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By T. Fliß

The protection of natural resources is of essential importance in times of rapidly increasing populations and resulting shortage of agricultural land. Soil and groundwater resources play a central role for the production of food or feed of any kind. The intensive agricultural and environmentally friendly use of these resources must ensure sufficient income and sustainability of life for future generations. Mining projects often represent a particularly deep intervention into ecosystems due to their size as well as the most expensive treatment processes. Conventional mines comprising of shafts and developed mining fields require the stockpiling of waste rock and in particular to potash mining, the discharge of brines from raw salt processing. In contrast, mining operations based on the solution mining method can be operated without major environmental impacts and lower security risks. While the solution mining for the production of rock salt finds application since more than 500 years, exist a procedure to produce potash using solution mining only since the 1980's. For solution mining drill holes are used to exploit the potash, launched from the surface into the deposit. The exploitation of the raw material occurs by the dissolution of the potash injecting solvents and creating so-called brine caverns. Currently, a number of mining projects in Carnallite deposits by the solution mining method are in progress around the world. Often these projects are located in sensitive ecosystems. K-UTEC project and support actual a solution mining operation of a Carnallite deposit for a Chinese customer in South-East Asia. This work comprises a comprehensive geological and geomechanical modeling as well as stability analyses. Furthermore the cavern design and brine field layout as well as the planning of the brine processing and the plant design. The present paper introduces this project as a case study. The application of a special solution mining procedure and processing design ensures an emission-free mining operation (Zero Disposal Plant). The emission-free operation is achieved by utilizing the full extent of the caverns to dispose the liquid solutions from processing. The presentation of principal salt processing and technical equipment will be rounded by information about the geology of the deposit. Since the deposit includes a number of sensitive minerals, such as Tachyhydrite and Bischofite the presentation comprise a lot of interesting items with special view at the brine field operation. K-UTEC designed and delivered a special blanket measuring system and a well cement according the request of the customer. K-UTEC, a research and engineering company with more than 60 years of experience in the sector of potash and rock salt mining, developed the world's first solution mining operation for Carnallite in Germany more than 30 years ago. In recent times K-UTEC served in different solution mining projects worldwide, with special view at the environmental impact, as well as the optimal utilization of the deposits.

Aug 1, 2013

By Stephen P. Mulqueen

Searles Lake is an evaporite basin located near the community of Trona in northwestern San Bernardino County, CA. Searles Valley Minerals Operations Inc. (SVM), a subsidiary of Nirma Limited, currently manufactures more than 1.58 Mt/a (1.75 million stpy) of industrial minerals from natural brines produced from several lakebeds within the basin. The chemical manufacturing facilities in Searles Valley represent extremely complex operations involving solution mining and mineral extraction processes.

Jan 1, 2012

By Charles H. Jacoby

The solution mining of evaporites has a history of approximately 5,000 years. The insitu leaching of metalliferous ore will have many of the same characteristic problems which have confronted industry for years in the production of evaporite minerals. Basically we will be converting the less soluble forms of valuable metals into their more soluble salts and producing these in much the same manner as, for example, sodium chloride. There are a number of problems which we are faced with that are more complex and complicated and, therefore, will require a higher degree of sophistication than previously employed. One of our most important undertakings will be the clearcut definition of the problems involved. While a great deal of expertise can be drawn from the solution mining of evaporites and the oil industry, problems peculiar to the hydrometallurgical field will need to be solved. One of these is the introduction of permeability into an impermeable rock so as to expose the sought after values of metals which by volume are infinitesimal when compared with sodium chloride, potash or other type water soluble mineralization. After establishing this permeability which will be miniscule when compared to a solution cavity, there will be the maintenance of this permeability. In general, salt deposits are of a somewhat uniform chemical composition and thus their chemistry was relatively simple. Each metalliferous ore body is somewhat unique in its chemistry and will need to be treated accordingly.

Jan 1, 1974

By H. Lorenzen, D. Buyze

"Magnesium-bearing salts occur in the Zechstein Basin in the north eastern part of the Netherlands at a depth of 1500m to 2500 m.Exploration results justified the exploitation of these salts by means of solution mining for the production of refractory grade magnesium- oxide. This paper discusses design criteria, operation parameters, and methods used for magnesium chloride solution mining by Noordelijke Zoutwinning B. V. (NOZO), an operating company of Billiton International Metals B. V.A unique variation of widely used solution mining techniques has been developed for mining the complex Veendam salt deposit. NOZO extracts salt through deviated wells with a set of parallel, suspended tubings. Cavern fluid pressure is maintained close to that of overburden rock. These special design features provide an answer for the complex characteristics of the minerals, halite, carnallite, bischofite and kieserite, from which a solution rich in magnesium is generated. Dissolution chemistry and rock mechanical behaviour of these salts are unlike those of rock salt. Throughout a few years, NOZO demonstrated adequate process control while they continue improving the operation.IntroductionBilliton, a wholly owned company of the Royal Dutch /Shell Group of Companies, is active in metal exploration, mining, processing, and trading, mainly in the non-ferrous sector.Since 1972 Billiton has been active with solution mining magnesium salts in the northeastern part of the Netherlands, in the Province of Groningen, near the city of Veendam . Solution mining techniques were developed in conjunction with the ""Koninklijke/Shell Laboratorium Amsterdam"" (KSLA) and the ""Koninklijke/Shell Exploration and Production Laboratorium"" (KSEPL), Rijswijk. The company's objective is to produce magnesia sinter (MgO) from magnesium-chloride brine (MgClz) and de-carbonated dolomite (CaO.MgO). The magnesia produced serves as base material for the manufacturing of refractory bricks, used for furnace linings in the steel industry."

Jan 1, 1986

By Charlie Yates, Max Ramey, Kurt Nielsen, Michael Hardy

The Yankee Gulch sodium minerals project (YGP) is a solution mining project operated by American Soda. The mine operates on a federal lease administered by the U.S. Bureau of Land Management (BLM). Commercial operations began in November2000. In 1964, Irv Nielsen discovered nahcolite mineralization where the YGP pilot plant is now located near the Piceance Creek in Rio Blanco County, Colorado (Nielsen, 1969).Development of the project accelerated after Williams Corp., of Tulsa, OK, joined with American Alkali in1996 to form American Soda. Pilot testing by American Soda led to commercial permitting, plant design, construction and startup. Figure 1 shows the location of the Yankee Gulch leases and the location of the upper and lower plant sites.

Jan 1, 2003

By M. Hardy, K. Nielsen, M. Ramey

American Soda, LLP has commissioned the first solution mine for recovery of naturally formed sodium bicarbonate (nahcolite) from low-grade deposits using high-pressure, high-temperature injection fluid. This project, known as the Yankee Gulch Project, was commissioned33 years after discovery of the deposit and followed an intensive four-year feasibility study that included a full-scale pilot test. The nahcoliteis co-mingled with oil shale and is impermeable. Solution mining is achieved by a combination of thermo-mechanical cracking and dissolution. Elevated temperatures are required to initiate the thermally induced cracking and to enhance solubility of the nahcolite, which is highly temperature dependent. This paper will provide an overview of the development of the project from discovery, characterization, pilot testing, permitting and commissioning, with emphasis on the solution mining aspects.

Jan 1, 2003

By Arcy A., D&apos Shock

This paper delineates the scope of the developments which have taken place in expanding the utilization of the soluble salt provinces. The location, geology, extractive technology, as well as the growth of uses are reviewed. An expanding recent growth has been in the use of solution cavities for storing hydrocarbons. The development of the technology to obtain and operate these storage cavities as well as the development of the methodology for solution mining of the soluble salts are discussed.

Jan 1, 1985

By D’Arcy A. Shock, J. G. Davis

Continental Oil Co. has spent more than four years of research on the fundamentals of recovery of potash by solution mining. This work included laboratory investigations of salt solution, brine flow, selective extraction of KC1 from sylvinite, and control of cavity geometry. Laboratory results were expanded by means of a series of field tests, and subjects such as well completion and hydraulic fracturing were added to the investigation. Both single-well and multiwell mining systems were studied in the field work. This paper discusses one field test in which potash was solution mined from a thin sylvinite ore zone in the Carlsbad Potash Basin. A two-well mining system was used for this test.

Jan 1, 1970

By J. G. Davis

Continental Oil Company has spent over four years of research on the fundamentals of potash solution mining. This work included laboratory investigations of salt solution, brine flow, selective extraction of KC1 from sylvinite, and control of cavity geometry. Laboratory results were expanded by means of a series of field tests, and subjects such as well completion and hydraulic fracturing were added to the investigation. Both single-well and multi-well mining systems were studied in the field work. The current paper discusses one field test in which potash was solution mined from a thin sylvinite ore zone in the Carlsbad Potash Basin. A two-well mining system was used for this test. The potential economic value of solution mining has been recognized for many years, and applicable United States patents date back into the past century. Principal advantages of the process over conventional mining include (1) the use of drilled holes and solution techniques in- stead of excavated shafts and caverns and (2) the ability to mine both land and marine deposits through any type of overburden geology and below conventional mining depths.

Jan 1, 1969

By Robert C. Sutter

In 1958, it became obvious to some of us in the solution mining business that there were certain problems in connection with our sodium chloride brining operations which were industry- wide. These were the types of problems which, while they were important to the safe and economical operation of our salt brining operations, were not such that their solutions would give an individual company a great competitive advantage over his competitor; and since they involve the safe and efficient mining of a natural resource, it was obvious that the answers would, in any event, be shared industry-wide. Since we were dealing with underground solution mining and, consequently, unseen and remotely controlled operations, the problems are formidable and the solutions difficult. While all of us were doing work to improve our operations, none of us could justify the expenditures necessary for basic research in these areas. Consequently, the idea was conceived of research sponsored by many companies with the same problems. In 1960, 11 companies entered into a' formal agreement to jointly support research on a specific problem of sodium chloride solution mining. The project to be undertaken was the development of a method for measuring the size and extent of underground solution cavities in sedimentary salt beds. It was agreed that all research was to be performed by independent research organizations. A part-time consultant or administrator was retained to administer the research contracts and to provide technical advice.

Jan 1, 1966

By L. D. Boughton

Solution mining projects are conducted through one or more boreholes which penetrate en ore body. Proper drilling, completion and maintenance of the boreholes, therefore, is essential to the success of any solution mining operation. Wells drilled for solution mining encounter problems quite similar to problems encountered by the petroleum industry in drilling, completing and maintaining wells for the production of oil, gas or water. Many of the services developed and much of the experience gained by the petroleum industry is applicable to solution mining wells. As in the petroleum industry, each individual wellbore and ore body in a solution mining project provides its own problems. These vary greatly from well to well, and it is not possible to set down data or outline programs that will apply to all wells. Instead, the design of the drilling, completion, production and maintenance programs should be worked out for each individual well. The purpose of this paper, then, is to generally describe materials, equipment and techniques available for these programs and to discuss the purpose and sequence of their use.

Jan 1, 1971

By J. M. Keane

The Solution Mining review arrived too late to appear in the May issue. Solution mining, in its broadest definition, includes all forms of leaching where a lixiviant solution is brought into contact with a metalliferous or non-metallic ore and the resulting pregnant solution is processed for recovery of the valuable soluble material. Technologies such as dump leaching, heap leaching, stope washing and in situ lixiviant solution injection and recovery fit into this definition of solution mining. A publication entitled the US Gold Industry (Dobra and Thomas) reflects the major impact that solution mining techniques have had on precious metal recovery. In 1989 (the last year for which statistics are available), the United States passed Australia to become the third largest gold producing country in the world after South Africa and the Soviet Union. It is estimated that when the final figures are in for 1990, the US will probably pass the Soviet Union in gold output. If the state of Nevada is ranked as a separate country, it will rank fourth in the world in gold production for 1990. A good proportion of this increase in gold production over the past few years can be attributed to the application of solution mining technology to low-grade, precious-metal-bearing material. Solution mining techniques have also made inroads in copper production. Many operations located at former underground mine sites employ in situ leaching as an adjunct to conventional dump and heap leaching practices.

Jan 1, 1991

The solution mining review did not arrive in time for publication in the May issue. The term solution mining is commonly used to refer to heap leaching, dump leaching, in situ mining and bore hole slurry mining technologies. The US Bureau of Mines is continuing with research in these areas. Commercial application of these technologies is progressing. There is an ongoing cooperative research project between the Bureau of Mines and the Santa Cruz Joint Venture to evaluate in situ copper mining at a field site near Casa Grande, AZ. The project is currently in the environmental permitting stage. The Bureau is preparing an environmental assessment for the project as part of the National Environmental Policy Act. The Bureau is also continuing with laboratory experiments to study the leaching characteristics of atacamite ore from the field test site, as

Jan 1, 1993

By Y. J. Wang

This paper deals with the application of linear programming to the solution of mine ventilation network problems which involve only the controlled splitting of air. An airway whose air quantity is to be controlled to a prescribed value is called a "fixed-quantity" airway. In a network where the fixed-quantity airways are increased in number and are distributed such that the air quantities for the remaining airways are uniquely determined by Kirchhoff's first law, the problem reduces to determining the head losses and locations for air regulators and fans. This is one of the network problems encountered most often in underground coal mines. By formulating Kirchhoff's second law as a set of linear constraints and the total air horsepower supplied by fans as a linear objective function which is to be minimized, the problem is analyzed through the technique of linear programming. Some important properties of the problem are discussed and examples are presented.

Jan 1, 1971

By V. V. Geikhman

The paper updates the Plant experience in the development and implementation of an advanced environmentally friendly zinc production technology complying with the technological and economic level of producers in the world and the standards of maximum permissible gas emissions stipulated by the Russian legislation. General water recycling engineering allowed to ensure 95.6% water rotation level. All solid wastes formed during treating zinc concentrate are processed into marketable products or semiproducts and sold. As a result of implementing innovation techniques production at the Chelyabinsk Zinc Plant is non-waste.

Jan 1, 2006

By R. C. Croft

Many chemical methods of upgrading ilmenite to enhance its titanium dioxide content involve reduction of the FeO in this mineral followed by solution of the metallic iron produced. While the use of most mineral acids for this purpose entails acid regeneration or salt disposal problems, these difficulties can be overcome with carbonic acid. Satisfactory rates of iron removal have been achieved at temperatures below 100° C and at CO, pressures up to 600 psi. Lowering of gas pressure over soluble bicarbonate solutions permits recovery of CO. and precipitation of iron oxide. The removal of the manganese, often present in ilmenites, is also feasible with these treatments.

Jan 1, 1972

By Gang Qi

The solubility of nitrogen in pure molybdenum was measured over the temperature range 2173 to 2473 K and up to one atmosphere (101 kPa) of nitrogen gas pressure. Both thermochemical and kinetic aspects of this phenomenon were considered in this study. The solution of nitrogen in molybdenum may be expressed by the reaction 1/2N2(g) = {N} (Mo,s), for which the standard Gibbs energy is given by the expression {A}G° = 78,500 + 27.36T Joules/g atom N. The formation of molybdenum nitrides, specifically Mo2N, was considered. Attention was also focused on the mechanism of nitrogen solution in molybdenum. Estimates of the diffusivity of nitrogen atoms in solid molybdenum were derived from the kinetic data.

Jan 1, 1991

By Steven Brown, Richard Stephenson, Richard Partch, Hongyu Wang

Filler technology has enjoyed a revolution in attention and achievement in the past half century. The genesis of the advancements is greater find a mental understanding of the synthetic chemistries for and physical properties of colloidal matter and instrumentation capable of characterizing particle size, shape and surface features. Several advanced chemical methods for processing powders are now employed in ceramic, electronic, imaging, medicinal and plastic technology. This presentation will highlight solution phase synthetic methods for in situ coating of fillers such as SiC, Al2O3, AlN and SiO2 and some properties of the product solids.

Jan 1, 2003

By Matti Hämäläinen

Outokumpu has developed a new chloride leaching process, HydroCopper?, for copper concentrates. The process utilizes the cupric ion as oxidant, which is able to dissolve chalcopyrite. After solution purification monovalent copper is precipitated as cuprous oxide, Cu2O, using sodium hydroxide. Copper product is produced from Cu2O by reduction, melting and casting. An essential part of the new process is chlor-alkali electrolysis, which regenerates the reagents used. All impurity metals are removed before Cu2O precipitation, because otherwise they would report to the copper product, impairing its quality. A multistage solution purification scheme has been developed consisting of firstly, chemical precipitation of impurity metals by pH increase, secondly, cementation of silver and thirdly, removal of trace multivalent ions using ion exchange. This paper describes the characteristics of solution purification in the HydroCopper? process based on the laboratory tests and pilot runs made by Outokumpu Research Oy.

Jan 1, 2003

By V. Barranco, K. Yliniemi, A. Hubin, B. P. Wilson, D. Janas, M. Lundström, P. Hannula

Typical copper electrorefining electrolyte contains tens of grams of copper, some nickel and a wide variety of impurities. Some of these impurities comprise trace amounts of dissolved precious metals like Ag, Pd and Pt that currently are not fully exploited. This study presents an electrochemical method to recover precious metals via a combined electrodeposition-redox replacement (EDRR) process, where energy is used only to deposit copper during the ED-step, while the RR-step relies on the spontaneous replacement of copper by the precious metals (i.e. cementation). In order to conduct the recovery successfully, process parameters such as deposition potential (EDE), deposition time (tDE), redox replacement time (tRR) and the number of cycles (n) was adjusted. Investigations performed in synthetic electrolyte (40 g/L Cu, Ag = 10 ppm) proved the possibility to recover a high purity silver. Short deposition times (tDE) were found to result in small Cu particles that provided a suitably high surface area for silver cementation. In addition, experiments performed in real industrial electrolytes containing 44 g/L Cu and 54 ppb Ag (Boliden Harjavalta, Pori), demonstrated that EDRR could attain Ag recoveries of between 46–67% in an energy efficient, additive-free manner. INTRODUCTION The raw materials used in the state-of-art primary and secondary copper smelters contain mainly base metals, but also notable amounts of Ag, Pt and other precious metals. These valuable metals distribute mostly into the copper matte during the pyrometallurgical treatment (Tirronen et al., 2017) and end up into the cast anodes. During the electrorefining stage, metals more noble than copper such as gold and platinum, are not dissolved but enrich into the anode slimes. In contrast, silver may dissolve slightly and thus, minor chloride addition is used to retain silver in the slime as sparingly soluble AgCl. Moreover, other metals less noble than copper may also dissolve, such as nickel. Therefore the electrolytes used in electrorefining typically contain substantial amounts of copper, nickel and even arsenic as well as minor metals such as antimony and bismuth. In the Boliden electrorefinery these were reported to be in the magnitude of 51.2– 60.4 g/L of Cu, 10.9–15.8 g/L Ni, 7.2–15.9 As, 0.2–0.4 Sb and 0.1–0.4 Bi with an associated sulfuric acid concentration of 139–155 g/L (Lehtiniemi et al., 2018). Copper is the most noble of the dominating base metals in the electrolyte and is thus deposited on the cathode as 99.99% purity LME-A grade. Anode slimes are collected and subjected to precious metals treatment e.g. via pressure leaching—selenium recovery— Doré smelting—Ag refining—Au/Pt/Pd leaching and reduction process (Ludvigsson & Larsson, 2003). The Pori refinery, operating in Finland since 1941, not only produces 133 000 t Cu cathode and 2300 t nickel sulphate annually but also 66 t silver, 4.6 t gold and palladium and platinum (in year 2017).

Jan 1, 2019