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By T. Sterry Hunt

THE essential principle of this new process, now in operation in Chili and in North Carolina, for the extraction of copper from its ores, is the dissolving of the oxides of copper by a hot solution of protochloride of iron and common salt. In the action which takes place, the protochloride of iron is converted into peroxide, while the oxides of copper are changed into protochloride and dichloride, the latter of which, though insoluble in water, is readily soluble in a hot strong brine. From the solution thus obtained, metallic iron throws down the copper in a metallic state, regenerating the protochloride of iron; which is then ready for the treatment of a fresh portion of oxidized copper ore. In the case of slimy ores, the contact of the bath with the ore is effected by agitation in tubs ; but when the ores are granular, lixiviation in large vats is equally efficient and simpler. The hot solutions, charged with chlorides of copper, are digested in tanks with scrap-iron, or better, are made to flow through covered channels containing the scrap-iron, and in their passage lose the whole of their copper; the reaction at the same time evolving so much heat as to keep up the temperature of the liquid. In order to prevent a certain loss of chlorine, which otherwise takes place from the production of some basic ferric chloride in the reaction between the ferrous chloride and the oxides of copper (both protoxide and dinoxide being generally present in calcined ores), a portion of sulphurous fumes from the roasting is made to pass through the regenerated bath before adding it to fresh ore. This has hitherto been effected by injection, with the aid of a jet of steam.

Jan 1, 1873

By B. Silliman

THESE ores occur in the Laurentian rocks in the town of Clifton, St. Lawrence County, New York. The Clifton Mining Company have opened these magnetites upon their estate of 23,000 acres, on the waters of the Grasse River, an affluent of the St. Lawrence, which flows for about nine miles across the estate, exposing a section of the formation, and affording ample water-power at numerous points. In approaching this district from De Kalb Junction, upon the Watertown and Ogdensburg Railway, the observer passes from the zone of the specular ores, which abound to a great extent in Jefferson County, across a belt of non-metal-liferous limestones, continuing for some miles intermingled with metamorphic rocks, and gradually giving place to heavy beds of granitic and porphyritic gneiss, the weathered surfaces of which present a gray and rough appearance, from the washing out of the feldspar; leaving the quartz very prominent, and completely disguising the real character of the rock, which, when freshly broken, has a lively reddish appearance from the predominance of flesh-colored and red feldspar. Beds of fine-grained quartzite appear also intercalated in the granitic gneiss. These are the dominating rocks of the magnetite region, but the magnetite is always found, so far as the speaker's observation extended, associated with beds of calcite, carrying hornblende, black and green, biotite, and brown garnet interspersed with yellow and magnetic pyrites. The strike of these rocks is about northeast, and their dip about 40° to 45° southeast.

Jan 1, 1873

By R. W. Raymond

THE specimen of anthracite which I exhibit is from the Ortiz Mine Grant, about fifteen miles southwest of Santa Fe. The beds belong to the lignitic formation of the Galisteo, which Hayden and

Jan 1, 1874

By R. W. Raymond

I HAVE the pleasure of exhibiting samples of the rock in which the South African diamonds are said to occur, for which I am in debted to Mr. Franz Groeger, of Vienna, formerly an assistant of the Royal Imperial Geological Institution, whose account of the general geology of Southern Africa was contained in a recent number of the proceedings of that Institution. The rock is apparently a sort of tufa, evidently of volcanic origin. Mr. Groeger assured me that it could be seen in situ, bounded by uplifted stratified rocks; and that diamonds had been mined from it, by means of shafts, some distance below the surface. Groeger calls it "greenstone-tufa," and says of it, in the proceedings of the Geological Institution, " it breaks through the younger members of Group III [lower Trias and Jura], . . .. and crops out in oval masses, filling fissures . . ..The occurrence of this tufa is not locally limited, but has been traced and proved already over a large territory." DR. HUNT remarked that the material looked like the trass of the Rhine region. He thought it a new occurrence for diamonds. He believed diamonds to belong to ancient crystalline rocks, although these materials might be brought tip by volcanic agency, and the diamonds remain unaltered. In the volcanic rocks of Auvergne, crystals of sapphire, zircon, and spinel are found; and yet no one supposes that these minerals have been generated by volcanic agency. He had had a conversation with Bertrand de Lom on this subject, who agreed with him that these minerals, being hard and resistant,

Jan 1, 1874

By R. W. Raymond

WISH to call the attention of the Institute to a curious subject, brought to my notice last summer by Mr. Begger, the accomplished metallurgist of the smelting-works of the Boston and Colorado Company at Black Hawk, near Central City, Colorado. At these works, the richest auriferous sulphhrets of Colorado (particularly copper pyrites) are smelted in reverberatories, together with roasted tailings (iron pyrites), and the gold and silver are concentrated into a new, artificial sulphide, or copper matte, containing $1500 and upwards of the precious metals per ton, and this is shipped to Swansea. I will say in passing, that this shipment of an unrefined product, like the similar shipments from Utah and Nevada to San Francisco, Chi¬cago, St. Louis, Newark, New York, and Europe, of crude argentiferous lead or "base bullion," is not a sign of incomplete metallurgy here, but has a sound business reason. The separation of the precious metals in the West would be more expensive, to begin with ; and then it would necessitate the movement of these metals by express, at high rates and risk, to commercial centres or coining mints, while the base metals having no home market, must be shipped and sold at little or no profit. At present, the gold and silver, safely packed, as it were, in the base metals, are transported with safety as ordinary freight; and the base metals probably more than pay cost of shipment and separation. To return to the Black Hawk reverberatories. On a recent occa-

Jan 1, 1873

By Eckley B. Coxe

IN the anthracite coal regions of Pennsylvania the custom has been to sight either at an open light (generally a mine-lamp), or at the string of a plumb-bob. If the station was intended to be a permanent one, a spud, as it is called, that is, a nail resembling a horseshoe nail with a hole in the head, is driven into the timbers over the station, or, if there be no timber, a hole is drilled in the coal or rock roof, into which a wooden plug is driven, which serves to hold the spud. The first operation in making a survey is to lay out the stations, that is, to mark the place where the holes are to be drilled for the plugs or the points on the timbers where the spuds are to be driven in. This should be done before any instrumental work is begun, as much labor can generally be spared, and the use of very short sights can often be avoided, by carefully laying out the stations beforehand. When the stations were laid out, a plumb-bob was hung from the innermost spud, which I will call No. 1, the instrument was put in position at No. 2, by plumbing down and putting a centre-pin under the spud, and then setting up over the centre-pin, and another plumb-bob was suspended from No. 3. If great accuracy was not required, a mine-lamp was set up under the plumb-bobs, at No. 1 and No. 3, and the engineer sighted at them. If great accuracy was required, a lamp or some white surface was held by an assistant behind the strings of the plumb-bobs. To work with any speed by the latter method (i. e., the accurate one), it was necessary for the engineer to have three assistants on whom he could rely even when the chaining was done afterwards; viz.: one to hold the light behind the string at No. 1, one at No. 3, and an assistant at the instrument to hold the light while levelling, reading the in-

Jan 1, 1873

By R. P. Rothwell

AT this our first meeting I beg to call the attention of the members of our Institute to what is certainly a question of the greatest possible importance to the industries we represent; and more particularly to the welfare of the coal and iron trades : I refer to the enormous waste of coal in mining and in its preparation for market, as now practised in our anthracite coal-fields. It is a fact which many of you can certify to, that we are wasting fully one-ha f of all the coal in the veins we are now working, and there are cases, which might be mentioned where this proportion, immense as it is, has been greatly exceeded. The popular belief that our deposits of anthracite coal are "practically inexhaustible," is very far from being founded on facts. On the contrary, supposing the present rate of increase in the production to be maintained, it is probable that a maximum yield for our coal-fields would be attained in about fifteen years ; there are in fact some of our smaller basins where the principal veins are nearly exhausted and the production has already attained its maximum. There are others, again, where the depth attained-and it must be borne in mind that we commenced working at the surface outcrop-moderate though it is (scarcely ever reaching eight hundred feet), has so increased the cost of mining as to imperil the capital invested, and though it requires but little foresight to predict the time when the difficulties of mining will be very considerably increased by reason of the greater depth, greater quantity of water, fire-damp, and other fruitful sources of cost, yet, ignoring these recognized facts, we continue to waste more than one-half of the coal where it is obtained with the least danger, expense, and trouble, that is, near the surface-either above water-level or at a moderate depth below it. The inspection of almost any accurate mine map will satisfy you that, on an average, we leave fully one-third. of the coal in the ground as pillars to support the roof; in some places more than one-third thus remains, while it is very rare that less than one-quarter is left. In almost every case this coal is absolutely lost, for it will very rarely pay to reopen gangways and lay roads to it after that portion of the mine has been abandoned. Is it necessary in all cases to support the roof, and where it is, may not some artificial

Jan 1, 1873

By Edmund C. Pechin

I REGRET that I am unable to present this subject in definite form and detail. All I shall attempt at this meeting is to lay before you some curious facts, the bearings and explanations of which must be reserved for future consideration. I hope before the next meeting to have carried experiments far enough to furnish a more important contribution to the science of iron metallurgy. The Wickersham process consists in the introduction into the molten metal, as it runs from the furnace, of air from the hot blast. Mr. Samuel Wickersham is the originator of the plan, as applied in practice, although Mr. Martien had the idea a long time ago, and, I believe, .went to England about it. But at that time Mr. Bessemer was coming before the public with his invention, which engrossed the attention of iron-masters, and Mr. Martien accomplished nothing. The principal difficulty in our experiments at Dunbar was to get a practicable runner or trough, through which the molten metal should pass, and in which it should be exposed to the action of the blast. The runner we used was ten feet long, and perforated on the sides to permit the entrance of the air-currents. When we used a cast-iron and fire-clay runner, the heat was so great that before we were more than half done with a run, the lower part of the runner was melted, and we had a magnificent Fourth of July display of fireworks until the blast was shut off. We had to abandon fire clay. The runner with which we have had the best success ,is made of wrought-iron tubes, 2 1/2 inches in diameter, attached to a wrought-iron frame, and lined with a mixture of crushed conglomerate (quartz) and a little fire clay to give it cohesion. The wrought-iron shell curves inward over the upper edges, so as to catch and throw back into the current the flying sparks and particles of metal thrown out by ebullition. With this we have been able to run 12 to 14 tons at a heat with great ease. Mr. Wickersham has since prepared this material (pounded quartz) into a shaped brick or tile, with the necessary perforations for the passage of the air, which promises to answer every requirement for steady working. As regards the improvement in the quality of the iron, there seems to be no question. A large number of practical tests were made in

Jan 1, 1873

By Ezio Martino Buselli Cánepa

El programa de remediación de la Bahía de Ite ha superado los compromisos establecidos en el PAMA de Southern Perú Copper Corporation para dicha zona. En este sentido, el presente trabajo describe la aplicación de dicho programa a través de un manejo apropiado del agua para establecer humedales y lagunas. La presencia de sulfatos, óxidos de hierro y la adición de pequeñas cantidades de materia orgánica (estiércol) han creado condiciones apropiadas para la generación interna de alcalinidad y la formación de sulfuros de hierro que posteriormente serán incorporados en los sedimentos, de forma que se genere especies de flora y fauna, como ecosistemas altamente productivos en la zona utilizada.

Jul 31, 2003

By Rony Yupanqui C

El presente trabajo señala el proyecto de remediación de los relaves mineros realizado en la relavera Ticapampa, ubicado en el Distrito de Ticapampa – Huaráz, región Ancash, con el objetivo de remediar los relaves de TICAPAMPA depositados por más de 30 años y que contaminan al río Santa, fuente principal de irrigación del Valle del Callejón de Huaylas. El proyecto comprende la extracción de contaminantes del pasivo ambiental de Ticapampa a través de la flotación de los sulfuros de fierro, y la obtención de un material inerte (con bajo contenido de sulfuros contaminantes) para la fabricación de productos cerámicos por medio de resinas recientemente desarrolladas.

Sep 12, 2011

By Mark L. Matthews

In 1978, Congress enacted Public Law 95-604, the "Uranium Mill Tailings Radiation Control Act of 1978." The Act authorizes the Department of Energy to stabilize and control the tailings from designated inactive uranium mill tailings sites in a safe and environmentally acceptable manner. DOE has established the Uranium Mill Tailings Remedial Actions (UMTRA) Project Office to implement, in cooperation with the affected States, Indian tribes and owners of the sites, remedial actions at the sites. The UMTRA Project Office has initiated efforts to perform remedial actions in accordance with EPA cleanup standards.

Jan 1, 1981

By Robert S. Dalzell, Ernest A. Curth

Following the introduction of shields to the U.S. longwall mining scene and the steady increase in the number of shield faces during recent years, the occurrence of longwall -ground-control -associated accidents has shown a welcome downward trend. But even though the accident experience is favorable, problems exist. New mining systems, however efficient, have run afoul of roof control. Shield faces have suffered extended stoppages because of roof cavities. Therefore, the Bureau of Mines has reviewed foreign remedial techniques to evaluate their potential for domestic application. Such technology includes cribbing, strain absorbent modules (SAM'S), inflatables, wire meshing, chemical rock stabilization, synthetic foams, and monolithic fills.

Jan 1, 1984

By Suzanne R. Hess-Brittelle, Sharon L. Schulz, Tyler J. Quick, Amy F. Ebnet

"Abiquiu Dam is a rolled earth fill dam with impermeable core located on the Rio Chama in New Mexico. Abiquiu has had a history of excessive seepage through the fractured sandstone abutments since water was first impounded in 1963. The foundation was treated with a single row grout curtain in the cutoff trench prior to placement of the embankment. During the 1960’s and 1970’s, the grout curtain was extended 1,000 ft. into both abutments and sections of the foundation beneath the embankment were regrouted. Grouting of the foundation beneath the embankment required drilling through the embankment. Drilling fluid loss or loss of circulation within the impervious core was observed during multiple phases of supplementary grouting and during verification drilling following the 1970’s grouting program. It is likely that the drilling methods employed for these grouting and drilling programs caused hydraulic fracturing of the impervious core. The fluid losses in the embankment may be related to seasonal shutdown layers in the embankment or benches in the abutment foundations. In addition, it is likely that the impervious core was fractured from grout pressures during installation of grout pipe through the embankment.INTRODUCTIONAbiquiu Dam is located on the Rio Chama in New Mexico and consists of a rolled earth fill dam with impermeable core, controlled outlet works, and an uncontrolled rock-cut spillway. The dam was authorized for flood control and sediment retention and was designed as a dry dam, holding flood pools for relatively short durations. The foundation is comprised of Permian and Triassic age, interbedded mudstones and sandstones that were deposited in an active braided stream system. Sandstones are moderately fractured and have variable aperture and infilling. Generally speaking, joints are near vertical. Abiquiu has had a history of excessive seepage through the fractured sandstone abutments since water was first impounded in 1963. The foundation was treated with a single row grout curtain in the cutoff trench prior to placement of the embankment. In 1966-1968, the grout curtain was extended 500-ft into the left abutment and the foundation beneath a 560 ft. section of the embankment was re-grouted. In 1978-1980, the grout curtain was extended 1,000 ft. into the right abutment, an additional 500 ft into the left abutment and the foundation beneath the right 520-ft section of the embankment was re-grouted. The alignments of these grout programs are shown in Figure 1. Grouting of the foundation beneath the embankment required drilling through the embankment. Drilling fluid loss or loss of circulation within the impervious core was observed during both phases of supplementary grouting and during verification drilling following the 1978-80 grouting program. It is likely that the drilling methods employed for these grouting and drilling programs caused hydraulic fracturing of the impervious core. In addition, it is likely that the impervious core was fractured from grout pressures during installation of grout pipe through the embankment. This paper provides a summary of the drilling and grouting methods used during these programs and the potential for damage to the embankment."

Jan 1, 2016

By K. R. Johnejack, R. Quintanar, P. Lapointe

Chino Mines Company has investigated effects from historical mining to sediment along Hanover and Whitewater Creeks. Concentrations of metals were statistically stratified for risk assessment. Stratification by size was more prevalent than by depth, with concentrations higher in the fines. Concentrations with depth were mixed, but overbanks showed more stratification with higher concentrations in the surface. Members of a geomorphic feature type generally were not stratified. However, geomorphic features were stratified by type, with the active channel and bars being the most alike and the overbanks being the most different. Only a few metals showed decreasing concentrations with distance downstream.

Jan 1, 2002

By Arash Khosravifar, Ali N. Ibrahim

"Large areas of Iraq are covered with collapsible soils namely gypsiferous soil which is often used as the foundation soil for structures. In particular, the Mosul Dam foundation is comprised of high contents of gypsiferous soils. Intrusion of water through the foundation soil dissolves gypsum which acts as the binding material between soil particles. This phenomenon results in the formation of collapsible soils which can cause serious damages to the dam structure. The failure of Mosul Dam, with a reservoir as large as 11 billion cubic meter of water, can be catastrophic. In the past, Mosul Dam Authorities have been remediating the soil foundation by injecting cement mortar. This method has been proved not economic; therefore, new, more efficient, methods are desperately needed.This research study focuses on finding practical methods to remediate collapsibility of gypsiferous soils by improving their geotechnical properties. This study presents remediation of collapsible gypsum-rich soil by grouting. Three types of stabilizer materials were used to make the grout; (1) sodium silicate (Na2 O3 Si) which is a well-known chemical soil stabilizer, (2) bentonite slurry, and (3) silicone oil. The purpose for using these stabilizer materials is to provide an impermeable layer (waterproofing coat) around the gypsiferous soil particles and to fill the voids that may occur in the soil as a result of gypsum dissolution when subjected to water.A series of double oedometer (collapse) tests and direct shear tests were carried out on gypsiferous soils before and after remediation by grouting. The results show that the soil compressibility decreases in the grout-treated gypsiferous soil by reducing volumetric strain. Consequently, the potential for collapsibility decreases too. It was also shown that grouting, increases the shear strength of the soil at confining stresses smaller than 250 kPa by increasing the cohesion combined with a slight reduction in the internal friction angle.INTRODUCTIONGrouting is one of the ground improvement techniques which is often used to improve the loose foundation soils. Bruce (2003) provides step-by-step procedures on using grouting techniques for sealing dams and other water reservoirs. Grouting can be classified as permeation grouting, compaction grouting or hydraulic fracturing. Permeation grouting is an effective way to send the grout into the ground without disturbing the soil structure, i.e. free flow of grout into the soil voids where grouting is accomplished by injection of a fluid-like material that is capable of forming a gel and binding the soil particles together. Grout materials may be solution grouts or suspension grouts. The permeation grouting technique is generally used to minimize ground permeability and to control ground water flow, but it can also be used to strengthen and harden the ground (Raman et al., 2012)."

Jan 1, 2017

By Wanchai Teparaksa

Pile deviation generally can happen after installation of driven pile particularly in soft soil layers. In this case study, all 242 diameter 0.8 m spun piles were deviated from 20 to 820 mm. The large deviation was caused by lateral soil movement in the top very soft clay layer of thickness about 23 m. This very soft marine clay is very sensitive and anisotropic having high water contents of over 120% and low undrained shear strength of 5-10 kN/m2. The remedial works were carried out based on theory of load transfer and soil-structure interaction. All deviated piles were rectified and used as the foundation piles with strictly controlled pile load tests. The construction of a nine-storey building was successfully completed founded on the rectified piles and it has been opened for the service for over two years.

Jan 1, 2002

By Sandra M. Stash

An integrated copper production complex includes mining, milling and smelting facilities which are usually at or near a common site, and sized to complement one another in capacity. There may also be an electrolytic retlnery serving the complex, but not always totally dedicated to its production. Mines and mills without co-owned smelters are not usually considered integrated. The first marketable product of an integrated complex is blister, or in some cases electrolytically refined copper. The nature of integrated operation brings together all of the environmental issues associated with copper production, but currently operating and newly planned facilities are required to anticipate these issues and meet stringent regulations. Older complexes, however, may have legacies of 50 or more years of operation unencumbered by current levels of environmental strictures: nevertheless, they must be remediated. Using examples from closure and remediation of the mining and mineral processing facilities in the Upper Clark Fork River Basin of Montana, the authors review some of the problems encountered since CERCLA's1 enactment in 1980, and the solutions to those problems, bearing in mind that not all of the problems and solutions were technical. Much has been written about the mines of Butte -the "Richest Hill on Earth" as it was known in its day and the mills, smelters and refineries they spawned. These facilities comprised an archetype of the integrated copper complex: from ore to metal in facilities serving and depending on one another. Many great stories of technological innovations and business triumphs have been told about Butte and Anaconda's mining history and the place The Anaconda Company occupies in that history. However, relatively little has been written about the final days: 25 years during which the once-great complex was closed, and the remnants of past glories were remediated after nearly a century of operation. This paper offers some insights from the real world affecting similar complexes still operating, and, hopefully, lessons for others just starting down the path to final closure.

Jan 1, 2003

By James Dunn

“The strongest argument of the detractor (of mining)is that the fields are devastated by mining operations ...They argue that the woods and groves are cut down, for there is need of an endless amount of wood for timbers, machines and the smelting of metals. And when the woods and groves are felled, then are exterminated the beasts and birds, very many of which furnish a pleasant and agreeable food for man. Further, when the ores are washed, the water which has been used poisons the brooks and streams, and either destroys the fish or drives them away.” Georgius Agricola, 1556, De Re Metallica, translated by Hoover, 1950. Technical problems associated with the cleanup of historic mines are not new. Nor are they unique to the mining industry or the governmental agencies addressing them. Both face the same issues and challenges of defining the problems, evaluating remediation options and finding the most economic and effective solutions.

Jan 1, 1999

By D. Erik Spiller

Mineral processing technologies are being used in the environmental arena for remediation and secondary recovery. Comminution and/or scrubbing for liberation, coupled with separation of the liberated particles, is known as soil washing. Other metallurgical unit operations have found application in remediation and recycling: size classification, gravity concentration, flotation, magnetic and electrostatic separation, eddy current separation, and liquid/solid separation. This paper presents specific examples of the use of these technologies to clean up contaminated soils and plant residues, and to recycle valuable materials from waste streams.

Jan 1, 1993

By A E. McElnea, M A. Martens

An 18-month project was undertaken to test the effectiveness of controlled daily tidal exchange augmented with hydrated lime treatment of surface waters as an approach for remediating a severe acid sulfate soil disturbance at East Trinity, Cairns, north Queensland. Actual acid sulfate soils were producing hazardous levels of acid and heavy metal contaminants and degrading approximately 720 of the 940 ha East Trinity property and the adjacent foreshores. A government-led research team established a series of research projects with the aim of characterising the site (soils, water, terrain) and testing the effect of the lime-assisted tidal exchange management strategy on soils, water, sediments and biota.

Jan 1, 2003