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By H. N. Lawrie

This study was undertaken on account of the lack of definite knowledge concerning the influence of bismuth on wire-bar copper, and the small elimination of bismuth from copper-matte during the smelting-operations. The early workers who studied the influence of bismuth on copper confined their investigations to malleability and ductility—two physical properties which are related to the others so intimately that their determination is of primary importance. Karsten and Levo1,² using bending- and mealleability-tests, seem to have been the first to take up the subject, and while their results are incomplete, they agree in the main with the later work of Hampe.3 The bending-tests used by the first investigators consisted in bending the specimen until it failed. The malleability-tests were made by beating the material to a knife-edge with a hammer. Hampe not only determined the percentage of bismuth which would cause red-shortness and cold-shortness of the alloy, together with other influences of bismuth on the malleability and ductility of copper, but also took up the influence of the bismuth protoxide, BiO, on copper, and of bismuth sesquioxide, Bi,O,, on the copper protoxide, CuO. Hampe's conclusioris of the influences of these two latter compounds of bismuth on copper are as follows : "If the protoxide of bismnth be alloyed with metallic copper, it is not changed to metallic bismuth, but remains mechanically distributed throughout the copper.

Jan 1, 1910

By Henry M. Howe

The natural effect of large ingot-size should be to increase segregation. I have previously pointed1 to the excessive segregation in many large ingots as tending to confirm this, but I have shown that in case of ingots less than 16 in. square this expected effect of ingot-size is liable to masked by that of Note.—The "maximum enrichment" of each ingot, i.e., the excess of the richest spot over the average of the whole ingot, is first calculated in percentage of that average. The average of the maximum enrichment of the several ingots of a given group is the abscissa in Fig. 1. The number beside each spot tells the number of cases which that spot represents. FIG. 1.—Influence of Ingot-Size on Maximum EnrichNent in Steel Ingots. other variables. Under these conditions we should expect that, if large ingot-size really does tend to increase segregation, this effect would be shown by taking the average of large numbers of cases, so that the effects of these other variables might off-set and cancel each other.

Jan 1, 1910

By N. M. Langdon

In considering the magnificent success of Mr. Gayley's bold experiment of applying dry blast to the blast-furnace, whereby a saving of 20 per cent. of fuel per ton of iron is effected, the question arises whether still further economy in fuel is possible, and, if so, how it is to be attained. The manner in which the heat generated in the furnace is utilized in the production of pig-iron may be determined, by the method of Bell and Gruner, for any furnace for which the necessary data are obtainable ; and the study of the operation, under various conditions, of a number of furnaces, for which such information has been worked out, should enable us to form some conclusion on the subject. The tables and calculations here given cover the operations of several furnaces reported in our Transactions ; also the two furnaces using natural and dry blast ill Mr. Gayley's experiment, for which the heat-equation has been worked out by Prof. Joseph W. Richards in his admirable discussion ' of Mr. Gayley's paper, The Application of Dry Air Blast to the Manufacture of Iron, and, finally, various hypothetical furnaces. The full list is as follows : A. Isabella furnace, with natural blast. B. Isabella furnace, with dry blast. The data stated for A and B in Table 111. are those given by Professor Richards, except that the heat-units are given for one unit of iron instead of 100 units, and some items of heat supplied, as stated by Richards, have been subdivided, the total being the same as given by Richards. (Columns A and B are introduced in Table 111. for comparison with C and D.)

Jan 1, 1910

By Milnor Roberts

The Nicola Valley coal-field is small, but it seems likely to become important because of its commanding position in a rich region that is developing rapidly. Bituminous coking-coal in workable quantity has not been found at any other point between the Crow's Nest Pass region, about 400 miles to the east, and Vancouver island, 250 miles westward. The Canadian Pacific railway reached the Nicola valley two years ago ; two other lines, the Canadian Northern and the Great Northern, are building towards the valley. The vast region between the Rocky mountains and the Pacific coast, extending northward for several hundred miles from the international boundary, which has been the scene of extensive mining- and smelting-operations for many years, is filling up with settlers, who are attracted by the wealth of minerals and timber, the rich soil of the valleys, and the fine climate. The Nicola river, flowing westward through the valley of that name in the Yale district, discharges into the Thompson river, which is the eastern branch of the Fraser. The transcontinental line of the Canadian Pacific railway crosses the mouth of the Nicola river at Spence's bridge, 178 miles from Vancouver. From Spence's bridge the Nicola branch line ascends the valley for 40 miles to Merritt, the coal-center, and continues 7 miles farther to the town of Nicola. Thus the haul from the mines at an elevatioiz of 2,000 ft. to salt water is 218 miles down river-grades. The Nicola branch will be continued about 150 miles farther eastward to Penticton, where it will connect with an extension of the line through the rich Kootenay and Boundary districts. The Canadian government has granted a subsidy of $6,000 per mile, to which the provincial government is planning to add $5,000 per mile, to assist in the construction of the Nicola extension. Upon the

Jan 1, 1910

By J. McD. Porter

In many of the old placer-mining districts are still to be found large tracts of gold-bearing gravel not suitable to be worked with a dredge, because the bed is too shallow or the gulch too narrow. Frequently there is not enough grade to handle the gravel successfully by ground-sluicing or a bedrock flume, or it contains too many boulders to be worked succeeefully with the ordinary hydraulic pipe or tube elevator. In southwestern Oregon, two practical placer-miners named Ruble, after working for years trying to make money out of placer-ground coutaining many large boulders, invented and patented a hydraulic elevator of an entirely new type, and one that has been found to work very successfully in flat ground and in gravel containing many large boulders. It is a very simple contrivance. A few years ago I acquired the property near Pierce City, Idaho, known as the American placer-mine. Various attempts had been made to work this ground. A bed-rock flume had been installed by one company, an Evans elevator by another, and still other methods were tried on a smaller scale. All were

Jan 1, 1910

By George J. Young

Jan 1, 1911

By W. P. Rumancik, C. P. Lazzara, A. C. Smith

The United States Bureau of Mines (USBM) developed SPONCOM to aid in the assessment of the spontaneous combustion risk of an underground mining operation. A prior knowledge of the spontaneous combustion risk of the coal and factors that increase that risk can be useful in the planning and development of proactive monitoring, ventilation, and prevention plans for the mining operation. Interactive data input screens prompt the user for information about the coal's chemical and physical properties, the geologic and mining conditions encountered in the mining of the coal, and the mining practices employed. During the input process, 'expand' screens provide the user with specific information on each input parameter. This information includes a description of the parameter and its effect on the overall spontaneous combustion risk. The program logic determines the coal's relative spontaneous combustion potential, based on the coal's proximate and ultimate analyses, and heating value. The program then evaluates the impact of the coal properties, geologic and mining conditions, and mining practices on the spontaneous combustion risk of the mining operation. The program output provides details on each factor that increases the risk of spontaneous combustion.

By C. G. Maier

Relatively infrequent use by metallurgists of the term "sponge chromium" as contrasted to more than occasional reference to "sponge iron" may be ascribed to the fact that the former material is not a commercial product, while the latter has been known and used, at least in one form (Swedish sponge iron), for several decades. It is doubtful whether a true sponge chromium ever has been prepared heretofore in the laboratory by more than one or two investigators. Nature presents a much. more difficult problem to the investigator endeavoring to make sponge chromium than pertains to the production of more easily reducible elements such as iron or nickel. Recent widespread interest among metallurgists in the possibilities of powder metallurgy is ample incentive to explore the feasibility of producing pure chromium metal in finely divided form. The shift in terminology of this statement from "sponge" to the "finely divided form" is deliberate in emphasis of distinction between terms that occasionally have been used loosely. It would seem desirable that a uniform usage descriptive of finely divided metals be adopted. While to some it might seem preferable that the terra "powdered" metal be reserved for a finely divided form produced by mechanical means, as, for example, chromium produced by the mechanical comminution of electrolytic sheets or flakes, current usage of the term "powder metallurgy' involves no distinction as to source type of material. It is usually accepted, however, that a sponge metal is one reduced from oxide or other combined form at temperatures below the melting point of metal or oxide so that the particles of metal are pseudomorphic, at least macroscopically, with the source material, and, in consequence of the loss of material without change of external shape of the particles necessarily have an open, porous, or "spongy" structure.

Jan 1, 1942

By Clyde E. Williams

MODERN steelmaking has gradually evolved from an inefficient small-scale operation, utilizing tiny units, to a highly efficient one utilizing large units almost completely mechanized. The leading position of the United States in the steel industry is due to the possession of easily assembled high-grade raw materials and large-scale highly developed plants. Modern integrated steel operation is largely one of material handling. Mining and transportation of iron ore, coal, and fluxes, coking the coal in by-product ovens, smelting the ore with coke and limestone in blast furnaces, converting the resulting pig iron into steel in the Bessemer, or in the open hearth when supplemented with scrap, and fabricating the resulting steel ingots in the shapes of commerce all are done on a huge scale, mostly by machinery, most of the labor being employed either in operating the machine or keeping it in repair. At the same time the quality and uniformity of the product have been greatly increased by the development of scientific knowledge and operating skills. Thus, the steel industry in this country is highly developed both mechanically and technically.

Jan 1, 1942

By Edward P. Barrett

SPONGE IRON has been defined as the metallic product formed by the reduction (removal of combined oxygen) of iron ore or other iron oxides at temperatures below the fusion point of iron. This product probably derived the name "sponge iron" from its porous nature. When the reduction proceeds at slightly higher temperatures and the particles of metal weld together or finally even melt to yield pellets or balls that lack the porosity and low-density characteristic of sponge iron, the product might more correctly be called "direct iron."

Jan 1, 1954

By Edward P. Barrett

DURING the past few years numerous references have been made in the technical press and Bureau of Mines Bulletin 270 to sponge iron' and so-called "direct metal" processes. The idea has been prevalent that sponge iron and "direct metals" are cheap commodities. In many instances it has been proposed that these processes be used to treat low-grade ores, utilizing low-grade coals as reducing agents. It is questionable whether or not high-grade sponge iron can be made from low-grade materials. Particles contain¬ing iron oxide and gangue become, upon almost complete deoxidation, particles containing metallic' iron and gangue. The possibility of mechanically separating the metallic iron from the gangue in these particles depends . on the physical characteristics of the particular ore under treatment. Some ores, in which the minerals constituting the gangue break free from the iron oxide upon crushing, may be concentrated magnetically after the iron oxides have been reduced to metal. The finely disseminated ores are least amenable to concentration. In general, high-grade sponge iron can only be made from high-grade raw materials. Sponge iron containing small amounts of sulfur can only be made from raw materials containing small amounts of sulfur or by

Jan 1, 1930

By Frederick F. Frick

SPONGE iron as produced at Anaconda is a fine, -35 mesh, impure product, about 50 pct metallic iron, obtained from the reduction of iron calcine at a temperature of 1850°F by use of coke resulting from slack coal. The metallic iron particles are bulky and spongey and precipitate copper readily and rapidly from a copper sulphate solution. Investigation of the treatment of Greater Butte Project, Kelley, ore at Anaconda early showed the desirability of using sponge iron as a precipitant for the copper in solution resulting from desliming of the ore in a dilute sulphuric acid solution.

Jan 1, 1953

By Chas. G. Maier

The absence of plants on the Pacific coast for the reduction of iron ores usually is attributed to the fuel situation there. Thus, the bulletin of the. State Division of Mines for 1933, entitled "California Mineral Production," says: "There are considerable deposits of iron ore known in California, notably in Shasta, Mad era, Placer, Riverside, San Bernardino, and Los Angeles Counties, but production has so far been limited for lack of an economic supply of coking coal." It has been estimated that the six major steel plants of the Pacific coast have an annual ingot capacity of 600,000 tons. The present need for tin plate averages 300,000 tons yearly for California alone, of which some 12 percent is manufactured locally. If the consump¬tion of other iron and steel products in 1929 may be taken as an approximate, estimate of the normal requirement for such products, it may be estimated further that, 65,000 to 75,000 tons each of cast-iron pipe and steel reinforcing bars and 300,000 to 400,000 tons of structural shapes and plates will be required annually in California.

Jan 1, 1936

By Z. A. Zhou

In Canadian oil sands processing, flotation is used to recover liberated bitumen droplets from oil sands slurries. Similar to conventional mineral flotation practice, a fundamental limitation of recovering bitumen from low grade oil sand ores is its slow and ineffective aeration of the liberated small bitumen droplets. Gas nucleation and cavitation could provide better mechanisms for accelerating bitumen-bubble attachment. A research program was undertaken to examine factors affecting spontaneous bubble nucleation on bitumen surfaces. The results demonstrate that surface hydrophobicity and existence of gas nuclei in process water play a critical role for bubble nucleation. While there are more bubbles nucleated on highly hydrophobic silanated glass surfaces than on moderately hydrophobic bitumen, bubble nucleation on clean hydrophilic glass surfaces is negligible. Heating process water up to 85 ~ 95oC (as used in commercial operation) or boiling tap water prior to gas nucleation tests is shown to remove sufficient amount of gas nuclei existing in the water, thereby drastically reducing the number of bubbles nucleated on bitumen. Enhancing gas nuclei formation in hot process water is identified as a promising strategy to improve bitumen-bubble attachment during oil sands conditioning, and hence to increase bitumen recovery from low grade ores.

Jan 1, 2014

By R. N. Chakravorty, K. K. Feng

"There is growing evidence that modern methods of mining coal increase the risk of spontaneous combustion. Seemingly unimportant at this time, this hazard could prove to be a barrier to growth and development of the coal industry in some areas of Canada. The paper presents bedrock knowledge on spontaneous combustion gathered by scanning and evaluating current technical and research literature. Special efforts have been made to identify significant coal and environmental factors and to establish criteria for susceptibility. In addition to the state-of-the-art knowledge, preliminary results from on-going studies are discussed."

Jan 1, 1973

By H W. Wu, D Humphreys

The structure of a comprehensive research project into mine fires study applying the Ventgraph mine fire simulation software, preplanning of escape scenarios and general interaction with rescue responses is outlined. The project has Australian Coal Association Research Program (ACARP) funding and also relies on substantial mining company site support. This practical input from mine operators is essential and allows the approach to be introduced in the most creditable way. The effort is built around the introduction of fire simulation computer software to the Australian mining industry and the consequent modelling of fire scenarios in selected different mine layouts. Application of the simulation software package to the changing mine layouts requires experience to achieve realistic outcomes. Most Australian mines of size currently use a ventilation network simulation program. Under the project a small subroutine has been written to transfer the input data from the existing mine ventilation network simulation program to æVentgraphÆ. This has been tested successfully. To understand fire simulation behaviour on the mine ventilation system, it is necessary to understood the possible effects of mine fires on various mine ventilation systems correctly first. Case studies demonstrating the possible effects of fires on some typical Australian coal mine ventilation circuits have been examined. The situation in which there is some gas make at the face and effects with fire have also been developed to emphasise how unstable and dangerous situations may arise. The primary objective of the part of the study described in this paper is to use mine fire simulation software to gain better understanding of how spontaneous combustion initiated fires can interact with the complex ventilation behaviour underground during a substantial fire. It focuses on the simulation of spontaneous combustion sourced heatings that develop into open fires. Further, it examines ventilation behaviour effects of spontaneous combustion initiated pillar fires and examines the difficulties these can be present if a ventilation reversal occurs. It also briefly examines simulation of use of the inertisation to assist in mine recovery. Mine fires are recognised across the world as a major hazard issue. New approaches allowing improvement in understanding their consequences have been developed as an aid in handling this complex area.

Jan 1, 2005

By Z. Yanni, W. Xuan, Z. Jingyu, D. Jun

"In order to conserve the coal resources, many coal mines which have been mined begin to re-mine. Re-mining face is of complicated circumstances and coal spontaneous combustion is unknown, so experiments are designed to study the characteristics of multiple oxidized coal samples. The investigation into the oxidation of coal is conducive to the safe mining of the coal seam groups and thick coal seams. The non-caking coal is collected as coal samples. The raw coal sample with initial oxidation and the sample after second oxidation and third oxidation are obtained after a certain treatment of the coal. The temperature-programmed system, and proximate and ultimate analysis are adopted to compare the releases of gaseous products of spontaneous combustion characteristic parameters of the multiple oxidized coal sample. With the increase of oxidation times, experimental results indicate that the oxygen consumption rate, the release rate of carbon monoxide and the intensity of heat release are significantly decrease. The characteristic temperature dropped and the size of the pores in coal is smaller as well. INTRODUCTION China accounts for 13% of global coal resources [1-2]. In recent years, more and more coal mines begin to re-mine in order to conserve resources. This production mode is to mine coal pillar left by last exploitation or unavailable for mining. In the process of slicing mining for coal seam groups or thick coal seams, the second or multiple oxidation due to the mining-induced effect, may take place in the goaf of the lower seam. So the spontaneous combustion is prone to occur in this area. The study on oxidation of coal is conducive to the safe mining of the coal seam groups and thick coal seams. Scholars [3-7] have discussed the workability of re-mining for coal mines, verify the feasibility of the existing mining technology for re-mining area, and set up the prevention measures of coal spontaneous combustion. But all these measures are only based on on-site observation data, instead of experiment on spontaneous combustion characteristic parameters of re-mining coal samples which have a great importance for early prediction and forecast. The authors aim at investigating the multiple-oxidated coal spontaneous combustion law, and perfecting the coal spontaneous combustion mechanism to provide a basis for the prediction and forecast."

Jan 1, 2015

By Thomas H. Koenning, James R. Boulton

The coal mined by Cyprus at the Shoshone mine near Hanna, WY is highly susceptible to spontaneous combustion. Spontaneous heatings have occurred in the gob of several of the longwall panels and, in some cases, following roof falls. Prevention and detection methods have evolved over the years as more has been learned about the occurrences. Seal design and construction have progressed to reduce air leakage into the gob. Pressure balancing has been successful as a supplement to good workmanship in reducing leakage. Early heating detection has improved as knowledge has been gained. Prior methods of detection relied upon thermocouples detecting a temperature change. Later a gas chromatograph was used to analyze gob gas samples. Initially the products of combustion (POC) were relied upon for detection. Most recently, lack of oxygen depletion in the gob has been used as an early warning of problems. Examples are presented to illustrate the evolution of spontaneous combustion control at the Cyprus Shoshone coal mine. Methods have been developed which minimize the oxygen concentration in the gob and reduce the potential for spontaneous combustion.

Jan 1, 1997

By P Marianelli, J Theiler, B Beamish, A Spillman

The presence of reactive pyrite in waste rock contributes to the hazard of spontaneous combustion in emplacement facilities as it acts as an initiator of self-heating at low ambient temperatures. Organic carbon also present in the waste rocks acts as a fuel at elevated temperatures above 120°C and can lead to thermal runaway resulting in eventual ignition. A new laboratory test method (adiabatic incubation testing) is now available that can identify the presence of reactive pyrite and quantify the self-heating behaviour of the waste rock. McArthur River Mine has a waste rock profile that contains pyritic shale units, which have created spontaneous combustion events in the past. A systematic sampling and testing program is underway to characterise the spontaneous combustion hazard likelihood of the McArthur River Mine waste rocks to provide a sound database for future mine planning of the waste removal and emplacement. This paper presents some initial outcomes of this program and shows the leading practice in spontaneous combustion hazard assessment and management that has been adopted at McArthur River.CITATION:Beamish, B, Marianelli, P, Theiler, J and Spillman, A, 2018. Spontaneous combustion hazard assessment of McArthur River Mine waste rock, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 422–426 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By Thomas H. Koenning

The number of spontaneous combustion incidents in the U.S. is expected to increase as the consumption of lower rank coals and the use of longwall mining becomes more prevalent. A spontaneous combustion incident holds the potential for substantial loss of life from a mine fire or explosion if not prevented or controlled at an early stage. Laboratory tests have been developed which are useful in ranking the susceptibility of various coals to spontaneous combustion. Ventilation circuits and mining methods can be designed to minimize the risk of spontaneous combustion. Early detection of spontaneous combustion is possible with the combined use of continuous monitoring, periodic gas sampling, and inspection.

Jan 1, 1989