Search Documents

By Takeshi Yoshikawa, Kazuki Morita, Kunitoshi Matsunaga

"In metallurgical grade silicon (MG-Si), most impurities mainly exist at the grain boundaries and distribute in silicon grains at extremely small contents. Grain boundary phases in MG-Si transform into liquid above the eutectic temperature, and migrate towards high temperature regions when heated under a temperature gradient. With the migration of all liquid phases in MG-Si to the surface, the impurity contents will be decreased less than their solubilities in principle.In the present work, the fundamental research was conducted to discuss the possibility for purification using the liquid phase migration technique. The purification limit was estimated by thermodynamic calculations, and metallic impurities were estimated to be effectively removed except for Fe and Al. The migration behavior of the liquid phase in the synthesized silicon substrate was investigated by unidirectional heating under infrared radiation at 1523-1548 K, and the proceeding of migration was confirmed. The migration velocity was 1.4--2.0xl0-7 mis, and found to be controlled by the liquid phase diffusion.IntroductionPhotovoltaic energy is one of promising energy resources in a sustainable society because of its inexhaustibility and cleanliness. Although the production and installation of solar cells have increased significantly during the last decade, the cost of solar cell installation is still high. To enable the widespread use of photovoltaics and for the photovoltaic electricity price to reach grid parity, a low-cost and abundant feedstock of solar grade silicon (SOG-Si) is essential. Recently, a modified Siemens process and a fluidized bed reactor process were developed to address the cost and energy issues associated with the conventional Siemens process. However, their cost reduction potential is limited because of the large energy consumption needed to convert silicon into gaseous compounds. Purification of silicon through metallurgical routes offers a promising way for producing SOG-Si from metallurgical grade silicon (MG-Si), because it enhances productivity and can also lower the process costs. Although several metallurgical processes such as directional solidification [l ], vacuum refining [2-4] and plasma oxidation [5-7], have been developed, processing times and refining efficiencies still have to be optimized."

Jan 1, 2013

By David S. Butts

The high cost of energy has made many solution mining corporations turn from fuel consuming evaporators to solar energy and solar ponds. The generally held concept of a solar pond is an area enclosed by dikes into which brine is pumped, water evaporated by the sun, and the resulting salts scraped from the bottom of the pond. This paper will show that solar ponding is not simple. It is a science involving six main areas. These areas are (1) land conditions, (2) meteorology, (3) fresh water, (4) accessibility, (5) manpower and (6) mineral resources. Each area is discussed to identify important parameters that must be investigated before the viability of a solar pond complex can be established as a mineral recovery step.

Jan 1, 1985

By M I. Pownceby, M A. Rhamdhani, S Purohit, G Brooks

The use of concentrated solar flux for high temperature metallurgical applications is a wellresearched area with several reported literatures on solar calcination and metal oxide reduction. This paper presents two such processes with potential to reduce the carbon footprint from ironmaking through using concentrated solar flux. The first process involves solar flux incorporation to the recently developed lime-magnetite pellet (LMP) route of magnetite ore agglomeration. The second process is a hybrid solar-smelting route for iron ore-coal composite pellets that utilises solar flux to provide process heat. Both the concepts of solar agglomeration and solar smelting process were investigated using a solar simulator-hybrid reactor set-up at Swinburne University of Technology. Results from solar agglomeration experiments at 950°C suggested no change in the reaction mechanism of the LMPs under solar irradiation compared to electrical heating. The percentage and morphology of the primary phases (mainly CaFe3O5) appeared similar for both solar and electric heated LMPs. The solar-smelting of magnetite concentrate-lignite coal composite pellets at 1130°C showed a maximum metallisation of 55 per cent after 1.5 hrs of reaction. The solar-smelt process has about 25 to 35 per cent lower CO2 emission compared to the blast furnace ironmaking. Technoeconomic analysis of implementing a CST facility in an existing composite pellet process suggested a payback period of about ten years at a heliostat cost of $A100/m2 and natural gas cost of A$10/GJ. The economics of CST implementation can be further enhanced by decreasing the thermal losses from the heliostat field and reactor.

Nov 8, 2021

By Santhanam Sundaram

The potential for the utilization solar energy for the production of industrial process steer in mineral processing industries is discussed briefly. To advance the technical and economic feasibility of solar-thermal systems applications, U.S. Department of Energy has funded several projects. NL industries of Newberry Springs, California is one among them and has been chosen as a case study. The NL Industries solar system consists of 950 square meters of Del, single-axis, tracking, parabolic-trough, concentrating collectors. It was designee to produce a portion of the 420°. 530°k. steam utilized in a trying operation reduce the moisture content of hectorite ore from 10 percent to 4 percent. (Hectorite is an hydrous magnesium silicate which, when refined, is of significant commercial interest because of its applications in various chemical and food processes.) is estimated that implementation or this solar system could result an annual savings of 3.545 billion KJ ,3.360 billion BTUs), or the equivalent of 90 cubic meters (600 barrels) of oil and a net reduction of 1,860 kilograms (4100 pounds) of air pollutants annually. The technical, economic and institutional issues encountered in the course of this project are also discussed. Finally, the impact of the commercialization of solar energy applications in mineral processing industries is evaluated.

Jan 1, 1981

By Milind Deo, Neale R. Neelameggham

The mixture of carbon dioxide and water vapor - called Soda [as in carbonated water] can be converted to easily stored transportation fuels. Earlier papers on Soda- fuel metallurgy noted that this conversion is endothermic requiring energy. Reduced state metallic elements - preferably the alkali, alkaline earth elements, or aluminum can act as oxygen carriers. Availability of such a combination in commonly land fille waste materials is shown. Plant based wastes which are normally composted form a better-controlled reagent. The energy required for the reaction can come from solar energy. This paper describes possible reactor designs, which can accommodate this conversion effectively using carbon dioxide recovered from flue gases.

Jan 1, 2008

By Jerry Grott

Southwest Salt Company is solution mining the Luke Salt Body of probable late Miocene age. The discovery hole, from which the first core was recovered, was drilled in 1968. The deposit was encountered at a depth of 880 feet, and the bit was still in salt at the bottom-hole depth of 4,500 feet. The solar ponds, developed on land formerly dedicated to agriculture, have an annual capacity of about 90,000 tons. Because land values are very high, mining rates and procedures are governed by the need for near-saturated brine to minimize land requirements. Because of the frequency of dust storms, the salt operation uses a unique wet-harvesting method. Most inventory is kept in the ponds under brine and harvested only a few days before shipment. Studies of the nature of crystal growth and the distribution of windblown and brine impurities led to the development of procedures for processing salt of high chemical purity and low insolubles content. Chemical purity exceeds that of most salt produced in fuel-fired evaporators. Salt is shipped from Phoenix as tar east as west Texas and as far west as central California. Occasional shipments have been made to Hawaii and Alaska.

Jan 1, 1987

Solar Salt, Lunar Ambitions I Bauerti The title of this paper is `Solar Salt, Lunar Ambitions'. It is largely the result of a lack of imagination and a tight deadline. I was seeking a catchy title to convey the image of being 'here' and wanting to get `there', with `there' being a long way away and our being held 'here' by powerful gravitational forces. I tried `Solar Salt, Lunar Landings', but that implied we had already reached `there' when, on reflection, we had not. A colleague suggested 'Solar Salt, Luna Park' which is a fun park in Sydney and, I must admit, there was appeal in the image of having embarked on a wild roller coaster ride with stomach-wrenching twists and turns and the only reward being a pair of sweaty palms, and a feeling of nausea. That's sometimes how it feels when you launch into change. In the end I settled for the more sedate `Lunar Ambitions'. It contained that suggestion of hope and continual striving which are central to the idea of best practice. I will discuss our experiences in this area shortly, but I would firstly like to provide some background to our business. The salt industry is steeped in history and tradition. As one learned commentator observed, common salt is 'a substance seemingly too ordinary to think about, yet it is the oldest of man's raw materials and the basis of some of his newest inventions' (Multhauf, 1978). From ancient times, salt was recognised as a key necessity of life and it has played a role in the rise and fall of governments throughout history. The Romans recognised its importance when they gave their soldiers money regularly to purchase salt, hence our modern word 'salary'. Today, while culinary use remains important, the main consumer of salt is the chemical industry (Figure 1).

Jan 1, 1995

By Ernest N. Patty

Placer gold-bearing gravels of interior Alaska and the Yukon are, for the most part, permanently frozen, and are described as permafrost. The first step in preparing these gravels for dredging is to strip by bulldozer the surface layer of tundra, brush, and scrub timber, and to expose the ebony colored surface of the frozen mud at the grass roots. This mud varies from a frozen, muddy ooze to a sandy silt and locally may contain layers of peat. The whole mass is intercalated with ice dikes and lenses. The thickness will vary from a few feet up to 100 ft, depending upon local conditions. A freshly exposed surface will thaw to a depth of 4 in. per day during the summer season. Common practice is to expose a large surface of this mud to the sun and each day's thaw is then swept off by water and carried away in suspension.

Jan 1, 1951

By Lenny Winkel

With the aim to develop a solar-driven process for the extraction of copper from sulfide concentrates research on the decomposition of copper sulfides under inert atmospheres has been initiated. Thermogravimetric measurements on chalcocite (CuzS) revealed that copper is formed already at 1823 K. Chalcopyrite (CuFeS2) also disintegrates at this temperature, although at a lower rate. Copper and iron have been identified in the solid residue. The results confirm the feasibility of copper extraction by direct decomposition of sulfides under atmospheric pressure. The decomposition under inert atmosphere prevents generation of SO2, it also alters the behavior of volatile impurities during decomposition of copper sulfide concentrates. Chemical eqUilibrium calculations for chalcopyrite contaminated with enargite (Cu3AsS4) have shown that the absence of an oxidic slag allows for a complete evaporation of arsenic and subsequent separation from intermediate sulfides. The need to better assess the potential of direct sulfide decomposition has prompted the development of an experimental setup for studying the decomposition reactions. The experiment has been devised such that data on the decomposition kinetics and on impurity removal can be obtained at temperatures up to 2500 K.

Jan 1, 2003

By Lenny Winkel

With the aim to develop a solar-driven process for the extraction of copper from sulfide concentrates research on the decomposition of copper sulfides under inert atmospheres has been initiated. Thermogravimetric measurements on chalcocite,(Cu2S) revealed that copper is formed already at 1823 K. Chalcopyrite (CuFeS2) also disintegrates at this temperature, although at a lower rate. Copper and iron have been identified in the solid residue. The results confirm the feasibility of copper extraction by direct decomposition of sulfides under atmospheric pressure. The decomposition under inert atmosphere prevents generation of SO2, it also alters the behavior of volatile impurities during decomposition of copper sulfide concentrates. Chemical equilibrium calculations for chalcopyrite contaminated with enargite (Cu3AsS4) have shown that the absence of an oxidic slag allows for a complete evaporation of arsenic and subsequent separation from intermediate sulfides. The need to better assess the potential of direct sulfide decomposition has prompted the development of an experimental setup for studying the decomposition reactions. The experiment has been devised such that data on the decomposition kinetics and on impurity removal can be obtained at temperatures up to 2500 K.

Jan 1, 2003

By M. Neises, M. Roeb, C. Sattler, S. Stenger

"A two-step thermo-chemical cycle process has been developed and investigated. It is based on metal oxide redox pair systems, which can split carbon dioxide as well as water molecules by extracting oxygen atoms and reversibly incorporating them into their lattice. If concentrated solar radiation is used as the heat source, a promising method exists to produce synthesis gas from water and CO2. An easy way of operation is gained by the combination of a ceramic substrate as the absorber structure, which can be heated to high temperatures with concentrated solar radiation, and of a metal oxide coating which is capable to carry out the redox reactions. The performance and kinetics of a ferrite based redox material coated on ceramic substrates were investigated in a laboratory set-up. CO2 could be reduced with significant conversions. In addition, several side reactions were observed like the formation of carbon and like the Boudouard reaction.IntroductionThe search for alternative energy carriers and for processes able to reuse carbon dioxide stimulates the research for sustainable routes of alternative fuel production. In the scope of this search thermo-chemical processes combined with sources of concentrated solar energy have become more and more attractive. Ideally, the only raw materials for such processes are water (H2O) and carbon dioxide (CO2) enabling not only a process free of emissions, but also allow to reduce emissions of other processes by reusing CO2 to provide synthesis gas, which itself can be applied to produce chemical commodities or even better synthetic fuels like methanol or petrol.In contrast to the direct splitting of those raw materials, thermochemical cycles split water and CO2 in several steps and enable hydrogen (H2) and carbon monoxide (CO) generation at temperatures controllable by today’s technical equipment. One of the most interesting thermochemical cycles is a two-step process using metal oxide based redox systems. During the first step of this cycle (the regeneration step) the metal oxide is reduced setting some of its lattice oxygen free according to reaction (1). In the next step (the splitting) the reduced and activated material is oxidised by withdrawing oxygen from water and CO2 and at the same time hydrogen and CO is set free according to reactions (2a) and (2b) respectively."

Jan 1, 2011

By Greg Joachims

Composition of salt in the Permian Flowerpot Shale in northwest Oklahoma suggests that the salt in this formation was deposited in the early phase of solar evaporation. Brine produced through natural dissolution of the subsurface salt has netted very pure brines, with relatively low concentrations of magnesium salts that should result from late-stage precipitation of salt deposits from sea water. Over the last 100 years, extensive studies of sea- water evaporites, in relation to brine density, have been a topic of discussion. The development of evaporation models has facilitated the increased production and purity of solar salt (salt produced through evaporation of brine by the sun's energy). Conversely, this information can be utilized to gain an understanding of how rock-salt formations were precipitated from sea water by analyzing the elemental constituents of the rock salt and of the resulting brine. By evaluation of well-documented, phase-curve tables of sea-water evaporation, a basic theory can be formulated on how the Flowerpot salt unit was formed.

Jan 1, 1999

By Leonardo de Oliveira Turani

A energia eólica, fonte de energia renovável e de baixo impacto ambiental, vem crescendo rapidamente na última década, em especial no Brasil. A conversão da energia cinética dos ventos em energia elétrica é realizada por aerogeradores, que são acopladas em torres, que na sua maioria são constituídas de anéis sobrepostos de aço, os quais são fabricados e montados com o emprego de várias etapas de soldagem. Em função disso, o conhecimento da soldabilidade dos aços estruturais é um fator importante para indústria eólica, dando subsídios para a elaboração de procedimentos que permitam a redução dos custos de soldagem e a seleção adequada dos aços empregados. Este trabalho objetivou a avaliação da soldabilidade do aço estrutural EN 10025-4 S355M através de ensaios mecânicos e metalográficos de juntas soldadas pelo processo de arco submerso (SAW) em duas diferentes técnicas: Single Arc e Tandem Arc. Os resultados mostraram que o aço S355M apresentou excelente soldabilidade, com destaque para o processo SAW Tandem Arc, o que possibilita a maior exploração desta técnica como uma excelente alternativa para a redução do tempo de soldagem durante a fabricação de torres eólicas.

Aug 8, 2018

By Milton Sergio Fernandes de Lima

A soldagem a laser do Ti-6Al-4V necessita de cuidados especiais quanto à reatividade do cordão com o ar. A fragilidade da solda é apontada como um dos entraves para o uso da liga em algumas aplicações de engenharia. Neste estudo, foram realizadas soldas em chapas de Ti-6Al-4V em diferentes condições experimentais. Verificou-se que a dureza aumenta com o inverso do logaritmo da velocidade de soldagem. A dureza, embora heterogênea na largura do cordão, é resultado da contaminação com oxigênio da estrutura hexagonal da fase a-Ti e da formação de óxido de titânio. Um sistema otimizado de proteção gasosa, protegendo ambas as superfícies e em particular a região do plasma, foi eficaz para melhorar o comportamento mecânico das juntas. Os resultados obtidos em tração uniaxial mostraram que houve um ganho expressivo nas medidas de tensão e deformação. Portanto, o sistema é indicado e recomendado para materiais com sensibilidade à contaminação atmosférica.

Aug 16, 2017

By Matheus Soares Siman

A soldagem GTAW tem importância fundamental para a indústria não só pelo excelente controle do aporte térmico, como também ao fato de proporcionar, repetitividade e reprodutibilidade. No entanto, este apresenta uma série de desafios, principalmente em relação à determinação de algumas variáveis e como essas podem afetar a resistência das juntas soldadas. Neste trabalho, investigou-se a influência de diferentes procedimentos de soldagem em tubos de aço SAE 4130 sem costura com e sem a deposição e com a aplicação ou não de pré-aquecimento. Após procedimentos de soldagem, as propriedades mecânicas e a microestrutura da junta soldada, zona fundida, zona termicamente afetada e metal base, foram avaliadas por meio de ensaios de microdureza, de dobramento e análise metalográfica. Foi possível avaliar a influência da aplicação do pré-aquecimento e analisar as propriedades mecânicas e microestrutura das juntas soldadas. Os perfis de microdureza revelaram a importância do pré-aquecimento. O ensaio de dobramento possibilitou a avaliação das juntas de maneira qualitativa. Porém, um ensaio quantitativo, como o de tração, possibilitaria mais informações.

Oct 30, 2017

By Felipe Lacerda Giro

Atualmente, a soldagem por extrusão de peças semi-acabadas (chapas) em PEAD tem se mostrado como uma solução atraente para a fabricação de pequenas embarcações de serviço. Neste sentido, a qualidade da soldagem torna-se um elemento fundamental para a garantia da integridade estrutural da embarcação. Neste trabalho são apresentados os resultados da análise da influência de diferentes fatores na qualidade da soldagem por extrusão de chapas de polietileno de alta densidade. Os fatores analisados envolveram o aporte de calor, a preparação do chanfro, a velocidade de soldagem e a pigmentação do fio de solda. A influência de tais fatores na qualidade da solda foi avaliada tendo como referência os resultados de ensaios de flexão em corpos de prova.

Aug 17, 2017

By Milton Lissberger

MILTON L. LISSBERGER, ? New York, N. Y.-Solder is a mechanical mixture of tin and lead, a fact which is susceptible of very simple demonstration. A bar of solder of a grade even as low as 30 per cent. tin and 70 per cent. lead, passed through a buffing machine, will show a surface practically identical with that of a bar of second-quality or reclaimed tin. The buffings, on chemical analysis, will prove to be almost pure lead. According to the best practice, solder is made in the following manner. Virgin pig lead is first melted, and when it is thoroughly liquefied, virgin pig tin is added, together with a small amount of flux; the latter is for the purpose of bringing to the surface the so-called "liver," consisting of impurities that may have remained in either the lead or the tin as a result of incomplete refining. The combined material, when completely liquid, is thoroughly stirred for some hours, and is then cast into small pigs. Just before casting, and continuously during this operation, the molten metal yields dross, consisting largely of the oxides of lead and tin; this should be carefully skimmed off. After the pigs have cooled, they are taken to a smaller kettle, remelted, and cast into the desired shape for use; or if wires, ribbons, etc., are to be made, the solder is cast into slugs suitable for extrusion and rolling. During this second operation, the skimming of dross should be even more carefully done than at first. Hand mixing has proved to be the only reliable method for the production of the best quality of solder, irrespective of its percentages of lead and tin. The best quality of solder is not necessarily that which contains the highest percentage of tin, but rather is that composition which performs best on the required piece of work. In order to produce

Jan 12, 1918

By Daniel J. Rider

In 1980 the Niagara Frontier Transportation Authority contracted for three miles of cut and cover box structure and station construction in Main Street, Buffalo, New York. Project depths ranged from 30 feet to 60 feet below street grade. Soils, Figure No. 1, consisted of loose to very compact sands and gravels. Ground water level was generally 20 feet below grade. Specifications required a soldier pile and timber lagging support system with external dewatering. Soldier piles were to be installed in prebored holes with bentonite slurry and lean concrete backfill. Conventional pile driving was not allowed due to concerns over excessive noise and vibrations and its effect on nearby historic structures and the surrounding population

Jan 1, 1987

One of the engineering proposals in the last Congress which was of interest to engineers was the soldiers' land settlement plan proposed by Secretary Lane, under which returned soldiers, sailors and marines would be employed on construction work in the reclamation of swamp and arid lands and would thereafter be given preference in the selection and settlement of those lands. This bill failed in the fillibuster at the end of the session. It is likely that some sort of a plan for soldiers' settlement will come before the next Congress. A new bill has been written up for introduction at the next session which proposes an "infiltration method" of buying improved farms in established communities for' the soldiers' settlement purpose, under the authority and direction of the Farm Loan Board. The contrast of this bill to the one recommended by Secretary Lane is of vital importance to engineers at this time; first, because of the broad engineering improvement program that the latter bill proposes as against no engineering improvement under the infiltration plan; secondly, the community settlement plan of Secretary Lane means improvement of waste lands requiring much engineering work.

Jan 7, 1919

By G. E. Bandelis

In this paper, solid bed erosion processes and the mechanisms involved when a two-phase liquid-solid mixture flows over a bed of solids in a horizontal annulus are analyzed. There are few such studies available with some authors arguing that the flow rate for erosion is always less than the flow rate for the suspension of solid particles thus necessitating further study and analysis of such phenomena. Tests were run to determine the mechanism of erosion and the erosion velocities of the solid bed formed in a concentric annulus for three flu-ids, water, a low concentration water solution of Carboxyl-methyl-cellulose (CMC), which behaved as a Newtonian fluid and a higher concentration CMC water solution which behaved as a power law fluid. Glass spheres of 2 mm nominal diameter were used as solids. The flow rate at which erosion occurred together with the mechanism of bed erosion were determined visually, while the whole process was video recorded. Our tests indicated different erosion mechanisms and different erosion velocities for the three tested liquids, with the liquid viscosity playing a major role. The first mechanism, observed for water flow, gives erosion from the front of the bed while the second mechanism, observed for the flow of the two viscous fluids, gives erosion from the top of the bed. The role of each of the parameters to erosion is investigated, whether it is turbulent flow with the turbulent fluctuations being more capable to remove the solids from the formed bed or whether it is liquid viscosity, which results in the hydrodynamic shearing force. The results demonstrate that liquid viscosity plays a role in the erosion mechanism and yields different erosion velocities of the solid bed hence, it should be taken into account when modeling flow pattern transitions for solid-liquid flows. Prior studies have not identified this and it could be the reason of the disagreement between theoretical models and experimental and field data.

Jan 1, 2006