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Separation in magnetic fluids is one of the modern techniques that offer a unique approach to material manipulation in a broad spectrum of industries. Its wide-scale application has been restricted so far for a variety of reasons, including limited throughput, inefficient recovery of magnetic fluids and the cost of commercially available magnetic fluids. This situation has changed recently. Very selective separators, with automated density control, capable of treating a variety of materials in a wide spectrum of densities and particle sizes have been built by DebTech and applied in the diamond industry. Technology for the recovery of magnetic fluids has been developed and low-cost magnetic fluids, with high magnetisation and low viscosity are being produced on a production scale. Scale-up of the technology has been addressed and units capable of treating large tonnages of material have been designed. Such a development thus offers the minerals industry a technology that surpasses the existing technologies in selectivity, efficiency and versatility

Jan 1, 2000

By Tsuyoshi Hirajima, Hideyuki Okamoto, Himawan .. T. B. M. Petrus, Keiko Sasaki

"Flotation of arseno bearing minerals from their copper ore has been an interest due to the increasing awareness on protecting the environment by minimizing the possibility of exposed arsenic compound. Some approaches have been proposed, but the mechanisms of separations have not yet fully understood. In this study, oxidation using oxygen was applied. Instead of the complex copper ore flotation results, pure single mineral of tennantite and chalcopyrite foatability was conducted using Hallimond tube. Resembled with the flotation results of copper concentrate containing tennantite, the separation possessed the best result at alkaline condition (pH 11) at where the arsenic content was reduced from 3300 ppm to 1800 ppm. In order to be able to understand the mechanism of the separation atomic force microscope (AFM) was utilized. AFM images showed changes in morphology and behavior when minerals were treated in both acid and alkaline condition. It was found that the morphological change showed the reaction products representing the rate of reactivity of tennantite and chalcopyrite. From the measured force of adhesion, it can be observed that in alkaline condition the surface of both minerals is more hydrophilic than that in acidic condition possessing higher value. This is in accordance with the X-ray photoelectron spectroscopy (XPS) spectra in which hydroxide moieties occupied the mineral surface in alkaline condition while elemental sulfur is in acidic condition."

Jan 1, 2014

By G. N. Shannon

Keywords: inclusions, slag, modeling, interfacial energy, capillary force, particle flotation, particle separation A previously introduced model of inclusions separating across a steel-slag interface, developed by Nakajima/Okamura and Bouris/Bergeles, is expanded to include different inclusions shapes (octahedral and plate-like, besides spherical) as well as comparison between model ladle-, tundish-, and mold-slags. Investigation of the relation of these shapes with the interfacial capillary force ? which arises due to the dynamic interfacial energy during separation ? has shown that the force has a significant effect on whether the inclusion separates rapidly or settles at the interface. For the slags considered, the most significant physical property is found to be viscosity, which resulted in fast separation times for inclusions in the mold and ladle slags, relative to the more viscous tundish slag. Particle dissolution (using experimental data) is included in separation modeling.

Jan 1, 2005

By S. Mathur

Future Florida phosphate reserves contain higher MgO than presently mined deposits. The high MgO content is contributed by dolomite and Mg-rich clay, palygorskite. Selective flocculation was attempted to reduce the MgO content of apatite in synthetic mixtures of apatite with dolomite and palygorskie. Mixed mineral selectivity was predicted in the apatite-dolomite and apatite- palygorskite systems with Poly(ethy1ene oxide) (PEO) flocculant. Loss of selectivity in the mixed mineral systems was primarily attributed to heteroflocculation, which was minimized by addition of a Site Blocking Agent (SBA), a lower molecular weight fraction of PEO, prior to addition of the flocculant. A 80:20 mixture of apatite-dolomite (or palygorskite) was upgraded as 95% apatite at more than 80% recovery level in the product fraction.

Jan 1, 1995

By A. Iizuka

This study was aimed at separating and recovering arsenic, antimony, and tin from refining byproducts generated in a nonferrous smelter. The target byproduct was a silicate slag containing the above elements. The silicate structure of the slag was destroyed by alkali roasting, which then enabled leaching of arsenic, antimony and tin in solution effectively. Arsenic was selectively leached out by hot water after alkali roasting of the slag, while remained antimony and tin in the residue were leached out by a hot hydrochloric acid solution. However, when the solid-liquid ratio in the leaching solution was increased, hydrous gelatinous silica (gel-like silica) was formed during the hydrochloric acid treatment and filtration became difficult. Therefore, high temperature and high pressure leaching was attempted to improve the filterability of the silica leaching residue. In the high temperature and high pressure treatment, the hydrous gel-like silica was transformed into easily filterable aggregated silica, and thus, filtration became easy. By investigating the neutralization and sulfurization treatment for the obtained hydrochloric acid leachate (second leachate), it was possible to separate antimony and tin. INTRODUCTION This study aims to separate arsenic and recover valuable metals such as antimony and tin from refining byproducts generated in a nonferrous smelter. The target smelting byproduct is antimony-containing slag in this study. In many cases, alkali roasting was adopted as pretreatment for extraction and recovering valuable metals from smelting residues and wastes (Rao, 2006). For antimony-containing slag in this study, one effective method for separating arsenic is to convert arsenic to sodium arsenate (Na3AsO4) by roasting with a sodium compound and then to remove arsenic by hot water leaching. In addition, by alkali roasting, the silicate structure of the slag is destroyed, and effectively alkalizing tin and antimony is accomplished. Then, precipitating and recovering tin and antimony leached into the acid solution are considered possible by sulfurization and neutralization treatments. In this research, we conducted basic studies on the following. 1) Destruction of silicate structure in slag by alkali roasting and leachability of arsenic. 2) Conversion of hydrous gelatinous silica to aggregated silica by hydrochloric acid treatment of residues after arsenic leaching under high temperature and high pressure, as well as leachability of antimony and tin. 3) Separation and recovery of antimony and tin by sulfurization and neutralization treatments of hydrochloric acid leachate. These topics of investigation can support to consider the separation and recovery process of arsenic, antimony, and tin from antimony containing slag.

Jan 1, 2019

By Javad Koleini S M

The sources of arsenic compounds vary from As(lll) oxide produced from roasters to wastes containing arsenic from chemical or mineral processing plants. The removal of arsenic via co-precipitation with iron is currently proposed as an acce

Jan 1, 1994

By A. S. Block-Bolten

Two innovations in nickel-arsenic separation have been studied on a laboratory scale. The first requires only a nitric acid atmospheric leach without preliminary roasting and leads to favorable final conditions for precipitation of arsenic as highly stable FeAsO4, The second is an NaOH-H2O2 pressure leach which is an alternative to the known NaOH-O2 pressure leach. Either method offers the possibility of rapid and efficient separation of nickel from arsenic and is applicable, for example to the high grade niccolite deposits in the Great Slave Lake area of northern Canada.

Jan 1, 1982

By J. D. Miller, J. E. Sepulveda

Tar sand deposits in the state of Utah contain more than 25 billion bbl of in-place bitumen. Although 30 times smaller than the well-known Athabasca tar sands, Utah tar sands do represent a significant domestic energy resource comparable to the national crude oil reserves (31.3 billion bbl). Based upon a detailed analysis of the physical and chemical properties of both the bitumen and the sand, a hot-water separation process for Utah tar sands is currently being developed in our laboratories at the University of Utah. This process involves intense agitation of the tar sand in a hot caustic solution and subsequent separation of the bitumen by a modified froth flotation technique. Experimental results with an Asphalt Ridge, Utah, tar sand sample indicated that percent solids and caustic concentration were the two most important variables controlling the performance of the digestion stage. These variables were identified by means of an experimental factorial design, in which coefficients of separation greater than 0.90 were realized. Although preliminary in nature, the experimental evidence' gathered in this investigation seems to indicate that a hot-water separation process for Utah tar sands would allow for the efficient utilization of this important energy resource. The projected increase in the ever-widening gap between the domestic energy demand and the domestic energy supply for the next few years has motivated renewed interest in energy sources other than petroleum, such as tar sands, oil shale and coal. Although a number of research programs on the exploitation of national coal and oil shale resources have already been completed, very few programs have been initiated on the processing of tar sand resources in the United States. In recognition of their significance as a domestic energy resource, investigators at the University of Utah have designed an extensive research program on Utah tar sands. An important phase of this program, and the main subject of this publication, is the development of a hot-water process for the recovery of bitumen from Utah tar sands, as a preliminary step toward the production of synthetic fuels and petrochemicals. The term "tar sand" refers to a consolidated mixture of bitumen (tar) and sand. The sand in tar sand is mostly a-quartz as determined from X-ray diffraction patterns. Alternate names for "tar sands" are "oil sands" and "bituminous sands." The latter is technically correct and in that sense provides an adequate description. Tar sand deposits occur throughout the world, often in the same geographical areas as petroleum deposits. Significantly large tar sand deposits have been identified and mapped in Canada, Venezuela and, the United States. By far, the largest deposit is the Athabasca tar sands in the Province of Alberta, Canada. According to the Alberta Energy Resources Conservation Board (AERCB),2,3 proved reserves of crude in-place bitumen in the Athabasca region amount to almost 900 billion bbl. To date, this is the only tar sand deposit in the world being mined and processed for the recovery of petroleum products. Great Canadian Oil Sands, Ltd. (GCOS) produces 20 million bbl of synthetic crude oil per year. Another plant being constructed by Syncrude Canada, Ltd. is expected to produce in excess of 40 million bbl of synthetic crude oil per year. According to the Utah Geological and Mineral Survey (UGMS), tar sand deposits in the state of Utah contain more than 25 billion bbl of bitumen in place, which represent almost 95% of the total mapped resources in the United States.4 The extent of Utah tar sand reserves seems small compared to the enormous potential of Canadian tar sands. Nevertheless, Utah tar sand reserves do represent a significant energy resource comparable to the United States crude oil proved reserves of 31.3 billion bbl in 1976.5 Tar sands in Utah occur in 51 deposits along the eastern side of the state.4 However, only six out of these 51 deposits are worthy of any practical consideration (Fig. 1). As indicated in Table 1, Tar Sand Triangle is the largest deposit in the state and contains about half of the total mapped resources. Information regarding the grade or bitumen content of Utah deposits is still very limited. The bitumen content varies significantly from deposit to deposit, as well as within a given deposit. In any event, the information available6-8 seems to indicate that Utah deposits are not as rich in bitumen as the vast Canadian deposits which average 12 to 13% by weight.9 Although many occurrences of bitumen saturation up to 17% by weight have been detected in the northeastern part of the state (Asphalt Ridge and P. R. Spring), the average for reserves in Utah may well be less than 10% by weight. Separation Technology As in any other mining problem, there are two basic approaches to the recovery of bitumen from tar sands. In one

Jan 1, 1979

By J. F. Sepulveda, J. D. Miller

Tar sand deposits in the state of Utah contain more than 25 billion bbl of in-place bitumen. Although 30 times smaller than the well-known Athabasca tar sands, Utah tar sands do represent a significant domestic energy resource comparable to the national crude oil reserves (31.3 billion bbl). Based upon a detailed analysis of the physical and chemical properties of both the bitumen and the sand, a hot-water separation process for Utah tar sands is currently being developed in our laboratories at the University of Utah. This process involves intense agitation of the tar sand in a hot caustic solution and subsequent separation of the bitumen by a modified froth flotation technique. Experimental results with an Asphalt Ridge, Utah, tar sand sample indicated that percent solids and caustic concentration were the two most important variables controlling the performance of the digestion stage. These variables were identified by means of an experimental factorial design, in which coefficients of separation greater than 0.90 were realized. Although preliminary in nature, the experimental evidence gathered in this investigation seems to indicate that a hot-water separation process for Utah tar sands would allow for the efficient utilization of this important energy resource.

Jan 9, 1978

By Kenneth N. Han, Yuhong Chen

The removal of carbonaceous material from Carlin gold ore has been investigated via froth flotation. The effect of type and concentration of various oils as flotation collectors and of sodium silicate as the dispersion agent on the overall recovery of carbonaceous material has been studied. Other variables affecting froth flotation efficiency were also examined closely. These included particle size, pH of the solution, and temperature. The effect of reduction and oxidation of carbonaceous material on froth flotation efficiency has also been investigated. This investigation showed that aromatic type oil was the most effective collector. Also found in this investigation was that oxidized carbonaceous material was difficult to float unless the oxidized portion was subject to reduction before flotation. More than fifty percent of the carbonaceous material was able to be removed via froth flotation. It can be concluded from this study that the effect of pH and temperature during the rougher flotation state is of little significance to the overall recovery of carbonaceous material. Since pyrite is responsible for the high consumption of chlorine, removal of pyrite is very important in order to reduce the overall consumption of chlorine.

Jan 1, 1990

Sanes are utilized to make molds for metal castings in the foundry industry. Approximately a half ton of sand is disposed of for each ton of metal cast in this country. The purpose of this investigation was to study and develop a process to separate chromite sand and silica sand from reclaimed sands for a steel foundry. Physical separations were utilized to yield silica and chromite sands with desirable molding properties. Several different separation methods, including electrostatic, magnetic, and various gravitational approaches were examined. Experimental results are presented. A method was developed to separate chromite sand from silica sand after mechanical or thermal reclamation. The reclaimed sands are passed through a rare earth magnetic separator to separate chromite sand and magnetic impurities from non-magnetic silica sand. Chromite sand can be recovered from magnetic silica sand or magnetic impurities very effectively using a wet concentrating table. The applicabilities of the separation methods are discussed.

Jan 1, 1995

By Zizheng Zhou

The separation of cobalt from other base metals can be achieved using diffusion dialysis in a two-compartment reactor separated by an anion exchange membrane. In this work, a Neosepta AFX membrane was used to study the separation of various metals in an acid-chloride solution. The separation of one metal from another was investigated on the basis of the various chloro-complex stabilities. The metals investigated included cobalt, nickel, copper(II), iron(III), aluminum, zinc and cadmium. The impact of several critical experimental conditions, including the initial metal and chloride concentration in the feed solution and their initial concentration in the receiving solution, on the separation factor and the metal transfer rate is reported in this work. Effective separation of different metal pairs was achieved under the experimental conditions.

By Juan Patricio Ibáñez

Separation of arsenic and copper from Cu-As-H2S04 electrolytes by electrodialysis has been investigated at room temperature. The effects of current density and pH were studied. An arsenic-free copper solution was obtained for all the tested conditions. The transport efficiency for copper ions was found to be higher than 98% after 3 hours' test. Transport of arsenic and copper through the ion exchange membranes was increased by increasing pH and current density. Solution pH was found to be a key parameter for the separation process, since it controls the speciation of the ions to be transported and the formation of unwanted precipitates which reduce the global efficiency of the electrodialysis process. The main conclusion is that electrodialysis is a promising technique to be used in separating and/or concentrating ions of interest in copper electrometallurgy.

Jan 1, 2003

By Chen Song

Keywords: Mixed extractant, Copper, Cobalt, Nickel, Synergistic effect During separation process of copper and cobalt from nickel sulphate solution, the effects of constitutions and compositions of mixed extractant D2EHPA and PC88-A or Cyanex 272, has been studied. In one step extraction cycle, the following results are obtained:[Ni]/[Co]>4000 and [Ni]/[Cu]>40000 in nickel sulphate solution, [Co]/[Ni]>1000 and [Co]/[Cu]>30000 in cobalt chlorinate solution, [Cu]/[Ni]>10000 and [Cu]/[Co]>200 in copper sulphate solution. It was elucidated that the above-mentioned synergistic mixtures can effectively separate cobalt and copper from nickel sulphate acid solution and achieve a greater synergistic effect.

Jan 1, 2005

By G. M. Ritcey, B. H. Lucas

In the conventional alkaline leaching of concentrate containing nickel, copper and cobalt, copper is usually removed from the system, prior to nickel reduction, by sulphide precipitation. A new process is described for the selective extraction of copper and separation from cobalt and nickel, using liquid-liquid extraction. General Mills LIX-63 dissolved in a kerosene diluent is the extractant. Trace amounts of co-extracted cobalt and nickel are easily removed by a scrub treatment, and copper is recovered from the extract by sulphuric acid stripping, thus providing a solution amenable to the oroduction of electrolytic copper. Estimated processing costs are included together with a proposed flowsheet.

Jan 1, 1972

By M. Gaft, G. Panczer

Sedimentary francolite and magmatic apatite are characterized by specific laser-induced time- resolved luminescence, which allows phosphate to be distinguished from accompanying dolomite. The "selective window" parameters are: he, = 337 nm, delay time after laser pulse is 0.5-5 ps, and detection spectral range is 400-525 nm. In the case of nonuniform distribution of phosphate minerals, it makes it possible to accomplish lasero- luminescent sorting and to receive intermediate product with a lowered dolomite contents.

Jan 1, 1999

By Junji Shibata

Heavier rare earth, which is contained in a small amount in ores such as bastnesite and monazite, has been accumulated as a heavier rare earth residue without doing separation and purification due to the lack of suitable methods. The heavier rare earth residue includes seven rare earth elements such as Tb, Dy, Ho, Y, Er, Tm and Yb. Separation and recovery process of Dy, Y, Tm and Yb from leached solution of the heavier rare earth residue was investigated by using a column method with solvent impregnated resin. The solvent impregnated resin was prepared by impregnation of organophosphorous extractant whose trade name is PC-88A into a macro porous resin, Amberlite XAD-7. It was almost impossible to separate them in simple adosorption and elution steps. However, we attained to individually separate Dy, Y, Tm and Yb from the leached solution first by changing eluent concentration gradually from pH2 to 0.02kmol/m3 HC1 in the elution step, and secondly by using a development column and changing eluerit concentration in the elution step. The separation process flow was proposed for a heavier rare earth residue by using the solvent impregnated resin method.

Jan 1, 1998

By Martha Gellner, Lutz Wuschke, Hans-Georg Jackel, Urs A. Peuker

"Electric vehicles are an alternative to the existing combustion engine driven cars. According to the EU Battery Directive a substantial recycling rate of at least 50 wt.-% has to be met for aged batteries since 2006. Existing recycling techniques are based on energy intensive pyro- and hydrometallurgical process, which are not able to recover all components. Aluminum and lithium for instance are slagged. The EU-Project “ABattReLife” investigated possibilities for a mechanical processing in order to create a sustainable process and a closed material loop from grave to cradle. After a sufficient liberation of the Li-ion batteries, components like the doped carbon black fraction (mainly lamination of electrode foils), the separator foil and the housing material can comparatively easily be separated from the other components by screening and air sifting. The remaining mixture consists of anode and cathode foils which have a similar free-settling ratio and are more difficult to separate from each other. A second comminution and compaction step modifies the particle size and shape as well as the degree of delamination. These changes influence the density of the electrode foils in order to improve the separation efficiency. Yield and purity of the generated metal concentrates were parameters to show if the separation was successful. The specific energy consumption for the different methods of processing was estimated in order to benchmark the cost-benefit ratio for each one.The studies have been accomplished with a zig zag sifter (model TUBAF), a hammer mill (model HM 340 Jehmlich) and with a Petkus-Sifter. Finally a process flow sheet was developed for a Li-ion battery recycling plant in pilot scale."

Jan 1, 2016

By Toshihide Takenaka

The management of radioactivated stainless steel from a terminated nuclear reactor will become an important subject in the near future. The separation of the elements in stainless steel should be effective to reduce the management labor. In this study, the separation of the elements in stainless steel by an electrorefining tcchnique was investigated in an aqueous solution. The electrochemical reactions of the elements in stainless steel werc studied by voltammetry and potentio-static electrolysis was carried out. A stainless steel anode was dissolved electro-chcmically with good anodic current etliciency in a chloride solution. The residue, where Ni was concentrated, was found on the anode after electrolysis. The electrodeposit in a stainless steel cathode consisted mainly of Fe and Cr and the Ni content in it was less than 0.5wt% under suitable condition. It is concluded that an electrorefining technique is effective for the separation of the elements in stainless steel.

Jan 1, 2003

By K. Haga

In this study, flotation tests were performed to investigate behavior of enargite and chalcopyrite ores from different sources synthetically mixed for separation of enargite. Flotation parameters including; pH, reagents concentration and type and flotation time were controlled to obtain an enargite concentrate with high As and chalcopyrite concentrate and final tailings with As content below 0.5 mass%. The copper ore bearing enargite mineral contained 5.87 mass% As and 16.50 mass% Cu while the chalcopyrite bearing ore contained 0.32 mass% As and 21.63 mass% Cu. The two ore samples were mixed at 7:3 (enargite: chalcopyrite) by weight ratio to prepare a mixed ore sample with arsenic content at 3.16 mass% and 18.25 mass% Cu for the flotation study. For enargite single ore flotation, the 38?75 µm size fraction showed that over 98% enargite was selectively recovered within 5 min at slurry pH of 4.0 and arsenic content in the final tailings was reduced to 0.22 mass%. In mix ore (enargite+chalcopyrite) flotation, 97% of enargite was first removed at pH 4 followed by chalcopyrite flotation at pH 8, and over 95% recovery was achieved in 15 min flotation time. Arsenic content in the final tailings was reduced to 0.1 mass%.

Sep 1, 2012