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By M L. Habner, S D. Munro

In a gold CIP/CIL circuit, adding new circuit water to a final tails thickener and then directing the thickener overflow to the head of the circuit significantly reduces the cyanide concentration at the TSF discharge spigot. The new water is used to dilute the final tails. The dilution and recycle of the tails in this manner may have the added benefit of reducing reagent consumption, in some cases to the point where the reagent savings justify the expenditure and Cyanide Code compliance is achieved at no extra cost. Potential circuit configurations and water recycles can be modelled by splicing a flowsheeting and thermodynamics package, such that changes to the composition of the water can be reduced to chemical speciation with a Gibbs free energy minimisation enabling a complete understanding of the circuit water chemistry.

Jan 1, 2007

In a gold CIP/CIL circuit, adding new circuit water to a final tails thickener and then directing the thickener overflow to the head of the circuit significantly reduces the cyanide concentration at the TSF discharge spigot. The new water is used to dilute the final tails. The dilution and recycle of the tails in this manner may have the added benefit of reducing reagent consumption, in some cases to the point where the reagent savings justify the expenditure and Cyanide Code compliance is achieved at no extra cost. Potential circuit configurations and water recycles can be modelled by splicing a flowsheeting and thermodynamics package, such that changes to the composition of the water can be reduced to chemical speciation with a Gibbs free energy minimisation enabling a complete understanding of the circuit water chemistry.

Jan 1, 2007

By N Lima, A Piçarra, L Filippov, I Filippova, M Marques, K Silva

The iron industry produces a considerable amount of tailings per annum, due to its substantial volumes of production. The actual iron ore processing routes require the removal of slimes fractions. In addition to iron oxides and quartz, the iron ore slimes are generally composed of other minerals such as kaolinite and finely dispersed iron hydroxides which impact significantly the performance of reverse cationic flotation. In this study, we propose a two stage processing route that would allow further beneficiation of iron slimes which are not successfully beneficiated, avoiding their disposal as waste. The new amidoamine reagent was tested as a collector in a two-stage route to process two samples of iron ore slimes with d50 close to 10 μm and with high kaolinite content (13 to 20 per cent). The results showed that it was possible to obtain iron concentrate with 66.5 per cent iron and 48.4 per cent mass recovery for a feed containing 48.9 per cent Fe associated with hematite (39 per cent) and goethite (32 per cent). The collector efficiency was improved by mixing with frother for the slimes with higher goethite content of 55 per cent: the concentrate grade was increased from 58.8 per cent to 64.5 per cent with addition of the frother at the expense of reducing operation metallurgical recovery from 87.8 per cent to 75.6 per cent. The efficiency of the process was improved by applying an external energy impact to disperse the fine particles and clean the surface of the minerals. The new amidoamine collector does not require a depressor such as corn starch and may provide the development of new concentration routes for complex ultrafine iron ores. The combination of the amidoamine-based flotation at first stage with high intensity magnetic separation allowed development of optimised two-stage processing routes to valorise the iron ore slimes rejected to the tailings in the actual flotation plant.

Sep 18, 2023

By H. Bhikha

The minerals industry is committed to the principles of sustain-ability. Reducing water consumption is a priority area, especially for regions of water scarcity. This paper presents a systemic optimization of the water balance of the Skorpion Zinc refinery with the aim of reducing water consumption. An Aspen Plus simulation of the process is used. The validity of the simulation is tested by measuring key output variables and comparing results to plant data. A number of water minimization scenarios are investigated, Including unit operation and circuit configuration changes. The scenarios leading to the largest reduction in water consumption are through the full recycle of treated effluent water, which results in water savings of up to 19%. Reducing process water and/or recycling of untreated water is prohibited by the build-up of trace elements, which affect product purity. The Skorpion process already features a highly optimized water balance, with unit operational changes merely resulting in a shift in the water balance. Consequently, the largest area for improvement is through the re-use of effluent water. Keywords Skorpion zinc water usage, process optimization, sustainability.

Jan 1, 2011

By C. Kennedy, S. Jensen

Traditionally, mineral processing plants are designed to achieve the highest recovery of valuable material with limited regard for the cost of managing waste products-both solid and water components. As an industry, we are confronting ever more stringent environmental standards and lower grade deposits requiring more intensive processing. The most profitable processing route can, in fact, lead to costly issues downstream. Issues or risks associated with waste management include water treatment and handling and storage of potentially acid generating material. The capital and operating costs of dealing with these issues are significant and should be considered as a consequence of plant design and optimisation. The authors of this paper are involved with a number of projects where process operation changes offer opportunities to mitigate risks associated with water and waste management. Examples of these changes will be discussed along with the estimated benefits to the value of the project and reduction of long-term environmental risks. Process changes include 1) the application of in-plant water treatment as opposed to dealing with the entire tailings management facility and 2) the potential to reduce metal leaching and acid rock drainage through the preferential liberation of carbonate minerals in the grinding process.

Jan 1, 2014

By Erik Spiller

"Water and cyanide are highly contentious and conflict issues that many gold mining companies encounter worldwide when dealing with local farming communities, industries and cities competing for water as well as non-government and government organizations. Historically, the gold industry has used processes that required minimum amounts of water to treat and recover gold at locations around the world. Examples are dry grinding for refractory gold treatment in the late 1800s and early 1900s and dry blowing in arid/desert regions to recover alluvial gold. In recent times, new dry processing equipment has been developed and include equipment such as air tables and jigs. Researchers have also modified a Knelson concentrator to concentrate gold from dry solids. High pressure grinding rolls (HPGR) with air classifiers are used to treat industrial minerals and pilot trials have shown that the technology can be applied to comminute refractory gold ores ahead of roasting. Dry stacked tailings is being applied on gold mines to reduce overall water consumption This paper will review the available technologies that in combination may be able to substantially reduce the quantity of water used in the processing of gold ores.INTRODUCTION Water makes up most of the world: the planet is 75% water. Some 97.5% is saline water largely in the oceans, so that only 2.5% is fresh water and useful for human needs. The demand for water is driven primarily by population and concomitant economic growth. Overall, some 70% of the water withdrawn from the environment is used in agriculture, 20% by industry, 7% by households and 3% for mining (Brown, 2003: Maupin et al., 2010). Whilst the water needs of the mining industry are minor compared to those of agriculture, an operating mine requires a relatively large quantity of water on a daily basis to carry out operations. Mining activities are often located in remote, arid environments, with limited access to water. There are a multitude of water resources available to the mining industry for its needs. However, much of this water is saline and over the last two decades there has been a continual decline in water quality (i.e. salinity has increased). In today‘s world, there are enormous internal and external pressures to reduce water consumption at a mine, and/or alternatively use water not considered a resource by the local community. Strategies to meet these objectives can be achieved by implementing good water management practices, by recycling process water, reducing water losses by evaporation and seepage (i.e. by increasing and improving dewatering practices) and employing new technologies such as dry stacking and dry processing (Dunne, 2010)."

Jan 1, 2017

By Graeme Jameson

"In current flotation circuits it is customary to grind the whole of the mill feed to an initial size, which is determined by the liberation characteristics of the ore, and the ability of the flotation machines to float the fully liberated particles. Usually, the product of the primary mill will be ground further in a ball mill, to improve the liberation of the values and hence the product grade, before passing to rougher flotation cells. The final grind size is ore-dependent, and is a balance of factors including the relation between surface liberation and grind size, the grain size of the valuable particles within the host rock, and the feed grade. The P80 for the feed to flotation may be as high as 300 µm for free-milling copper ores, and as low as 53 µm for finely disseminated complex ores. The grinding of the feed ore requires considerable input of energy. The rate of replacement of wear components such as mill liners and media, is proportional to the energy input. The costs of these two factors - energy and wear - are usually comparable and together they form the major part of the running costs of a concentrator, and indeed, of the whole mining operation. The energy required increases as the final grind size decreases. This talk will focus on the reduction of milling costs that could be achieved, using a fluidized bed flotation technology that can give high recoveries at coarse particle sizes. A number of different circuit designs will be presented, using the new technology. Calculations show that reductions in the running costs of a mine and associated concentrator of the order of ten to twenty percent could be achieved."

Jan 1, 2014

By J. P. Rider

Average production from longwall mining operations in the United States has risen from approximately 800 tons per shift in 1980 to over 4,600 metric tons per shift in 1999. Such a large increase in production has the potential to generate significantly more dust. Previous NIOSH research has shown that, on average, respirable dust levels generated by the shearer accounts for 50% of the airborne dust generated during longwall mining. Ventilating air and water are primary controls being used in an effort to reduce longwall dust levels. Longwall operators are applying more air and water than ever before and have expressed concern over reaching maximum practical limits for these controls. Full-scale laboratory tests are being conducted to evaluate the impact on shearer-generated dust levels for changes in face air velocity, water quantity at the shearer, water spray pressure, spray system design, mining height and cutting direction. Results of this research should identify the most appropriate control levels for various operating conditions. In addition, general recommended dust control practices for longwall mining will be discussed. KEYWORDS Longwall, coal dust

Apr 1, 1975

By H. J. Le Roux, W. B. Drummond

1. INTRODUCTION We have a moral responsibility towards the world to reduce the harmful deposits we emit into the environment arising from beneficiation technologies. Industry has not willingly spent money to limit these emissions because it affected their profit margin with the end result of emitting harmful elements into the environment. Governments have thus rightly stepped in and enforced systematic reduction of these emissions through legislation. In the past beneficiation of sulphur bearing ores was typically done through hydro-metallurgical concentration, smelting, followed by Sulphur removal by converting processes like the Pierce Smith converter. The latter two processes emitted substantial quantities of Sulphur into the atmosphere. Spiralling costs and legislation have resulted in the quest to develop more efficient and environmentally friendly processes to achieve the same end results. New hydro-metallurgical processes like the ActiVox process has completely eliminated the pyro-metallurgical processes. Kansanshi are also operating a similar process. It however elicits other ground water and spillage pollution hazards and problems of it?s own. Various improvements has also been made to the pyro-metallurgical stages, examples being combined smelting and converting with the Noranda reactor, the Codelco CMT furnace, one step flash smelting/converting or the Mitsubishi continuous smelting, converting and slag cleaning process. The new converting processes are also normally enhanced using oxygen leading to higher SO2 gas strength with only a marginal increase in off-gas volume. These processes have led to better efficiencies and a more controlled environment that reduces pollution, but does not eliminate it completely. The fact that there are still more than 70 existing Pierce Smith converter plants throughout the world that needs to be replaced or upgraded at tremendous capital cost, means that we will have the environmental problems for some time to come. The need thus exists to cost effectively get these existing plants into a state where they meet the new environmental regulations, community and safety requirements. This paper will concentrate on just one aspect of this quest, i.e. reduction/removal of off-gasses emanating from the converting of non ferrous sulphur mattes to achieve higher or specialised grades of refined metals.

Jan 1, 2005

By R. Khanna, M. Dubikova

A variety of carbonaceous reducing materials are being used for the production of ferroalloys. Reductant materials include not just carbons such as coke, coal, char but also bio-carbons in form of charcoal produced from different types of wood. This paper discusses critical properties and reactions of carbonaceous materials and their significance in dictating reductant performance. Main considerations include among others, gasification of reductant, dissolution of carbon into molten metal, and direct reduction of slag by solid carbon. These are discussed in relation to material properties such as structural order, mineral matter content, composition, physical characteristics etc. A brief review of both conventional and novel approaches towards characterisation of carbonaceous materials has been included. Due to complexity and heterogeneity of carbonaceous reducing materials and a wide range of process requirements, the selection of the most appropriate reducing agent will depend on a number of considerations such as the availability of raw material and associated costs, product and process requirements and environmental aspects of waste gas emissions.

Jan 1, 2004

By J. C. Nigro

The potential use of prereduced pellets in the burden of the blast furnace continues to be a topic of interest. Several excellent papers have been written describing the theoretical and experimental rewards. (1) (2) (3) (4) (5) (6) (7) (8) (9) Significant increases in iron output and substantial savings in coke consumption are major advantages over conventional iron oxide pellets. The savings are especially important in areas where good coking coal is at a premium. Lower handling and transportation costs may also be factors favoring prereduction. When considering the overall cost of making and smelting prereduced materials the optimum metallization level becomes significant. An analysis by Agarwal and Pratt of the thermodynamic aspects of blast furnace operation with all prereduced pellets shows that the criteria controlling coke consumption depends upon the degree of reduction and upon the percentage of oxygen (present as FeO) removed by solution loss.(8) The authors state that although the chances of obtaining large fuel savings are greatly improved when metallization is high, reduction to the highest degree, which is costly, may not result in the lowest energy requirement per ton of hot metal; thus, over reduction could possibly result in wasted energy in the blast furnace.

Jan 1, 1968

The typical reactions which the reductants undergo during ferroalloy production are reviewed, and identified as reaction with CO2 and with SiO, and dissolution in metal. Available reactivity tests for these three reactions are reviewed. It is proposed that it is worthwhile considering dissolution kinetics as a reactivity parameter. Greater crystallinity of the reductant decreases CO2 and SiO reactivity, but increases dissolution rates.

Jan 1, 2002

By Prakash C. Kapur

A principal first order and a minor summation term contribute to the solution of the discretized batch grinding equation when formulated in cumulative retained mode. Depending on the interrelationships between the selection and breakage parameters, the minor term may be advantageously modified in a number of ways. The reduced grinding equations thus obtained are solved by iterations to give relatively simple solutions which are tested against experimental data. The implications and advantages of the reduced grinding equations are briefly discussed.

Jan 1, 1969

By Norman F. Schulz

Representative sample s of typical manganiferous iron ores from the Cuyuna Range, Minnesota, were reduced to the metallic iron state at temperatures just short of fusion with an excess of coke in the manner prescribed by the R-N Direct Reduction Process. The magnetic separation characteristics of the reduced ores were determined at several grinds by means of the Davis magnetic tube concentrator. The efficiency of metallic iron concentration by magnetic separation was a direct function of the degree of metallization of the ore sample and of the degree of liberation attained in grinding. Some improvement of liberation characteristics was observed if a small amount of sodium chloride was present in the ore during reduction. Despite the extremely fine -grained structure of the crude ores, iron concentrates containing more than 90% Fe at iron unit recoveries of 90% or more were obtained from well-metallized samples of three of the four ores tested. The rejection of manganese to the tailings corresponding to such separations varied from 80 to 95%.

Jan 1, 1967

By R Higashi, D Maruoka, T Murakami, Y Iwami

The ironmaking industry consumes a large amount of fossil fuel derived carbon as heat source, reducing agent of iron ores and carburising agent of reduced iron. Although the demand for drastic decrease of carbon dioxide emission, carbon is an essential element for smelting process of molten iron. The carbon recycling ironmaking process by circulating CO has been already proposed to achieve carbon neutrality. However, the production of molten hot metal is not considered in this process because sufficient amount of carbon does not dissolve in reduced iron by CO. Therefore, our group has suggested a new carbon recycling ironmaking process which can produce hot metal. In this process, free carbon and iron carbides produced by carbon deposition reaction using metallic iron as a catalyst are used. It is known that only Fe3C is obtained as iron carbide by using CO gas, however, Fe5C2 is also produced by adding H2 gas. The composite agglomerated with these carbonaceous materials and fine iron ore (Deposited Carbon-Iron oxide Composite: DCIC) is reduced and melted in a furnace. It is reported that Fe3C in DCIC accelerates the reduction reaction and melting of the composite. In this study, the effects of iron carbides and free carbon on the melting behaviour of DCIC are investigated. Fe3C, Fe5C2 and free carbon were produced by vapour deposition using porous iron whiskers and CO-CO2-H2 gas. These were agglomerated with hematite reagent at a certain ratio to prepare DCIC samples with and without Fe5C2. The samples were heated up to 1300°C in inert atmosphere. The DCIC containing Fe5C2 completely melted and iron nuggets were obtained after the experiment. This behaviour was not observed in the composite without Fe5C2. This indicates that using Fe5C2 is more preferable than Fe3C for molten iron production using DCIC.

Jun 19, 2024

By Y. S. Sun, P. Gao, Y. F. Li, J. W. Yu

"Oolitic hematite ore is one of the most refractory iron ores in the world. It is not feasible to separate iron minerals from raw ore by conventional mineral processing methods. In recent years, a new technology called coal-based reduction followed by magnetic separation has been employed to produce metallic iron powder from oolitic hematite ore effectively. In order to find the nucleation mechanism, a thermodynamic analysis of the carbothermic reduction of oolitic hematite ore was conducted by the HSC 6.0 thermochemical software. The phase transition and microstructure changes during the coal-based reduction were also investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). The results showed that the iron oxides in the oolitic ore were reduced to metallic iron following the route of Fe2O3–Fe3O4–FeO–Fe in reduction process. The reduction reactions preferentially occur in the high activity regions to form a higher concentration of Fe elements, and then more supersaturated Fe separated out to form new phase nuclei. Under the action of homo-aggregation and principle of minimum free energy, the iron cores continuously absorbed migratory Fe around and grew into quasi-spherical iron particles embedded in slag phase. INTRODUCTION With the rapid increase of steel industry, premium grade iron ore in China has been gradually exhausted, and its supply has become bottleneck for the development of iron and steel industry (Guo et al., 2015). Therefore, it is urgent to exploit the refractory iron ores, such as oolitic hematite ore. Oolitic hematite ore is widely distributes in France, Germany, America, Canada, Pakistan, China, and among other countries (Maynard and Van Houten, 2004; Li et al., 2011). In China, the explored reserve of oolitic hematite ore is 3.72 billion tons, which accounts for approximately 1/9 of total iron ore resources of China (Gao et al, 2016). Oolitic hematite ore possesses complex composition,"

Jan 1, 2018

By C. R. Kuzell

GEOGRAPHICAILY the industry of reducing and refining of copper continued to migrate from the .United States during 1931. While this country is losing the predominant position of its copper industry, our engineers still enjoy their pre-eminent position as leaders in the design and operation of the new plants being brought into production in the four quarters of the globe. Progress in the art, as indicated by the construction of the recently completed works, has not been revolutionary. Standard methods have been followed, augmented by novel features in flow-sheets demanded by the results of progress in the art of ore-dressing, and by reason of problems incidental to the peculiarities of the new ores being treated. Design and construction progress has likewise been orderly and without radical departure from less recent practice; new features in primary and secondary equipment being logical developments to provide for special conditions to keep abreast of improve¬ments in accessory apparatus. The new plants are being rapidly brought in without hazardous novelties and for the purpose of yielding the principal ingredient, copper, in as large a volume as it will he possible to market; the old United States procedure. In the meantime the domestic plants are shut down or operating at a very low capacity, threatened with untimely demise unless the metallurgist can extract and develop other valuable products from the ores. International agreements .and tariff protection may be a temporary reviving stimulant, but for many mines the days of profit will be numbered unless the ores can be made to yield as values the ingredients now being discarded. Invisible progress in this direction has been made during the past year, and it is to he hoped that time will prove that the outstanding progress of 1931 was in the development of processes for the ultimate recovery of by-products from copper ores, perhaps even relegating the value of the copper yield to secondary importance.

Jan 1, 1932

By AIME AIME

STEADY advance has been made in the art of lead smelting and refining during the year. The bringing of natural gas to the Salt Lake valley has led to its adaptation to lead smelting operations. The Tooele plant of the Anaconda Copper Mining Co. has put into practice the high blast pressure and constant volume for lead blast furnaces, which we understand was first advanced by John F. Austin. It would appear that within limits, capacity is nearly proportional to the volume of air. If the charge is dense, a constant pressure, as in the old practice. did not get much air through the charge and the furnace slowed up. The constant volume idea makes the charge smelt at the same rate as if the charge were porous. The cost of a little additional power insures capacity operation at all times.

Jan 1, 1932

THE progress in lead smelting practice in the United States during 1930 has been along previously defined lines. Since most of the material treated is high-grade concentrate relatively high in zinc, practically all the plants have been forced to adopt double sintering. This generally results in there being' no matte fall, and most of the copper in the charge is recovered in the furnace dross. The furnace dross is . smelted with. scrap iron and flux .in small reverberatories, giving a shipping matte or speiss high in copper and low in lead. Details of this reverberatory. furnace practice vary at the different plants. There is a decided tendency toward moreintensive filtration of blast- furnace and sinter fume. Bag capacity has been in- creased by using higher pressures and more frequent shaking.

Jan 1, 1931

By Zhucheng Huang, Lingyun Yi, Bin Chai, Tao Jiang

"A high iron content manganese ore was reduced at 900~1200°C and followed by a magnetic separation process. SEM and EDS analyzes were employed to examine the transformation of microstructure and phase in reduced sample and the mechanism was revealed. Results showed that elements enriched during reduction. Iron existed in the metal iron phase and most of oxygen formed compound with manganese. Consequently a clear distinguish between iron phase and manganese minerals formed, which was beneficial to the separation of iron and manganese. But the iron phase can not be monomer dissociation in grinding process and manganese compounds turned into magnetic product as package and mechanic inclusion due to the isomorphism of iron and manganese and the small particle size. And MnO could be found partially in iron phase, which hindered the further separation of manganese and iron.IntroductionManganese is widely used in industry. The amount of manganese used in steel industry is very huge and 90% manganese is used in steel industry. Manganese ore resources are rich in China, yet with fewer rich ore but more low-grade ore which accounts for 93.6% and fine refractory ore. The constitution of the ore is very complex and more than 73% of all the manganese ore contains iron[l,2]. With the increasing of consumption of steel, the demand for manganese is becoming larger and larger and the imported ore accounts for more than 50%. Therefore, how to use the manganese ore efficiently has very significant meaning. The main method is manganese residual, which is simple and stable. However, the development of the method is limited by the quality of manganese ore, the huge amount of manganese residual, the technology of blast furnace process and economics[3,4]. Chemical benefication which may pollute environment and is difficult to recover iron is still being researched[5,6]. The paper investigated the process in which anthracite coal was the reducing agent for coal-based direct reduction and magnetic separation of the ore, and SEM with EDS measurements were employed to examine the transformation of phase in reduced sample and the mechanism was revealed[7,8]."

Jan 1, 2013