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By L. M. Lenahan, J. D. Sheets

INTRODUCTION The Raleigh-Durham International Airport (RDU) in North Carolina is the fourth largest airport in the southeast region of the United States. The Raleigh-Durham Airport Authority is currently underway with planning, designing and constructing are placement Passenger Terminal as part of the Major Capital Improvements Program at Raleigh Durham International Airport. The Terminal C Expansion and Renovation Project will replace the existing Terminal C structure with a new processor building and concourse. The project is separated into several contracts. The early stage contracts are constructing a west side storm water management facility, relocating taxiways, installing new drainage systems, installing new aircraft apron pavement, Demolition, the Central Energy Plant and Early Foundations. The later projects are the Terminal Building, Passenger Boarding Bridges, Information Technology Systems and Integration, Furniture, Furnishings & Equipment and Specialty Millwork. The Terminal Building will be constructed in two phases. Phase 1 constructs the north half of the new terminal. Airline operations will move to the new terminal at the completion of this phase. Phase 2 completes construction of the south processor building. The full build out of the project, subject to funding availability, will replace the remainder of the south concourse. The Program’s primary focus is to replace the existing passenger Terminal C with a new terminal that will provide more passenger gates and larger passenger screening, ticketing and baggage handling facilities. The planning for the New Terminal C Program began in 2002 with construction starting in March, 2003. The continuing growth of passenger airline travel in the Raleigh/Durham metropolitan area requires RDU to expand its facilities to keep up with the present and future growth within the Region. In October of 2002, the RDU Airport Authority selected Parsons Transportation Group as the Program Manager/Construction Manager to help assist in the development of the Terminal C expansion program. RDU Airport Authority selected the Seattle Washington Office of URS Corporation as the Engineer of Record for the West Side Storm Water Management Facilities. The Westside Storm Water Management Facilities Project became one of the early critical path activities of the overall RDUAA Terminal C Expansion Program. The Briar Creek Reservoir had been constructed to accommodate storm water runoff to the west of the Airport. The existing 1.5 m culvert that drained runoff from the airport terminal (area) to the reservoir was insufficient in supporting the additional flows

Jan 1, 2005

MR. MARGOLF: Our final speaker this afternoon before we have an opportunity for some questions for the members of the panel, is a gentleman who has spent more than 40 years in the newspaper industry. He started out as an office boy while he was still in high school. He worked his way through college working for a newspaper in Lexington, Kentucky where he graduated from the University. He has a long association with the Albuquerque Tribune but what brings him here today is in his position as editor of The Rocky Mountain News which is certainly one of our largest circulations. I think it is the largest circulation newspaper in the Rocky Mountain states. Ralph Looney, in that

Jan 1, 1982

By Gokhan Inci

Stability problems with dam spillways on existing landslides and appropriate mitigation measures to remedy them are ongoing concerns for geotechnical engineers. The first successful application of drilled piers as stabilizing structures under the spillway was at the Trinity Dam in Sicily, Italy. ?Underpinning? was considered as an alternative to spillway relocation during the Alpaslan 2 embankment dam design in eastern Turkey. Based on the available literature the first application of drilled piers to stabilize a spillway chute in the U.S. was at the Ralston Dam in Colorado. Ralston Dam, which is a 175-foot-high zoned fill dam located 15 miles northwest of downtown Denver, was built in the late 1930s. The concrete spillway for the dam was built on the Pierre Shale Formation in the left abutment. Since reservoir operations began, mass movements have occurred downstream of the chute area. These movements have required periodic spillway maintenance. After the occurrence of recent movements and because of high piezometeric levels, URS was contracted by Denver Water to develop a more permanent solution by the installation and monitoring of additional instrumentation, analysis of slope stabilizing measures, design, repair, and reconstruction of the distressed section of the spillway chute. With state of the art modifications that include: 1) a stabilizing berm with a toe trench that improves the global stability; 2) seepage prevention and control measures that prevent the infiltration of water; and 3) the structural support of the replaced chute section with drilled piers and reinforced concrete the probability of future displacements or other problems have been reduced for the Ralston Dam Spillway.

Jan 1, 2007

By Olli Haavisto, Heikki Häkkänen, Tommi Kauppinen, Navid Khajehzadeh

Raman analysis is a well-established method for finding the abundant minerals in an ore sample. In this study, Raman spectroscopy is tested as a method for rapid and contactless on-line mineral analysis. Rapidness might enable on-site analysis of rock drillcore, which in turn would lead to more cost-efficient solutions in mineral exploration. This paper discusses the use of Raman analysis to identify minerals and to measure their concentration. The sample set under study consists of rock drillcore collected from Agnico-Eagle Kittilä Mine, Finland. Selected parts of the sample set are measured by Raman spectroscopy and the minerals are identified using reference spectra from a public source. Moreover, the direct measurement of concentration of different minerals with the help of Non-negative least squares (NNLS) optimisation algorithm is considered. The optimisation algorithm was constructed to form a linear combination of reference spectra which best represent the measured spectrum, or an average of measured spectra, from an ore sample. The results show that NNLS can identify abundant minerals in a given sample. Also through this method of analysis the results of a traditional point-count method can be expanded: It was observed that, due to grain size, multiple minerals consistently appear in the spectra measured over an area, which means that point-count method is not a proper way to interpret the spectra. This can be seen as a new result, as formerly the discussion has attended to other methods.

Jan 1, 2014

By E R. Ramanaidou

The value of Raman spectroscopy to undertake mineral and chemical characterisation of iron ores was assessed by applying the technique to representative samples of banded iron-formations (BIF) and a BIF-derived, martite-goethite ore. The common iron oxides haematite, magnetite and goethite as well as gangue minerals such as quartz and carbonates all show distinct Raman spectra that enables these phases to be easily detected and mapped in situ for either samples prepared as polished blocks or unprepared material. Raman spectroscopy also offers the potential of in situ chemical characterisation. Shifts in the excitation bands of carbonate detected in BIF were related to the Mg content of Fe-carbonate and confirmed the first world-wide occurrence of a high Mg-bearing siderite (pistomesite) in BIF.The discriminatory power of Raman spectroscopy coupled with the potential of the technique to offer large-scale (volumetric) characterisation of iron ore will be of great value not only to the existing BID and CID ore types, but also to the newly emerging magnetite iron deposits (MID).

Jul 11, 2011

By Gretel Parker

In situ Raman spectroscopic investigations of copper iron sulfides in leach solutions have been undertaken. Coupling potentiodynamic techniques to Raman spectroscopy produces a powerful tool for studying mineral surface response to changing conditions, while ESEM and high-vacuum techniques provide complementary ex-situ information on surface structure and composition. Oxidative acid leaching of chalcopyrite at ambient temperature yielded a product with S-S bonds that were shifted from those seen with covellite, with little evidence of elemental sulfur formation. Leaching of chalcopyrite led to non-homogeneous product distribution. Raman spectroscopy was able to identify the products formed on the mineral surfacein situ while leaching was occurring. Raman mapping and imaging demonstrated a surface distribution of the products which can be related to composition and structure changes of the mineral surface. The surface formed on chalcopyrite after anodic oxidation at 0.570 V vs. Ag/AgCl in 0.1 mol dm-3 HCl undergoes laser-induced transformation.

Jan 1, 2003

By Daojin Cao

Aiming at many controversial reports on Raman spectral pattern of octamolybdate ion in aqueous solution appearing in the literature, a new method for the establishment of corresponding relation between Raman spectral pattern and chemical components of aqueous molybdate solution was put forward using spectroscopy measure and component analyses of saturated solution of ammonium octamolybdate hydrate known structure. It was found that the main characteristic of Raman spectral pattern of the saturated solution was described as the same ?double-peaks, hereinto a weak peak at the boundary? as some literature, but chemical components of the saturated solution were affirmed to be octamolybdate ion (Mo8O264-) and double protonated heptamolybdate ion (H2Mo7O244-), which were in equilibrium in aqueous solution each other. The authors propose that the pattern of the saturated solution can be regarded as the standard pattern of primiparous octamolybdate ion during acidified molybdate solution. It is satisfying that the standard pattern is applied to the identification of primiparous octamolybdate ion during acidified molybdate solution.

Jan 1, 2006

By Gregory A. Hope, Kym Watling, Matthew I. Jeffrey, Ronald Woods

Surface enhanced Raman Spectroscopy carried out in real time has been applied to identify surface species formed during gold leaching in chloride and thiosulfate media. Chloride ion is adsorbed prior to the gold dissolution potential, but its coverage is significantly diminished at the beginning of leaching. A gold chloride band is again observed when dissolution is rapid, together with bands characteristic of AuC14- ions in solution. With thiosulfate, a thin gold sulfide layer is formed slowly in the potential region where leaching occurs. At higher potentials, thiosulfate is oxidized to sulfur and sulfate, both products being identified by Raman spectroscopy.

Jan 1, 2005

By B. C. Cornilsen, X. Shan, D. H. Carlson, J. H. Johnson

Airborne respirable Diesel Particulate (DP) presents an additional health hazard in that it has been shown to be mutagenic. This problem is of increasing concern as more coal mines introduce diesel vehicles. If the DP present in coal mine air is to be controlled it must first be measured. This paper describes development of the laser Raman spectroscopic measurement of the amount of DP in DP/coal mixtures collected on filters in the laboratory and in coal mines. The Raman technique provides a chemical measure of the carbonaceous material in each component, and is not dependent upon particle size. When this work was begun there were no known analytical methods for this measurement. Side-by-side in-mine comparisons of the results obtained from Raman, neutron activation analysis, and size selective analyses (MOUDI and personal samplers) are presented. The neutron activation and size selective analyses were obtained by the USBM Twin Cities Research Center and University of Minnesota. Good agreement has been found among these three methods.

Jan 1, 1991

By Merete Tangstad, Gabriella Tranell, Jeff Kline

"Raman spectroscopy as an instrumental technique for the determination of silicate structure is widely accepted. This method was utilized for analysis of structural modifications associated with the addition of network modifying species. Silicate melts are described by the extent of oxygen bridging. Therefore, understanding the effect different oxides have on modifying the silicate structure will provide valuable information regarding the removal of boron from silicon in slag refining processes. Samples ranging from CaO/SiO2 = 0.56-1.2 were evaluated with and without varying concentrations of B2O3. The addition of CaO to SiO2 revealed Q2 species constitute 45% of the Qn species and addition of B2O3 to the high concentration CaO system results in an increase in Q2 and a decrease in Q0 . The disappearance of the Raman band associated to the three-member ring in the low concentrated CaO system indicates boron addition and destruction of the ring.IntroductionExtensive studies on the structure of silicate systems have been performed using Raman spectroscopy with consensus on the Raman shift associated with different bridging oxygen units [1]. Most of these studies are motivated by the lack of a fundamental understanding of the processes involved in petrology. Due to this, an opportunity exists to build on the knowledge obtained from these studies and conduct more research on slag structures relevant to industrial applications, as these systems are often compositionally similar to magmatic melts. Raman spectroscopic studies of industrial slags will provide insight into the possible structural modifications necessary to enhance removal of impurity species from the metal phase to the slag phase."

Jan 1, 2012

By A. G. Jackson, Rand R. Biggers, John D. Busbee, Iman Maartense, David P. Lubbers, David C. Liptak

"This paper describes the application of Raman Spectroscopy for characterizing superconducting YBCO thin film parameters. Attenuation of the substrate Raman spectrum as a function of material deposited is established. Also a correlation between film quality and Raman spectrum is explored. The identification and discrimination of superconducting and non-superconducting phases of YBCO is presented. The critical temperature (Tc) of a film as a function of its oxygen content is also established using Raman peak ratios. These results provide significant implications toward the use of Raman Spectroscopy for in situ monitoring and control of the PLD process. Film quality can be controlled via optimization of film oxygen content and reduction of improper YBCO phases. Film thickness can be controlled by monitoring the response of the substrate material. Also the PLD process can be studied and modeled using this powerful observation tool.IntroductionSuperconductors are materials that possess unique characteristics when cooled to sufficiently low temperatures. Below a material's critical temperature (Tc) it exhibits zero resistance to current flow. One such material, yttrium barium copper oxide (YBCO) has a critical temperature of approximately 92° K. Due to its high critical temperature YBCO is being aggressively researched for many possible applications, because of high current carrying capability and strong pinning of flux lines.YBCO in the 123 form is a ceramic material that was discovered in February, 1987. Its unit cell structure is shown in Figure 1 [ 1,2]."

Jan 1, 1997

By F. M. Doyle, Jun Li, Milton E. Wadsworth, E. Peters

The Raman spectroscopic technique was used to study electrochernically oxidized pyrite in-situ. It was found that Raman-active sulfur oxidation products could be detected after a proper potential was applied to the pyrite electrode for a threshold period of time. There existed a minimum potential below which sulfur could not be observed. However, when the applied potential exceeded a certain limit, the intensity of the sulfur spectra decreased. The minimum potential at which sulfur could be observed changed with solution pH. For both acid (pH 2.7) and weak alkaline (pH 9.2) solutions, the minimum potential was 0.8 V/SCE, whereas for neutral (pH 6.5) solutions the value was 0.4 V/SCE. In strong alkaline solutions (pH 12.5) surface sulfur oxidation products could not be detected at any potential.

Jan 1, 1993

By Jun Li

Several metal sulfides were examined in-situ by Raman spectroscopy before and after anodic oxidation. Results obtained for chalcocite, chalcopyrite, covellite, galena, pyrrhotite and pyrite electrodes are presented. Under appropriate conditions, sulfur was detected after a potential was applied to the mineral electrodes for a threshold period of time. For all the minerals, application of a negative potential on the oxidized mineral reduced the surface product and the sulfur peaks disappeared from the observed spectra. For those minerals containing sulfur as S< in the crystal lattice, polysulfides were identified as oxidation intennediates.

Jan 1, 1993

By Vadym Drozd, Yongzhou Sun, Shah Najiba, Jiuhua Chen, Andriy Durygin

"Phase transitions of the potential hydrogen storage compound, ammonia borane (NH3.BH3), was investigated using Raman spectroscopy and a diamond anvil cell at high pressures up to 9.5 GPa and low temperatures down to 90K. At room temperature, ammonia borane has three phase transitions in this pressure range. Upon cooling, four new phases were discovered through changes in characteristic Raman spectra. This result provides information about the stability of new bonding characteristics of this potential hydrogen storage material at low temperature and high pressure region.IntroductionDevelopment of hydrogen technology requires the safe, efficient and environmental friendly materials for hydrogen storage and hydrides have attracted much attention as hydrogen storage media. Among chemical hydrides, ammonia borane (BH3NH3) stands out due to its high gravimetric and volumetric hydrogen density ' "". Despite high hydrogen content, this compound is very stable. It releases hydrogen in several steps by thermal decomposition in the temperature range of 100°C to 500°C. Direct thermal decomposition also causes toxic borazine emission. Recent research interests on ammonia borane include destabilizing this compound to lower the dehydrogenation temperature with an enhanced hydrogen release rate using different techniques, e.g. the nanoscaffolds'', ionic liquids"" and acid'"" or transition metal catalysts' ""'. As a molecule of ammonia borane consists of protonic (NH) and hydritic (BH) hydrogens bonded by the polarized dative bond, thermal or catalyzed decomposition requires breaking of N-H and B-H bonding. Still now, the detailed information about the bonding characteristics of ammonia borane is not sufficient to understand details about its phases and structures. The development of methods to enhance hydrogen discharge rate from ammonia borane requires a detailed study about the structural and dynamical properties that control the stability and the intermolecular interactions of this material. This study is motivated to investigate the stability of the existing phases and also to explore the existence of any new phases at different temperatures and pressures which may have enhanced hydrogen release and uptake properties."

Jan 1, 2012

By Brian Metcalfe, Kord Wissmann, Gianni Martinez

The Middle East consists of vast deserts that reach temperatures up to 50 degrees Celsius, with some areas characterized by endless sand dunes. When the project team selected the location for a large new transportation project, little did they know that the site would be characterized by soft, nearly normally consolidated silt and clay extending below a thin sand crust. Searching for solutions, the design team elected to reinforce the subsurface with Rammed Aggregate Pier® (RAP) ground improvement elements and desired verification that the novel method would stand the test of prolonged static loads. Because the concrete pavements would serve to spread the load, a “zone load test” was performed, consisting of applying a uniform bearing pressure of 150 kPa over a 7.5m square concrete footing. Unlike individual pier load tests, the zone test allowed the project engineers the opportunity to confirm design parameter values under large-loading area conditions, a situation not often available to most designers. This paper presents the results of the zone load test whose results may be interpreted to better understand design parameter values. This paper is of particular significance because it adds a value contribution to the relatively few numbers of “group load tests” available in the literature for ground improvement applications.

May 1, 2022

By Brian Metcalfe, Kord Wissmann, Gianni Martinez

The Middle East consists of vast deserts that reach temperatures up to 50°C (122°F), with some areas characterized by endless sand dunes. When project team members selected the location for a large new transportation project, little did they know that the site would be characterized by soft, nearly normally consolidated silt and clay extending below a thin sand crust. Searching for solutions, the design team elected to reinforce the sub­surface with rammed aggregate pier ground improvement elements and wanted verification that the method would stand the test of prolonged static loads. Because the concrete pave­ments would serve to spread the load, a "zone load test" was performed, consisting of applying a uniform bearing pressure of 150 kPa (22 Psi) over a 7.5 m (25 ft) square concrete footing. Unlike individual pier load tests, the zone test allowed the project engineers the opportunity to confirm design parameter values under large­loading area conditions, a situation not often available to most designers. This paper presents the results of the zone load test, which may be interpreted to better understand design parameter values, and is of particular significance because it adds a valuable contribution to the relatively few numbers of "group load tests" available in the literature for ground im­provement applications.

Feb 1, 2024

By John G. DiGenova

The Allwell Center Ice Arena at Plymouth State University, Plymouth, New Hampshire is located in the flood plain of the Pemigewasset River. To maintain the arena near the level of the surrounding area, foundation design required use of uplift elements to resist hydrostatic loads caused by frequent flood conditions. Soils beneath the arena consisted of very loose to medium dense alluvial deposits overlying thick glaciolacustrine deposits. Bedrock was encountered at depths of 115 feet (35 m) or more. A mat foundation with a sealed building system was developed for the arena to guard against flood events. Several alternatives were investigated to provide uplift capacity for the mat foundation, including the Rammed Aggregate Pier® (RAP) system, driven precast-prestressed concrete piles, driven H-piles, and deep drilled soil/rock anchors. Evaluations indicated that the most cost effective uplift solution was a tension RAP system that developed uplift resistance in the shallow alluvial deposits. A total of 344 55-kip (245-kN) capacity RAP elements were required for the project. The RAPs were designed to resist tensile loads using threaded steel bars. Dual corrosion resistance was provided to the uplift elements by including sacrificial steel and galvanizing the oversized bars and connection plates. A pre-construction test program was conducted on RAP elements drilled to a depth of approximately 25 feet (7.6 m) and installed using various shaft construction procedures and materials. Ten test piers were constructed and six were tested to verify that the piers could resist 200 percent of the design load with measured deflections of less than 1 inch (25 mm). The RAP system also provided improved bearing conditions for the perimeter wall and mat foundations by densifying and stiffening the upper alluvial soils.

Jan 1, 2011

By V. O. Tenorio, D. Tolmachoff, K. Willa Brown, K. J. Kingsbury, J. B. Nickels, G. J. Nail

A major design feature to consider from the initial pioneering works until reaching full mine production of icy regolith at the South Pole of Moon will be the ramp. This will allow the access of equipment and personnel in and out of the excavation area. Although most of the requirements considered when designing a ramp on the Earth are similar, the fact of working in low gravity, with zero atmosphere, the potential exposure to high radiation, extreme temperature levels and drastic changes of illumination, from intense light to total darkness, are new factors to be included. Transversal sections are obtained according to the progression sequence of the production levels, with changes in length, gradient, friction factor of the terrain and curvature when required by the location characteristics and the specification of the equipment utilized. A MATLAB script was developed to calculate all the variables, in order to obtain 3D generated surfaces from the range of possible profiles.

Mar 2, 2022

By Robert L. Russell

The Bunker Hill Mine, located in the Coeur d&apos;Alene Mining District at Kellogg, Idaho, has been a major producer of lead-silver-zinc ores since its discovery in 1887. The mine has produced over 29 million tons of ore from some 20 to 25 veins and ore zones, and now covers an area approximately one mile in length and one-half mile in width. The active section of the mine extends from 2500 ft above sea level to 1600 ft below sea level. Production is presently at the rate of about 1700 tons of ore per day. A two-mile adit, the Kellogg Tunnel, at the 2500 elevation, provides access to the main shaft area. Ore is hoisted to the adit level through a 5000-ft, 500-inclined shaft, extending to the lowermost haulage level 1200 ft below sea level. Primary shaft service for men and materials is supplied by three major internal, inclined shafts equipped with double-drum hoists. Present production requires ten levels to serve for mainline track haulage. These range up to 5000 ft in length and are either 200 or 400 vertical feet apart. Also, many intermediate levels exist throughout the mine. The conventional and autoloader mechanized square-set and cut-and-fill mining methods used throughout the mine have been the subject of a recent paper(l). One-third of current production is from vein-type ore bodies which are long distances from main shaft areas. Such veins generally dip about 450, have relatively narrow widths of from 3 to 20 ft, and usually contain less than 500,000 tons of ore. For many years, ore bodies thus situated have been developed by means of a separate inclined, timbered service shaft-raise connecting two or more main haulage levels. These commonly range from 400 to 1000 ft in vertical extent and are equipped with 25 to 50 hp electric, single-drum hoists. Intermediate levels are driven as conventional track drifts at 100-ft vertical intervals between the haulage levels. Ore and waste from the intermediate levels are trammed to orepasses for delivery to the lowermost haulage level servicing an ore body. The final result may be visualized as a number of small mines within a large mine. The problems of high development costs and high total development time, and the large amount and high cost of providing materials handl ing and ore haulage service while producing from this isolated type of stope block, made it desirable to consider totally new approaches in developing and mining a number of similar areas.

Jan 1, 1971

By Robert L. Russell, Henry W. Zimmerman

The Bunker Hill mine in the Coeur d&apos;Alene mining district at Kellogg, Idaho, has been a major producer of Pb-Ag-Zn ores since its discovery in 1887. The mine has produced over 29 million tons of ore from some 20 to 25 veins and ore zones and now covers an area approximately 1 mi long by 0.5 mi wide. The active section of the mine extends from 2500 ft above sea level to 1600 ft below sea level. Ore production is presently at the rate of about 1700 tpd. A 2-mi adit, the Kellogg tunnel, at the 2500 elevation provides access to the main shaft area. Ore is hoisted to the adit level through a 5000-ft. 50º-inclined shaft extending to the lowermost haulage level 1200 ft below sea level. Primary shaft service for men and materials is supplied by three major internal inclined shafts equipped with double-drum hoists. Present production requires ten levels to serve for main line track haulage. These range up to 5000 ft in length and are either 200 or 400 vertical ft apart. Also, many intermediate levels exist throughout the mine.

Jan 1, 1971