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By I. P. Barbosa, P. S. M. Soares, I. O. C. Masson

"Permanent magnets have been applied extensively to several electronic products such as printers, TV sets, microphones, microcomputers and headphones, presently manufactured in large scale by industrial economies. Sm-Co alloys represent about 20% of the world market for permanent magnets and their industrial processors generate 20-30% of magnetic scraps which can be recycled. This paper discusses a process route to recycle SmCo5 using acid treatment, solvent extraction of Sm and electrowinning of Co. The results confirm the feasibility of the alternative proposed. Basic operational variables are suggested as guidelines to design a plant for recycling magnetic scraps.The use of hydrometallurgical processes to recycle scraps from the industry of permanent magnets has been suggested in some recent papers related to recycling of metallic alloys [ 1 ]. These research efforts might be understood as a worldwide tendency towards the development of self sustainable metallurgical processes which mean the reduction of environmental impacts.CETEM -Center for Mineral Technology leads in Brazil several research programs concerning recycling and treatment of industrial residues. The work on samarium purification and concentration by solvent extraction, producing also a solution of cobalt sulfate as partially reported here is one of these programs. Previous results related to the sulfuric acid digestion of SmCo5 are presented somewhere else [2]"

Jan 1, 1997

By Elif Emil-Kaya, Bernd Friedrich, Merve Papakci

Samarium (Sm), one of the rare earth elements (REEs), and cobalt (Co) are used in the production of SmCo permanent magnets, which have excellent temperature stability, corrosion resistance and oxidation resistance. Of the two types of SmCo magnets, one contains a high amount of iron, approximately 15.2 percent. This paper focuses on the recycling of iron (Fe)-bearing SmCo. In this study, an oxidative leaching process with nitric acid was developed to eliminate iron through in situ hydrolysis and to dissolve REEs and Co. The influence of experimental conditions on the formation of an amorphous iron compound through the hydrolysis of Fe3+ in a nitric acid environment was thoroughly examined based on a Taguchi orthogonal array. The optimal parameters for oxidative leaching were determined to be an acid concentration of 3 mol/L, a solid-to-liquid ratio of 1/10, and a process temperature of 60 °C.

Jul 1, 2024

By Bernd Friedrich, Elif Emil‑Kaya, Merve Papakci

In the production of SmCo permanent magnets with excellent temperature stability, corrosion resistance, and oxidation resistance, samarium (Sm), one of the rare earth elements (REEs), and cobalt (Co) are employed. Cobalt (Co) is a crucial component in tool materials, nickel-based alloys, tablet and smartphone batteries, and electric car batteries. REEs and Co have been listed as critical raw materials by the European Union Commission for many years. Due to the ever-growing demand for Co and REEs in technological applications, the recovery of these elements from secondary sources has garnered significant interest. There are two types of SmCo magnets, one of which contains a high amount of iron, approximately 15.2%. This paper focuses on the recycling of Fe-bearing SmCo. In this study, an oxidative leaching process with nitric acid was developed to eliminate iron through in situ hydrolysis and to dissolve REEs and Co. The influence of experimental conditions on the formation of an amorphous iron compound through the hydrolysis of Fe3+ in a nitric acid environment was thoroughly examined based on a Taguchi orthogonal array. The optimal parameters for oxidative leaching were determined to be an acid concentration of 3 mol/L, a solid-to-liquid ratio of 1/10, and a process temperature of 60 °C.

Feb 15, 2024

By C. Takano

The integrated iron and steelmaking industry generates large amounts and many types of solid dusts and sludge, at different phases of the production. Within these are: sludge of the Blast Furnace; coke fines; fine and coarse fractions from oxygen converters; sludge from water treatment at rolling mill unit; and others. In this paper the above dusts and sludge were physically and chemically characterized. The obtained results allowed defining self-reducing pellets using these materials. The high temperature behavior of the pellets were evaluated. Good results, with no decrepitation and swelling, and high yield of reduction, show that it is feasible to recycle them, as self-reducing pellets, in oxygen steelmaking converter.

Jan 1, 2001

By F. Baerhold

Recycling of hydrochloric acid from the pickling of mild steel using pyrohydrolysis is a state-of-the-art technology. Recent developments have focused on the production of a high value iron oxide by-product, where the chemical purity and physical properties are the main issues. New processing routes, especially for TiO2 and Ni production, use leaching operations with hydrochloric acid. The feasibility of those processes depends on the availability of an economic and reliable process for the recovery of the acid. Depending on the level and type of impurities and the required specification of the by-product, pyrohydrolysis in a fluid bed or in a spray roast reactor can be the ideal solution. In stainless steel annealing and pickling lines, a mixture of nitric and hydrofluoric acids is used to remove the scale from the surface after heat treatment. Nitrate emissions from the pickling and the rinsing processes have to be avoided because of more stringent environmental regulations. An annealing and pickling line that is totally wastewater-free was developed, where not only the nitric/hydrofluoric acid but also the rinse water, is completely recycled. New developments to increase the HNO3-recovery rate and to obtain a metal oxide by-product that is easier to recycle are presented.

Jan 1, 2006

By F. Ferella

In this paper several leaching tests were per-formed to optimize the leaching section of a hydrometallurgical process for the recycling of alkaline and zinc-carbon batteries. Zinc and manganese oxides were dissolved by an acidic-reductive leaching using sulphuric acid and oxalic acid as reductant. Leaching tests were developed according to a full factorial design. The operational variables were pulp percentage, sulphuric acid concentration, temperature and oxalic acid concentration. Additional tests were performed to evaluate the precipitation rate of Mn and Zn oxalates. Finally a hydrometallurgical process were proposed for the recycling of alkaline and zinc-carbon batteries, in which Zn and MnO2 are recovered from purified solution by electrowinning: Zn is recovered as metallic compound, while Mn can be recovered as electrolytic manganese dioxide (EMD), but recovery of further manganese compounds is possible with simple process changes.

Jan 1, 2006

By S. k. Kim, H. B. Trinh, R. R. Srivastava

"Spent auto-catalyst is a promising secondary resource of platinum group metals (PGMs), which are being extensively used in automobiles catalytic converters to control the hazardous gaseous emissions (CO, NOx and hydrocarbons). Several pyro or hydrometallurgical routes has been employed to recover PGMs from such spent materials but there is no proper process for recovering the other constituents metals. Therefore, it causes the loss of other major constituents like, Al and Mg along with rare earth metal Ce. In the present study, we investigate the dissolution of Al and Mg using sodium hydroxide (NaOH) roasting followed by a sulfuric acid (H2SO4) leaching; thereby concentrating the PGMs and Ce in leached residues. The effect of roasting temperature, time and amount of NaOH were varied. Subsequently, the dissolution behavior of metals in H2SO4 as a function of acid concentration was investigated from the roasted samples. At an optimal condition for roasting at 600°C with 1:1 NaOH-to-catalyst ratio and 60 min duration, the maximum of Al and Mg were dissolved in 1 M H2SO4 solution at ambient temperature (~25°C). Thus obtained leached residues containing enriched PGMs and Ce content can be treated separately for the recovery of these high-value metals.INTRODUCTION Spent auto-catalyst has been considered as a potential resource for recovering the platinum group metals (PGMs) (Jha et al., 2013). The commonly used auto-catalyst is made of cordierite (2MgO.2Al2O3.5SiO2) in which the chloro complexes of PGMs are impregnated onto the surfaces of porous washcoat of alumina substrate (Aberasturi et al., 2011). The average concentration of PGMs in ore are 2-4 g/ton for Pt, 7-2 g/ton for Pd and 0.2-0.5 g/ton for Rh, whereas, an individual catalytic converter weighing about 1 - 2 kg contains on average 1.56 g Pt, 0.62 g Pd and 0.156 g Rh (Upadhyay et al., 2013). Moreover, recovery of PGMs from spent auto-catalyst offers other advantages like, simple process, low cost and less pollution, as compared to recovery from primary resources (Dong et al., 2015).Therefore, technologies to recover PGMs from spent auto-catalyst has become attractive in the recent past and their recycling contribution has been accounted for 35% Pt, 26% Pd and 36% Rh of the quantity consumed in the production of auto-catalysts (Johnson Matthey, 2016)."

Jan 1, 2017

By M. Foguenne, A. van Lierde, P. Henry

Leaching experiments were carried out on a spent catalyst sample with a honeycomb structure, containing 47.5% Ti, 5.8% Mo, 2.7% Si, 2 035 ppm As, 52 ppm Pb and 8.8 ppm Hg. More than 93% of the Mo and As was removed by direct alkaline leaching after grinding to 80% -36 micrometres. The residue contained 0.3% Mo and 60 ppm As. To obtain a TiO2 matrix with 30 ppm As, acid leaching at controlled pH with 90 kg/t Al scrap was followed by oxidising alkaline leaching. Treatment of the direct alkaline leach solution or of the mixed solutions from the two-stage process involved two successive operations: purification by neutralisation with Al(OH)3 addition to raise the Al concentration to 4 g/l, and ion exchange on Amberlite IRA 94 S resin. Whatever the type of solution treated, elution with 200 g/l NH4OH solution gave an eluate of very high purity containing 164 g/l Mo, less than 70 mg/l V and less than 2 mg/l As

Jun 19, 1905

By Jitka Jandová

A laboratory process based on simple and environmental friendly operation, aimed at recycling of spent Li/MnO2 batteries, is described in this study. This process involves roasting Li/MnO2 batteries in a vacuum furnace at 650°C, followed by selective leaching Li2CO3 from calcined electrode material in distilled water at ambient temperature and controlled crystallization of pure Li2CO3.

Jan 1, 2006

By Carlos A. Nogueira

Spent Ni-Cd batteries contain in the electrode materials heavy metals like Ni, Cd and Co, which must be recycled due to environmental problems. Pyrometallurgy is normally used for recycling these end-of-life products, but alternative processes by hydrometallurgy, integrating also physical operations, can be used. Hydrometallurgy seems to be useful, because metals can be efficiently recuperated in chemical forms with commercial value. The economical viability of this recycling process can be improved increasing the treatment capacity, through the application to different types of residues with similar characteristics like Ni-MH and domestic batteries, or other residues containing Ni/Co, like sludges, dusts or spent catalysts. Spent Ni-Cd batteries were first physically processed using shredding and wet sieving operations. Best results were achieved using an output of 6 mm in the shredder and 1.4-2 mm in the physical separation by wet sieving, resulting a fine fraction containing 70% of the initial electrode material and only 6% of the initial scrap. The acid leaching of the obtained material in the previous operation was studied, being the parameters like: temperature, H2SO4 concentration and the liquid/solid ratio (L/S) optimized. The values attributed to the factors which concerned the best results obtained on the leaching process were mainly influenced by Ni recovery. In opposition, Co and Cd were easily leached in a wide range of conditions. To attain an overall recovery, with minimum costs, of the three metals, the values of T~100ºC, [H2SO4]=2.3-2.7 M and L/S=8-10 L/kg were considered the most appropriate.

Jan 1, 2006

By Joner Oliveira Alves

The aim of this work was to study the use of steelmaking slag as raw material to the production of rock wool and glass wool. Firstly, the chemical composition of the slag was analyzed. These results were used to infer the amount of additives to assemble the charge for the experiments. A laboratory-scale electric furnace was used to melt the mixtures used as charge. The melt material were turned into a water filled recipient, this process was performed in order to impose a fast freezing that is a characteristic of mineral wool production. Finally, with the rest of the melt material it was performed the Herty Viscosity Test. Samples of the produced material were characterized by different analyses. The results found in this research may lead to a technological innovation, because they indicate that the use of steelmaking slag to produce rock wool and glass wool is possible.

Jan 1, 2009

By Nathália M. Campelo, Alexandre P. Umpierre, Fabricio Machado

"The present work illustrates the reuse of macoporous anion exchange resins (employed for decolorization of solutions of organic substances such as sugar syrup and fruit juice concentrates in the soft-drink and beverages industries), based on crosslinked styrene-divinyl benzene copolymer (Sty-DVB) to the production of polymeric materials. Micro-sized particles of polystyrene and poly(styrene-ethyl acrylate) were obtained by mass-suspension sequential polymerization process. The proposed experimental technique was able to perform proper dispersion of the Sty-DVB in the thermoplastic matrix of polystyrene. The final material showed good thermal stability, showing degradation profile similar to that observed for the pure polystyrene. It was also noticed that polymer particles with spherical morphology can be obtained. In addition, the incorporation of ethyl acrylate monomer into the polystyrene chains minimizes the undesirable effect of fracture in polymeric particles, improving the mechanical and end-use properties of the final polymeric composite.IntroductionIn face of the industrial development, the development of techniques that are safer and less aggressive to the environment has become one of the main challenges in the industrial field. In this scenario, processes more efficient in terms of energy and raw materials can be regarded as an important requirement to minimize the production of waste. The reuse of waste becomes an attractive alternative for most industries engaged with sustainable and economic development.In this context, both the primary and the secondary mechanical recycling are potentially attractive because they allow for reuse of polymeric waste (post-industrial or post-consumer) as a source of raw material in the supply chain by using traditional methods of processing, so that the final materials can exhibit characteristics similar or superior to those observed in the virgins polymeric materials, considered as a starting product in the process of reuse of plastics [1-3]."

Jan 1, 2012

By Axel Hoppe

Although Tantalum is not usually regarded as a precious metal, its pricing structure is very similar to that of Silver. Different from precious metals, Tantalum has only industrial applications and its use is about 1000 metric tons per year. The intrinsic value of Tantalum already in .the past was a driving force for its recycling. Based on these facts the Tantalum industry world-wide is approaching the closed-loop concept of its recycling. A detailed material flow of Tantalum processing as well as recovery of residues and used products will be discussed.

Jan 1, 1995

By A. N. Aposhian

The electronics industry generates tin/lead bearing by-products that can be recycled for their metal value. This paper will cover the processes used to recycle these tin/lead bearing byproducts from the plating, circuit-board fabrication and assembly industries. Though these processes are well known to the companies who do the recycling, few outside the industry including the generators of the by-products, understand the processes or needs of the industry. This paper will give a broad overview of these processes, and describe the services provided by this industry. The paper will also touch upon the future of the recycling industry, including the legislative and environmental push for the elimination of lead from electronics.

Jan 1, 2000

By Nicola Baldo, Marco Pasetto

"Recycling of tyre rubber in the road pavement, may be one of the best way to reduce waste tires in large quantities and, at the same time, improve some engineering properties of asphalt mixtures. The paper discusses the results of an experimental study, developed in order to analyse the potentialities of crumb rubber from road tyres in bituminous mixtures, using the dry process. Two types of porous asphalt mixtures and reference mixes without rubber were formulated by the traditional Marshall methodology, and mechanically evaluated by means of the Indirect Tensile Stiffness Modulus test, the Creep test (with confinement), and the Indirect Tensile Fatigue Test. Results of this study indicate that the tyre rubber has a positive influence on the performance characteristics, depending also on the grading and volumetric properties of the mix being studied: an interesting increase of the fatigue life, a better stiffness behaviour at lower temperatures and a bigger permanent deformation resistance at high temperatures are guaranteed. Introduction Recycling the rubber from used tyres, in the construction of road pavement layers, is potentially one of the more interesting and advantageous solutions from both the technical and environmental points of view, in order to reduce the total amount of car and lorry tyres to dispose. In road-building techniques, a technology, termed “wet”, for modifying bituminous binders with crumb rubber has by now become well consolidated. There have been numerous scientific studies conducted on this technology and its applications, particularly in the United States, where it has been adopted and codified in specific technical regulations (ASTM D-6114). If the wet process can be considered amply tested, the same cannot be said for a second technology, termed “dry”, which deserves careful study to evaluate its suitability and advantages. In “dry” processes, the rubber is usually used as a partial substitute of aggregate of equivalent grading and mixed with bitumen after integrating the crumb rubber in the lithic skeleton."

Jan 1, 2008

By Rod L. Norfleet

Cemented tungsten carbides are a sintered powder - metallurgical product essential to modern industry. Because of their moderate unit price and our dependence upon foreign sources for the component raw materials, a growing recycling industry has developed in the United States. There are two basic approaches taken to recycling cemented carbides; those which leave constituting materials unaltered or direct-reuse and those which separate the constitutes back to the raw components. To separate the carbides back to their raw components usually requires expensive chemical processing and is thus confined to the lower value materials such as grinding sludges. The direct-reuse methods recycle cemented carbides back to an intermediate level, a powder capable of being recompacted and resintered into a functional end-product. The three most commonly used methods of direct-reuse recycling, the coldstream process, bloaching and the Bernard or zinc process, are reviewed,

Jan 1, 1984

By Tatsuo Itou

Both sales volume of Aluminum Can and its recycling rate are remarkably increasing here in Japan. In 1993, recycled can volume was 11.78 billion cans ( 116,258 metric tons ) and its recycling rate 57.8 percent. We, MITSUBISHI MATERIALS CORPORATION. the leading manufacturer of aluminum can in Japan and our affiliated companies are very deeply involved in recycling used beverage cans ( U.B.C ) and recycling them back to can stock. In this paper. I would like to present the following; 1. Recent trend of beverage can consumption in Japan. 2. Trend of aluminum can and its recycling rate in Japan. 3. Future of aluminum can business in Japan.

Jan 1, 1995

By Anjan Kumari, B. K. Soni, Manis Kumar Jha, A. Vidyadhar, Vinod Kumar

"In the present paper, recovery of valuable metals from the poly-cracked ash obtained by pyrolysis of discarded PCBs has been studied following physical beneficiation and a hydrometallurgical process alternate to smelting. The ash is subjected to comminution for the separation of metallic components from non-metallic fractions by scrubbing, tabling and froth flotation which enriched the metal in the concentrate -97% which was further screened to separate high and low metal concentrate. The finer fraction containing -12% metallic value was leached in acidic solution. Almost all (Cu, Pb, Fe, etc) were leached in 4M HN03 at 90°C in 75 min at a pulp density 100 g/L. The characterization of both ash and residues were made by XRD, EPMA, EDS, etc. to validate the experimental results. The metals from the leach liquor could be recovered/separated using solvent extraction techniques which can further be processed to get pure metal salts/ sheets.IntroductionPrinted circuit boards (PCBs) are an essential component of electrical and electronic equipments (EEEs) as it plays an important role during operation of these devices. The world market of PCBs has reached nearly $60 billion in 2012, with 1.7 percent real growth over 2011 [1]. The diverse technology-driven global market is expected to grow at an average annual rate of 5% by 2014 [2]. The waste EEEs are generated due to replacement of obsolete equipments with modem ones and thus their demand is also increasing rapidly [3]. The discarded e-wastes are being piled up as landfills which affect the environment and cause health threats to living organisms, if not disposed of properly. These e-wastes contain metals some of which are precious, few are hazardous and others as valuable."

Jan 1, 2014

By K. Park, J. Sohn

Recovery of industrially useful metals from various secondary sources is an important issue in Korea whose natural resources are limited and needs in the strategic metals are on the rise. In order to meet such needs, researchers at the Korea Institute of Geoscience and Mineral Resources have launched a number of projects to help the nation to recover various metals from secondary sources. In this study, silver is successfully recovered from spent silver-oxide batteries first by distillation to remove mercury. The distilled residue was next subjected to leaching of silver using nitric acid. The study involves finding optimum conditions to leach silver from the distilled residue and subsequently to recover silver from the leach liquor by chemical precipitation. The chemically precipitated products are then subjected to reduction roasting to recover silver metal.

Jan 1, 2002

By A. Rahimi

Refractory castables based on alumina-silicate aggregates are commonly used in casting wheel components and launders. In this research the recycling process of waste magnesia chrome bricks for production of refractory castable lining for launders and casting wheel ladles at Iranian Sarcheshmeh copper complex (I.S.C.C.) is discussed. The smelting plant of ISCC consumes 4,000 tons refractory materials and produces 2,000 tons waste refractories annually. In order to reduce the environmental pollutions and gain the economical advantages, the recycling of waste refractories proved to be a solution [1]. In ISCC, 800 tons alumina or alumina-silicate refractory castables are used for linings of anode furnace ladles and launders annually [2]. In the present work, the spent bricks from reverberatory, converter and anode furnaces were analyzed in term of microstructural changes from hot zone to the cold end to evaluate the changes in texture and chemical composition. Different formulations based on recycled magnesia chrome aggregates and various particle size distribution and cement content were tested. Economic recycled magnesia chrome refractory mixture was prepared after crushing and sizing the non-deteriorated regions of wasted bricks. After evaluation of physical and mechanical properties of samples, one ton of refractory castable was prepared and successfully installed in the casting wheel ladles.

Jan 1, 2007