical bioleach/cyanide tailings which were produced. This paper summarizes the results of that work.

Jan 1, 1990

By Brad Seymour

In cooperation with Cyprus Twentymile Coal Co., researchers from the National Institute for Occupational Safety and Health (NIOSI-I), Spokane Research Laboratory, conducted a study at the Foidel Creek Mine, an underground coal mine near Oak Creek, CO, to evaluate the stability of underground working conditions as a longwall advanced through a series of backfilled cross-panel entries. Instruments installed in the cross-panel entry pillars, backfill, longwall panel, and adjacent headgate entry were continuously monitored by a computerized data acquisition system as the longwall approached and advanced through the backfilled section of the panel. Data collected from these instruments were analyzed to determine the magnitude and direction of the secondary principal stress changes ahead of the longwall face, deformation and closure of the headgate entry, and stability of the cross-panel entry pillars and backfill. A three-dimensional, boundary element model was calibrated to accurately predict mining-induced stress changes and the distance they occurred ahead of the longwall face. As the longwall advanced through the backfilled entries, most of the mining-induced load was supported by the cross-panel entry pillars. The backfill provided stability for the root and Moor of the in-panel entries and also confined the entry pillars significantly improving their load-carrying capacity. Comprehensive information derived from backfill material property tests, instrument data, underground observations, and numeric modeling results document the safety and stability of the 8-Right minethrough and should provide beneficial case study information fur other longwall backfilling applications in the future.

Jan 1, 1998

By Mark Larson, Doug Tesarik, Joe Shoemaker, Brad Seymour

In cooperation with Cyprus Twentymile Coal Co., researchers from the National Institute for Occupational Safety and Health (NIOSH), Spokane Research Laboratory, conducted a study at the Foidel Creek Mine, an underground coal mine near Oak Creek, CO, to evaluate the stability of underground working conditions as a longwall advanced through a series of backfilled cross-panel entries. Instruments installed in the cross-panel entry pillars, backfill, longwall panel, and adjacent headgate entry were continuously monitored by a computerized data acquisition system as the longwall approached and advanced through the backfilled section of the panel. Data collected from these instruments were analyzed to determine the magnitude and direction of the secondary principal stress changes ahead of the longwall face, deformation and closure of the headgate entry, and stability of the cross-panel entry pillars and backfill. A three-dimensional, boundary element model was calibrated to accurately predict mining-induced stress changes and the distance they occurred ahead of the longwall face. As the longwall advanced through the backfilled entries, most of the mining-induced load was supported by the cross-panel entry pillars. The backfill provided stability for the roof and floor of the in-panel entries and also confined the entry pillars significantly improving their load-carrying capacity. Comprehensive information derived from backfill material property tests, instrument data, underground observations, and numeric modeling results document the safety and stability of the 8-Right mine through and should provide beneficial case study information for other longwall backfilling applications in the future.

By Kasai H, Hibi T, Matsuishi S

Coal oil mixture (COM), a liquid fuel pro- duced by mixing together coal and heavy oil on the 50-50 basis, has been brought to a level of practical use in Japan, being actually employed by a oil fired system at Yokosuka Thermal Power Station of The Tokyo Electric Power Co., Inc. A COM Production Plant, built in Onahama which is located about 160 miles from Yokosuka, required COM to be transported by sea. Mitsubishi Heavy Industries, Ltd. therefore performed a series of studies to develop a spe- cialized COM carrier, the world's first of its kind. Long lasting high stability is of pri- mary importance to successful use of COM. Much have been done in the way of research on stability of COM in the static storage, and the mechanism of COM static: stability is almost completety known. On the other hand, the knowledge about the COM dynamic stability, such as the stability while being transported aboard the COM carrier at sea, is still limited at the moment. The motion of COM aboard the COM carrier and how COM would settle were studied by tests. A visualization test on the COM behavior under dynamic motion was also performed and the mechanism of COM dynamic stability was analysed. The tests showed that the ship rolling motion had @n effect of promoting the settling of coal content of COM in the cargo hold. And studies were also made to device a method for esti- mating the settling quantity of coal during sea Transportation.

Jan 1, 1987

By R-H Yoon

The thin film pressure balance (TFPB) technique was used to measure the kinetics of thinning of single foam films and disjoining pressures in the presence of sodium dodecyl sulfate (SDS) and electrolyte (NaCl). The results were analysed in view of the Reynolds equation to determine the role of surface forces in film thinning. It was found that film thinning is controlled by surface forces at thicknesses below approximately 200 nm. It was also found that hydrophobic force plays an important role particularly at low SDS and NaCl concentrations. The values of the hydrophobic force constant (K232) estimated from the film thinning experiments were used to predict the disjoining pressure isotherm using the extended DLVO theory, which were found to be in excellent agreement with experiment. The TFPB technique was also used to measure the equilibrium thicknesses (He) of the foam films stabilised by a non-ionic surfactant, n-octanol, in the presence of NaCl. At a given ionic strength, He increased noticeably with increasing octanol concentration at very low concentrations. This observation suggests that hydrophobic force is at its maximum level in the absence of surfactant and decreases with increasing surfactant concentration. The results obtained with the single foam films were used to explain the stability of the three-dimensional foams.

Jan 1, 2005

By K. Kalgraf

The motion and stability of the metal/electrolyte interface is determined by Navier-Stokes equation. The equation may be decomposed into two independent equations by taking the divergence and curl of Navier-Stokes equation. The divergence determines the motion and stability of magneto-gravitational waves. The curl of Navier-Stokes equation gives an equation containing only velocity and magnetic field, and states that the magnetic field is driving a circulation pattern in the cell, and this magneto-flow has its own stability conditions. The waves are called Alfven waves, and their stability properties are related only to magnetic field and geometry.

Jan 1, 2001

By J. F. Lupo

Heap and valley leach operations rely on solution collection piping placed within the heap to enhance both solution recovery and to assist overall solution management. The most common piping used in leaching operations is solid or perforated High Density Polyethylene (HDPE) pipe and Corrugated Polyethylene pipe (CPE). These pipes are widely used because of their low cost, ease of installation, durability, and flexibility. The typical recommended maximum design depth of burial for HDPE and CPE pipes is on the order of 30 meters (100 feet). However, ore heap heights at many facilities exceed 30 meters and some are now approaching 180 meters (600 feet) in height. At very high ore heap heights, the stability and performance of HDPE and CPE pipes becomes a critical issue for leaching facility design and operation. Failure of solution collection piping can lead to poor solution recovery, high hydraulic heads on the liner system, and in some cases, unstable ore slopes due to high solution pressures near slopes. This paper presents a review of methods that have traditionally been used to evaluate pipe stability under high normal loads. A common shortcoming of these methods is the inability to account for beneficial effects of ore arching around pipes and the time-dependent creep (stress relief) behavior of polyethylene (PE) materials. A new analytical approach is developed and presented which includes the effects of ore arching around pipes and creep of PE materials. The results of the new approach show that PE pipes will deform under high heap loads, but can remain stable and functional. Pipe stability is shown to be dependent on the type of pipe backfill and initial backfill compaction. The new approach represents a useful tool for designing applications for PE pipe under high normal loads.

Jan 1, 2001

By R. J. Mitchell

"High narrow backfills of significant strike length approach the stress conditions associated with a free standing wall but this lower bound design approach is not considered efficient for earth structures. This paper considers the design of high narrow backfills using upper bound limit analysis, retaining wall theory with backfill arching and centrifuge model tests. Complex toe support situations pertaining to operational factors at Falconbridge's Lockerby Mine are investigated. It is shown that the susceptibility of high narrow fills to toppling is much lower than anticipated from the retaining wall analysis and that toppling can be avoided by a suitable toe support. It is also concluded that adhesion between the fill and an adjacent pillar can markedly increase the stability of the fill. INTRODUCTIONFalconbridge's Lockerby Mine pillar projects will expose cemented tailings backfills to heights (H) up to 55 m. The exposed backfills may have strike lengths (L) greater than the heights but are relatively narrow, having widths (w) of up to 12 m. The bulk cement content of the fills varies from 8.3% (12.1 T:C) to 3.0% (33.1 T:C). Exposed faces may have up to a metre of overhang due to stope overblasting, as shown in Figure 1. These fills have a solids specific gravity of close to 3.0 and were placed at a pulp density of about 68%. The tailings have a fairly uniform grain size with 32% less than 0.075 mm (200 sieve) and about 12% slimes (less than 0.02 mm sizes). The fill exposed by early pillar removal will be backed by adjacent, near vertical, ore pillars. Future pillar removal may expose similar fills which are not supported by an adjacent ore pillar but which will be backed by either an open void or by uncemented backfill. Furthermore, these fills may be undercut when the pillar slot is driven, further reducing stability (case 3, Fig. I) or a wedge could be left to help support the fill (case 2, Fig . 1). This paper presents limit equilibrium analyses for these various backfill conditions in a 22: 1 T:C fill and com- pares the results to data from centrifuge model studies at a scale factor of A= 157 as indicated in Figure I. Prototype fills have a 6 m deep cone plug of 16:1 T:C which is accounted for in the comparison of centrifuge model test with analytical results."

Jan 1, 1989

Hydraulic backfill is generally retained in stopes using permeable barricades. Mitchell et al (1975), Mitchell (1992) and Grice (1989) have shown that under normal drainage conditions, barricades experience low levels of loading. Cowling et al (1988) have also shown that barricades are susceptible to piping failures if excess water has ponded on the upper backfill surface and if leakage of backfill from the barricades has occurred. During 1997, six hydraulic backfill barricades failed in four different Australian mines. Fortunately, in each case, the quantity of backfill slurry released was small, and no injuries to personnel nor damage occurred. Detailed investigation of two of the incidents showed that the primary cause of failure could be attributed to the delivery of excess quantities of transport water from the low-density slurry. For each of the incidents investigated there was evidence of the development of piping failures, which resulted in hydrostatic loading conditions on the barricades from the ponded water on the upper backfill surface. The circular failure surfaces in the barricades were characteristic of the application of point loading conditions. This paper discusses the circumstances that led to these incidents and analyses the modes of failure. The standards for the safe operating of hydraulic backfill systems are reviewed along with requirements for ongoing management and control. The design requirements of barricade construction are analysed and some appropriate guidelines introduced.

Jan 1, 1998

Hydraulic backfill is generally retained in slopes using permeable barricades. Mitchell et a! (1975), Mitchell (1992) and Grice (1989) have shown that under normal drainage conditions, barricades experience low levels of loading. Cowling et a! (1988) have also shown that barricades are susceptible to piping failures if excess water has ponded on the upper backfill surface and if leakage of backfill from the barricades has occurred. During 1997, six hydraulic backfill barricades failed in four different Australian mines. Fortunately, in each case, the quantity of backfill slurry released was small, and no injuries to personnel nor damage occurred. Detailed investigation of two of the incidents showed that the primary cause of failure could be attributed to the delivery of excess quantities of transport water from the low-density slurry. For each of the incidents investigated there was evidence of the development of piping failures, which resulted in hydrostatic loading conditions on the barricades from the ponded water on the upper backfill surface. The circular failure surfaces in the barricades were characteristic of the application of point loading Conditions.

Jan 1, 1998

Retreat longwall method with re-use of gateroad has been traditionally employed in Japan, mainly because of the advantage of higher recovery. But the Miike Colliery has newly introduced the interpanel-pillar system to maximize the production efficiency. The Department of Mining, Kyushu University, in cooperation with the Miike Colliery and the Coal Mining Research Center (CMRC), has conducted research into the optimum design of interpanel-pillar, because this system may be adopted in other coal mines as well. Field measurements of the deformation of the gateroads and of stress distribution in the pillar show that the designed layout of the panel and pillar and the supporting system are proper from the viewpoints of gateroad maintenance and spontaneous combustion in the pillar.

Jan 1, 1990

The accuracy with which block estimates are perceived is obtained by calculation of the kriging variance. This is dependent upon the model chosen for the semi-variogram of the deposit. For an extensive series of spherical semi-variograms the changes in the kriging variance resulting from various degrees of misassignment of the relative nugget effect are investigated. The results are reported as contour maps of percentage change in kriging variance as a function of the range and relative nugget effect of the true model.

Jan 1, 1985

By C. H. Page, Brenne

Theoretical modelling of a proposed sub-level open stoping mining system was carried out to assess pillar instability and potential for hanging wall caving. This modelling was done, at first, without detailed information concerning the rock mass structure and classification. After mining commenced, the deviance in behaviour from that predicted by the modelling indicated that the structure was having an appreciable modifying effect on behaviour. Further analysis was carried out with detailed engineering geological information and a recently developed pillar design method. The outlined procedure produced results for pillar size and strength that explained the behaviour that had been recorded.

Jan 1, 1983

By Y. -J. Park, K. -H. You, Y. -T. Choi, Lee. H. -W.

Many large caverns are being constructed in great depths in Korea mainly for the storage of oil and LPG. These caverns are mostly located near the port where rock conditions are reasonably good. In some instances, the horizontal stress is very high and endangers the stability of the cavern. The purpose of this study is to assess the stability of large caverns excavated in a rock mass with high horizontal stress where Ko value is close to 3. Result shows that stress exerted in the shotcrete at crown exceeds allowable value when the 3rd bench is excavated. Also found is the tensile failure of shotcrete near the boundaries between benches. In Korea werden viele grosse Kaverne fuer Aufbewahrung vom Oel und Fluessiggas in grosser Tiefe gebaut. Am Meisten befinden sich diese Kaverne in der Naehe von Haefen, wo der Fels gute Verhaeltnisse zum Bauen einer Kaverne besitzt. In einigen Faellen ist die Horizontalspannung sehr gross und dadurch wird die Stabilitaet vom Kaverne gefaerdet. Der Zweck dieser Arbeit ist die Stabilitaet des im Fels gebauten grossen Kavernes mit hoher Horiaontalspannung zu schuetzen, wo Ko-Wert sich auf 3 naehrt. Die Ergebnisse zeigen, dass die Spannung im Spritzbeton an der Krone den zulaessigen Wert ueberschreitet, wenn das dritte Bank ausgegraben wird. Im Bereich des Spritzbetons zwischen Baenke wurde das Zugversagen festgestellt. Des larges cavités nombreuses sont en train d’être construites en grand profondeur en Corée prin-cipalement pour le stocage du pétrole et LPG. Ces cavités sont pour la plupart situées près de la porte oú les conditions des roches sont résonablement bons. En quelques cas, la contrainte hori-zontale est trés haute et met en danger la stabilité de la cavité. L’objet de cet étude est d’estimer la stabilité des large cavités excavées dans une masse de roche ayant une haute contrainte horizontale oú la valeur de Ko est proche à 3. Le résultat montre que la contrainte exercée dans le shotcrete à la couronne dépasse la valeur admissible quand le troisième banc est excavé. En plus une faillite en tension du shotcrete près de la frontière entre des bancs est trouvée.

Jan 1, 2003

By J. Leja, N. Sheikh

The stability of lead ethyl xanthate precipitate in aqueous environment of different pH (4.5 to 10.5) and at temperatures 25°C-60°C was investigated. Dissolution leads to a wide variation of pH, xanthate, and lead ions concentration in solution and to a deposition of solid products of reactions. X-ray diffraction patterns of these solids enabled identification of Pb(OH)3, PbCO3, and PbS as constituents of the remaining undecomposed Pb(EtX)1, together with some unidentified compounds (which give rise to intensive peaks with d values of 2.82A and 1.71A, and numerous peaks of lesser intensity).

Jan 1, 1974

By N. Sheikh

In galena flotation, lead ethyl xanthate, Pb(EtX)2, is precipitated and is physically adsorbed in the form of multilayers on the chemically adsorbed first layer of Pb(EtX). 1,2) The solid particles are coated with layers of Pb(EtX)2 in heterogeneous manner over surface areas possessing both anodic and cathodic character (3,4) It is anticipated that the mode of formation of Pb(EtX)2 and the number of ions present, together with stable or unstable by-product species, have great influence on the surface characteristics of galena. The information obtained from a study of these parameters may have important practical applications in flotation. Lead ethyl xanthate is sparingly soluble in water. The metal and xanthate ions released to the aqueous solution during its dissolution undergo various types of reactions depending upon the pH values of the system. Extensive work (5,6) has been carried out to elucidate the mechanism involved in acid decomposition of xanthate ions. Different decomposition paths (7,8) have been proposed for the hydrolytic decomposition of xanthate in neutral and alkaline solutions, The concentrations of lead ions vary due to a number of chemical reactions, regulated by the pH and the temperature of the bulk phase. The hydrophobic character of Pb(EtX)2 may change with the nature of chemical reactions. Some of the numerous by-product species in solution may adsorb on the solid and change the properties of surface film either favourably or adversely. The flotation performance of galena, therefore, may depend to a considerable extent on the physical and chemical stabil¬ity of Pb(EtX)2 layers. Since little work has been reported in literature dealing with the stability of Pb(EtX)2 and its correlation with the flotation of galena, attempts have been made In this study to evaluate the behaviour of freshly formed Pb(EtX)2 in aqueous systems at various pH values.

Jan 1, 1971

The aim of the study was to determine the ranges of stability and instability of the metal hydroxides and metal cyanide species that may be formed during the gold extraction process, Merrill-Crowe gold precipitation, and Inco S02/Air or ferrous ion cyanide removal processes.Following cyanide detoxification by the Inco S02/Air process, the main components of concern in the tailings will be:

Jan 1, 1997

By R. W. Smith, Z. Sadowski

The stabilities of finely divided mineral suspensions were determined as functions of pH and concentrations of polyethylene oxide, sodium ligninsulfonate, sodium dodecybulfate, and sodium oleate. In addition, the electrokinetic potentials of the minerals were determined under identical pH and additive concentration conditions. Flocculation or dispersion of the suspensions is discussed in terms of both the amount and manner of adsorption at the appropriate solid-liquid interface as it is influenced by additive concentration and pH.

Jan 1, 1986

By A. Adu-Acheampong

A geotechnical study was conducted to identify the cause(s) of stope instability at the Ashanti Mine (Obuasi, Ghana). As part of the investigation, laboratory testing of rock was performed and the rock mass was classified according to the Q-System (Barton et al., 1974).Numerical analyses were performed using the computer program FLAC (Itasca, 2001). The observed failure zone around the stopes was simulated using both Mohr-Coulomb and Hoek-Brown (Sheorey,1997) models. Yielding along peripheral graphite bands and tensile failure were clearly identified to be the major contributors to stope instability.

Jan 1, 2003