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By R. F. Pearce

The paper in based on laboratory and pilot plant investigations which led to the development of a series of processes for production of high purity metals from nickel-copper-cobalt mattes of a wide range of composition. The selection of ammonia pressure leaching or acid pressure leaching for various mattes is discussed. This is followed by discussion of various methods for leach solution purification and metal separation. The metals of high purity are produced by reduction with hydrogen from purified solutions. Examples are given of complete flowsheets for a number of mattes. Drawing upon those examples, general principles for the selection of the most suitable treatment process for particular material are outlined. Under certain circumstances, those processes may replace part of the pyrometallurgical treatment and all of the electrolytic refining steps which are customary in the treatment of nickel-copper-cobalt mattes.

Jan 1, 1959

By G. P. Demopoulos

"The recovery and separation of platinum-group metals (PGM) from primary and secondary materials currently attracts a lot of interest due to the high value of the metals and their increasing demand for high-tech applications. Thus, the traditional refining processes are gradually replaced by newer more efficient separation techniques such as solvent extraction and ion exchange. In this paper the classical and modern refining techniques are reviewed and the pertinent solution chemistry dictating proper processing strategies in each case is discussed. The technological advantages of the modern separation methods are emphasized and reference to the recovery of PGM from primary as well as secondary materials is given. INTRODUCTIONDue to their outstanding physicochemical properties, such as catalytic activity, conductivity and corrosion/oxidation resistance, precious metals now find extensive usage outside of the traditional jewellery and investment industries. The increasing use of precious metals in such areas as electronics and catalysis, as well as their increasing high value, has led to a growing interest in their recovery and separation from primary and secondary materials.Quantitatively the demand of platinum metals in the western world by area of application is described in Table I. Platinum and palladium represent 90% of the total demand, Rh and Ru 8% and the remaining is taken by Ir and Os. In terms of value the following were the average prices (US$/oz) of the metals in the second half of 1986: 500 Pt, 125 Pd, 1200 Rh, 650 Os, 400 Ir and 80 Ru. Due to these prices, exploration, mining, reclamation and refining activity were very high in South Africa, the biggest producer of Pt metals in the world, as well as in other areas: United States (Stilwater deposit), Canada (Sudbury, Marathon and Lac des Isles, Ontario; Kenly Lake, Quebec, etc.), Australia, Europe and elsewhere"

Jan 1, 1989

By Harold L. Hinds

The refining of precious metals from steel wool cathoodes is completed by one of two methods: 1) By direct fire smelting or: 2) Acid treatment of the cathodes to dissolve the steel wool and then followed by fire smelting. To further the refining of the cathodes, the Miller Process and the Wohlwill Process are used.

Jan 1, 1981

By H. L. Hinds, L. L. Trautman

The refining of precious metals from steel wool cathodes is completed by direct fire smelting or acid treatment of the cathodes to dissolve the steel wool followed by fire smelting. To further the refining of the cathodes, the Miller process and the Wohlwill process are used.

Jan 1, 1984

Discussion of the paper of DR. L. EDELEANU, presented at the Pittsburgh meeting, October, 1914, and printed in Bulletin No. 93, September, 1914, pp. 2313 to 2332. F. W. BUSHONG,* Pittsburgh, Pa.-This process of extraction is particularly advantageous in the case of Roumanian oil, on account of its high aromatic content. I have prepared a paper, which will appear probably next month in the Journal of Industrial and Engineering Chemistry, describing a series of two-degree fractions of oil from the Nowata field in Oklahoma. I have made extractions with liquid sulphur dioxide in accordance with Dr. Edeleanu's method, and found that the Oklahoma oils, for instance the kerosene fractions, are purified in this way, although the quantity taken out does not at all compare with that taken out of the Roumanian oil. I have made careful analyses of separate fractions, before and after extraction, and they show a very distinct fractional separation-. I like the distinction, brought out by Dr. Day in previous discussions, in regard to oils, rather than oil, and his beautiful illustration of fractionation. Just as fuller's earth, and other clays, will enable us to obtain lower-boiling fractional portions of the oils, and eventually retain a residuum which is hard to get rid of, or to remove, so there is an advantage to be gained by the use of a reagent which begins at the other end by taking out these last constituents first, namely, ozone. I have also analyzed the ozonides and they are derivatives of hydrocarbons very much poorer. in hydrogen than we have heretofore supposed. Similar results have been obtained with Roumanian, Russian, and Italian petroleums. Furthermore, I have prepared ozonides from a fraction of Oklahoma oils, both before and after ex-' traction with liquid sulphur dioxide, and found that the ozonide obtained from the extract is the same as that precipitated out of the original oils. In other words, the residual substance, which the fuller's earth retains, is the one first thrown down by the use of ozone, but it may also be extracted by liquid sulphur dioxide- and be thus separated in apparently unaltered condition. The analysis of this extract corresponds to the formula C15H20, which is surprising, since it is lower in hydrogen content than we have been in the habit of considering among the constituents of our oils. The extract was probably contaminated with other hydro-carbons, but I think it is unquestionable that we must look for hydro-carbons in petroleum which correspond to a formula at least -as low in hydrogen as C15H2o, and possibly even as low as C15H16.

Jan 4, 1915

By L. Edeleanu

Crude petroleum is a mixture of various groups of hydrocarbons and some bodies containing oxygen or sulphur.

Jan 1, 1915

ALTHOUGH the refining period of the heat is generally defined as A starting after the charge has been completely melted, it may more properly be considered as beginning with the first efforts to facilitate the shaping up of the slag and the making of corrective additions for the control of slag or metal composition. Such actions may be initiated during the latter half of the lime boil. The early part of the refining period may, then, in essence overlap the latter part of the melting period. The primary aims of the refining period are to reduce phosphorus and sulphur from the steel bath to levels safely below the maximum contents specified, to eliminate carbon as rapidly as possible and still allow time for proper conditioning of the slag and attainment of the necessary bath temperature, and to deliver the heat ready for tapping or furnace deoxidation, with slag in the proper physical and chemical condition, and with carbon and oxygen contents and the temperature of the steer bath at the proper levels for the composition and grade of steel being produced. The particular conditions that fulfil these aims are distinctly different, depending upon whether the steel is to be finished according to fully-killed, semikilled, or rimming practice and also depending upon the carbon range specified. Regard- less of the type of charging practice employed, the object of the refining period is to produce repeatedly the desired finishing and tapping conditions for the grade of steel being produced. The variations and proportions of raw materials used in the charge may cause some variations in the degree of control required during refining, but not in the method of control. The refining period can therefore be discussed from a viewpoint largely independent of charging and melting practice. SHAPING UP THE SLAG In the first helper's vocabulary, refining practice consists in "shaping up" his heat. This includes elimination of sulphur, phosphorus, and carbon, putting the slag in proper condition, and adjusting bath temperature. Shaping up the slag is a major consideration because

Jan 1, 1944

ALTHOUGH the refining period of the heat is generally defined A as starting after the charge has been completely melted, it may more properly be considered as beginning with the first efforts to facilitate the shaping up of the slag and the making of corrective additions for the control of slag or metal composition. Such actions may be initiated during the latter half of the lime boil. The early part of the refining period may, then, in essence overlap the latter part of the melting period. The primary aims of the refining period are: (1) to reduce phosphorus and sulfur from the steel bath to levels safely below the maximum contents specified; (2) to eliminate carbon to a specified level as rapidly as possible and still allow time for proper conditioning of the slag and attainment of the necessary bath temperature; and (3) to have the heat ready for tapping or furnace deoxidation, with slag in the proper physical and chemical condition, and with carbon and oxygen contents and the temperature of the steel at the proper levels for the composition and grade of steel being produced. The particular conditions that fulfill these aims are distinctly different, depending upon whether the steel is to be finished according to fully killed semikilled, or rimming practice and also depending upon the carbon range specified. Regardless of the type of charging practice employed, the object of the refining period is to produce repeatedly the desired finishing and tapping conditions for the grade of steel being produced. The variations and proportions of raw materials used in the charge may cause some variations in the degree of control required during refining, but not in the method of control. The refining period can therefore be discussed from a viewpoint largely independent of charging and melting practice. SHAPING UP THE SLAG In the first helper's vocabulary, refining practice consists in

Jan 1, 1964

ALTHOUGH the refining period of the heat is generally defined as starting after the charge has been completely melted, it may more properly be considered as beginning with the first efforts to facilitate the shaping up of the slag and the making of corrective additions for the control of slag or metal composition. Such actions may be initiated during the latter half of the lime boil. The early part of the refining period may, then, in essence overlap the latter part of the melting period. The primary aims of the refining period are: (1) to reduce phosphorus and sulfur from the steel bath to levels safely below the maximum contents specified; (2) to eliminate carbon to a specified level as rapidly as possible and still allow time for proper conditioning of the slag and attainment of the necessary bath temperature; and (3) to have the heat ready for tapping or furnace deoxidation, with slag in the proper physical and chemical condition, and with carbon and oxygen contents and the temperature of the steel at the proper levels for the composition and grade of steel being produced. The particular conditions that fulfill these aims are distinctly different, depending upon whether the steel is to be finished according to fully killed. semikilled, or rimming practice and also depending upon the carbon range specified. Regardless of the type of charging practice employed, the object of the refining period is to produce repeatedly the desired finishing and tapping conditions for the grade of steel being produced. The variations and proportions of raw materials used in the charge may cause some variations in the degree of control required during refining, but not in the method of control. The refining period can therefore be discussed from a viewpoint largely independent of charging and melting practice. SHAPING UP THE SLAG In the first helper's vocabulary, refining practice consists in

Jan 1, 1951

By R. H. Duval

"In May 1936, Pamour started producing gold by cyanidation of flotation concentrates, and in 1939 was milling about 1, 600 tons per day.Refining records dating from 1939 show two oil-fired furnaces in use, (Rockwell type 46 11 x 29 11 inside oval shell).Refining time averaged 7. 83 hours during the year 1939, indicating a complete refining shift of about 9. 33 hours. That year appears to be characteristic of the period with regard to time required and results obtained.For that year total fineness (gold + silver) of the bars averaged 940 (approx.), but it frequently dropped below this figure, sometimes far below.Furnace lining life varied widely from three to seven or more months. Sillimanite was the standard lining but Mullfrax 41 was frequently used.For many years refining practice remained practically unchanged, and in 1960 procedure still consisted essentially of mixing a flux(% Composition Borax 41, Silica 11, Soda-Ash 11, Nitre 15, Mn02 22) with cyanidation precipitate in the ratio of l. 2 to l and heating to a medium heat (yellowishred, 2000° F) with a low flame for a long time. Time required was about 10. 5 hours per refining. Results were still much as detailed above.At this time it was decided to revise refining procedure, in an effort to shorten refining time and obtain consistently good bullion fineness."

Jan 1, 1965

By R. D. Lindsay

"Pamour Porcupine Mines, Limited is involved in the mining, milling and primary refining of various gold, gold - copper and refractory gold ores. Pamour operates five mines in the Porcupine Mining District of Ontario, and two 2,550 t/d milling facilities.Both metallurgical facilities use conventional cyanidation technology including zinc cementation for precipitation of gold and silver from solution. The precipitation process, as applied to clarified leach solutions (less than 1 ppm suspended solids) at Pamour is called the Merrill - Crowe process. Precipitates from both milling operations are treated at Pamour's Area Refinery. Schumacher precipitates, unlike Pamour No. 1, require an ''Acid Treatment Stage"" prior to refining to remove the high contained copper. This is accomplished by leaching the precipitates initiallv with sulphuric acid to remove zinc and then with sulphuric acid and manganese dioxide to dissolve copper. Refining procedures after ''Acid Treatment"" are essentially the same for both precipitates.The following considerations highlight the basic principals applied to refining cyanidation precipitates at Pamour, including:"

Jan 1, 1986

By S. Hartman

The Escalante Silver Mine in Southwest Utah produces an average of 71.000 kg (2.3 million troy ounces) of silver dore annually. Precipitates from a cyanide leach circuit are treated by either acid leaching prior to fusion or a direct fusion with nitre. Process development, plant experience, and a comparison of both methods will be discussed. Plant experience from the custom treatment of a gold/silver precipitate containing matte producing elements will also be covered.

Jan 1, 1989

The following paper describes the refining practice for the production of lead, silver and gold at the works of The Broken Hill Associated Smelters Pty. Ltd., Port Pirie, South Australia.The refinery is situated on the wharf frontage and is built parallel with it. The refinery occupies an area of approximately 3380 square yards. (Fig. 8)There are two buildings, one containing the softening and de-silverising sections, measuring 225 ft. x 57t ft., while the other building, which measures 225 ft. x 90 ft. covers the de-zincing, lead moulding, retorting, cupellation, and dore parting sections. (Fig. 1)The retorting, cupellation, and dore parting sections are completely isolated from the rest of the plant by strong small-mesh wire gratings welded to steel uprights. The dore parting plant and generator room are further isolated by a brick wall, built up to the roof. The two main buildings are steel structures, with outer walls and roof of "Robertson" corrugated sheeting; the side and end walls are open for some distance above the ground, and this, coupled with the high roof which is 50 ft. from ground level, ensures the free access of air and light. Conditions are such that operators work in a clear atmosphere.

Jan 1, 1937

By W. Bleloch

In the process described, hydrogen is used to generate high-temperature steam and oxygen in the molten bath. Steel is decarburized to low levels to produce a pearlite-free steel suitable for deep drawing. The process makes use of the favourable thermodynamics in the reactions between steam, carbon, and iron, as well as providing high-temperature oxygen for the decarburizing reaction. The process can easily be incorporated in existing BOF (basic oxygen furnace) plant but can also be contemplated as a greenfield process.

Jan 1, 1987

By Walter Miller

During no similar period in the development of petroleum refining technology has so much progress been made in methods and equipment for the economical utilization of heat. Drastically severe commercial and economical conditions controlling the refining industry during 1927 gave a great impetus to improved efficiency and more economical operation in all departments. I think it is fair to say, however, that more progress has been made in the department of heat utilization than in other branches. I use the word utilization advisedly in the dual sense of better primary generation and application of heat and of saving by recovery methods. It was because of this trend that the subject, "Economical Application of Heat," was made the keynote of the refinery engineering sessions just completed. No new, outstanding elemental discoveries can be claimed for the year along this line. Some of the progress made has been in the development of better furnaces and distilling equipment embodying the more modern principles of boiler practice in obtaining complete combustion of the fuel, low excess air requirements and high transfer rates through the heating surface. Transfer rates of 3000 to 6000 B. t. u. per sq. ft. per hr. were considered good some time ago in the older type of equipment. Today a transfer rate of 25,000 to 35,000 B. t. u. is an actual accomplishment in commercial installations and engineers are talking of the feasibility of 50,000, 75,000, even 100,000 R. t. u. per sq. ft. per hr. Contributing most to bringing this about have been the rational use of the velocity factor on both the oil and firing side of the heating surface, and the study and application of the principles of radiant heat in furnace design. Vapor Heat Economy The principle of heat exchange, especially against oil vapors, has been applied to a greater extent than ever before. The recovery of heat from oil vapors is not new. This was practiced 20 years ago or more in Europe,

Jan 1, 1928

By M. Abdellatif

Keywords: Magnesium, pyrometallurgy, Mintek Samples of crude magnesium produced by the Mintek Thermal Magnesium Process were refined in two stages. The first stage consisted of co-melting of batches of the crude metal and MgCl2-KCl flux (cleaning), followed by stirring at 30 rpm for 30 minutes and settling of the sludge (mixture of molten salt and solid impurities) from the magnesium melt. The operating temperature was 680?730°C. Most of the contained calcium and significant proportions of iron and silicon were transferred into the sludge phase, which left a metal containing, on average, 950 ppm Si, 470 ppm Fe, and 230 ppm Ca. In the second stage, small-scale refining tests were conducted on cleaned samples from the first stage, as well as on crude magnesium. FeCl3 was used as the refining agent. These tests were carried out at 715?760°C with various amounts of the refining agent. The refined metal was suitable for the production of various magnesium alloys, particularly AZ91D.

Jan 1, 2006

By U. Heuer, B. Rathmann

Many mining operations have gained an impressive expertise in trouble shooting and maintenance with their existing fleet over the years. Whether it is an in-house maintenance group or an external service group - most of the systems weak points are well known and can be corrected by maintenance personnel. As some of these issues get more and more serious each year, too much time is lost in unscheduled downtime, often taking hours to be repaired and to find the failure with obsolete diagnostic tools (Fig. 1.). Many of the breakdowns result from failures that cannot be detected in advance. The maintenance system is much more reactive than preventative. The state of the art of mining equipment today uses advanced, efficient, and reliable systems for electrical drives, control and diagnostics of the machines. The demand for highly sophisticated solutions on such mining equipment is well known. Mining operators need to ensure the highest level of productivity, lowest operating costs, least maintenance and highest reliability in a drive system. The paper will introduce you to the state of the art of drives technology for dragline (Fig. 2) and shovel mining equipment (Fig. 3).

Jan 1, 2007

By S Furman, M Caccetta, A Hacket, B McDonald, M A. Wells, D Lau

In 2004, the Western Australian Department of Industry and ResourcesÆ Burrup Rock Art Management Committee commissioned a number of independent scientific studies to evaluate the condition of rock art in the Burrup Peninsula near Karratha (Western Australia). These studies are evaluating the physico-chemical aspects of the effect of environmental modification on the visible appearance of the rock art. Because of the cultural significance of the sites, the research approach has been to employ non-destructive testing strategies and work in the field has progressed with respect for the importance of the area. This paper only reports the spectral mineralogy monitoring at each of the sites to evaluate whether changes in mineralogy are observed on rock surfaces. Reflectance spectroscopy is a non-destructive, in situ materials characterisation technique that provides information about the mineralogy. The minerals detected include haematite, kaolinite, chlorite, goethite, gibbsite and manganese oxides. Current results indicate that the surface mineralogy of the rock art has not changed in the last four years.

Jan 1, 2008

By A Rantala, J Timperi and J Kaartinen, T Maksimainen, O Haavisto

"X-ray fluorescence (XRF) is the most common technique used for online slurry assaying in base metal flotation applications. Typically, assays from feed, concentrate and tailings slurries are used to monitor and control the flotation circuit, with possible additional sampling locations in other main slurry flows inside the circuit. The elemental content detection from the XRF spectrum is relatively straightforward as the spectrum contains element-specific peaks whose height corresponds to the element concentration in the sample. However, centralised XRF analysers measure the elemental concentrations line-by-line, which may increase the sampling interval for an individual line and cause unnecessary response delays, especially in large flotation plants. Reflectance spectroscopy is an emerging technique that can be used to obtain more frequent measurements from slurries. The measurement is based on the mineral-specific absorbance of light in the visible and near-infrared (VNIR) wavelength range. Due to this relatively inexpensive and simple measurement system, it is possible to conduct the measurement simultaneously in several slurry lines. However, the information contained in the VNIR spectra is more difficult to interpret as concentrations of all the minerals in the sample contribute to the measured spectrum and changes in solids content, particle size and mineralogy disturb the elemental content estimation. Therefore, frequent calibration of the measurement is required. This study presents the application of combined reflectance spectrum and XRF measurements for rapid online slurry assaying in a copper-nickel flotation plant. The XRF assays are utilised as calibration samples for the reflectance spectrum measurement, keeping the calibration model up-to-date. The rapid reflectance spectrum analysis is then used to provide an almost continuous estimate of the slurry contents, enabling further improved process monitoring and control.Citation:Haavisto, O, Maksimainen, T, Rantala, A, Timperi, J and Kaartinen, J, 2016. Reflectance Spectroscopy with X-ray Fluorescence for Rapid Online Assaying in a Copper-nickel Flotation Plant, in Proceedings 13th AusIMM Mill Operators’ Conference 2016, pp 85–92 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Oct 10, 2016

By Olli Haavisto, Juha Timperi

"Accurate on-line assays of mineral slurries are the basis for effective operation of flotation circuits. Typically the elemental content measurements are obtained by an X-ray fluorescence (XRF) analyzer, which samples the process lines and performs the analysis concurrently line-by-line. For a more frequent measurement of each slurry line the XRF measurements can be complemented with reflectance spectrum information. In reflectance spectroscopy the absorbance properties of the slurry in the visible and near-infrared wavelength range are analyzed. The advantage of reflectance spectroscopy is that measurements can be obtained quickly and simultaneously from several slurry lines. However, since the shape of the spectrum is only indirectly affected by the slurry elemental contents, frequent calibration of the measurement against the XRF analyzer is necessary. This study elaborates the combination of reflectance spectrum analysis with XRF. Results of laboratory tests for different slurries are presented and the operation of the system in a copper-zinc flotation plant is demonstrated.IntroductionElemental analysis of mineral flotation slurries is the most important factor in evaluating the performance of concentration processes. Timely on-line assays are also used as the basis for controlling the circuits and ensuring that the grade and recovery targets are reached. X-ray fluorescence (XRF) is the dominant technology in on-line elemental slurry analysis, and typically centralized XRF analyzers are used. The advantage of a centralized analyzer is that one measurement probe can be used to acquire the data from several slurry lines. This reduces the overall operating cost of the system when compared to distributed analyzer system design with several measurement probes requiring maintenance and spare parts. Slurry samplers are installed in the interesting process flows and representative sample flows are brought to the analyzer, where the slurry is further sampled and measured consecutively by the XRF analyzer. Due to the centralized structure of the analyzers and consecutively measurement of the sampling lines the sampling interval per slurry line can be relatively long. In larger concentration plants with several sampling lines a typical assay interval is in the range of 10-20 minutes."

Jan 1, 2016