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By Jose Luis Pineda Villarreal

New technologies emerge every day with practical applications for open pit mining. For every operation, managers need to understand the best way to increase efficiency in drilling, blasting, fragmentation and hauling routes.

Jan 1, 2018

By John E. Anderson, Charles A. III Cravotta, Eleanora I. Robbins, E. Terrance Slonecker, Gordon L. Nord

Remote sensing is being tested for its ability to identify the severity of impact on streams that are subjected to contaminated mine drainage (CMD) in the Southern Anthracite Coalfield of Pennsylvania. Airborne digital multispectral video images of acidic and near-neutral CMD are being compared with field spectra, water chemistry, mineralogy, and microbiology. Spectral differences in the visible region of the electromagnetic spectrum are caused by the presence of schwertmannite in the acidic precipitates and ferrihydrite in the near- neutral precipitates. The acidic CMD averages 1,500 mg/L sulfate and has bacteria coated with schwertmannite; the near-neutral CMD averages 87 mg/L sulfate and has bacteria coated with ferrihydrite.

Jan 1, 2000

By P. A. Riveros, W. D. Gould, R. Molnar, D. W. Koren, P. Bédard

This paper reports the results of the field demonstration campaign of a new process for removing and destroying ammonia from mining/ metallurgical effluent solutions. The 50-day campaign was carried out at a uranium plant in Saskatchewan, Canada. The process was developed by adapting and integrating two well established technologies: zeolite adsorption/ elution to extract the ammonia from the effluent stream and to produce a concentrated ammonia eluate; and conversion of the ammonia in the eluate to innocuous nitrogen by applying bacterial nitrification-denitrification (NH3 = > NO3 - => N2). The data show that reasonable target criteria were met, under very challenging operating conditions. Problem areas and possible causes for poor performance are identified. Preliminary and generic cost estimates of the process are also presented.

Jan 1, 2003

By Thomas M. Harris

Cation exchange is not sufficiently selective to be used for the removal of heavy metal ions from a general industrial wastewater. However, if the metals can be converted to polyvalent anions through complexation, they may be removed both selectively and efficiently by anion exchange. This approach, referred to as chelation-assisted anion exchange (CAAE), has been examined using industrial wastewater samples contaminated with Ni2+ and Cr3+. For this particular application, the Ni2+ is complexed with 8-hydroxyquinoline-5-sulfonic acid, and the Cr3+ with sulfosalicylic acid. Removal efficiencies and adsorption isotherms for both the complexants and the complexes were determined in batch-mode tests.

Jan 1, 1994

By J. Brendan Mclaughlin, Casimir J. Koshinski, Michael V. Rose, Wolfgang Baum

Mercury contamination is a worldwide problem in the mining, smelting, and refining of gold, silver, and copper. In these areas, mercury may be found as a naturally-occurring material in ores and concentrates, and/or in secondary feedstocks such as leach residues, pyrometallurgical treatment residues, refinery by­products, electrowinning electrodes, autoclave discharge solids, and waste water and acid plant sludges. The United States Environmental Protection Agency (EPA) has designated mercury one of the most harmful heavy metal contaminant in the environment and has implemented regulations that prohibit land disposal of characteristically hazardous wastes containing greater than 0.20 mg/1 TCLP mercury without prior treatment, thus increasing the cost of managing these materials. The presence of mercury in mine, smelter, and refinery by­products and wastes severely decreases, and in some cases eliminates, the ability to recover residual metal values from the contaminated material. The lost revenue associated with this disposal, combined with the increased direct cost of waste treatment, and/or disposal and protecting workers and the environment, can adversely affect overall profitability. The safe, efficient, and economical removal of mercury from gold, silver, and copper mining by-products requires a treatment process that is capable of liberating the mercury from the wide variety of compounds and matrices in which it may be contained, reducing the mercury content in the matrix to desired levels, and recovering the mercury in pure saleable form, without producing any secondary solid, liquid, or gaseous wastes. This paper reviews results from commercial operations and pilot scale tests using a thermal process owned and operated by Mercury Recovery Services, Inc. (MRS) to remove and recover mercury from copper acid plant blowdown sludge, Merrill­Crowe precipitate from gold/silver mining operations, and Cottrell and salt slag dusts from a precious metals refinery.

Jan 1, 1997

By Gordon D. Jarvinen

Polymer Filtration (PF) Is an innovative, selecthle metal removal technology. Chelating, water-soluble polymers are used to selectively bind the desired metal ions and ultrafiltration is used to concentrate the polymer-metal complex producing a permeate with low levels of the targeted metal ion. When applied to the treatment of, Industrial metal-bearing aqueous process streams, the permeate water can often be reused within the process and the metal ions reclaimed. This technology is applicable to many types of industrial aqueous streams with widely varying chemistries. Application of PF to 'aqueous streams from nuclear materials processing and electroplating operations will be described.

Jan 1, 1999

By Shijie Wang

In pressure oxidation leaching of copper anode slimes, than 65% of the tellurium is m' cxtraoted during decopperizing. About l0- 15% of the selenium is also dissolved simultane¬ously by severe leach conditions. Current operation for the treatment of the leachate is to constantly recirculate the leach solution through a bed of copper turnings. The tellurium and sele¬nium are precipitated from the leach liquor as copper telluride and copper selenide and sepa¬rated from the solution by filtration. In order to improve the reaction efficiency and reduce the process cost, viz, minimize the copper addition, cut retention time, and reduce the energy consumption; a chemical reducing agent is studied and the cementation process tested in the laboratory. In this paper, the test results are presented and the process chemistry is discussed.

Jan 1, 2003

By Milner E. F

Thallium is largely volatilized during sintering in the conventional sinter/blast furnace production of lead. The new direct oxygen smelting processes will force the thallium into the bullion, necessitating a means of removal to avoid contamination of the refined lead. Pilot plant testwork demonstrated that thallium was efficiently removed from lead bullion by treatment with molten zinc chloride. The spent zinc chloride salt was treated in the laboratory to recover lead sulphate, a zinc chloride solution, and a thallous chloride salt containing over 80% thallium. Cominco is installing this thallium process as part of its Trail Lead Smelter Modernization Program which will commission a QSL bath smelter in late 1989.

Jan 1, 1989

By M. Misra, J. Nanor

The removal and stability of arsenic over a wide pH range (3.0-10.0) from synthetic solutions and industrial waste effluents (including mining waste tailing slurry) can be accomplished with addition of impure lanthanum chloride alone or in conjunction with ferric sulfate. The long term stability of these correspond­ing precipitated compounds is critical from the disposal stand­point. In this paper test results of this new process for arsenic removal and stabilization from the above mentioned systems are presented. Also, precipitated arsenic compounds (lanthanum arsenate, lanthanum-ferric arsenate, ferric-lanthanum arsenate and ferric arsenate) from synthetic solutions have been charac­terized. The characterization technique used was XRD. XRD patterns which shows that the lanthanum arsenate and lan­thanum-ferric arsenate formed in acidic and alkaline pH at room temperature are crystalline. On the contrary, ferric arsenate and ferric-lanthanum arsenate compounds formed under the same conditions as lanthanum arsenate were amorphous.

Jan 1, 1998

By M. Misra

The dissolution of mercury during gold cyanidation is the cause of many environmental, health and processing problems. A study was undertaken to find a suitable reagent for the removal of mercury bearing complexes from the leach liquor. Removal of mercury from synthetic solutions and process water from a gold mine was investigated using sodium sulfide, sodium and potassium dimethyl dithiocarbamates as precipitating reagents. The results have shown that efficient mercury removal could be achieved by addition of potassium dimethyl dithiocarbamate (KDTC), by formation of stable mercury compounds. The resultant mercury-potassium dimethyl dithiocarbamate precipitates are stable under present plant operating conditions and do not have any deleterious effect on gold adsorption by activated carbon. Furthermore, it is also possible to stabilize the mercury in the heap during cyanidation by adding dimethyl dithiocarbomate.

Jan 1, 1998

By C. H. Bucknam, A. M. Raichur, M. Misra

Simultaneous dissolution of mercury along with gold occurs during cyanidation of gold ores. A method has been found for the efficient removal of mercury from the gold cyanide solution by treating with dithiocarbamates which form stable compounds with mercury. The mercury concentration in the leach solution can be brought down to low levels by adopting this treatment. Furthermore, it is also possible to stabilize the mercury in the ore heap itself by addition of this reagent so that mercury does not dissolve in the cyanide solution during heap leaching. Only trace amounts of mercury were detected in the pregnant solution obtained from a heap treated with dithiocarbamates. In this paper, process parameters are discussed in detail.

Jan 1, 1997

By Martín Reyes

Iron concentration by ion flotation techniques, from sulfate solutions in presence of zinc was studied in a laboratory flotation column by continuous mode using a synthesized sand shell plate sparger, an anionic collector, promoters, and surfactant propylenglicol 400. Effects of experimental parameters, such as the concentration of reagent: potassium amyl xanthate and dithiophosphate, superficial gas velocity, and superficial liquid velocity were studied in terms of the recovery and enrichment of Fe (III). The results show that the iron elimination from the solution in the presence and absence of zinc (II) are of 59 % and 72 % respectively. The flotation efficiencies decrease with an increase of the concentration of xanthate and air flow rate. The best recovery was achieved, at Jg 0.1 cm/s, Jl 0.72 cm/s and a mixture of xanthate and dithiophosphate as promoter. It was also demonstrated that it is possible to selectively separate and concentrate iron (III) from solutions containing zinc. The behavior of iron ion flotation in a flotation column is reported in this research as a gas hold up, superficial gas velocity, bubble size and superficial bubbles area flux function. The results show that the extraction of aqueous ions of metal iron by ion flotation is strongly affected by: [C], Jg (cm/s), eg (%), Db (mm), Jl (cm/s), y Sb (s-1).

Jan 1, 2009

By C. M. Davidson

Contamination of by-product: sulfuric acid, by dissolved oxides of nitrogen ('nitrates') occurs under some operating conditions encountered in sulfide roasting and smelting,, notably when oxygen-enriched air is used. This 'nitrate' lowers the value of the acid and increases the effective cost of smelter gas desulfurization. The present paper describes measures taken at one smelter acid plant to remove this 'nitrate'; it discusses the mechanism by which 'nitrates' in some cases concentrate in one part of the plant and can be purged for more efficient treatment; and it describes a process developed by C-I-L Inc. for removal of 'nitrates' from such a purge stream. Advantages of the process include very low reagent cost, recovery of all sulfuric acid values and safe handling of nitrous fumes.

Jan 1, 1983

By P. Shang

Fly ash and zeolite have strong absorption to cations since their porous microstructure. The porosities of fly ash and zeolite can also be increased by modification, which improves the absorption of the materials. This research showed that the effects of modified fly ash and zeolite to remove ammonia nitrogen from rainwater. The optimal reaction time, additive amount of materials, and pH value of the stormwater to remove ammonia nitrogen were experimentally determined. For modified fly ash, the optimal removal rate of ammonia nitrogen from 100 ml stormwater was 74.41% with the addition of 10.0g fly ash, 1.5 hours of the reaction time, and 8 of pH value. To the modified zeolite, the optimal removal rate of ammonia nitrogen was 51.22% at the reaction conditions of 2.0g of zeolite, 1 hour of reaction time, and 7 of pH value.

Jan 1, 2010

By T. Y. Yan

The various ion exchange reactions occurring during the restoration of formations contaminated with ammonia during in situ uranium leaching are reviewed. Data are presented on the restoration of a previously leached laboratory packed column using line saturated brine. Although this restoration fluid selectively and effectively removed the ammonia, 24.5 pore volumes are required to reduce the ammonia concentration from 500 to 3 ppm. The presence of NaCl in the restoration fluid is beneficial in + improving the selectivity of the system for NH removal and reducing ca++ ion consumption.

Jan 1, 1982

By R. M. Cunningham

Asarco operates one of the largest individual copper electrolytic refineries in the world at Amarillo, Texas. The feed for this refinery is a mixture of anodes produced at Asarco smelters and copper purchased t?om a number of primary and secondary sources. The variation in feed makes it imperative that the refinery practices state-of-the-art quality control to minimize the effects'of unwanted impurities in the electrolytic refining process. In late 1993, a plant designed to sigru6cantly reduce the antimony and bismuth levels in the electrolyte was commissioned. The purification plant uses ion exchange technology in conjunction with a novel strippiing system developed by Zeneca Specialties (U.K.). The strippiing system permits the recycling of the eluant and thus avoids the extremely high costs of stripping with conventional reagents. In addition, the environmental impact of treating the eluant for recovery of antimony and bismuth is minimized. This paper outlines the development of the technology and, in particular, describes the operational practices and improvements at Amarillo since the commissioning of the plant.

Jan 1, 1997

By Kazutoshi Haga, Batnasan Altansukh, Atsushi Shibayama, Ryuji Oinuma

"Recently, the arsenic grade in copper ores has been increasing year by year. Arsenic bearing minerals (enargite (Cu3AsS4) and tennantite (Cu12As4S13)) coexist with typical copper minerals such as chalcopyrite (CuFeS2). The removal of arsenic from copper ores that contain relatively high arsenic content is essential due to its adverse impact on the environment and the resulting economic consequences. In this study, arsenic removal and dissolution behaviour of Cu and As from enargite (Cu3AsS4) were investigated using ferric sulphate (Fe2(SO4)3) solutions containing sodium chloride under high pressure oxidation conditions. The effects of numerous parameters including the concentration of Fe2(SO4)3 and NaCl, temperature, total pressure, leaching time and particle size were studied while other variables such as pulp density and stirring speed were fixed at 100 g/L and 750 rpm. The results showed that more than 60% of the copper was dissolved in a 0.1 M ferric sulphate solution under the high pressure oxidative conditions, whereas the leaching rate of arsenic was less than 20%. SEM observation revealed that elemental sulphur was deposited on the surface of enargite forming a passivation layer and the residue was agglomerated. Those phenomena may cause a decrease in the copper leaching rate. It was found that more than 80% of copper was dissolved in the ferric sulphate solution in the presence of 0.34 M sodium chloride under the conditions optimized, whereas the dissolution of arsenic in the mixture did not exceed 2%. XRD analysis of the solid residues from the leaching experiments used ferric sulphate and mixtures of ferric sulphate and sodium chloride showed arsenic to be present as scorodite (FeAsO4).INTRODUCTION In recent years, there has been an increase of the arsenic (As) content of copper ores due to the gradual depletion of high grade copper ores. In some copper deposits, arsenic occurs in the form of minerals such as enargite and tennantite. The removal of arsenic in ores containing copper is critical to the production of pure copper and the management of the environmental challenges caused by the smelting process. Due to the environmental risk caused by arsenic emission and the deteriorated quality of the copper product, smelting of enargite concentrates is not an effective method for the extraction of copper (Padilla et al., 2010; Safarzadeh et al., 2014; Long et al., 2012). Therefore, a number of studies have been carried out to develop arsenic removal technologies from copper ores using various methods such as hydrometallurgy (Curreli et al., 2009; Tongamp et al. 2010), pyrometallurgy (Dalewski., 1999; Padilla. et al, 2012) and bio-oxidation (Ehrlich, 1964; Sasaki et al., 2010). Several hydrometallurgical leaching processes like sulphuric acid, alkaline sodium sulphide and sodium sulphate and ferric sulphate leaching have been developed to treat enargite ores and concentrates. The alkaline sodium sulphide leaching process has been developed for the removal of arsenic from enargite (Anderson, & Twidwell, 2008; Parada et al., 2014). The mechanism of the dissolution of arsenic from enargite in sodium sulphite solution is"

Jan 1, 2016

By A. D. Davis

The Gilt Edge Superfund Site is a former heap-leach gold mine that currently is being remediated in the Black Hills of South Dakota. Mine runoff water is treated before release from the site. The field pH, before treatment, is about 3, and the water contains arsenic and some heavy metals, in addition to sulfate concentrations of about 1400 to 1500 mg/L. In the Keystone area of the Black Hills, naturally occurring arsenic has been detected in ground-water samples from wells. Keystone City Well #4, which is not used currently, showed arsenic concentrations of 36 parts per billion (ppb) and sulfate concentrations of about 19 mg/L. With field samples of water from these sites, a limestone-based method was successful in reducing arsenic and heavy metals concentrations. The results are significant because previous research with the limestone-based method mainly had involved samples prepared with distilled water in the laboratory, in which interference of other ions such as sulfate did not occur. The research indicates the potential for broader field applications of the limestone-based removal method.

Jan 1, 2011

By Y. Wang

Arsenic-bearing acidic effluent from hydrometallurgical processes contains many harmful metal ions and must be appropriately treated before discharge. In the present study, arsenic, copper, zinc, aluminum, and magnesium were co-precipitated by means of the Fenton reaction. The precipitates obtained under different conditions were investigated to determine their stability. The results indicate that pH value and hydrogen peroxide (H2O2) dosage have significant effects on the removal of various elements. Arsenic, copper, zinc, and aluminum (but not magnesium) can be removed at pH 5–6 and anH2O2/As mole ratio of 2 at ambient temperature. The precipitates were mainly amorphous and granular with particle size in the micrometre range. The arsenic concentration in leachate from the toxicity characteristic leaching test was 3.6 mg/L, which proves that the precipitates are effective in fixing arsenic.

Aug 3, 2023

By Abbas H. Mirza

Arsenic and selenium are found in low quantities together with other metals in several nonferrous metallurgical process streams such as scrubber blowdown solution, acid plant wastewater, gas cleaning plant water, etc. Normally, the other metals in these streams are present as cations and can be precipitated by conventional lime treatment and sulfide polishing. However, arsenic and selenium are invariably present as anions, AsO33-and AsO43 in the case of arsenic and SeO32 and SeO42 for selenium. Conventional lime treatment removes most of the arsenic, but it does not remove selenium. The present paper reviews the processes and technologies developed to date on the removal of arsenic and selenium from metallurgical process streams.

Jan 1, 1996