Search Documents

By W. R. Finney

THE formation of scale in boilers and other industrial equipment, and the corrosion of such equipment, are closely related problems. Since in the petroleum industry these problems cover a very broad field, this paper has been confined to the effects of scale and corrosion on gas engines, compressors, pipes and fittings, used in plants extracting gasoline from natural gas, and the steps taken in arriving at a workable plan for combating these evils at the Midwest Refining Co.'s plants in the Salt Creek field, Wyoming. Eliminating, or at least minimizing, the many deleterious effects occasioned by the use of bad water in jackets and cooling systems of gas engines and compressors has been the subject of much study for many years but no generally accepted plan has been evolved. The problem was unusually difficult at Salt Creek, as the severe winters of Wyoming bring operating conditions quite different from those encountered in warmer states, and the water available was especially bad. While the conditioning of water to prevent scale and to lessen corrosion may not be a particularly difficult problem in plants in large industrial centers, it becomes much more difficult when attempted at plants remote from railroads and by men without previous experience to guide them. In fact this difficulty has been so great in the Wyoming oil fields that until comparatively recently it has been the practice to allow much equipment to be ruined rather than to attempt corrective measures. At the Midwest plants this problem was given attention first by the plant men and later by both plant men and laboratory staff. To the latter it was simply one of many problems which arise in connection with field and plant operations, which must be studied and, if possible, solved. Many mistakes were made during the course of this investigation, but since mistakes, properly interpreted, are of value in guiding one's steps aright, it is believed that a review of the different stages of development which have led up to the present method of handling this problem will prove of interest to the industry.

Jan 12, 1926

By Brian K. Failon

Scale formation is a problem that affects many mineral processing systems because the processes require the use of large volumes of water. Scale composition may vary from circuit to circuit, but the scale deposition mechanisms and needs for prevention are often somewhat similar. Likewise, there is a degree of commonality in the prediction, detection, and elimination of scaling conditions in various water systems. This paper briefly reviews some of the conditions which lead to scale formation, as well as some of the common problems associated with unchecked scale growth. The primary focus of the paper is on the variety of chemical scale inhibitors available for use in mineral processing circuits, and the actions of each type. The means of predicting and detecting scaling tendencies are also addressed, and include both direct and indirect methods, i-e., stability index determination and chemical analysis of deposits.

Jan 1, 1986

By N. Fardin, O. Stephansson, L. Jing

A pair of silicon rubber replicas of size 250 mm by 250 mm, from a natural rock joint, was used to produce several high strength concrete fracture replicas of different sizes, from 50 mm by 50 mm to 200 mm by 200 mm. The morphology of the concrete fracture replicas were digitized at the laboratory using a 3D-laser-scanning machine with high accuracy and resolution. The scale dependency of the geometrical properties, including surface roughness and aperture, of the samples were investigated using fractal method. The investigation was extended to study the scale effect on the mechanical properties of the concrete fracture replicas. Four concrete replicas having same geometry from each sampling size were sheared under four different normal loads. The results show that normal and shear stiffness and peak shear strength decrease with increasing sample size and decreasing normal stress. It is concluded that for accurate determination of geometrical and mechanical properties of rock joints in the laboratory and field scales, samples with size equal to or larger than stationarity limit are required. Silikongummiabdrücke der Größe 250 mm x 250 mm einer natürlichen Kluft dienten als Vorlage für mehrere Hochfestbeton Rissreplikas verschiedener Größe. Die Morphologie der Beton Rissreplikas wurde mittels eines 3D-Laserscanners hoher Genauigkeit und Auflösung im Labor digitalisiert. Die Skalenabhängigkeit der geometrischen Eigenschaften, dies inklusive Oberflächenrauhigkeit und Öffnungsweite, wurden mittels Fraktalen bestimmt. Die Studie wurde durch die Untersuchung der mechanischen Eigenschaften der Betonrepliken erweitert. Hierbei wurden vier Betonrepliken der selben Geometrie jeder Probengrösse unter vier verschiedenen normalen Belastungen abgeschert. Die Ergebnisse zeigen das sowohl Normal- und Schersteifigkeit als auch die Spitzenscherfestigkeit mit zunehmender Probengrösse und abnehmender Normalspannung abnehmen. Es hat sich gezeigt, daß für eine genaue Bestimmung der geometrischen und mechanischen Eigenschaften von Felsklüften im Labor und im Feld Proben einer Größe gleich oder größer des stationären Limits verlangt werden. Deux répliques en gomme de silicone d’une fracture naturelle, de dimension 250 mm par 250 mm, ont été utilisées pour produire des répliques en béton de haute résistance de dimensions allant de 50 mm par 50 mm à 200 mm par 200 mm. La morphologie de ces répliques a été digitalisée au laboratoire à l’aide d’un laser-scanner 3D haute résolution et haute précision. L’influence de l’échelle des propriétés géométriques, incluant rugosité et ouverture, a été étudiée en utilisant la méthode des fractales. Des essais complémentaires ont été réalisés afin d’étudier l’effet d’échelle sur les propriétés mécaniques des répliques de fracture en béton. Quatre répliques béton de même géométrie pour les différentes tailles d’échantillons ont été cisaillées sous quatre valeurs de contrainte normale. Les résultats montrent que la rigidité normale et tangentielle ainsi que la résistance de pic diminuent en proportion de l’augmentation de la taille de l’échantillon et de la diminution des contraintes normales. On peut en conclure que, pour une détermination précise des propriétés géométriques et mécaniques des fractures au laboratoire et sur le terrain, des échantillons de taille égale ou supérieure à la limite stationnaire sont nécessaires.

Jan 1, 2003

By N. Shi, T. G. Joseph

ABSTRACT: A prototype test dipper (at 1/20th volume and a geometric operating scale of 2.85) was compared during field trials against a conventional dipper with the same tare weight using the same test shovel. Both dippers followed similar dig trajectories, invoked by the shovel operator. A Microsoft® Visual Basic-embedded spreadsheet was used to interpret qualitative visual and quantitative numerical loading data collected on the hoist and crowd dig response. Overall the concept dipper, even with a 50% greater capacity, provided indications of a smoother dig cycle with lower peak hoist loading events and a lower energy per unit excavated.

Jan 1, 2011

By Michael N. Allenby

One of the least discussed areas in the ever-improving technologies of gold recovery from ore bodies and tailings is the chemistry of the waters used in the plants. Carbon-in­ pulp, carbon-in-leach, heap/dump leaching and iological oxidation processes are all affected by water quality. The remoteness of a lot of the plants means that the large water requirements can often only be met by a ground water source. The chemistry of waters from different sources poses different problems, but generally a lot of these waters are scale forming. Scale-forming tendencies can be described by calcium, magnesium, barium and strontium assays. They can be notated by Langelier and Ryznar indices. They can be plotted by computer programmes that print out scaling indices at different conditions. The propensity to scale can -be readily determined. The prevention of scaling -or at worst minimisation of scaling -is the ambition of the suppliers of scale inhibition programmes. This prevention/minimisation technology is discussed below.

Jan 1, 1993

By C. Michael Dickinson

In support of the DNA Deep Basing Program, SRI International has been performing scale model experiments on protective structures since 1973. The SRI program includes field and laboratory tests of mini- structure models with surrounding natural or simulated geology. This paper contains a synopsis of some of the results of this research.

Jan 1, 1984

By Smith S. F, Terezopoulos N. G

This paper discusses experimental results of physical scale models employed to study the stability of a pillar between rectangular roadways. A programme of laboratory investigations utilising a bi-axial test rig has been undertaken to examine the influence of various stressfields on the stability of pillars between mine roadways. The effect of pillar height/width ratio on the overall stability is studied. Observations of failure characteristics in and around pillars are discussed especially in relation to the various stressfields applied to the models.

Jan 1, 1992

By K. Goshtasbi Goharizi

This paper discusses experimental results of physical scale models employed to study the stability of a pillar between rectangular roadways. A programme of laboratory investigations utilising a bi-axial test rig has been undertaken to examine the influence of various stressfields on the stability of pillars between mine roadways. The effect of pillar height/width ratio on the overall stability is studied. Observations of failure characteristics in and around pillars are discussed especially in relation to the various stressfields applied to the models.

Jan 1, 1992

By Dennis V. Woods, J. Duncan Crone

"In order to determine its capabilities and to aid in the interpretation of fie ld results, a scale model study and field tests were carried out on the Crone borehole pulse electromagnetic (PEM) system. The model results indicate that if a borehole passes in the vicinity of a tabular conductive body, the system will not only detect the presence of the body, but will also return information as to its conductivity-thickness product, size, altitude and position.The effect of variation of these electromagnetic and geometric factors on the shape of the response curve from a borehole PEM survey is displayed by a number of suites of scale-model response curves. These model curves can be used directly as type curves in the interpretation of field results. Field tests of a prototype PEM system provide a check on the scale-model results and also summarize the procedure of interpreting field data using the model type curves.The borehole pulse EM system can be effectively used as a follow-up geophysical instrument for locating and delineating known conductive bodies. It can also be profitably utilized as a primary geophysical exploration tool in areas of deep mineralization below the depth limit of conventional airborne and ground geophysical systems. The probed area of a diamond drill hole in these cases is increased from a 1- inch drill core to a zone extending hundreds of feet from the hole."

Jan 1, 1980

By A. Becker, C. Gauvreau, L. S. Collett

"A scale model was designed to simulate the airborne Barringer INPUT time domain electromagnetic system. The amplitude of the response to a vertical conductive dyke varies considerably with the conductor's thickness conductivity product (TCP). The response increases from a minimum detectable level at a TCP of about 2 mhos, rises to its maximum value at a dyke TCP of 15 mhos and then falls again so that conductors with a TCP exceeding 500 mhos would probably remain undetected. Measurements made with both standard receiver coil configurations (maximum or minimum coupled) indicate comparable effectiveness for both systems, either from the viewpoint of vertical conductor detection or from the viewpoint of discrimination against overburden anomalies."

Jan 1, 1972

By J. S. Roti

Calcium-based scale precipitation is a common problem in mill reclaim waters. An accumulation of these adherent deposits can result in a rapid reduction in water flow, loss of pump efficiency and eventual interruption in ore production. Heap leach applications can also experience the added problems of plugged sprinkler heads, blinded leach pads and fouled carbon columns when scale control is not maintained. The primary cause of scaling in precious metal recovery is the relative insolubility of calcium carbonate. The presence of the calcium ion and bicarbonate alkalinity is common in almost every water source. If the temperature or pH of the water is allowed to increase, the bicarbonate breaks down to carbonate and combines with calcium by the following reaction: Ca +2 +2HCO3 ? CaCO3 + H2 + CO2

Jan 1, 1986

By Laura A. Sanders

Mineral scale formation is prevalent in numerous mining operations. Such scale formation can occur in the direct-contact heat exchangers ahead of an autoclave. In these heat exchangers, the incoming slurry comes into contact with steam in a stage-wise fashion, which is re-circulated from the downstream flash vessels to heat the slurry in stages ahead of the autoclave. Calcium sulfate scaling causes severe problems in mining operations where increased temperatures are involved due to rising temperatures promoting calcium sulfate scaling through a decreasing solubility. In a number of these operations, the scale formation can occur in the presence of mineral solids, where fine-grained charged particles are at concentrations in excess of 35%. Scale prevention is not difficult in standard aqueous systems; however, the presence of solids leads to significant deficiencies in the prevention of scale due to the adsorption of the polymer onto the charge solids instead of the polymer interaction with the scale. Therefore, a technical solution to prevent mineral scale build up occurring in presence of pulp slurry in mining operations is needed. Several novel antiscalant technologies were developed and evaluated which provided a substantial improvement in the scale prevention in such systems.

May 1, 2013

By J Wu

Swirl Flow Technology (SFT), a novel approach for agitation in large industrial slurry tanks, was jointly developed and patented by CSIRO and Queensland Alumina Ltd (QAL). Currently, SFT is used in 16 alumina precipitation tanks at QAL, with the first installation in January 1997. This paper provides insight to the underlying fluid dynamics, which were investigated through pilot-scale experiments. A key finding was that SFT produces tank wall velocities approximately four times that of conventional draft tube agitator systems for the same power input, whilst for solids suspension, much less power is needed. SFT is energy efficient and practical in scaling suppression as demonstrated by the full-scale experience at QAL.

Aug 8, 2011

By James Y. Oldshue, Paul M. Kubera

Most coillillercial processing applications employing mixers in various types of slurry systems are continuous flow. These applications may also be multiple stage, with the stage number varying anywhere from two or three to ten or more. Two questions that usually come up at the beginning of any proposed pilot plant study are (1) can the pilot plant unit be operated batch-wise, and the results extrapolated both on the basis of scale and fluid motion to the full-scale tank which will be continuous-flow (and probably multi-stage), or (2) does the pilot plant need to be operated in a continuous-flow fashion, and if so, does the exact number of tanks/stages that are proposed for the plant need to be used in the pilot plant? We will consider these possibilities in sequence and present the principles involved in running some of the various pilot-plant arrangements.

Jan 1, 1992

By Gerd Oberheuser, Hans Kellerwessel

Comminution with high compression roller mills finds rising interst in ore and minerals industry. Energy saving and upgrading of existing grinding facilities is one of the main reasons. Beside these possibilities other positive effects on the downstream units operations require also intense testwork. Basic interdependencies of the operational parameters gained at the testwork and their influence on the upscaling procedure are described.

Jan 1, 1995

By Whiten W. J

Data from ball mills of a wide range of sizes are analysed using detailed mathematical models and non-linear least squares fitting techniques. In this way model parameters are obtained describing the behaviour of ball mills over a wide range of mill sizes and operating conditions. These parameters define the flow and breakage of each size fraction of ore in the mill. Flow of coarse particles through the mill is found to depend on the proportion of coarse particles present. The breakage rates of coarse particles are found to decrease markedly with mill diameter for mills over 3 m in diameter.Simulation of grinding circuit throughput at constant productsizing for different mill diameters shows that throughput is proportional to theoretical mill power consumption for mills up to about 3 m in diameter. Thereafter the throughput gradually falls below that indicated by power consumption, the decrease becoming quite significant for large diameter mills. Simple qualitative physical arguments are presented to explain this behaviour. The models developed have applications to ball mill scale up. Work on their further development is continuing.

Jan 1, 1982

By M. J. Friedel

The scale-dependent hydraulic properties in a fractured porphyry copper oxide deposit are investigated for relevance to In Situ Leach Mining (ISLM) design. In most well field designs, mine operators assume that hydraulic properties represent a continuous spatial function, or continuum. The problem, however, is that the representative elemental volume, the volume over which hydraulic properties are described as a continuum, is a domain (if it exists) that occurs between end members representing varying degrees of heterogeneity. At the Cyprus Casa Grande mine, transmissivity fluctuations are spatially correlated. This suggests that, at the scale of ISLM, the hydraulic process is heterogeneous, and a typical continuum representation is inappropriate for design. Alternatively, a conditional stochastic approach using the Simulated Annealing (SA) technique is deemed useful for the imaging of heterogeneous hydraulic properties. Specifically, SA preserves transmissivity extremes and spatial complexity, both necessary for accurate conditioning of a flow simulator. Also, the stochastic continuum approach provides an avenue whereby uncertainty (or risk) may be addressed. Currently, the SA weaknesses are that it is computationally time consuming and that uncertainty may increase when simulating under conditions of statistical isotropy. Recognizing that ISLM exerts a dynamic influence on hydraulic properties with time, the mine design should be re-evaluated at intervals throughout the evolution of the leaching process.

Jan 1, 1994

By Michael J. Friedel

The scale-dependent hydraulic properties in a fractured porphyry copper oxide deposit are investigated for relevance to in situ leach mine (ISLM) design. In most well field designs, mine operators assume that hydraulic properties represent a continuous spatial function, or continuum. The problem, however, is that the representative elemental volume, the volume over which hydraulic properties are described as a continuum, is a domain (if it exists) that occurs between end members representing varying degrees of heterogeneity. At the Cyprus Cas a Grande mine, transmissivity fluctuations are spatially correlated suggesting that at the scale of ISLM, the hydraulic process is heterogeneous and a typical continuum representation is inappropriate for design. Alternatively, a conditional stochastic approach using the simulated annealing (SA) technique is deemed useful for the imaging of heterogeneous hydraulic properties. Specifically, SA preserves transmissivity extremes and spatial complexity, both necessary for accurate conditioning of a flow simulator. Also, the stochastic continuum approach provides an avenue whereby uncertainty (or risk) may be addressed. Currently, the SA weaknesses are that it is computationally time consuming, and uncertainty may increase when simulating under conditions of statistical isotropy. Recognizing that ISLM exerts a dynamic influence on hydraulic properties with time, the mine design should be reevaluated at intervals throughout the evolution of the leaching process.

Jan 1, 1993

By L. M. Nolan

Chemical Mechanical polishing, or CMP, has four components in the polishing interface; namely the polishing pad, the polishing fluid, the abrasives in the fluid, and the surface being polished. Understanding the way that load is transferred between these components is key to understanding and predicting wafer polishing. Numerous models of CMP and the different load sharing arrangements which occur between these four components have been proposed. These include models by Luo and Dornfield (1) and Fu, Chandra and colleagues (2). Other models focus on just one or two loading arrangements, such as `hydroplaning' when all load is transmitted by the liquid in the case of Runnels and Eyman (3). In this work, we consider four possible combinations of load transfer from pad to wafer in CMP. These combinations are listed below in Table 1 and are illustrated schematically in Figure 1. It is important to note the role of scale in this process; the illustrations in Figure 1 are drawn to scale from actual profilometer scans obtained over a length of 5 with particles of 150 nm in diameter. Table 1 - Load Transfer Combinations Load Regime Illustration Wafer - Fluid - Pad Figure la Wafer - Particles/Fluid - Pad Figure lb Wafer - Particles - Pad Figure lc Wafer-Pad Figure ld The interest in load-sharing between the system components is because some configurations are anticipated to achieve higher polishing rates than others. For instance, in hydroplaning, or hydrodynamic lubrication, the lateral force exerted on the polished surface by the particles can be no higher than the fluid shear force developed in the gap between the pad and wafer. This is not expected to generate high rates of material removal from the surface (4). For contact that is largely between the pad and the wafer, such as the regime depicted in Figure ld, the lateral load is transmitted to the wafer by the pad and is hence limited by the pad's low rigidity. This regime is not expected to generate high material removal rates either. The highest levels of material removal are expected from regimes where the mechanical load exerted on the system is transmitted by the particles, in combination with either the fluid or the pad. Under what circumstances does the polishing regime change from one to another? What must occur in order to initiate or terminate contact between the system components? This is an ongoing question in the field of tribology, and has traditionally been viewed in terms of the pressure and velocity applied to the system, the thickness of the fluid film between the two surfaces, and the roughness of those surfaces (4). In this paper, we propose a new mechanism ? that the load on the particles may be sufficient to totally embed them in the polishing pad, at which point they are no longer able to transmit load and polish the wafer surface. This is illustrated schematically in Figure 1(d).

Jan 1, 2010

By Heiskanen K., Koivistoinen P.

A common belief is that autogenous grinding suits itself only to certain oretypes. It is shown that properly designed autogenous grinding can be used even with very difficult ores with energy consumptions which are equal or lower than obtained with rod-ball mill grinding. The basic feature in the design is the large port grate developed by Outokumpu. The scale-up of the mills can be done on the basis of the base mill concept. It enables to compare different mill sizes and types. Simple scale-up equations are presented based on actual mill data and experimental work.

Jan 1, 1992